Introduction ; SK Group, SKC 1. SK Group A powerful company that is creating a happy society with the backing of people’s trust • SKC, SK Corp., SK Chemicals, SK Gas, SK E&S • SK Telecom, SK C&C, SK Telink, SK Telesys • SK Networks, SK E&C, SK Shipping, Sheraton Walkerhill • 2004 Total Sales : US$ 53,745 million ; - Energy&Chemicals 42%, Telecommunications 27%, Trading&Service 31% - The 4th biggest Group in Korea 2. Group History SK Launches the Initiative “From Petroleum to Fibers” Focusing on Export, SK reaches the $100-million mark SK aggressively expands its energy and chemicals businesses SK makes major advances in the telecommunications industry SK Shifts its core businesses to IT and life science 1953 Sunkyong Textiles was founded 1976 Sunkyong Textiles change its name to Sunkyong Ltd. and become a general trading company 1980 Yukong Ltd. was acquired. Other related companies were added : Yukong Line, Yukong Gas etc. 1994 SK assumed management of Korea Mobile Telecom, which becomes SK Telecom on 1997 2000 SK Telecom was licensed to provide asynchronous (W-CDMA) IMT-2000 service 1989 SKC produced Magneto-Optical disks, the 4th company in the world 1993 SKC became the 1st company in Korea to produce laser discs 1969 Sunkyung Fibers was founded, Produce polyester filament yarn 1978 SKC became the 4th company in the world to develop polyester film SKEC was founded 1996 SK Telecom became the first organization in the world to commercialize super-clear CDMAbased digital wireless telephone service 2001 SKC and SK Evertec merged. SK Evertec became SKC Co., Ltd. 2003 SK Group celebrated its 50th anniversary 2004 SK Telecom launched the world's first satellite for DMB service SK Global (former Sunkyong Ltd.) changed its corporate name to SK Networks 3. SKC Co., Ltd. History 1976 1978 1980 1986 1999 2001 2002 2004 SKC founded Introduction of polyester films for the 1st time in Korea (With currently 4th market share in the global market) Development of video tapes for the 1st time in Korea Manufacturing of CD for the 1st time in Korea. Developed mass media products with the latest technology such as MOD, MD, DAT, and CD-R Completion of local plants in China and Georgia Initiated mobile communication and information technology business. Merging with SK Evertech, a precision chemistry corporation and developed TFT LCD and materials and continued to develop the core displaying products Manufacturing lithium ion polymer batteries for mobile communication devices. R&D in IT products such as PDP color filter Start to produce PI film for the 1st time in Korea. SKC Co., Ltd. (as of 2004) Sales ; USD 1,270million Total Assets ; USD 1,377million Employees ; 2,496 4. SKC Business Fields Division Product Business Start 2004 Sales Competitive Power Film PET Film PEN Film PI Film 1978 USD 260 million 1st in Korea 3rd~4th in the world Mobile Material LIPB 2003 Display Material Films for LCD PDP Filter 1998 Mobile Device Handset 2001 USD 324 million ‘SKY’ Whole Supply to SK Teletech Chemical PO, PG, SM 2001 (Merge) USD 415 million PO, PG Sole Supplier of Korea Market 1st Class in Korea USD 272 million 1st in the world 6 5. SKC Global Network 6 1 25 4 7 83 Domestic Offices Overseas Manufacturing Line Overseas Offices 1 Seoul Head Office : Seoul Suwon Plant : Polyester Film & R&D Center Jinchon Plant : PI Film Chonan Plant : Media, Specialty Film etc. 2 China Suzhou Plant : Specialty Film China Huizhou Plant : Specialty Film China Tongling Plant : Polyester Film 3 US Georgia Plant : Polyester Film 4 Taiwan Taipei Office 5 China Guangzhou Office China Shanghai Office 6 Europe(Germany) Frankfurt Office 7 Japan Tokyo Office 8 SKC Inc. : US Georgia 7 6. SKC Film Division Seoul Head Office Kyobo Tower, 1303-22, Seocho 4-dong, Seocho-gu Seoul 137-070, Korea Suwon Plant : PET Film, PEN Film, PI Film (#0) 633 Chongja-dong, Changan-gu, Suwon-si, Kyonggi-do, 440-300, Korea Suwon Film R&D Center 911 Chongja-dong, Changan-gu, Suwon-si, Kyonggi-do, 440-300, Korea Georgia Plant : PET Film SKC Inc. One SKC Drive Covington, GA 30014, U.S.A Jincheon Plant : PI Film (#1~ ) 766 Nowon-ri, iwol-myeon, Jincheon-gun, Chungcheongbuk-do, 365-822, Korea 8 SKC Polyimide Film 9 1. SKC PI film History 2001 Start the polyimide film R&D 2002 Participate in the government’s polyimide R&D