DIMENSIONAL ANALYSIS Chapter 5, Section 3A LET’S REVIEW THE METRIC SYSTEM In General: Kilo = 1000 of base Deci = 0.1 of base Centi = 0.01 of base Milli = 0.001 of base Example: Kilometer = 1000 m Meter = base unit Decimeter = 0.1 m Centimeter = 0.01 m Millimeter = 0.001 m CONVERTING UNITS OF MEASUREMENT You convert units of measurement in your everyday life. How would you convert from minutes to seconds? 1 minute = 60 seconds Doing unit conversions in chemistry is no dif ferent, we just call it dimensional analysis. Hint: Unit conversions are exact numbers, so the only sig figs you count are the ones in your original number In chemistry, we use conversion factors, a ratio used to convert from unit to another. I will give you non-metric conversion factors. Ex grams to pounds As a conversion factor, minutes to seconds would be written like this: 60 seconds 1 minute STEPS FOR CONVERTING UNITS 1. Identify the unit you are starting in, and identify the unit you need to convert to. 2. Choose the appropriate conversion factor(s) to get from your starting unit to your ending unit. 3. Set-up your problem, so your units are easily compared and canceled 4. Multiply the top, multiply the bottom, divide the top by the bottom MINUTES TO SECONDS How many seconds are in 5 minutes? 1. Starting units: minutes, ending units: seconds 2. Conversion factor: 60 seconds/ 1 minute 3. Set-up: 5 minute 60 seconds 1 minute 4. Multiply top: 5 x 60 = 300, Multiply bottom: 1 , Divide top by bottom: 300/1 = 300 seconds, this answer already has the correct number of sig figs METRIC CONVERSIONS How many meters are in 300 centimeters? 1. Starting units: centimeters, Ending units: meters 2. Conversion factor: 0.01 m = 1 cm, or 100 cm = 1 m 3. Set-up: 300 centimeter 1 meter 100 centimeter 4. Multiply top: 300 x 1 = 300, Multiply bottom: 100, Divide top by bottom: 300/100= 3 meters, this answer already has the correct number of sig figs 2 CONVERSION PROBLEMS For some dimensional analysis problems you will have to use 2 conversion factors to get to an answer. But you still use the same steps! Let’s look at an example: How many seconds are in 4 hours? 1. Starting units: hours, Ending units: seconds 2. Conversion factors: 60 minutes = 1 hour, 60 seconds = 1 minute 3. Set-up: 4.0 hours 60 minutes 60 seconds 1 hour 1 minute 4. Multiply the top: 4 x 60 x 60 = 14400, Multiply the bottom: 1 x 1 = 1 , Divide top by bottom: 14400/1 = 14400 seconds, sig fig answer 14000 seconds 2 CONVERSION PROBLEMS How many yards are in 250 centimeters? Hint: 1 m = 1 .094 yds 1. Starting units: centimeters, Ending units: yards 2. Conversion Factors: 100 cm = 1 m, 1 m = 1 .094 yds 3. Set-up: 250.0 cm 1m 1.094 yds 100 cm 1m 4. Multiply the top: 250 x 1 x 1 .094 = 273.5, Multiply the bottom: 100 x 1 = 100, Divide the top by the bottom: 273.5/100 = 2.735 yards, this answer already has the correct number of sig figs PRACTICE TIME! Try practicing dimensional analysis on your own on the worksheet. This worksheet will be a part of your homework packet. MULTI-STEP CONVERSION PROBLEMS Many dimensional analysis problems will have more than 2 conversions. However, you follow the same steps The length of a marathon is 26.2 mi. What is this distance in kilometers? Hint: 1 mi = 1760 yds, 1 m = 1 .094 yd 1. Starting units: miles, Ending unit: kilometers 2. Conversion factors: 1 mi = 1760 yds, 1 m = 1 .094 yd, 1 km= 1000 m 3. Set-up: 26.2 mi 1760 yd 1m 1 km 1 mi 1.094 yd 1000 m 4. Multiply top: 26.2 mi x 1760 yd x 1 m x 1 km = 46112, Multiply bottom: 1 mi x 1 .094 yd x 1000 m = 1094, Divide top by bottom: 46112/1094 = 42.1 km (correct sig figs) MULTI-STEP CONVERSION How many seconds are in 25 days? 1. Starting unit: days, Ending unit: seconds 2. Conversion factors: 1 day = 24 hrs, 1 hr = 60 min, 1 min = 60 sec 3. Set-up: 25 days 24 hrs 60 min 60 sec 1 day 1 hour 1 min 4. Multiply the top: 25 x 24 x 60 x 60 = 2160000, Multiply the bottom: 1 x 1 x 1 = 1 , Divide top by the bottom: 2160000/1 = 2160000 seconds, sig fig answer: 2200000 WHAT ABOUT MEASUREMENTS WITH 2 UNITS? Some measurements, like density (g/mL), have two units. You can still use dimensional analysis to convert one or both of the units present. You will still use the same steps, but your set -up will be longer and you have to be more careful about canceling your units. For your conversion factors, I recommend separating them into the units you need to use for the top unit and the bottom unit Let’s look at a few examples 2 UNIT CONVERSIONS Race cars routinely travel at an average speed of 225 mi/hr. What is the speed in km/ hr? Hint: 1 mi = 1760 yd, 1 m = 1 .094 yd 1. Starting units: mi/hr, Ending units: km/hr, Note: hours is the same in both 2. Conversion factors: 1 mi = 1760 yd, 1 m = 1 .094 yd, 1000 m = 1 km 3. Set-up: 225 mi 1760 yd 1m 1 km hr 1 mi 1.094 yd 1000 m 4. Multiply top: 26.2 mi x 1760 yd x 1 m x 1 km = 46112, Multiply bottom: 1 mi x 1 .094 yd x 1000 m = 1094, Divide top by bottom: 46112/1094 = 42.1 km/ hr (correct sig figs) 2 UNIT CONVERSIONS Silver has a density of 10.5 g/cm3; what is the density of silver in kg/L? 1. Starting units: g/cm3, Ending units: kg/L, Note: you have to convert both units 2. Conversion factors: Top unit: 1000 g = 1 kg, Bottom unit: 1 cm3 = 1 mL, 1000 mL = 1 L 3. Set-up: 10.5 g 1 kg 1 cm3 1000 mL cm3 1000 g 1 mL 1L 4. Multiply the top: 10.5 x 1 x 1 x 1000 = 10500, Multiply the bottom: 1 x 1000 x 1 x 1= 1000, Divide top by the bottom: 10500/1000= 10.5 kg/L. 2 UNIT CONVERSIONS You are driving at 50 mi/ hr; how fast are you going in m/s? Hint: 1 mi = 1760 yd, 1 m = 1 .094 yds 1. Starting units: mi/hr, Ending units: m/s 2. Conversion Factors: Top unit: 1 mi = 1760 yd, 1 m = 1 .094 yd, Bottom unit: 1 hr = 60 min, 1 min = 60 s 3. Set-up: 50 mi 1760 yd 1m 1 hr 1 min hr 1 mi 1.094 yd 60 min 60 sec 4. Multiply the top: 50 x 1760 x 1 x 1 x 1= 88000, Multiply the bottom: 1 x 1 .094 x 60 x 60= 3938.4, Divide the top by the bottom: 88000/3938.4= 22 m/s LET’S PRACTICE This worksheet is great practice for the skills we learned today and yesterday. Use this worksheet to gauge your understanding of dimensional analysis This worksheet will be a part of your homework packet due on the day of the test.