and decays, Radiation Therapies and Diagnostic, Fusion and Fission This Lecture: Radioactivity, Nuclear decay Radiation damage, radiation therapies and diagnostic Evaluations for Prof. T. Montaruli today Previous lecture: nuclear physics Final Exam • Fri, Dec 21, at 7:45-9:45 am in Ch 2103 • About 40% on new material • 2 sheets allowed (HAND WRITTEN!) • The rest on previous materials covered by MTE1 MTE2 MTE3. New material not covered by MTE1,2,3 • Ch 40.4-5 particle in a box: wave functions, energy levels, photon absorption and emission, 40.10 tunneling • Ch 41.1-3 H-atom quantum numbers and their meaning, wave functions and probabilities, electron spin • Ch 41.4-6 Pauli exclusion principle, multi-electron atoms, periodic table, emission and absorption spectra • Ch 41.8 Stimulated emission and Lasers • Ch 42.1-3 Nuclear structure, atomic mass, isotopes, binding energy, the strong force • Ch 42.5 Radioactivity, Ch 42.6 Nuclear decay, Ch 42.7 Biological applications Women Nobel Prizes The only 2 female Nobel Prizes in Nuclear Physics! 1903 Marie Curie (with Pierre) in recognition of the extraordinary services they have rendered by their joint researches on the radiation phenomena discovered by Professor Henri Becquerel Maria Goeppert-Mayer 1963 Shell Model of Nucleus Nuclear Physics • Strong force: attractive force keeping p and n in nucleus (short range) • It is convenient to use atomic mass units to express masses – 1 u = 1.660 539 x 10-27 kg – mass of one atom of 12C = 12 u • Mass can also be expressed in MeV/c2 – From rest energy of a particle ER = mc2 – 1 u = 931.494 MeV/c2 12 C 6 • Binding energy: mnucleus < Zmp + (A-Z)mn = Zmp + Nmn • The energy you would need to supply to disassemble the nucleus into nucleons Ebinding = (Zmp+Nmn-mnucleus)c2 = (Zmp+Zme+Nmn+ -Zme-mnucleus)c2 =(ZmH + Nmn - matom) c2 5 Fission and Fusion 6 Stable and Unstable Isotopes Isotope = same Z Isotone = same N Isobar = same A Stability of nuclei • Dots: naturally occurring isotopes. • Blue shaded region: isotopes created in the laboratory. • Light nuclei are most stable if N=Z • Heavy nuclei are most stable if N>Z • As # of p increases more neutrons are needed to keep nucleus stable • No nuclei are stable for Z>83 Radioactivity • Discovered by Becquerel in 1896 • spontaneous emission of radiation as result of decay or disintegration of unstable nuclei • Unstable nuclei can decay by emitting some form of energy • Three different types of decay observed: Alpha decay emission of 4He nuclei (2p+2n) Beta decayelectrons and its anti-particle (positron) Gamma decayhigh energy photons Penetrating power of radiation • Alpha radiation barely penetrate a piece of paper (but dangerous!) • Beta radiation can penetrate a few mm of Al • Gamma radiation can penetrate several cm of lead Is the radiation charged? • Alpha radiation positively charged • Beta radiation negatively charged • Gamma radiation uncharged The Decay Rate • probability that a nucleus decays during Δt Prob(in t) rt Constant of proportionality r = decay rate (in s-1) • number of decays (decrease)= NxProb=rNΔt N=number of independent nuclei N rN t rt N(t) N0e # radioactive nuclei at time t # rad. nuclei at t=0 The number of decays per second is the activity N R rN t 1 r time constant The half-life • After some amount of time, half the radioactive nuclei will have decayed, and activity decreases by a factor of two. • This time is the half-life N0 N(t1/ 2 ) N0ert1/2 2 ln2 ln2 0.693 t1/ 2 r Units • The unit of activity, R, is the curie (Ci) – • The SI unit of activity is the becquerel (Bq) – • Therefore, 1 Ci = 3.7 x 1010 Bq • The most commonly used units of activity are the millicurie and the microcurie An Example • 232Th has a half-life of 14 x109 yr • Sample initially contains: N0 = 106 232Th atoms • Every 14 billion years, the number of 232Th nuclei goes down by a factor of two. N0 N(t1/ 2 ) N0ert1/2 2 N0 N0/2 N0/4 N0/8 Radiocarbon dating • 14C (Z=6) has a half-life of 5,730 years, continually decaying back into 14N (Z=7). • In atmosphere very small amount! 