Have out for today • Your periodic table • Your scientific calculator 9.1 Mole Ratios • Now that we know what a balanced equation means, we can use an equation to predict the moles of products that a given number of moles of reactants will yield. • For example: 2H20(l) 2H2(g) + O2(g) 2 mol H2O yields 2 mol H2 and 1 mol O2 So what if… I start with… 2H20(l) 2H2(g) + O2(g) Then instead of 2 mol, I have 4 mol of H2O…how many mol of each product do I get? 4 2(g) + __O 2 2(g) 4H20(l) __H Now suppose… Given the same equation 2H20(l) 2H2(g) + O2(g) If we decompose 5.8 mol of water, how many moles of products are formed? Start with O2. Let’s use a mole ratio – ratio of moles of one substance to moles of another substance in a balanced chemical equation 2H20(l) 2H2(g) + O2(g) 2 mol H2O = 1 mol O2 forms 2 conversions factors: 1 mol O2 2 mol H2O and 2 mol H2O 1 mol O2 Start with the number given in the problem 5.8 mol H2O 1 mol O2 2.9 mol O 2 1 2 mol H2O And since… 2H20(l) 2H2(g) + O2(g) …the ratio of water to hydrogen is 2 mol H2 1 mol H2 2 mol H2O 1 mol H2O the amount of H2 produced is 5.8 mol. So try this. • Calculate the number of moles of oxygen required to react exactly with 4.3 mol of propane, C3H8, in the reaction described by the following balanced equation. C3H8 (g) + 5O2(g) 3CO2(g) + 4H2O(g) 4.3 mol C3H8 ?? mol O2 4.3 mol C3H8 5 mol O2 21.5 mol O2 1 1 mol C3H8 Last example • Ammonia is used in huge quantities as a fertilizer. It is manufactured by combining nitrogen and hydrogen according to the following equation: N2(g) + 3H2(g) 2NH3(g) Calculate the moles of ammonia that are produced from 1.3 mol of hydrogen reacting with excess N2 1.3 mol H2 2 mol NH3 0.867 mol NH3 1 3 mol H2 One Step Stoichiometry Worksheet 9.2 Mass calculations Consider the reaction of powdered Al and finely ground iodine to produce aluminum iodide. Al(s) + I2(s) AlI3(s) What mass of iodine is needed to react with 35.0 g solid aluminum? FIRST: be sure the equation is balanced. 2Al(s) + 3I2(s) 2AlI3(s) Because the balanced equation deals with moles instead of grams • SECOND – convert 35.0 grams of aluminum to mol of aluminum 35.0 g Al 1 mol Al 1.30 mol Al 26.8 g Al 1 THIRD – Use the coefficients to determine the mole ratio required to go from mol of Al to mol I2 and convert. 1.3 mol Al 3 mol I2 1.95 mol I2 1 2 mol Al Mole ratio Last step! FOURTH – Convert the number of moles of I2 into grams. 1.95 mol l2 253.8 g l2 mol I2 1 495 g l2 So…given 2Al(s) + 3I2(s) 2AlI3(s) It takes 495g of I2 to react with 35.0g of Al Now, given the same reaction… 2Al(s) + 3I2(s) 2AlI3(s) Find the mass of AlI3(s) formed by the 35g of Al(s) with 495g of I2(s). 35.0 g Al 1 mol Al 1 mol AlI3 407.68 g AlI3 26.8 g Al 1 mol Al 1 1 mol AlI3 530 g AlI3 Homework • Section 9.2 review – # 2,4 & 6 only! • Due tomorrow!!! I will not accept this late for credit!