Tuesday Lecture – Sugar Reading: Textbook, Chapter 7, 8 Quiz Quiz 1. We use the name “potato” for two different food crops, the “Irish Potato” and the “Sweet Potato”. Which of these is a root and which is a stem? 2. What are the two major crops that serve as the source of sugar for people? 3. What plant is the topic of your plant project? Sweets – A Plant Specialty Sweets – A Plant Specialty Sugar – chemist = carbohydrate, formula CH2O Sweets – A Plant Specialty Sugar – chemist = carbohydrate, formula CH2O - many chemicals included in this category Sweets – A Plant Specialty Sugar – chemist = carbohydrate, formula CH2O - many chemicals included in this category Sugar – consumer – the specific sugar sucrose 2 units (disaccharide): glucose-fructose Sweets – A Plant Specialty Sugar – chemist = carbohydrate, formula CH2O - many chemicals included in this category Sugar – consumer – the specific sugar sucrose 2 units (disaccharide): glucose-fructose Monosaccharides: glucose, fructose Sweets – A Plant Specialty Sugar – chemist = carbohydrate, formula CH2O - many chemicals included in this category Sugar – consumer – the specific sugar sucrose 2 units (disaccharide): glucose-fructose Monosaccharides: glucose, fructose Note – terminology can get confusing here – mixture of chemical and colloquial terms: Glucose = d-Glucose = Dextrose Fructose + Glucose - bee sugar (in honey); “inverted” sugar Primary Plant Sources of Sugar sugar Sugar Cane – Saccharum officinarum 10% yield 10 tons/hectare Primary Plant Sources of Sugar sugar yield Sugar Cane – Saccharum officinarum 10% 10 tons/hectare Sugar Beet – Beta vulgaris 17% 7 tons/hectare Primary Plant Sources of Sugar sugar yield Sugar Cane – Saccharum officinarum 10% 10 tons/hectare Sugar Beet – Beta vulgaris 17% 7 tons/hectare Sorghum – Sorghum bicolor Palm – Phoenix dactylifera Primary Plant Sources of Sugar sugar yield Sugar Cane – Saccharum officinarum 10% 10 tons/hectare Sugar Beet – Beta vulgaris 17% 7 tons/hectare Sorghum – Sorghum bicolor Palm – Phoenix dactylifera Maple – Acer saccharum 8% (sap) Where Sugar is Produced Sugar Cane Saccharum officinarum – member of Poaceae (Grass family) Native to: Polynesia Harvesting Sugar Cane Refining Sugar Cane 1. Cane solids are separated from juice 2. Juice is processed to concentrate sugar 3. Syrup is boiled and sugar is crystallized Sugar Cane Products “Raw” Sugar – shipped to country where used, further refined there Sugar Cane Products “Raw” Sugar – shipped to country where used, further refined there Sugar Types: - standard crystals “regular” sugar (crystal size can vary) Sugar Cane Products “Raw” Sugar – shipped to country where used, further refined there Sugar Types: - standard crystals “regular” sugar (crystal size can vary) - ground crystals (+ cornstarch) powdered (confectioner’s) sugar Sugar Cane Products “Raw” Sugar – shipped to country where used, further refined there Sugar Types: - standard crystals “regular” sugar (crystal size can vary) - ground crystals (+ cornstarch) powdered (confectioner’s) sugar - crystals “glued” with sugar syrup sugar cubes Sugar Cane Products “Raw” Sugar – shipped to country where used, further refined there Sugar Types: - standard crystals “regular” sugar (crystal size can vary) - ground crystals (+ cornstarch) powdered (confectioner’s) sugar - crystals “glued” with sugar syrup sugar cubes - crystals mixed with syrup from refining brown sugar Sugar Cane Products “Raw” Sugar – shipped to country where used, further refined there Sugar Types: - standard crystals “regular” sugar (crystal size can vary) - ground crystals (+ cornstarch) powdered (confectioner’s) sugar - crystals “glued” with sugar syrup sugar cubes - crystals mixed with syrup from refining brown sugar - crystals mixed with glucose “blended” sugar (cheaper) Sugar Cane Products “Raw” Sugar – shipped to country where used, further refined there Sugar Types: - standard crystals “regular” sugar (crystal size can vary) - ground crystals (+ cornstarch) powdered (confectioner’s) sugar - crystals “glued” with sugar syrup sugar cubes - crystals mixed with syrup from refining brown sugar - crystals mixed with glucose “blended” sugar (cheaper) Byproducts: - Molasses - syrups of various types Sugar Cane – History Sugar Cane – domesticated in New Guinea (?) Sugar Cane – History Sugar Cane – domesticated in New Guinea (?) 2992 B.C. – unrefined sugar being produced in India Sugar Cane – History Sugar Cane – domesticated in New Guinea (?) 2992 B.C. – unrefined sugar being produced in India 642 A.D. – Arab-speaking peoples get sugar refining from Persia Sugar Cane – History Sugar Cane – domesticated in New Guinea (?) 2992 B.C. – unrefined sugar being produced in India 642 A.D. – Arab-speaking peoples get sugar refining from Persia 11th Century - Crusaders bring sugar to Europe (1099 in England) Sugar Cane – History Sugar Cane – domesticated in New Guinea (?) 