Identifying World Customs Organization (WCO) Harmonized Codes Trinidad and Tobago October 2011 Objectives of a correct Harmonized System (HS) classification • Uniform information. • Same tariff treatment for all importers of the same substance. • Information gathering is less complex. Licensing System Complete Statistics Correct data reporting pursuant to Art. 7 of the Montreal Protocol HARMONIZED SYSTEM (HS) The Harmonized Commodity Description and Coding System, generally referred to as "Harmonized System" or simply "HS“. Is a multipurpose international product nomenclature developed under the auspices of the World Customs Organization (WCO), an independent intergovernmental body. The tariff schedule containing the headings, subheadings and the corresponding number codes, the notes to the Sections, of the Chapters and the Subheadings, as well as the General Rules for the interpretation of the HS. HARMONIZED SYSTEM (HS) THE HS CONTAINS o 21 SECTIONS o 96 CHAPTERS o 1.200 HEADINGS o 5,000 six figure groups called Subheadings 124 CONTRACTING PARTIES AND ONE CUSTOMS UNION. 202 COUNTRIES USE THEIR TARIFF SCHEDULE. HARMONIZED SYSTEM (HS) GOVERNMENTS USE HS FOR: • Exchange of trade data. • Establish duties and other taxes. • Control of regulated substances. • Development of Rules of Origin. • Preparation of statistics. • Price and quota controls. • Economic research and analysis. HARMONIZED SYSTEM (HS) 32 08. 10 Chapter All countries must classify the same substance under Heading Subheading the same Subheading HARMONIZED SYSTEM (HS) The Harmonized System is based on a fundamental principle that goods are classified by what they are. In some cases, end-use is considered when a product is specifically constructed for it. General Rule Nº1 for the interpretation of the Harmonized System: The titles of Sections, Chapters and sub-Chapters are provided for ease of reference only; for legal purposes, classification shall be determined according to the terms of the headings and any relative Section or Chapters Notes. Classification analysis of unmixed substances CHAPTER 29: ORGANIC CHEMICALS Definition of unmixed substances Legal Note N.º1: Classification analysis of unmixed substances Note 1 of Chapter 29, continuation Except where the context otherwise requires, the headings of this Chapter apply only to: (a) Separate chemically defined organic compounds, whether or not containing impurities; (b) Mixtures of two or more isomers of the same organic compound (whether or not containing impurities), except mixtures of acyclic hydrocarbon isomers (other than stereoisomers), whether or not saturated (chapter 27) (c) The products of headings 2936 to 2939 or the sugar ethers, sugar acetals and sugar esters, and their salts, of heading 2940, or the products of heading 2941, whether or not chemically defined; (d) Products mentioned in (a), (b) or (c) above dissolved in water; (e) Products mentioned in (a), (b) or (c) above dissolved in other solvents provided that the solution constitutes a normal and necessary method of putting up these products adopted solely for reasons of safety or for transport and that the solvent does not render the product particularly suitable for specific use rather than for general use; (f) The products mentioned in (a), (b), (c), (d) or (e) above with an added stabilizer (including an anticaking agent) necessary for their preservation or transport; (g) The products mentioned in (a), (b), (c), (d), (e) or (f) above with an added antidusting agent or a coloring or odoriferous substance added to facilitate their identification or for safety reasons, provided that the additions do not render the product particularly suitable for specific use rather than for general use; Classification analysis of unmixed substances Note 1 of Chapter 29, continuation Except where the context otherwise requires, the headings of this Chapter apply only to: (a) Separate chemically defined organic compounds, whether or not containing impurities; (b) Mixtures of two or more isomers of the same organic compound (whether or not containing impurities), except mixtures of acyclic hydrocarbon isomers (other than stereoisomers), whether or not saturated (chapter 27) (c) The products of headings 2936 to 2939 or the sugar ethers, sugar acetals and sugar esters, and their salts, of heading 2940, or the products of heading 2941, whether or not chemically defined; (d) Products mentioned in (a), (b) or (c) above dissolved in water; (e) Products mentioned in (a), (b) or (c) above dissolved in other solvents provided that the solution constitutes a normal and necessary method of putting up these products adopted solely for reasons of safety or for transport and that the solvent does not render the product particularly suitable for specific use rather than for general use; (f) The products mentioned in (a), (b), (c), (d) or (e) above with an added stabilizer (including an anticaking agent) necessary for their preservation or transport; (g) The products mentioned in (a), (b), (c), (d), (e) or (f) above with an added antidusting agent or a coloring or odoriferous substance added to facilitate their identification or for safety reasons, provided that the additions do not render the product particularly suitable for specific use rather than for general use; a) Separate chemically defined organic whether or not containing impurities; compounds, Classification analysis of unmixed substances Note 1 of Chapter 29, continuation Separate chemically defined compound Substance consisting of a molecular species (e.g. Covalent or Ionic) whose composition is defined by a constant relationship between its elements, and is represented by a single structural diagram Impurities Exclusively applied to substances whose presence in the chemical compound is exclusively and directly due to the manufacturing process (including purification). These substances may come from: – Unreacted substances, – Impurities found in the reagents, Example: CH3CFCl2 1,1-dichloride-1-fluoroethane (HCFC-141b) – Reactive agents used in the manufacturing process (including purification), – By-products. Classification analysis of unmixed substances Note 1 of Chapter 29, continuation Except where the context otherwise requires, the headings of this Chapter apply only to: a) b) Separate chemically defined organic compounds, whether or not containing impurities; Mixtures of two or more isomers of the same organic compound (whether or not containing impurities), except mixtures of acyclic hydrocarbon isomers (other than stereoisomer), whether or not saturated (Chapter 27); c) The products of heading Nos. 29.36 to 29.39 or the sugar ethers and sugar esters and (b) Mixtures of two or more of the same organicNo. compound (whether their salts, of heading No.isomers 29.40, or the products of heading 29.41, whether or not or defined; notchemically containing impurities), except mixtures of acyclic hydrocarbon isomers d) The products mentioned in (a), (b) or (c) above dissolved in water; (other than stereoisomers), whether or not saturated (chapter 27); e) The products mentioned in (a), (b) or (c) above dissolved in other solvents provided that the solution constitutes a normal and necessary method of putting up these products Isomer: Compound mixtures presenting the