The Mole It's not a spy, a machine for digging tunnels, a burrowing animal, or a spot of skin pigmentation - it's - a unit of measurement containing about 6.02 x 23 10 particles. 1 dozen atoms is 12 atoms! 1 pair of atoms is 2 atoms! 1 gross of atoms is 144 atoms! 1 mole of atoms is 602,214,199,000,000,000,000,000 atoms! Avogadro’s Number (NA) 6.022 x 1023 particles / mole Amadeo Avogadro 1776-1856 How BIG is 6.022 x 1023 ? Could Bill Gates ever become a “moleonaire”? How much interest would you get per second if 1 mole of $ was invested at an annual interest rate of 1% • 6.02 x 1023$ x (1/100) = 6.02 x 1021$ (1 year) • 6.02 x 1021$ / 365 days = 1.65 x 1019$ (1 day) • 1.65 x 1019$ / 24 hours = 6.87 x 1017$ (1 hour) • 6.87 x 1017$ / 60 min = 1.15 x 1016$ (1 min) • 1.15 x 1016$ / 60 sec = 1.90 x 1014$ (1 sec) 190 TRILLIONS per SECOND ! Bill Gates only currently has 70 billion $ (70 x 109 $) 1 second of interest (at 1%) on a mole of $ is equivalent to 3000 times Bill’s Gates total wealth! To become a moleonaire Bill Gates would have to earn 33,000 trillion $ a day for the next 50 years! Not likely! Too bad Bill! Soooo sad… The Pacific Ocean How much water is there in the Pacific Ocean? • Approximately 6 x 1020 L • which is equivalent to 6 x 1023 mL ! • The Pacific Ocean contains a mole of mL of water A Galactic Analogy • A mole of periods (.) lined up side by side would equal the radius of our galaxy (30,000 light years!) A mole is big… real big. But is it really that important? Yes. Why? Importance of the Mole • Scientists use the mole to help count atoms, molecules, and compounds – Example: • 0.5 Moles of CO2 = 3.01x1023 Molecules of CO2 • 0.25 Moles of Carbon = 1.5x1023 atoms of Carbon • How many molecules are there in 2.0 moles of O2? 6.02 ´10 23 molecules 2.0moles ´ = 1.2 ´10 24 molecules 1.0mole • How many ATOMS are there in 2.0 moles of O2? – 2.4 x 1024 Atoms of Oxygen What is Avogadro’s Number? If I had a half-dozen eggs how many would I have? If I had a half-mole of eggs how many would I have? If I had a half-mole of copper atoms how many would I have? Importance of the Mole • Practice – How many molecules are in 5.0 moles of NO2? – How many atoms are there in 0.25 moles of Sulfur? – How many molecules are there in 7.6 moles of C2O4? – How many ATOMS are there in 7.6 moles of C2O4? Importance of the Mole • Moles tell us how many particles there are of something. – Example: • 1.0 moles of Sodium atoms = 6.02x1023 atoms of Sodium • A mole is a big number… what do you suppose the mass of one mole of sodium atoms is? – 23.0 grams! • Golly-gee-whilickers! How did you find that out? • Hmmm… !!!THE PERIODIC TABLE!!! Moles of atoms • Off the Periodic Table: – 1 mole C = 12.011 g C – 1 mole B = 10.81 g B – 1 mole Cu = 63.55 g Cu – 1 mole element = (atomic mass) g element • We can then say that …. Moles=grams / molar mass • This is useful information! Watch! Aluminum Can Lab • How many moles of Aluminum (Al) are in an aluminum can? • How many atoms of Aluminum (Al) are in an aluminum can? Importance of the Mole • Scientists can use the mole to determine how many particles are in a sample. – Example: • If you have 5 grams of water, how many water molecules do you have? – 1st we need to determine the Molar Mass for Water How do I find Molar Mass you Ask? • Determine the formula for the molecule. – EX. Water is Dihydrogen Monoxide • H 2O • Find the molar mass for each atom in the molecule. – H = 1.008 g/mole – O = 15.994 g/mole But Wait!! • There are two hydrogen atoms in a molecule of water, so… – 2H = (1.008 g/mole) X 2 = 2.016 g/mole H • Now that I know the molar mass for the atoms in water, I can calculate the formula mass for water: 2.016 g/mole H + 15.994 g/mole O 18.01 g/mole H2O In Summary: Mole Formulas (You need to know these!) • Moles * Molar mass = Mass of Sample – (I write it as Moles*MU = MG) – Moles is how many moles you have – Unit Mass is the mass of whatever unit you are dealing with (atoms, molecules, etc) – Mass of Sample is the mass of your sample • Moles =NP/NA – NP = Number of particles (how many atoms, molecules, etc. your sample contains) – NA=Avogadro’s Number