Using Chemical Formulas 7-3 Beaker Breaker 1. Name the following compounds: CaCl2 = ____________ P3O6 = _____________ FeCl2 =______________ H2SO4 =______________ Formula Masses • sum of the average atomic masses of all the atoms represented in a formula • (can be of a molecule, formula unit or ion) • Formula mass of H2O: • 2 (ave. atomic mass of H) +1(ave. at. mass of O) • = 2(1.01 amu) + 1(16.00 amu) • = 2.02 amu + 16.00 amu • = 18.02 amu Calculate the formula mass of the following: • • • • sulfuric acid calcium nitrate phosphate ion magnesium chloride • • • • • • • • sulfuric acid 98.09 amu H2SO4 calcium nitrate 164.10 amu Ca(NO3)2 phosphate ion 94.97 amu PO43magnesium chloride 95.21 amu MgCl2 Molar Masses • sum of the masses of the elements present in a mole of the molecules or formula units that make up a compound • Molar mass of water, H2O: • 1 mole H2O = 2 mol H + 1 mol O • 2 mol H x 1.01 g H = 2.02 g H 1 mol H • 1 mol O x 16.00 g = 16.00 g O 1 mol O 18.02 g • Molar mass of water = 18.02 g/mol What is the molar mass of… • aluminum sulfide • sodium nitrate • barium hydroxide What is the molar mass of… • • • • • • aluminum sulfide Al2S3 150.17 g/mol sodium nitrate NaNO3 85.00 g/mol barium hydroxide Ba(OH)2 171.35 g/mol Beaker Breaker 1. Name the following the compounds: CaBr2 =_______________ H3PO3 =_______________ C3I7 =_________________ CuCl3 = _______________ Gram-Mole Conversions Using Molar Mass as a conversion factor between “moles” ↔ “mass” • What is the mass, in grams, of 0.50000 moles of barium hydroxide? • Given: 0.500000 mol Ba(OH)2 • Find: g Ba(OH)2 • Know: 1 mol Ba(OH)2 =171.35 g Ba(OH)2 • 0.500000 mol Ba(OH)2 x 171.35 g Ba(OH)2 1 mole Ba(OH)2 • = 85.675 g Ba(OH)2 How many moles are in 6.60 g of ammonium sulfate? • Given: 6.60g (NH4)2SO4 • Find: 0.0499 mol (NH4)2SO4 • Know: 1 mol(NH4)2SO4 = 132.17 g (NH4)2SO4 • (NH4)2SO4 = 2(N) + 8(H) + 1(S) + 4(O) • = 2(14.01) + 8(1.01) + 1(32.07) + 4(16.00) • 132.17 g/mol • 6.60g (NH4)2SO4 x 1 mol(NH4)2SO4 132.17 g (NH4)2SO4 • = 0.0499 mol (NH4)2SO4 (4.99 x 10-2mol) Gram-Mole Conversions Remember…. 1 mole = 6.02 x 1023 “things” • How many molecules are in 50.0 g of water? • • • • • Given: 50.0 g H2O Find: molecules H2O Know: 1 mol H2O = 18.02g 1 mol H2O = 6.02 x 1023 molecules H2O 50.0 g H2O x 1 mol H2O x 6.02 x 1023 molecules 18.02 g H2O 1 mol H2O • = 1.67 x 1024 molecules H2O White Board Practice with Partners How many moles of compound are there in the following a. 6.60g (NH4)2SO4 b. 4,500g Ca(OH)2 Answers • A. 0.0500mol • B. 61mol White Board Practice with Partners • How many molecules are there in the following: a. 25.0g H2SO4 b. 125g of C12H22O11 Answers • A. 1.53 x1023 molecules • B. 2.20 x1023 molecules Beaker Breaker • 1. 2. 3. 4. Write the formulas of the following compounds Nitric Acid =___________ Hydroiodic acid =____________ Magnesium Fluoride =____________ Tetracarbon nonahydride =__________ Percentage Composition • % = part x 100 whole • percentage by mass of each element in a cmpd Find the % copper in copper(I) sulfide • % Cu = part Cu x 100 whole Cu2S • % Cu = mass of Cu in 1 mole of Cu2S x 100 mass of 1 mol of Cu2S Or...% Cu= mass of Cu in 1 mole of Cu2S x 100 molar mass of Cu2S • Cu2S = 159.17 g/mol (molar mass..on bottom) • 1 mol Cu2S, there are 2 mol Cu = 127.10 g Cu (top term) Know: Find the % copper in copper(I) sulfide • % Cu = mass of Cu in 1 mole of Cu2S x 100 mass of 1 mol of Cu2S • 1 mol of Cu2S = 159.17 g Cu2S • 1 mol of Cu2S= 2mol Cu = 2(63.546g)= 127.10g • = 127.10 g Cu x 100 159.17 g Cu2S • = 79.852% Cu in Cu2S What is the percent carbon in ammonium carbonate? Know: (NH4)2CO3 • % C = grams of C in 1 mol (NH4)2CO3 x 100 molar mass of (NH4)2CO3 • 1 mol (NH4)2CO3 = 1 mol C = 12.01 g C • 1 mol (NH4)2CO3 = 96.11 g (NH4)2CO3 12.01 g C x 100 96.11 g • = 12.50% C • = Beaker Breaker 1. Phosphoric acid can be used in orthodontics to roughen the surface of teeth before the placement of braces. Write the chemical formula for phosphoric acid. 2. Explain your method used to arrive to that answer. a. NH41+ Ammonium b.ClO3Chlorate c. OHHydroxide d.SO42Sulfate e. NO3Nitrate f.CO32Carbonate g. PO43Phosphate h. CH3COOAcetate i. HCO3Bicarbonate j. CrO42Chromate Homework Check Pg 236 #25 Mix Review Challenge Write the name or formula of the following: 1. MgSO3 =______________ 2. Sodium Hydroxide = __________ 3. Nickel (II) Fluoride =___________ 4. P2H3 =__________ Answers 1. 2. 3. 4. Magnesium Sulfite NaOH NiF2 Diphosphorus Trihydride Mix Review Challenge • Write the name or formula of the following: 5. Sulfurous acid =___________ 6. Copper (II) Chloride =_________ 7. AlPO4 =____________ 8. TetraSulfur Heptoxide =__________ Answers 5. H2SO3 6. CuCl2 7. Aluminum Phosphate 8. S4O7