same chemical function or the adopted solely for reasons of safety or for transport and that the solvent does not render same chemical functions, provided isomers coexist the product particularly suitable for specificthat use these rather than for general use; naturally or are simultaneously same operation. f)formed The products mentioned induring (a), (b), the (c), (d) or (e)synthesis above with an added stabilizer (including an anti-caking agent) necessary for their preservation or transport; g) The products mentioned in (a), (b), (c), (d), (e) or (f) above with an added anti-dusting agent or a coloring or odoriferous substance added to facilitate their identification or for safety reasons, provided that the additions do not render the product particularly suitable for specific use rather than for general use;; Classification analysis of unmixed substances Note 1 of Chapter 29, continuation Except where the context otherwise requires, the headings of this Chapter apply only to: a) b) c) d) e) Separate chemically defined organic compounds, whether or not containing impurities; Mixtures of two or more isomers of the same organic compound (whether or not containing impurities), except mixtures of acyclic hydrocarbon isomers (other than stereoisomers), whether or not saturated (Chapter 27); The products of heading Nos. 29.36 to 29.39 or the sugar ethers and sugar esters and their salts, of heading No. 29.40, or the products of heading No. 29.41, whether or not chemically defined; The products mentioned in (a), (b) or (c) above dissolved in water; The products mentioned in (a), (b) or (c) above dissolved in other solvents provided that the solution constitutes a normal and necessary method of putting up these products adopted solely for reasons of safety or for transport and that the solvent does not render the product particularly suitable for specific use rather than for general use; The products mentioned in (a), (b), (c), (d) or (e) above with an added stabilizer (including an anti-caking agent) necessary for their preservation or transport; The products mentioned in (a), (b), (c), (d), (e) or (f) above with an added anti-dusting agent or a coloring or odoriferous substance added to facilitate their identification or for safety reasons, provided that the additions do not render the product particularly suitable for specific use rather than for general use; c) The products of heading Nos. 29.36 to 29.39 or the sugar ethers and sugar esters and their salts, of heading No. 29.40, or the products of heading No. 29.41, whether or f) not chemically defined; g) Classification analysis of unmixed substances Note 1 of Chapter 29, continuation Except where the context otherwise requires, the headings of this Chapter apply only to: a) b) c) d) e) Separate chemically defined organic compounds, whether or not containing impurities; Mixtures of two or more isomers of the same organic compound (whether or not containing impurities), except mixtures of acyclic hydrocarbon isomers (other than stereoisomers), whether or not saturated (Chapter 27); The products of heading Nos. 29.36 to 29.39 or the sugar ethers and sugar esters and their salts, of heading No. 29.40, or the products of heading No. 29.41, whether or not chemically defined; The products mentioned in (a), (b) or (c) above dissolved in water; The products mentioned in (a), (b) or (c) above dissolved in other solvents provided that the solution constitutes a normal and necessary method of putting up these products adopted solely for reasons of safety or for transport and that the solvent does not render the product particularly suitable for specific use rather than for general use; The products mentioned in (a), (b), (c), (d) or (e) above with an added stabilizer (including an anti-caking agent) necessary for their preservation or transport; The products mentioned in (a), (b), (c), (d), (e) or (f) above with an added anti-dusting agent or a coloring or odoriferous substance added to facilitate their identification or for safety reasons, provided that the additions do not render the product particularly suitable for specific use rather than for general use l; d) The products mentioned in (a), (b) or (c) above dissolved f) in water; g) Classification analysis of unmixed substances Note 1 of Chapter 29, continuation Except where the context otherwise requires, the headings of this Chapter apply only to: Separate chemically defined organic compounds, whether or not containing impurities; a) Mixtures of two or more isomers of the same organic compound (whether or not containing impurities), except mixtures of acyclic hydrocarbon isomers (other than stereoisomers), whether or not saturated (Chapter 27); b) The products of heading Nos. 29.36 to 29.39 or the sugar ethers and sugar esters and their salts, of heading No. 29.40, or the products of heading No. 29.41, whether or not chemically defined; c) The products mentioned in (a), (b) or (c) above dissolved in water; d) The products mentioned in (a), (b) or (c) above dissolved in other solvents provided that the solution constitutes a normal and necessary method of putting up these products adopted solely for reasons of safety or for transport and that the solvent does not render the product particularly suitable for specific use rather than for general use; e) The products mentioned in (a), (b), (c), (d) or (e) above with an added stabilizer (including an anti-caking agent) necessary for their preservation or transport; f) The products mentioned in (a), (b), (c), (d), (e) or (f) above with an added anti-dusting agent or a coloring or odoriferous substance added to facilitate their identification or for safety reasons, provided that the additions do not render the product particularly suitable for specific use rather than for general use; e) The products mentioned in (a), (b) or (c) above dissolved in other solvents provided that the solution constitutes a normal and necessary method of putting up these products adopted solely for reasons of safety or for transport and that the solvent does not render the product particularly suitable for specific use rather than for general use; Classification analysis of unmixed substances Note 1 of Chapter 29, continuation Except where the context otherwise requires, the headings of this Chapter apply only to: a) b) c) d) e) f) g) Separate chemically defined organic compounds, whether or not containing impurities; Mixtures of two or more isomers of the same organic compound (whether or not containing impurities), except mixtures of acyclic hydrocarbon isomers (other than stereoisomers), whether or not saturated (Chapter 27); The products of heading Nos. 29.36 to 29.39 or the sugar ethers and sugar esters and their salts, of heading No. 29.40, or the products of heading No. 29.41, whether or not chemically defined; The products mentioned in (a), (b) or (c) above dissolved in water; The products mentioned in (a), (b) or (c) above dissolved in other solvents provided that the solution constitutes a normal and necessary method of putting up these products adopted solely for reasons of safety or for transport and that the solvent does not render the product particularly suitable for specific use rather than for general use; The products mentioned in (a), (b), (c), (d) or (e) above with an added stabilizer (including an anti-caking agent) necessary for their preservation or transport; The products mentioned in (a), (b), (c), (d), (e) or (f) above with an added anti-dusting agent or a coloring or odoriferous substance added to facilitate their identification or for safety reasons, provided that the additions do not render the product particularly suitable for specific use rather than for general use; f) The products mentioned in (a), (b), (c), (d) or (e) above with an added stabilizer (including an anti-caking agent) necessary for their preservation or transport; Classification analysis of unmixed substances Note 1 of Chapter 29, continuation Except where the context otherwise requires, the headings of this Chapter apply only to : a) b) c) d) e) f) g) Separate chemically defined organic compounds, whether or not containing impurities; Mixtures of two or more isomers of the same organic compound (whether or not containing impurities), except mixtures of acyclic hydrocarbon isomers (other than stereoisomers), whether or not saturated (Chapter 27); The products of heading Nos. 29.36 to 29.39 or the sugar ethers and sugar esters and their salts, of heading No. 29.40, or the products of heading No. 29.41, whether or not chemically defined; The products mentioned in (a), (b) or (c) above dissolved in water; The products mentioned in (a), (b) or (c) above dissolved in other solvents provided that the solution constitutes a normal and necessary method of putting up these products adopted solely for reasons of safety or for transport and that the solvent does not render the product particularly suitable for specific use rather than for general use; The products mentioned in (a), (b), (c), (d) or (e) above with an added stabilizer (including an anti-caking agent) necessary for their preservation or transport; The products mentioned in (a), (b), (c), (d), (e) or (f) above with an added anti-dusting agent or a coloring or odoriferous substance added to facilitate their identification or for safety reasons, provided that the additions do not render the product particularly suitable for specific use rather than for general use; g) The products mentioned in (a), (b), (c), (d), (e) or (f) above with an added anti-dusting agent or a coloring or odoriferous substance added to facilitate their identification or for safety reasons, provided that the additions do not render the product particularly suitable for specific use rather than for general use; Classification analysis of unmixed substances Note 1 of Chapter 29, continuation Example: Due to safety reasons 2% chloropicrin (odoriferous substance) is added to methyl bromide. When the content is more than 2%, it is no longer considered an unmixed substance. Chloropicrin acts as fungicide, therefore, renders it more appropriate for a specific uses and is classified as a mixture (3808.) Classification analysis of unmixed substances Section VI (Chapters 28 a 38) PRODUCTS OF THE CHEMICAL OR ALLIED INDUSTRIES Legal Note Nº 2 of Section VI …., any goods classifiable in heading 3004, 3005, 3006, 3212, 3303, 3304, 3305, 3306, 3307, 3506, 3707 or 3808 by reason of being put up in measured doses or for retail sale are to be classified in those headings and in no other heading of the tariff schedule. Classification analysis of unmixed substances. section VI, continuation Example Methyl bromide 98% (with 2% chloropicrin as odoriferous substance) packaged in 1 or 11/2 pounds cans, represent one dosage, therefore, according to the stipulations of Note 2 of Section VI, it cannot be classified by Chapter 29. In accordance with the Note, it classifies by 3808. Classification analysis of unmixed substances. section VI, continuation It can only be classified in chapter 29, when it is packaged in containers with valves that allow repeated use. In 30, 50, 100 Kg. cylinders or in iso-tanks (tank containers). Classification analysis of unmixed substances. HCFC 2903. HALOGENATED derivatives OF HYDROCARBONS. 2903.1 - Saturated chlorinated derivatives of acyclic hydrocarbons: 2903.11 --Chloromethane (methyl chloride) and chloroethane (ethyl chloride) 2903.12.--Cichloromethane (methylene chloride) Only with chlorine 2903.13. --Chloroform (trichloromethane) 2903.14. --Carbon tetrachloride (Annex B, Group II) 2903.15. --Ethylene dichloride (ISO) (1,2-dichlorideetano) 2903.19 --Other (Saturated chlorinated derivatives of acyclic hydrocarbons) 2903.19. 1,1,1-Trichloroethane (methyl chloroform) (Annex B, Group III) 2903.19. 1,1,2-Trichloroethane 2903.19. Others Control Classification analysis of unmixed substances. HCFC, continuation 2903.2 - Unsaturated chlorinated derivatives of acyclic hydrocarbons: Note: It does not contain ODS Only unsaturated and only with chlorine 2903.21. --Vinyl chloride (chloroethylene) 2903.22. –Trichloroethylene 2903.23. --Tetrachloroethylene (perchloroethylene) 2903.29. –Other (Unsaturated chlorinated derivatives of acyclic Control hydrocarbons) Classification analysis of unmixed substances. HCFC, continuation 2903.3 - Fluorinated, brominated or iodinated derivatives of acyclic hydrocarbons: Only with fluorine, bromine 2903.31. --ethylene dibromide (ISO) (1,2-dibromoethane). or iodine 2903.39 --Others (fluorinated derivatives, brominated derivatives y iodinated derivatives, of acyclic hydrocarbons). Fluorinated derivatives: 1,1,1,2-Tetrafluoroethane (R134a); R245fa, 1,1,3,3,3- Pentafluoro-2-(trifluoromethyl)-prop-1-ene, etc. Brominated derivatives: methyl bromide (bromomethane), bromoethane. Iodinated derivatives: Iodomethane, iodoform (triiodomethane), NOTE: This heading (2903) excludes products put up as charges for fireextinguishers or put up in fire-extinguishers grenades, of heading 3813. Classification analysis of unmixed substances. HCFC, continuation 2903.4 - Halogenated derivatives of acyclic hydrocarbons containing two or more different halogens: 2903.41 --trichlorofluoromethane (R11) 2903.42 –dichloridedifluoromethane (R12) Annex A, Group I 2903.43 --Trichlorotrifluoroethanes (R113) 2903.44 --Dichlorotetrafluoroethanes and chloropentafluoroethane (R114 & R115) 2903.45 -- Other derivatives perhalogenated only with fluorine and chlorine (Annex B Group I) 2903.46 --Bromochlorodifluoromethane, bromotrifluoromethane and (Halons. Annex A, dibromotetrafluoroethanes Group II) 2903.47 -- Other perhalogenated derivatives (This are not ODS. The ODS, for containing fluorine and chlorine, must be classified in 2903.45, more specific).Control 2903.49 --Others (Halogenated derivatives of acyclic hydrocarbons containing two or more different halogens): R22, R123, R124, R141b, R142b and Bromochloromethane Classification analysis of unmixed substances. Blend: Contains R22 And ???? Blend: butane & propane classified as R134a!!!!!! Chemical composition of a contaminated mixture labelled as R-134a analysed in Mozambique. (EIA) Classification analysis of mixtures containing ODS Remember Note 1 of Chapter 29: Unless provided otherwise, headings in this chapter only include: a) Separate chemically defined organic compounds, whether or not containing impurities. Because of this note, since mixtures are not a separate chemically defined compound, they are excluded from Chapter 29 and in general classify, in the other chapters of Section VI or VII Classification analysis of mixtures containing ODS, Chapter 38 Chapter notes. 