Resonance Structures Which one of these three structures is the correct one? • As it turns out, laboratory measurements show that all three bonds are equal. • When more than one Lewis structure can be drawn, the molecule or ion is said to have resonance. Resonance Structure • Resonance structures are simply alternate Lewis structures for a given ion or molecule. • The structures are changing so quickly that all we see is an average blur instead of being able to detect individual structures. Resonance Structure • We draw three Lewis structures because a single structure is insufficient to describe the real structure of the nitrate ion. Resonance Structure • ozone as a Lewis structure would be: • We draw two Lewis structures because a single structure is insufficient to describe the real structure of ozone. Bond Strength – Bond Length Bond # of electrons Bond Order Bond Strength Bond Length Single 2 1 Weakest Longest Double 4 2 Triple 6 3 Strongest Shortest Thus, triple bonds are stronger and shorter than double and single bonds. Bond Strength – Bond Length • Laboratory analysis show all three of the bonds in the nitrate ion to be the same strength and the same length. • They are longer and stronger than single bonds but shorter and weaker than double bonds. • What is the bond length between the N-O? Bond Strength – Bond Length • The ion behaves as if it were a blend of the three resonance structures. • The actual bond length for each N-O bond is 1 and 1/3, because the double bond is shared equally between all the N-O bonds. Polarity of Molecules • A polar bond has one end with a positive charge and the other with a negative chare. – The charge difference is due to the difference in electronegativity of the two bonded atoms. • The direction of greatest electronegativity is shown with an arrow called a dipole. C---F and C---H Polarity of Molecules • Non-polar molecules – the dipoles are all equal and opposite. They cancel out and the molecule is non-polar. Cl---Be---Cl • Polar molecules – the dipoles are not equal and opposite so the molecule has a net dipole and is polar. H---C---N Net Dipole Examples Draw all resonance structures, give the bond order and determine the polarity of each ion. 1. NO22. ClO43. SO3 4. C2H4