1 nucleus of 14C each 1012 nuclei of 12C If material alive, atmospheric carbon mix ingested (as CO2), ratio stays constant. After death, no exchange with atmosphere. Ratio changes as 14C decays So can determine time since the plant or animal died (stopped exchanging 14C with the atmosphere) if not older than 60000 yr Carbon dating A fossil bone is found to contain 1/8 as much 14C as the bone of a living animal. Using T1/2=5,730 yrs, what is the approximate age of the fossil? A. 7,640 yrs B. 17,190 yrs Factor of 8 reduction in 14C corresponds to three half-lives. C. 22,900 yrs So age is 5,730 x 3 =17,190 yrs D. 45,840 yrs Decay processes: = 4He Heavy nucleus spontaneously emits alpha particle • nucleus loses 2 neutrons and 2 protons. • It becomes a different element (Z is changed) Alpha particle • Example: 238 4 234 92 2 90 U He 92 protons 146 neutrons 2 protons 2 neutrons Th 90 protons 144 neutrons A quantum process • This is a quantum-mechanical process – It has some probability for occurring. • For every second of time, there is a probability that the nucleus will decay by emitting an particle. • This probability depends on the width of the barrier Coulomb repulsion • The -particle quantum-mechanicallydominates tunnels out of the nucleus even if energy is not > energy barrier Nuclear attraction dominates Potential energy of in the daughter nucleus vs distance Disintegration Energy • In decays energy-momentum must be conserved • The disintegration energy appears in the form of kinetic energy of products MXc2 = MYc2 + KY + M c2 + K EKY K = (Mx – My – M )c2 Textbook: neglect KY since M <<MYE=K ~ (Mx – My – M )c2 • It is sometimes referred to as the Q value of the nuclear decay Number of protons Decay sequence of 238U decay Number of neutrons Radon Zone 1 Highest Potential (greater than 4 pCi/L) uic kTimpre™ and a TI FF (QUncom essed ) decom pr esso r ar e needed t o see t his pict u r e. • Radon is in the 238U decay series uic kTimpre™ and a TI FF (QUncom essed ) decom pr esso r ar e needed t o see t his pict u r e. Zone 2 Moderate Potential (from 2 to 4 pCi/L) • Radon is an emitter that presents an environmental hazard • Inhalation of radon and its daughters can ionize lung cells increasing risk of lung cancer • Madison is in Zone 1! uic kTimpre™ and a TI FF (QUncom essed ) decom pr esso r ar e needed t o see t his pict u r e. QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. • In USA 20000 people die but a Geiger can help to identify problem in houses • Also used to predict Earthquakes! http://www.radonwisconsin.com/ Activity of Radon • 222Rn has a half-life of 3.83 days. • Suppose your basement has 4.0 x 108 such nuclei in the air. What is the activity? We are trying to find number of decays/sec. So we have to know decay constant to get R=rN r 0.693 0.693 2.09 106 s t1/ 2 3.83days 86,400s /day dN rN 2.09 106 s 4.0 108 nuclei 836decays/s dt 1Ci R 836 decays/s 0.023Ci 10 2.7 10 decays/s R Radiation damage The degree and type of damage caused by radiation depend on • Type and energy of the radiation • Properties of the absorbing matter Radiation damage in biological organisms is primarily due to ionization effects in cells that disrupts their normal functioning Alpha particles cause extensive damage, but penetrate only to a shallow depth Gamma rays can cause severe damage, but often pass through the material without interaction Other kind of radiations: eg. neutrons penetrate deeper and cause more damage. QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. Radiation Poisoning Killed Ex-Russian Spy The British authorities said today that A. V. Litvinenko, a former Russian Federal Security Service liutenant-colonel, and later dissident, died of radiation poisoning due to a rare and highly radioactive isotope known as Polonium 210. Highly radioactive metalloid discovered by M. Curie A N Isotopic mass (u) 210Po 84 126 209.98 T1/2 Activity (d) (uCi) 140 0.1 QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. Produced by bombarding bismuth-209 with neutrons in nuclear reactors. In the decay 210P creates 140 W/g so 1/2 a gram reaches 500 °C. Considered to power spacecrafts. Used in many daily applications: eg