1- This Chapter does not cover: a) Separate chemically defined elements or compounds with the exception of the following (generally, chapter 28 or 29) (1) Artificial graphite (heading No.3801.) (2) Insecticides, rodenticides, fungicides, herbicides, anti-sprouting products and plant-growth regulators, disinfectants and similar products, put up as described in heading No.3808. (formulated or in doses) (3) products put up as charges for fire-extinguishers or put in fireextinguishers grenades (heading No.3813) Classification analysis of mixtures containing ODS, Heading 3808. 3808- INSECTICIDES, RODENTICIDES, FUNGICIDES, HERBICIDES, ANTISPROUTING PRODUCTS AND PLANT-GROWTH REGULATORS, DISINFECTANTS AND SIMILAR PRODUCTS, PUT UP IN FORMS OR PACKAGINGS FOR RETAIL SALE OR AS PREPARATIONS OR ARTICLES (FOR EXAMPLE, SULPHUR- TREATED BANDS, WICKS AND CANDLES, AND FLY-PAPERS) 3808.91 -- Insecticides Methyl bromide insecticides 3808.92 -- Fungicides 3808.93 -- Herbicides, anti-sprouting products and plant-growth regulators 3808.94 -- Disinfectants 3808.99 -- Others (ECO GAS –Spain- R124 94,1% & ethylene oxide 8,6%) Control Classification analysis of mixtures containing ODS, Subheading 3813.00 3813.00- PREPARATIONS AND CHARGES FOR FIRE EXTINGUISHERS; CHARGED FIRE-EXTINGUISHING GRENADES. Charges for fire-extinguishers: light-weight containers (of glass, thin sheet-metal, etc.) designed to be themselves incorporated into fire-extinguishers, whether they contain: (1) Preparations (2) Two or more unmixed products, separated by a partition and intended to be put into contact al the moment of use (3) A single unmixed product. Charged fire-extinguishing grenades: containers charged with fire-extinguishing products (whether or not mixed), and used directly without incorporation in fire extinguishing appliances. These are glass or pottery containers which are thrown into the heart of the fire and which break freeing their contents, or glass containers the end of which need only be broken between the fingers to project the extinguishing product. Note: Fire-extinguishers, including portables, charged or not, are contained in the heading 8424. (Annex D of MP) Classification analysis of mixtures containing ODS, Subheading 3813.00, continuation. Fire extinguishing agent suitable for total flooding systems accepted under the SNAP programme (EPA): HCFC Agent Formula HFC-227ea HFC-125 HFC-23 HCFC-124 HCFC-blend A (drop-in agent respect to Halon 1301) HFC-236fa FC-2-1-8 FC-3-1-10 CF3CHFCF3 CHF2CF3 CHF3 CHCIFCF3 4,75% HCFC-123 82% HCFC-22 9,5% HCFC-124 3,75% Isopropenyl-1-metilcilohexano CF3CH2CF3 C3F8 C4F10 70% HFC-134a 15% HFC-125 CO2 FS 49 C2 Commercial names heptafluoropropano FM-200, FE-227 pentafluoroetano FE-25 trifluorometano FE-13 clorotetrafluoroetano FE-241 diclorotrifluoroetano clorodifluorometano NAF S-III clorotetrafluoroetano Name Hexafluoropropano Perfluoropropano Perfluorobutano FE-36 CEA-308 CEA-410 Halotron II Classification analysis of mixtures containing ODS. Subheading 3813.00, continuation. Fire extinguishing equipment suitable for portable fire extinguishers accepted under the SNAP programme (EPA): Agent HCFC-blend B HCFC-123 FC-5-1-14 HCFC-blend C (drop-in extinguisher agent respect to Halon 1211) HCFC-blend D HCFC-blend E HCFC HCFC-124 HFC-227ea (replaces Halon 1301) HFC-236fa Formula Name HCFC-123 HFC-134a Argon CHCI2CF3 C6F14 55% HCFC-123 31% HFC-124 10% HFC-134a 4% D-limoneno HCFC-123 + aditivo 90% HCFC-123 8% HFC-125% 2% D-limoneno CHCIFCF3 CF3CHFCF3 Diclorotrifluoretano Tetrafluoroetano CF3CH2CF3 Hexafluoropropano Commercial names Halotron I Diclorotrifluoretano Perfluorhexano Diclorotrifluoretano clorotetrafluoroetano Tetrafluoroetano FE-232 CEA-614 Diclorotrifluoretano Blitz III Diclorotrifluoretano pentafluoroetano NAF P-IV Clorotetrafluoroetano Heptafluoropropano NAF P-III FE-241 FM-200, FE-227 FE-36 Classification analysis of mixtures containing ODS. Subheading 3814.00 3814.00- ORGANIC COMPOSITE SOLVENTS AND THINNERS, NOT ELSEWHERE SPECIFIED OR INCLUDED; PREPARED PAINT OR VARNISH REMOVERS. This heading includes, provided that they are not separate chemically defined chemicals and are not included in a more specific heading, organic solvents and diluents organic (although containing 70% by weight or more of oil petroleum). Are more or less volatile liquid used, inter alia, for the preparation of varnishes and paints or the degreasing of mechanical parts, etc. Blends containing methyl chloroform and/or carbon tetrachloride and/or liquid HCFC Classification analysis of mixtures containing ODS. Subheading 3822.00 3822.00 Diagnostic or laboratory reagents on a backing and prepared diagnostic or laboratory reagents whether or not on a backing, other than those of heading No. 30.02 or 30.06 Reagents: The reagents of this heading are on a backing or in the form of preparations, therefore they are more than a single constituent. They may consist of admixtures of two or more reagents or of single reagent dissolved in solvents other than water. Reagents of this heading may also be put up in the form of kits, consisting of several components composed of various components. The products of this heading should de clearly identifiable as being for use only as diagnostic or laboratory reagents. This must be clear from their composition, labeling, instructions for in vitro or laboratory use, etc. Classification analysis of mixtures containing ODS. Subheading 3822.00, continuation REFERENCE MATERIALS Certified reference materials of this heading are reference materials intended to calibrate a device, evaluate a measurement method or attribute values to materials. For the classification of certified reference materials, heading 3822. has priority over any other tariff schedule, except for the products of Chapters 28 ó 29. This is why unmixed substances, although they are used as references, must be classified under Chapter 28 or 29. Classification analysis of mixtures containing ODS. Heading 3824. 3824. PREPARED BINDERS FOR FOUNDRY MOULDS OR CORES; CHEMICAL PRODUCTS AND PREPARATIONS OF THE CHEMICAL OR ALLIED INDUSTRIES (INCLUDING THOSE CONSISTING OF MIXTURES OF NATURAL PRODUCTS), NOT ELSEWHERE SPECIFIED OR INCLUDED. IMPORTANT: Before classifying a mixture under this heading, you must have the certainty that is not expressed or contained elsewhere (other heading). Classification analysis of mixtures containing ODS. Heading 3824, continuation. Example NASF S III mixture that we saw previously, contained HCFC (R22, R123 and R124). As we will see, mixtures containing halogenated derivatives of methane, ethane or propane are classified in Subheading 3824.74. But this mixture, since it is especially prepared for extinguishers, is under heading 3813 (more specific). Therefore, It must be classified in this heading and never under heading 3824. Remember: NOT ELSEWHERE SPECIFIED OR INCLUDED. Classification analysis of mixtures containing ODS. Heading 3824.7 Subheading Explanatory Note. Subheadings 3824.71 to 3824.79: Subheadings 3824.71 to 3824.79 includes mixtures containing halogenated derivatives of methane, ethane or propane, including the mixtures of these halogenated derivatives with