What Is a Solution? • Solutions can be made from any combinations of solids, liquids, and gases. Particles in a Solution • When a solution forms, particles of the solute leave each other and become surrounded by particles of the solvent. Colloids and Suspensions • Colloids and suspensions are mixtures that have properties different from those of solutions. Effects of Solutes on Solvents • At 0ºC, pure water freezes, but water mixed with a solute does not. Solutes lower the freezing point of a solvent. Solid (frozen) water Liquid water solution Assessment 1. What is a solution? 2. Suppose you mix food coloring in water to make it blue. Have you made a solution or a suspension? Explain. 3. How are solutions different from colloids and suspensions? Assessment 1. What happens to the solute particles when a solution forms? 2. What affects do solutes have on a solvent’s freezing and boiling points? 3. Why is the temperature needed to freeze ocean water lower than the temperature needed to freeze the surface of a freshwater lake? 4. Why does salt sprinkled on icy roads cause the ice to melt? CONCENTRATION Definition: The amount of a substance per defined space. Concentration usually is expressed in terms of mass per unit volume. Calculating a Concentration • To calculate the concentration of a solution, compare the amount of solute to the amount of solution and multiply by 100 percent. • For example, if a solution contains 10 grams of solute dissolved in 100 grams of solution, then its concentration can be reported as 10 percent. Try This • A solution contains 12 grams of solute dissolved in 36 grams of solution. What is the concentration of the solution? Solubility • Solubility is a measure of how much solute can dissolve in a solvent at a given temperature. Key Terms: Examples: unsaturated solution An unsaturated solution can continue to dissolve more solute. supersaturated solution A supersaturated solution has more dissolved solute than is predicted by its solubility at the given temperature. dilute solution A dilute solution is a mixture that has only a little solute dissolved in a certain amount of solvent. concentrated solution A concentrated solution is one that has a lot of solute dissolved in the same amount of solvent. Solubility is a measure of how much solute can dissolve in a solvent at a given temperature. A saturated solution contains so much solute that no more dissolves. solubility saturated solution Assessment 1. What is concentration? 2. What quantities are compared when the concentration of a solution is measured? 3. Solution A contains 50 g of sugar. Solution B contains 100g of sugar. Can you tell which solution has a higher sugar concentration? Explain. Assessment 1. What is solubility? 2. How can solubility help identify a substance? 3. What are the three factors that affect solubility? Acid: A substance that releases H+ ions in an aqueous solution “aqueous” means: water Characteristics of Acids: Acids have a sour taste Acids react with metals Acids contain Hydrogen Many are poisonous and corrosive to skin H Strong Acids (break down completely to give off many H+ ions) Weak Acids (only partially breaks down, gives less H+) Common Acids: Strong Acids The Formula Sulphuric acid Hydrochloric acid Hybrobromic acid Hydroiodic acid Nitric acid Perchloric acid H2SO4 HCl HBr HI HNO3 HClO4 All others considered Weak (examples) Weak Acid The Formula Acetic acid (vinegar) Carbonic acid HC2H3O2 HCO3 Base: A substance that releases OH- ions in an aqueous solution Characteristics of Bases: Bases usually taste bitter Bases feel slippery Bases contain hydroxide ions STRONG bases are also poisonous and corrosive to skin OH Common Bases: Strong Bases The Formulae Lithium hydroxide Sodium hydroxide Potassium hydroxide Rubidium hydroxide Caesium hydroxide Barium hydroxide Calcium hydroxide Strontium hydroxide LiOH NaOH KOH RbOH CsOH Ba(OH)2 Ca(OH)2 Sr(OH)2 (Hydroxides of Group 1 and Group 2 Metals are STRONG) All others are WEAK Some bases (VERY FEW) don’t have OHMost commonly: ammonia NH3 Section 3 Assessment 1. What are four properties of acids? Of bases? 2. How can you use litmus paper to distinguish and acid from a base? 3. How might you tell if a food contains an acid as one of its ingredients? Section 3 Assessment 1. What are three practical uses of an acid? Of a base? 2. Where are you most likely to find acids and bases in your own home? Explain. 3. Why is it wise to wear gloves when spreading fertilizer in a garden? Salts Reactions between acids and bases When and acid and a base react with each other, the characteristic properties of both are destroyed. This is called neutralization. Reactions between acids and bases General formula for acid base reaction: Acid + Base → H2O + Salt “Salt” means any ionic compound formed from an acid/base reaction NOT JUST NaCl !! Neutralization HCl + NaOH → H2O + NaCl acid base water salt Neutralization Another Example HNO3 + KOH → H2O + KNO3 H NO3 acid K OH base water salt pH pH stands for “potential hydrogen” and is a measure of how many H+ ions there are in solution. The MORE H+ there are, the LOWER the pH will be. Indicators An indicator is a compound that will change color in the presence of an acid or base Red Litmus-Turns blue in base Blue Litmus-Turns red in acid Universal indicator (pH paper) Used for the full pH range Phenolphthalein-Turns pink in base pH Scale Shows the range of H+ concentrations High H+ concentration Low H+ concentration Section 4 Assessment 1. What does a substance’s pH tell you? 2. If a solution has a pH of 6, would the solution contain more or fewer hydrogen ions (H+) than an equal volume of solution with a pH of 3? Digestion and pH