2992 B.C. – unrefined sugar being produced in India 642 A.D. – Arab-speaking peoples get sugar refining from Persia 11th Century - Crusaders bring sugar to Europe (1099 in England) Medieval times – Sugar = White Gold (1319 - $220/lb in England) Sugar Cane – History Sugar Cane – domesticated in New Guinea (?) 2992 B.C. – unrefined sugar being produced in India 642 A.D. – Arab-speaking peoples get sugar refining from Persia 11th Century - Crusaders bring sugar to Europe (1099 in England) Medieval times – Sugar = White Gold (1319 - $220/lb in England) 1493 – Columbus takes sugar cane to West Indies Sugar Cane – History Sugar Cane – domesticated in New Guinea (?) 2992 B.C. – unrefined sugar being produced in India 642 A.D. – Arab-speaking peoples get sugar refining from Persia 11th Century - Crusaders bring sugar to Europe (1099 in England) Medieval times – Sugar = White Gold (1319 - $220/lb in England) 1493 – Columbus takes sugar cane to West Indies 1700’s – American “Sugar Triangle” (sugar, rum, slaves) Sugar Cane – History Sugar Cane – domesticated in New Guinea (?) 2992 B.C. – unrefined sugar being produced in India 642 A.D. – Arab-speaking peoples get sugar refining from Persia 11th Century - Crusaders bring sugar to Europe (1099 in England) Medieval times – Sugar = White Gold (1319 - $220/lb in England) 1493 – Columbus takes sugar cane to West Indies 1700’s – American “Sugar Triangle” (sugar, rum, slaves) 1700’s – Sugar taxation Revolution Sugar Cane – History Sugar Cane – domesticated in New Guinea (?) 2992 B.C. – unrefined sugar being produced in India 642 A.D. – Arab-speaking peoples get sugar refining from Persia 11th Century - Crusaders bring sugar to Europe (1099 in England) Medieval times – Sugar = White Gold (1319 - $220/lb in England) 1493 – Columbus takes sugar cane to West Indies 1700’s – American “Sugar Triangle” (sugar, rum, slaves) 1700’s – Sugar taxation Revolution 1800’s – Sugar beet provides competition in temperate areas Currently: sugar production subsidized, taxed, politicized Napoleon Sweetens the Pot – Sugar Beet Beta vulgaris – Chenopodiaceae (Goosefoot Family) Sugar Beet Processing Lewistown, Idaho Sugar Factory, 1905 Caption to Photo: 10 year old boys can be very useful Where Sugar is Produced North American Sweetener Acer saccharum – Sugar Maple Maple Syrup Sap is collected in early spring Sap is boiled in “sugar house” 40 gallons sap 1 gallon syrup Glucose, Fructose - C6H12O6 glucose fructose fructose - “chair” sucrose Glucose, Fructose - C6H12O6 glucose fructose fructose - “chair” sucrose Starch - amylose Glucose, Fructose - C6H12O6 glucose fructose fructose - “chair” sucrose High Fructose Corn Syrup 1. Starch from Corn 2. Treat with alpha-amylase oligosaccharides 3. Treat with glucoamylase glucose 4. Treat with glucose isomerase mixture of glucose and fructose 5. Enrichment, “back-blending” to produce final product Starch - amylose Glucose, Fructose - C6H12O6 glucose fructose fructose - “chair” sucrose High Fructose Corn Syrup 1. Starch from Corn 2. Treat with alpha-amylase oligosaccharides 3. Treat with glucoamylase glucose 4. Treat with glucose isomerase mixture of glucose and fructose 5. Enrichment, “back-blending” to produce final product Starch - amylose Non-caloric Sweeteners from Plants Glycyrrhizin – from licorice root (Glycyrrhiza, a legume) - Used originally to make licorice candy - 30 x as sweet as table sugar - more than limited consumption has health effects - potential as an herbal medicine in anti-cancer treatments Non-caloric Sweeteners from Plants Glycyrrhizin – from licorice root (Glycyrrhiza, a legume) - Used originally to make licorice candy - 30 x as sweet as table sugar - more than limited consumption has health effects - potential as an herbal medicine in anti-cancer treatments Stevia – from sweetleaf plant, Stevia - Widespread use in Japan - regulatory issues, starting to be used elsewhere Non-caloric Sweeteners from Plants Glycyrrhizin – from licorice root (Glycyrrhiza, a legume) - Used originally to make licorice candy - 30 x as sweet as table sugar - more than limited consumption has health effects - potential as an herbal medicine in anti-cancer treatments Stevia – from sweetleaf plant, Stevia - Widespread use in Japan - regulatory issues, starting to be used elsewhere Miraculin – protein from miracle fruit, Synsepalum - Not sweet, but modifies taste receptors so foods are sweet Tuesday March 8 – optional assignment. Due Tuesday March 22. Write a brief paragraph, using proper English grammar, that explains: What was the “Sugar Trade Triangle” - what were the major elements (both geographical and trading items)? How did it impact the history of the U.S.A.?