other substances. The trade of mixtures containing halogenated derivatives of methane, ethane or propane mixtures, is controlled by the Montreal Protocol regarding ozone depleting substances. We must distinguish “containing” from “based on”. Under this subhedings, is enough if the blend contains an halogenated derivative of methane, ethane or propane, including the mixtures of these halogenated derivatives with other substances. Does not need to be based on (Principal component). Classification analysis of mixtures containing ODS. Heading 3824.7 • • 3824.7- Mixtures containing halogenated derivatives of methane, ethane or propane: 3824.71- Containing chlorofluorocarbons (CFCs), whether or not containing hydrochlorofluorocarbons (HCFCs), perfluorocarbaons (PFCs) or hydrofluorocarbons (HFCs). R502: CFC115 (51.2%) y HCFC (48.8%) This blends must contain CFC Classification analysis of mixtures containing ODS. Heading 3824.71, summary M E Z C LA S Refrigerante Refrigerant A Z EAZEOTROPIC O T R OMIXTURES P I C (1)A S(1) component component 1 1 component component 22 P.A. SIM Sub-heading R-500 R-12 74% R-152a 26% 3824.71 R-501 R-22 75% R-12 25% 3824.71 R-502 R-115 51% R-22 49% 3824.71 R-503 R-13 60% R-23 40% 3824.71 R-504 R-115 52% R-32 48% 3824.71 R-505 R-12 78% R-31 22% 3824.71 R-506 R-31 55% R-114 45% 3824.71 (1) Liquid blends with constant boiling points Classification analysis of mixtures containing ODS. Heading 3824.7, continuation 3824.72. –Containing: Bromochlorodifluoromethane Bromotrifluoromethane Bibromotetrafluoroethanes Halon 1211 Halon 1301 Annex A – Group II Halon 2402 3824.73. -- Containing hydrobromofluorocarbons (HBFC) Annex C – Group II Classification analysis of mixtures containing ODS. Heading 3824.74 3824.74 -- Containing hydrochlorofluorocarbons (HCFCs), whether or not containing perfluorocarbons (PFCs) or hydrofluorocarbons (HFCs) but not containing chlorofluorocarbons. IMPORTANT: MUST NOT CONTAIN CFCs. May contain other compounds. For example, R406A contains Isobutane (R600a). Remember the Note to Subheadings 3824.71 to 3824.79. Subheadings 3824.71 to 3824.79 include mixtures containing halogenated derivatives of methane, ethane or propane, including mixtures of these halogenated derivatives with other substances. Classification analysis of mixtures containing ODS. Heading 3824.7. Summary. ZEOTROPIC MIXTURES Refrigerant component 1 component 2 component 3 component 4 Sub-heading R-401A (MP-39) R-22 53% R-124 34% R-152a 13% XXXXX 3824.74 R-401B (MP-66) R-22 61% R-124 28% R-152a 11% XXXXX 3824.74 R-401C R-124 52% R-22 33% R-152a 15% XXXXX 3824.74 R-402A (HP-80) R-22 38% R-125 60% R-290 2% XXXXX 3824.74 R-402B (HP-81) R-22 60% R-125 38% R-290 2% XXXXX 3824.74 R-403A R-22 75% R-218 20% R-290 5% XXXXX 3824.74 R-403B R-22 56% R-218 39% R-290 5% XXXXX 3824.74 R-405A R-22 45% R-142b 2.5% R-152a 7% C318 5,5% (*) 3824.74 R-406A R-22 55% R-142b 41% HC-600a 4% XXXXX 3824.74 (*) R-C318: perfluorocyclobutane. Classification analysis of mixtures containing ODS. Subheading 3824.74. Summary. ZEOTROPIC MIXTURE, continuation Refrigerant component 1 component 2 component 3 component 4 Subheading R-408A R-22 47% R-143a 46% R-125 7% XXXXX 3824.74 R-409A R-22 60% R-124 25% R-142b 15% XXXXX 3824.74 R-409B R-22 65% R-124 25% R-142b 10% XXXXX 3824.74 R-411A R-22 88% R-152a 11% HC-1270 2% XXXXX 3824.74 R-411B R-22 94% R-152a HC-1270 3% XXXXX 3824.74 R-412A R-22 70% R-142b 25% FC-218 XXXXX 3824.74 R-414B R-22 50% R-124 R-142b 9.5% R-415B R-22 25% R-152a 75% XXXXX XXXXX 3824.74 YH12 R-22 10% R-142b 65% R-152a 25% XXXXX 3824.74 DYR-7 R-22 R142b 25% R21 20% XXXXX 3824.74 UR12 R-22 50,% R-124 50% XXXXX XXXXX 3824.74 YH12 R-22 50,% R-124 50% XXXXX XXXXX 3824.74 55% 3% 39% 5% HC-600a ,5% NOTE: Always take samples of the liquid phase. Invert can 3824.74 Classification analysis of mixtures containing ODS. Subheading 3824.74, continuation Some blends that classify under this Subheading R409A R401B R408A R402A Classification analysis of mixtures containing ODS. Subheading 3824.74, continuation Some blends that classify under this Subheading R22, 10% R142b, 65% R152a, 25% R22, 55%, R142b, 41% R600a, 4% Classification analysis of mixtures containing ODS. Subheading 3824.75 3824.75. – Containing carbon tetrachloride. IMPORTANT: Remember 1- Laboratory compound reagents and reference standards containing CCl4, must be classified under Subheading 3822.00. 2- Diluents and solvents under Subheading 3814.00 Classification analysis of mixtures containing ODS. Subheading 3824.76 3824.76. –Containing 1,1,1-trichloroethane (methyl chloroform). IMPORTANT: Remember 1- Laboratory compound reagents and reference standards containing methyl chloroform must be classified under Subheading 3822.00. 2- Diluents and solvents under Subheading 3814.00 Classification analysis of mixtures containing ODS. Subheading 3824.77 3824.77. –Containing bromomethane (methyl bromide) or bromochloromethane . Annex E Bromomethane BrCH3 Annex C – Group III Bromochloromethane H2CBrCl Classification analysis of mixtures containing ODS. Subheading 3824.78 3824.78 –Containing perfluorocarbons (PFC) or hidrofluorocarburos (HFC), but do not contain chlorofluorocarbons (CFC) or hydrochlorofluorocarbons(HCFC). These are blends containing only PFC o HFC (they do not contain Chlorine and/or Bromine) Classification analysis of mixtures containing ODS. Subheading 3824.78, summary AZEOTROPIC MIXTURES (1) Refrigerant component 1 component 2 Subheading R-507 (AZ-50) R-125 50% R-143a 50% 3824.78. R-508a R-116 54% R-23 39% 3824.78 R-508b (Suva 95) R-116 54% R-32 46% 3824.78. (1) Liquid mixture with a constant boiling point Classification analysis of mixtures containing ODS. Subheading 3824.74, Summary. ZEOTROPIC MIXTURES, continuation Refrigerant component 1 component 2 component 3 R-404a (HP-62) R-143a 52% R-125 44% R-134a R-407a R-134a 40% R-125 40% R-407b R-125 R-407c component 4 Subheading 4% XXXXX 3824.78 R-32 20% XXXXX 3824.78 R-134a 20% R-32 10% XXXXX 3824.78 R-134a 52% R-125 25% R-32 23% XXXXX 3824.78 R-407d R-134a 70% R-125 15% R-32 15% XXXXX 3824.78 R-410a R-32 50% R-125 50% XXXXX 3824.78 R-413a R-134a 88% R-218 9% R600a 3% XXXXX 3824.78 R-417a R-134a 53% R-125 43% R-600a 4% XXXXX 3824.78 70% XXXXX NOTE: Always take samples of the liquid phase. Invert can Classification analysis of mixtures containing ODS. Subheading 3824.79 3824.79. – Others (Mixtures containing halogenated derivatives of methane, ethane or propane) Examples: 1. Mixtures containing derivatives only with chloride, other than methyl chloroform or carbon tetrachloride. 2. Mixtures with iodinated derivatives (with or without F, Br and/or Cl). 