Substances are composed of atoms and elements Substance is matter that has the same fixed composition, can’t be broken down by physical processes Physical processes: boiling, changing pressure, cooling, or sorting Chemical process: change the original substance into new substance(burning, chemical reactions, reaction to light) REVIEW :Atom have specific protons for each element Two or more elements chemically combined in specific combinations and composition H2O, NaCl, H2SO4, Water, salt, sulfuric acid Mixtures are combinations of substances that are not bonded together and can be separated by physical processes (salt water, granite, salt and pepper) Heterogeneous Mixtures: mixture where substances are not mixed evenly ◦ Areas have different compositions ◦ Seeds in watermelon, minerals in granite, cereal in milk Homogeneous mixtures: contains 2 or more substances that are evenly mixed but are not chemically bonded together Shampoo, sugar water, Kool-Aid are examples Solutions is another name for homogeneous mixtures Solutions form when a solute (salt) dissolves in a solvent (water) Forming solids from a solution ◦ Crystallization occurs when cooling or evaporation takes place and leaves a solid ◦ Precipitates forms from a chemical reaction that produces a substance that isn’t soluable in solution and drops out Liquid solid solutions: solid (solute) dissolves in liquid(solvent) salt in water Liquid gas solutions: gas is dissolved in a liquid (gas dissolved in water: carbonated water) Liquid-liquid solutions: both solute and solvent are liquids ( vinegar and water) Smaller amount of one gas (solute) is dissolved in a larger amount of gas (solvent) Both solvent and solute are gases ◦ Example: Our atmosphere contains 78% Nitrogen and would be the solvent and other gases in atmosphere would be the solute In solid solutions, the solvent is a solid Solute can be a gas, liquid, or solid Solid-solid solution: alloys are mixture of 2 or more metals melted together and mixed (brass, steel) Water the Universal Solvent ◦Aqueous refers to a solution of where water is the solvent ◦Water can dissolve may different solutes Molecular Compounds: ◦ Water is formed by sharing electrons between 2 atoms of H and 1 atom of Hydrogen ◦ Water molecules when combined have areas of electrical charges that attract opposite charges, thus are polar charged When compounds are formed by gaining or losing electrons to bond elements together When atoms gain and lose electrons the number of electrons change and give an overall charge on the atoms Opposite charge atoms attract and hold each other together Because of the polar charge of water areas of water molecules attract the charged particles of ionic compounds and break them up (Page 627 figure 8) Water molecules moves in between sugar molecules and separate them (thus dissolving) What will dissolve? Like dissolves like ◦ Polar solvents dissolve polar solutes (salt and water) ◦ Nonpolar solvents dissolves non polar solutes If you have a polar molecule and nonpolar molecule (unlike polar molecules) they will not dissolve and will not form a solution Oil is a nonpolar molecule that will not mix with polar water, therefore these two substances will no form a solution Solubility is a measurement of how much a solute will dissolve in a given amount of solvent It is described as how much solvent can be dissolved in 100 ml of solvent at a certain temperature At 25@ C grams dissolved in 100 ml wataer Potassium chromate Barium sulfide 63 g .00025 g Liquid solid solutions: temperature affects how much solutes can be dissolved Usually an increase in temperature allows more solute to be dissolved ◦ Notice on chart that NaCl and CaCO3 become less soluble in higher temperatures Liquid-gas solutions: increase in temperature decrease the solubility of a gas dissolved in it Carbon dioxide is dissolved under pressure in water in pop cans ◦ Opening a warm can of pop vrs a cold can, the gas is released much faster and leaves the solution under warmer conditions faster A saturated solutions can hold no more solute in solution at a given temperature or pressure It will fall to bottom of solvent A hot solution can hold more solute than at lower temperatures and when cooling the hot saturated solution a supersaturated solution may form Rate of dissolving is sped up by: ◦ Increasing temperature ◦ Crushing the solute ◦ Stirring the solution Concentration of a solution tells you how much solute is present compared to the amount of solvent ◦ It is recorded by using percent of solute is compared to solvent ◦ Juices concentration are written by 15%, 20% etc When a solute is added to water (salt water) and you want to freeze it , a lower temperature is needed (to freeze salt water could be 31℃) If you want to boil salt water a greater temperature is needed to boil it Acids: are substances that release positive H+ ions in water called a hydronium ion When an acid mixes with water, acid dissolves and releases H+ ion Sour taste Conduct electricity Corrosive (break down substances) React strongly with metals releasing H gas Vinegar (acetic acid), citric acid, ascorbic acid we are familiar with H2SO4 (sulfuric acid) ◦ Production of fertilizers, batteries, paint HCl (hydrochloric acid) ◦ Muratic acid used in pickling that removes impurities from the surfaces of metals, cleans motar, bricks HNO3 (nitric acid) use in fertilizer, dyes, and plastic Bases are substances that accept H+ ions and give off to a solution of water with OH- ions Feels soapy, slippery Taste bitter Corrosives Conduct electricity Cleaning products Your blood is basic in solution NaOH (sodium Hydroxide) is known as lye and is used to make soap, clean ovens, unclog drains CaOH (calcium hydroxide) often called lime is put on athletic fields to mark lines pH is the measure of how acidic or basic a solution is Ranges from 0-14 where neutral pH is at 7 Below 7 covers the range of acid solutions (closer to 0 is more acidic0 Above 7 covers range of basic solutions (closer to 14 is more basic) Some acids are helpful (HCl in stomach to digest food however too concentrated HCl will eat away on tissue If more H+ (hydronium ions) are present the higher the acidic content (lower pH) Bases with large amounts of OH- ions (hydroxide) have greater concentrations and are more basic (higher pH) Each number on pH is 10 fold greater or smaller than the number before it: Comparing ph3 to ph1 is a difference of 2 2 102 means that there is a difference of 100 times more acidic Indicators are compounds that react with acidic and basic solutions and produce certain colors to indicate their acidity or basicity tendencies Neutralization is the reaction of an acid with a base When an acid and a base are combined, they will neutralization each other and the resulting pH will be 7 NaOH + HCl Base acid NaCl + H2O salt water