anti-static brushes in photographic shops Dangerous only if ingested because it is an emitter. Radiation Levels rad (radiation absorbed dose) = amount of radiation that increases the energy of 1 kg of absorbing material by 1 x 10-2 J Ground RBE (relative biological effectiveness = # of rads of X or gamma radiation that produces the same biological damage as 1 rad of the radiation being used rem (radiation equivalent in man) = dose in rem = dose in rad x RBE 0.30 rem/yr Mercury 9 60.6 rem/yr Apollo 14 146.2 rem/yr MIR Station 34.9 rem/yr Space Station 36.5 rem/yr QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. Upper limit suggested by US gov 0.50 rem/yr Beta decay • Nucleus emits an electron or a positron • Must be balanced by a positive or negative charge appearing in the nucleus. A Z A Z 1 X Y e A Z A Z 1 X Y 'e This occurs as a n changing into a p or a p into a n Example of -decay (radioactive form of carbon) decays by decay (electron emission). • Carbon Z = 6, 14C has (14-6)=8 neutrons. • A new element with Z = 7 • 14C 14 6 C 14 N e 7 Beta decay decreases number of neutrons in nucleus by one increases number of protons in nucleus by one We do not see it, but to explain this decay an antineutrino is needed The Positron and Antimatter • Every particle now known to have an antiparticle. • Our Universe seems to contain more matter (we are lucky otherwise everything would annihilate into photons!) Quic kT ime™ and a T IFF (Uncompres sed) decompres sor are needed to s ee this picture. Positron 1st detection in cosmic rays through bending in a Bfield and a bubble chamber (Anderson 1932) Decay Quick Question 20Na decays in to 20Ne, a particle is emitted? What particle is it? Na atomic number Z = 11 Ne Z = 10 A. B. C. D. Alpha Electron beta Positron beta Gamma 20Na has 11 protons, 9 neutrons 20Ne has 10 protons, 10 neutrons So one a proton (+ charge ) changed to a neutron (0 charge) in this decay. A positive particle had to be emitted. p n e e Nuclear Medicine: diagnostic • Basic Idea: – Inject patient with radioactive isotope (tracer) that decays in a positron – Positrons annihilate with electrons into gamma rays – Reconstruct the 3-D image Positron Emission Tomography image showing a tumor Positron Emission Tomography PET Gamma Photon #1 Nucleus (protons+neutrons) e+-e- electrons Basic Idea: – A short-lived radioactive tracer isotope emits a positron – Positron collides with a nearby electron and annihilates – e+ + e- 2 • Two 511 keV gamma rays are produced Gamma Photon #2 Isotope Max. Positron Range (mm) • They fly in opposite directions (to conserve momentum) 18F 2.6 11C 3.8 68Ga 9.0 82Rb 16.5 Emission Detection Ring of detectors • If detectors receive gamma rays at the approx. same time, we have a detection • Nuclear physics sensor and electronics Image Reconstruction • Each coincidence event represents a line in space connecting the two detectors along which the positron emission occurred. • Coincidence events can be grouped into projections images, called sinograms. • Sinograms are combined to form 3D images Cancer Radiation Therapy • 50-60% of cancer patients treated with radiation • Radiation destroys the cancer cells' ability to reproduce and the body naturally gets rid of these cells. • Although radiation damages both cancer cells and normal cells, most normal cells can recover from the effects of radiation and function properly. • Ionization (stripping atomic electrons) makes nuclear radiation dangerous Used radiations: • X and -rays (60Co) from 20 KV to 25 MV • Pion Therapy under study, less invasive then photons • Neutrons,protons,.. QuickTime™ and a TIFF (Uncompressed) decompressor are needed to see this picture. Gamma decay • Both and -decays can leave the nucleus in excited state • The nucleus can decay to a lower energy state (eg the ground state) by emitting a high energy photon (1 MeV-1 GeV) The X* indicates a nucleus in an excited state Decay Question? Which of the following decays is NOT allowed? U Th 1 238 92 234 90 2 214 84 210 82 3 14 6 4 2 Po Pb He C N 14 7 238 = 234 + 4 92 = 90 + 2 214 = 210 + 4 84 = 82 + 2 14 = 14+0 6 < 7+0