3. Mixtures with derivatives with chloride and bromide not considered in the PM. 4. Etc. Classification analysis of mixtures containing ODS. Subheading 3824.90 3824.90. – Others (chemical products and preparations of the chemical or allied industries -including those consisting of mixtures of natural products-, not elsewhere specified or included). Subheading 3824.90 includes chemicals products and other preparations of the chemical or allied industries which are unable to be classified in any other heading of the Section VI. Originally, before the fourth amendment (2007), this was the subheading where blends were classified. Amendment 2012 Harmonized System CHAPTER 29: Repeal subheadings 2903.4 to 2903.69. New 2903.7 -Halogenated derivatives of acyclic hydrocarbons containing two or more different halogens. Creation of new sub-headings 2903.71 to 2903.75 to separate: 2903.71-Chlorodifluoromethane (R22) 2903.72-Dichlorotrifluoroethanes (R123) 2903.73-Dichlorofluoroethanes (R141b) 2903.74-Chlorodifluoroethanes (R142b) 2903.75-Dichloropentafluoropropanes (R225) R124 is not Include!! Renumbering of the subheading 2903.46 as 2903.76 for: 2903.76-Bromochlorodifluoromethane (Halon 1211), Bromotrifluoromethane (Halon 1301) and dibromotetrafluoroethanes (Halon 2402) Amendment 2012 Harmonized System CHAPTER 29: Unification of subheading 2903.41 a 45 in new subheading 2903.77: 2903.77-Other derivatives perhalogenated only with fluorine and chlorine. Trichlorofluoromethane (R11), Dichlorodifluoromethane (R12), Annex A, Trichlorotrifluoroethanes (R113), Group I Dichlorotetrafluoroethanes (R114), Chloropentafluoroethane (R115) Other derivatives perhalogenated only with fluorine and chlorine: Annex B, Group I (CFC) Renumbering the subheading 2903.47 2903.78-Other perhalogenated derivatives (not as 2903.78 for: only with fluorine and chlorine: 2903.77) Creation of the new subheadings 2903.79 for: 2903.79-Others (halogenated derivatives of the acyclic hydrocarbons containing two or more different halogens. R124, the rest of Annex C, Group I and Bromochloromethane) Polyol Viscous liquids whose main chemical characteristic are hydroxyl (OH) groups composed of oxygen and hydrogen. These Groups react with the isocyanate groups (N=C=O) of the isocyanate giving place to urethane groups. It is worth distinguishing between polyetherpolyol and polyesterpolyol. POLYETHERPOLYOL: obtained from a reaction of polyhydroxylated alcohols (i.e., glycols, glycerin, raw sugar) or amine (i.e., ethylendiamine) with alkylene oxide. Polyols used for manufacturing rigid foam are mostly obtained from propylene oxide. POLYESTERPOLYOL: obtained from the reaction of polyvalent carboxylic acids (i.e., phthalic acid, terephthalic acid or adipic acid) with similar glycols, glycerin or polyalcohols. Water and polyol with ester structure are obtained. Polyol, continuation Functionality of a polyol Indicates the number of hydroxyl groups existing in the molecule. If the polyol is a mixture of components of different functionalities, then the mean functionality is indicated. The parts of a molecule that are capable of reacting, i.e., hydroxyl groups, are called functional groups. The content in hydroxyl groups in a compound is called hydroxyl index or OH index. Polyol: Formation of a polyurethane The manufacture of rigid PUR foam requires two main components that are liquid, a polyol and a isocyanate as well as an blowing agent. Generally speaking, an blowing agent and other auxiliaries, such as activators (reaction accelerators), foam stabilizers, flame retardants, etc. are mixed with the polyol. The polyaddition reaction that takes place when the polyol and the isocyanate are mixed leads to the formation of urethane structure macromolecules Heat Also the water present reacts with the isocynate to form a polyurea and carbon dioxide, which acts as an expansion agent, being able to be the only one present. Classification analysis of polyol containing ODS (poliuretano). (R141b) Section VII (chapters 39 and 38) products of the chemical or allied industries Legal Note N.º 1 of Section VII Goods put up in sets consisting of two or more separate constituents, some or all of which fall in this section and are intended to be mixed together to obtain a product of section VI or VII, are to be classified in the heading appropriate to that product, provided that the constituents are: a) Having regard to the manner in which they are put up, clearly identifiable as being intended to be used together without first being repacked; (b) Entered together (presented simultaneously); and (c) Identifiable, whether by their nature or by the relative proportions in which they are present, as being complementary one to another. Classification analysis of polyol containing ODS (R141b), continuation Systems: POLYOL + ISOCYANATE Systems are usually formed by two components: On the one hand, polyol (A) and on the other, isocyanate (B). These components are mixed in a determinate proportion, and therefore, in systems, are presented in this proportion. Summarizing, if the final mixture, has 1 part of component A and 1.4 parts of component B, for each ton of component A there will be 1.4 tons of component B. Therefore, a system, satisfies the requirements of Legal Note Nº 3 of Section VI: a) Clearly identifiable by their packaging, as intended to be used together without prior reconditioning; b) Presented simultaneously; and c) Complementary one to another. Classification analysis of polyol containing ODS (R141b), continuation As set out in the note, the systems are classified in the heading appropriate for the product formed in the reaction. As the system will react forming a polyurethane, it should be classified as such. SYSTEMS FORMED BY: POLYOL + ISOCYANATE CLASSIFY AS POLYURETHANE: Subheading: 3909.50 If a system contains R141b as an expansion (blowing) agent, an import or export license corresponds. There should be some sort of intervention of the Agency in charge of ODS controls. Classification analysis of polyol containing ODS (R141b), continuation Examples of Systems with R141b: Classification analysis of polyol containing ODS (R141b), continuation More examples of systems with R141b: Classification analysis of polyol containing ODS (R141b), continuation More examples of systems with R141b: Classification analysis of polyol containing ODS (R141b), continuation More examples of systems with R141b: BASF: ELASTOPOR System 480 ELASTOPOR System 486 DOW: VORACOR System CD923 VORACOR System CS 822 ELASTOPOR System 488 ELASTOPOR System 491 ELASTOPOR System 491 7AF HUNTSMAN: ELASTOPOR System XBP-1719-002F ELASTOPOR System R480-AF-RA ELASTOPOR RAP System 1219-051F Classification analysis of polyol containing ODS (R141b), continuation Legal Note Nº 3 of Chapter 39 Headings 39.01 to 39.11 only classify products of the following categories obtained by chemical synthesis: a) liquid synthetic polyolefins distilling at a proportion lower than 60% in volume at 300°C referring to 1.013 millibars when a low pressure distillation method is used (headings 39.01 and 39.02); b) Slightly polymerized resins of the coumarone-indene resin type (heading 39.11); c) other synthetic polymers having at least 5 monomeric units, on average; d) silicones (heading 39.10); e) resoles (heading 39.09) and other prepolymers. Classification analysis of polyol containing ODS (R141b), continuation POLYETHERPOLYOL POLYESTHERPOLYOL When having 5 or more When having 5 or more monomeric units, are classified monomeric units, are classified in the Subheading: in the Subheading: 3907.99- Others 3907.20- Other polyethers (Others polyesters) THE OTHER POLYOLS are those that do not satisfy Legal Note Nº 3 (have less than 5 monomeric units, normally sugars) are classified under Subheading: 3824.74- Containing hydrochlorofluorocarbons (HCFC – R141b), including with perfluorocarbons (PFC) or hidrofluorocarburos (HFC), but do not contain chlorofluorocarbons (CFC). Classification analysis of polyol containing ODS (R141b), continuation Note sobre Prepolymers: Urethane prepolymers are those mixtures in where a portion of polyol reacts with an excess of isocyanate. Forming in this manner a liquid prepolymer. This prepolymer is in itself, a diisocyanate, but unlike the original (MDI), it has a high molecular weight, which depends on the used polyol, and a higher viscosity. This prepolymer is allowed to react with another polyol, which may or may not contain foaming agent to finally form a polyurethane. These prepolymers, do not contain a foaming agent. Classification analysis of polyol containing ODS (R141b), continuation Examples of polyol with R141b: HUNTSMAN (3824.74) RUBITHERM WS 15000 RUBITHERM LP 14404 DALTOFOAM TA 30139 RUBITHERM WS 18003 BAYER (3824.74) BAYMER PE 8570/B16 BAYMER PD 0529/B16 BAYMER RB 7591/B26 BAYMER PE 8568/B30 BAYTHERM PE 7749/B24 BAYTHERM RF 7799/B25 BASF (3907.20) ELASTOPOR R480 AF-RA. ELASTOPOR RAD 2010-017F. ELASTOPOR XBP-1719-002F. MERCOSUR Tariff Schedule unmixed substances 2903 HYDROCARBONS HALOGENATED DERIVATES. 2903.1 -Saturated chlorinate derivatives of acyclic hydrocarbons: 2903.11 --Chloromethane (methyl chloride) y chloroethane (ethyl chloride) 2903.11.10 Chloromethane (methyl chloride) 2903.11.20 Chloroethane (ethyl chloride) 2903.12.00 --Dichloridemethane (methylene chloride) 2903.13.00 --Chloroform (trichloromethane) 2903.14.00 --Carbon tetrachloride 2903.15.00 --Ethylene dichloride (ISO) (1,2-dichlorideetano) 2903.19 --Others 2903.19.10 1,1,1-Trichloroethane 2903.19.20 1,1,2-Trichloroethane 2903.19.90 Others (methyl chloroform) MERCOSUR Tariff Schedule unmixed substances 2903.2 -Unsaturated chlorinate derivatives of acyclic hydrocarbons: 2903.21.00 --Vinyl chloride (chloroethylene) 2903.22.00 --Trichloroethylene 2903.23.00 --Tetrachloroethylene (perchloroethylene) 2903.29.00 --Others 2903.3 -Fluorinated derivatives, brominated derivatives and iodinated derivatives, of acyclic hydrocarbons: 2903.31.00 --Ethylene dibromide (ISO) (1,2-dibromoethane) 2903.39 --Others NOTE: This heading (2903) excludes products put up as charges for fireextinguishers or put up in fire-extinguishers grenades, of heading 3813. MERCOSUR Tariff Schedule unmixed substances 2903.39 --Others 2903.39.1 fluorinated derivatives 2903.39.11 1,1,1,2-Tetrafluoroethane (HFC-134a) 2903.39.12 1,1,3,3,3-Pentafluoro-2-(trifluorometil)prop-1-eno 2903.39.19 Others 2903.39.2 Brominate derivatives 2903.39.21 bromomethane (BrCH3) 2903.39.29 Others 2903.39.3 iodinated derivatives 2903.39.31 Iodoethane 2903.39.32 Iodoform 2903.39.39 Others (with Iodine) MERCOSUR Tariff Schedule unmixed substances 2903.4 -Halogenated derivatives of acyclic hydrocarbons containing two or more different halogens: 2903.41.00 --trichlorofluoromethane 2903.42.00 --dichloridedifluoromethane (CFC-12) 2903.43.00 --Trichlorotrifluoroethanes (CFC-113) 2903.44.00 --dichlorotetrafluoroethanes y chloropentafluoroethane 2903.45 --Others derivados perhalogenated only with flouride and chloride 2903.45.10 Clorotrifluoromethanes (CFC-13) 2903.45.20 Pentachlorofluoroethane (CFC-111) 2903.45.30 Tetrachlorodifluoroethanes (CFC-112) 2903.45.4 Propare perhalogenated derivatives, only with flouride and chloride 2903.45.41 HeptaChlorofluoropropanes (CFC-211) 2903.45.42 Hexachlorodifluoropropanes (CFC-212) 2903.45.43 Pentachlorotrifluoropropanes (CFC-213) 2903.45.44 Tetrachlorotetrafluoropropanes (CFC-214) 2903.45.45 Trichloropentafluoropropanes (CFC-215) 2903.45.46 dichloridehexafluoropropanes 2903.45.47 Cloroheptafluoropropanes 2903.45.90 Others (This position does not comprise ODS) (CFC-11) (CFC-216) (CFC-217) Annex A Group I (CFC-114 y CFC-115) Annex B Group I MERCOSUR Tariff Schedule unmixed substances 2903.46.00 --Bromochlorodifluoromethane, bromotrifluoromethane and dibromotetrafluoroethanes (Halons) 2903.47.00 --Other perhalogenated derivatives (Position does not comprise ODS) 2903.49 --Others 2903.49.1 Derivatives of methanes, ethane or propane, halogenated only with F y Cl 2903.49.11 Chlorodifluoromethane 2903.49.12 Clorofluoroethanes 2903.49.13 Dichloridetrifluoroethanes 2903.49.14 Chlorotetrafluoroethanes Annex C 2903.49.15 Dichloridefluoroethanes Group I 2903.49.16 Clorodifluoroethanes 2903.49.17 Dichloridepentafluoropropanes 2903.49.19 Others 2903.49.20 Derivatives of methanes, ethane or propane, halogenated only with F and Br 2903.49.3 Bromochlorotrifluoroethanes 2903.49.31 Halotano 2903.49.39 Others 2903.49.90 Others (Bromochloromethane) R22 R151 R123 R124 r141b r142b R225 (Not ODS) MERCOSUR Tariff Schedule Mixtures, heading 3808 3808.91 -- Insecticides 3808.91.1 Presented in forms or exclusive direct use containers in domisanitary applications 3808.91.11 Containing bromomethane (methyl bromide) or bromochloromethane 3808.91.19 Others. 3808.91.20 Presented otherwise, containing bromomethane (methyl bromide) or bromochloromethane 3808.91.9 Others. 3808.92 -- fungicides. 3808.92.1 Presented in forms or exclusive diretect use containers in domisanitary applications 3808.92.11 Containing bromomethane (methyl bromide) or bromochloromethane 3808.92.19 Others 3808.92.20 Presented otherwise, containing bromomethane (methyl bromide) or bromochloromethane 3808.92.9 Others MERCOSUR Tariff Schedule Mixtures, Subheading 3813.00 3813.00 PREPARATIONS AND CHARGES FOR FIRE-EXTINGUISHERS; CHARGED FIRE-EXTINGUISHING GRENADES 3813.00.10 Containing bromochlorodifluoromethane, bromotrifluoromethane or dibromotetrafluoroethanes (Halons) 3813.00.20 Containing hydrobromofluorocarbons of methanes, ethane or propane (HBFC) (Annex C Group II) 3813.00.30 Containing hydrochlorofluorocarbonsdel methanes, ethane or propane (HCFC) (Annex c Group I) 3813.00.40 Containing bromochloromethane (Annex C Group III) 3813.00.90 Others MERCOSUR Tariff Schedule Mixtures, Subheading 3814.00 3814.00 ORGANIC COMPOSITE SOLVENTS AND THINNERS, NOT ELSEWHERE SPECIFIED OR INCLUDED; PREPARED PAINT OR VARNISH REMOVERS. 3814.00.10 Containing chlorofluorocarbons of methane, ethane or propane (CFC), including those containing hydrochlorofluorocarbons (HCFC). 3814.00.20 Containing hydrochlorofluorocarbons of methane, ethane or propane (HCFC), but do not contain chlorofluorocarbons (CFC). 3814.00.30 Containing carbon tetrachloride, bromochloromethane or 1,1,1- trichloroethane (methyl chloroform). 3814.00.90 Others MERCOSUR Tariff Schedule Mixtures, Subheading 3814.00 3822.00 DIAGNOSTIC OR LABORATORY REAGENTS ON A BACKING AND PREPARED DIAGNOSTIC OR LABORATORY REAGENTS WHETHER OR NOT ON A BACKING, OTHER THAN THOSE OF HEADING NO. 30.02 OR 30.06. 3822.00.10 Reagents for determining blood or urine components on paper backing, rolls, without an additional hydrophobic backing not appropriate for direct use 3822.00.90 Others MERCOSUR Tariff Schedule Mixtures, continuation 3824.7 - Mixtures containing halogenated methane, ethane or propane derivatives 3824.71 – Containing chlorofluorocarbons (CFC), including hydrochlorofluorocarbons (HCFC), perfluorocarbons (PFC) o hidrofluorocarburos (HFC) 3824.71.10 Containing trichlorotrifluoroethanes (CFC-113) 3824.71.90 Others. (containing CFC) 3824.72.00 -- Containing bromochlorodifluoromethane, bromotrifluoromethane or dibromotetrafluoroethanes (Halons) 3824.73.00 -- Containing hydrobromofluorocarbons (HBFC) (Annex C Gpo. II) 3824.74 -- Containing hydrochlorofluorocarbons(HCFC including perfluorocarbons (PFC) o hidrofluorocarburos (HFC), but not containing chlorofluorocarbons (CFC) 3824.74.10 Containing chlorodifluoromethane (HCFC-22) and pentafluoroethane (HFC-125). Examples: R402A, R402B and R408A 3824.74.20 Containing chlorodifluoromethane (HCFC-22) y chlorotetrafluoroethane (HCFC-124). Examples: R401A, R401B and R409A 3824.74.90 The others. Examples: R406A. YH12 MERCOSUR Tariff Schedule Mixtures, continuation 3824.75.00 -- Containing carbon tetrachloride. 3824.76.00 --Containing 1,1,1-trichloroethane (methyl chloroform). 3824.77.00 --Containing bromomethane (methyl bromide) or bomochloromethane. 3824.78 --Containing perfluorocarbons (PFCs) or hydrofluorocarbons (HFCs), but not containing chlorofluorocarbons (CFCs) or hydrochlorofluorocarbons (HCFCs). 3824.78.10 Containing tetrafluoroethane y pentafluoroethane. 3824.78.90 Las demás. (containing PFC or HFC, but not CFC o HCFC) 3824.79.00 --Las demás. (Mixtures containing halogenated methane, ethane or propane derivatives) (control) 81 MERCOSUR Tariff Schedule Mixtures, continuation 3824.90 Others, (chemical products and preparations of the chemical or allied industriesincluding those consisting of mixtures of natural products-, not elsewhere specified or included). 3824.90.8 Products and preparations based on organic compounds, not elsewhere specified or included. 3824.90.89 Others. 82 Caribbean Community or CARICOM CARICOM gathers Antigua and Barbuda, Bahamas, Barbados, Belize, Dominica, Grenada, Guyana, Haiti, Jamaica, Montserrat, Saint Kitts and Nevis, Saint Lucia, Saint Vincent and the Grenadines, Suriname and Trinidad & Tobago. Countries participating as observers are Anguilla, Cayman Islands, Mexico, Venezuela, Aruba, Colombia, Netherlands Antilles, Bermudas, Dominican Republic and Puerto Rico, while the Virgin Islands are associate members. Caribbean Community or CARICOM, unmixed substances HS 2007 HEADING 29.03 DESCRIPTION OF GOODS RATE OF DUTY UNIT (S) Halogenated derivatives of hydrocarbons. Saturated chlorinated derivatives of acyclic hydrocarbons: 2903.11.00 Chloromethane (methyl chloride) and chloroethane (ethyl chloride) 0-5% kg 2903.12.00 dichloridemethane (methylene chloride) 0-5% kg 2903.13.00 Chloroform (trichloromethane) 0-5% kg 2903.14.00 Carbon tetrachloride 0-5% kg 2903.15.00 Ethylene dichloride (ISO) (1,2 dichlorideethane) 0-5% kg 2903.19.00 Other (Saturated chlorinated derivatives of acyclic hydrocarbons) 2903.19.10 1,1,1-Trichloroethane (methylchloroform) 0-5% kg 2903.19.90 Other (Saturated chlorinated derivatives of acyclic hydrocarbons) CONTROL kg Unsaturated chlorinated derivatives of acyclic hydrocarbons: 2903.21.00 Vinyl chloride (chloroethylene) 0-5% kg 2903.22.00 Trichloroethylene 0-5% kg 2903.23.00 Tetrachloroethylene (perchloroethylene) 0-5% kg 2903.29.00 Other (Unsaturated chlorinated derivatives of acyclic hydrocarbons) CONTROL kg Caribbean Community or CARICOM, unmixed substances Fluorinated, brominated or iodinated derivatives of acyclic hydrocarbons: 2903.31.00 Ethylene dibromide (ISO) (1,2 dibromoethane) 0-5% kg 2903.39.00 Other (methyl bromide) CONTROL kg 0-5% kg R12 0-5% kg R113 0-5% kg 0-5% kg Halogenated derivatives of acyclic hydrocarbons containing two or more different halogens: 2903.41.00 Trichlorofluoromethane R11 2903.42.00 Dichloridedifluoromethane 2903.43.00 Trichlorotrifluoroethanes 2903.44.00 Dichloridetetrafluoroethanes and chloropentafluoroethane R114 and R115 Does not have its own position NOTE: This heading (2903) excludes products put up as charges for fireextinguishers or put up in fire-extinguishers grenades, of heading 3813. Caribbean Community or CARICOM, unmixed substances 2903.45.00 Other derivatives perhalogenated only with fluorine and chlorine: 2903.45.10 Chlorotrifluoromethane 0-5% kg 2903.45.20 Pentachlorofluoroethane 0-5% kg 2903.45.30 Tetrachlorodifluoroethanes 0-5% kg 2903.45.40 Heptachlorofluoropropanes 0-5% kg 2903.45.50 Hexachlorodifluoropropanes 0-5% kg 2903.45.60 Pentachlorotrifluoropropanes 0-5% kg 2903.45.70 Tetrachlorotetrafluoropropanes 0-5% kg 2903.45.80 Trichloropentafluoropropanes 0-5% kg 2903.45.90 Other: 2903.45.91 Dichloridehexafluoropropanes 0-5% kg 2903.45.92 Chloroheptafluoropropanes 0-5% kg 2903.45.99 Other (No ODS) CONTROL kg 2903.46.00 Bromochlorodifluoromethane, bromotrifluoromethane and dibromotetrafluoroethanes 0-5% kg 2903.47.00 Other perhalogenated derivatives (No ODS) CONTROL kg Annex B Group I Halons Caribbean Community or CARICOM, unmixed substances 2903.49.00 Other: (Halogenated derivatives of acyclic hydrocarbons containing two or more different halogens) 2903.49.10 Derivatives of methane, ethane or propane, halogenated only with fluorine and chlorine (All Annex C Group I) 0-5% kg 2903.49.20 Derivatives of methane, ethane or propane, halogenated only with fluorine and bromine 0-5% kg 2903.49.90 Other (bromochloromethane) 0-5% kg 0-5% kg Halogenated derivatives of cyclanic, cyclenic or cycloterpenic hydrocarbons: 2903.51.00 1,2,3,4,5,6-Hexachlorocyclohexane (HCH, (ISO)), including lindane (ISO, INN) Caribbean Community or CARICOM, Mixtures headings 3813 and 3822 HS 2007 HEADING DESCRIPTION OF GOODS RATE OF DUTY UNIT(S) CONTROL kg 3813.00.00 Preparations and charges for fire-extinguishers; charged fireextinguishing grenades. 3814.00 Organic composite solvents and thinners, not elsewhere specified or included; prepared paint or varnish removers 3814.00.10 Thinners CONTROL kg 3814.00.90 Other CONTROL kg 3822.00.00 Diagnostic or laboratory reagents on a backing, prepared diagnostic or laboratory reagents whether or not on a backing, other than those of heading 30.02 or 30.06; certified reference materials. 0-5% kg Caribbean Community or CARICOM, Mixtures heading 3824. 3824.71.00 Containing chlorofluorocarbons (CFCs), whether or not containing hydrochlorofluorocarbons (HCFCs), perfluorocarbons (PFCs) or hydrofluorocarbons (HFCs) (Mixtures containing CFCs) 0-5% kg 3824.72.00 Containing bromochlorodifluoromethane, bromotrifluoromethane or dibromotetrafluoroethanes (Mixtures containing Halons) 0-5% kg 3824.73.00 Containing hydrobromofluorocarbons (HBFCs) (Annex C Group II) 0-5% kg 3824.74.00 Containing hydrochlorofluorocarbons (HCFCs), whether or not containing perfluorocarbons (PFCs) or hydrofluorocarbons (HFCs), but not containing chlorofluorocarbons (CFCs) (Mixtures containing HCFC) 0-5% kg 3824.75.00 Containing carbon tetrachloride 0-5% kg 3824.76.00 Containing 1,1,1-trichloroethane (methyl chloroform) 0-5% kg 3824.77.00 Containing bromomethane (methyl bromide) or bromochloromethane 0-5% kg 3824.78.00 Containing perfluorocarbons (PFCs) or hydrofluorocarbons (HFCs), but not containing chlorofluorocarbons (CFCs) or hydrochlorofluorocarbons (HCFCs) 0-5% kg 3824.79.00 Other (Mixtures containing halogenated derivatives of methane, ethane or propane) CONTROL kg Caribbean Community or CARICOM, Mixtures Subheading 3824. 3824.90.00 Others, (chemical products and preparations of the chemical or allied industries -including those consisting of mixtures of natural products-, not elsewhere specified or included). Should be monitored 5% kg Thank you!!! Lic. Juan Miguel Alter Ozone Programme Office Argentina