project with KRICT (Korea Research Institute of Chemical Technology) 2003 Place order of 1st PI production line (#0) 2004 PI film #0 line installed, start operation Succeed in 1st production of SKC PI film 2005 Finish IN, IF type development (1/2mil~1mil) Place an order for #1 mass production line 1st commercial sales of SKC PI film 2006 Finish IS type development 10 2. Polyimide Chemistry Polyimide O O Ar O O O O + H2N R NH2 N O O Ar O N + R 2H2O O n Dianhydride Diamine Polyimide Standard Type O O H2N O O O O NH2 + O N O PMDA ODA (Pyromellitic Dianhydride) (Oxy Dianiline) O ※ Alternative Commercial Dianhydride : BPDA (Biphenyltetracarboxylic Dianhydride) ※ Alternative Commercial Dianiline : PPD (p-Phenylene Diamine) O N O O n Polyimide 11 3. Manufacturing Process Dianhydride Diamine Solvent Polymerization Varnish Storage Drying Casting Curing Winding Annealing Corona Slitting & Packaging 12 4. SKC PI Film Type Type Description Competitors Thickness IN70 • Good Flexibiliry • Annealed and both side corona treated Kapton VN 1/2 ~ 1 mil (12.5~25㎛) IF70 • Good Dimensional Stability • Annealed and both side corona treated Apical NPI 1/2 ~ 1 mil (12.5~25㎛) IS70 • Much better dimensional stability and modulus • For 2-L FCCL Kapton EN 1.5 mil (38㎛) 13 5. Property Comparison (1) IN70 Mechanical Thermal Electrical Chemical ※1) ※ ※ Property Unit Dupont Kapton VN Kaneka Apical AH SKC IN70 Thickness ㎛ 25 25 25 Specific Gravity g/㎤ 1.42 1.42 1.42 Tensile Strength kgf/㎟ 24 25 28 Elongation % 72 100 91 Modulus kgf/㎟ 255 330 336 HS (2hr at 200℃) % 0.03※1) 0.08 0.05 CTE (100~200℃) ppm/℃ 32 32 30 Dielectric Strength ㎸/㎜ 300 320 300 Volume Resistivity Ω ·㎝ >1017 >1015 >1016 Dielectric Constant - 3.4 3.2 3.4 Moisture Absorption % 2.8 2.5 2.5 Measurement Condition : 30min at 150℃ Competitor’s Data : From their catalogues and home pages SKC’s Data : Measured data 14 5. Property Comparison (2) IF70 Mechanical Thermal Electrical Chemical ※ ※ Property Unit Kaneka Apical NPI SKC IF70 Thickness ㎛ 25 25 Specific Gravity g/㎤ 1.45 1.45 Tensile Strength kgf/㎟ 31 31 Elongation % 90 85 Modulus kgf/㎟ 420 460 HS (2hr 200℃) % 0.06 0.03 CTE (100~200℃) ppm/℃ 16 16 Dielectric Strength ㎸/㎜ 320 300 Volume Resistivity Ω ·㎝ >1015 >1016 Dielectric Constant - 3.2 3.4 Moisture Absorption % 2.5 2.5 Competitor’s Data : From their catalogues and home pages SKC’s Data : Measured data 15 6. SKC PI film Property (1) Thickness Variation Property Unit SKC Kapton Taimide Thickness Variation (Max.-Min.) ㎛ 1.0 0.9 3.0 Thickness Profile R(㎛) SKC 1.0 Kapton 0.9 Taimide 3.0 Wanda 4.5 16 6. SKC PI film Property (2) Surface (1) SKC Kapton Apical Before Corona Treatment After Corona Treatment HN VN NPI Contact Angle 67 27 68 38 35 Surface Tension 44 dyne/cm 68 dyne/cm ↑ 46 dyne/cm 66 dyne/cm 68 dyne/cm ↑ Contact Angle Picture 17 6. SKC PI film Property (3) Surface (2) Change with lapse of time Right after corona treatment 10 weeks after Contact angle 26 42 Surface Tension (dyne/㎝) 68 dyne/cm ↑ 64 dyne/cm Contact Angle Surface Energy 80.0 60.0 Inner Outer Surface Tension 40.0 20.0 70.0 60.0 50.0 0.0 Time 0 we ek 2 we ek 3 we 4 ek we ek 5 we ek 6 we ek 7 we 8 ek we 9 ek we 10 ek w 11 eek w e 12 ek w e 13 ek w ee k 1 0 we ek 2 we ek 3 we ek 4 we ek 5 we ek 6 we ek 7 we ek 8 we ek 9 we 10 ek w e 11 ek w e 12 ek w e 13 ek w ee k 40.0 1 Contact Angle Inner Outer Time 18 7. SKC PI Film Business Plan (1) Production Suwon #0 Jincheon #1 Jincheon #2 2004.10. 2006.06. Early of 2008 ㎡ 100,000 ㎡/M 700,000 ㎡/M (800,000 ㎡/M) 1,400,000 ㎡/M (2,200,000 ㎡/M) Ton 40 Ton/Y 300 Ton/Y (340 Ton/Y) 600 Ton/Y (940 Ton/Y) 520㎜ (Max. 580㎜) 250 ~ 1040㎜ (Max. 1,560㎜) 250 ~ 1040㎜ (Max. 2,080㎜) Start Capacity (Accumulated) Product width Available Thickness ※ Standard width is 520㎜, but available as customer’s demand ※ Providing by “inch” is possible 12.5~125㎛ 12.5~75㎛ 12.5~75㎛ • SKC will increase the production line to 5 lines until 2010. • The capacity will be more than 2,000 Ton/Y in 2010. 19 7. SKC PI Film Business Plan (2) R&D Type Application Status & Plan IN 3-L FCCL, Motors, Generators, PST Completed IF 3-L FCCL Completed IS 2-L FCCL, COF Will be completed in the 1st Qtr of 2006 UL UL94 Type In the process UL746B Thickness Grade Schedule Grade Schedule IN## 25㎛ V-0 05.12 200℃ 06.02 IN## 12.5~75㎛ V-0 06.02 200℃ 06.06 IF## 12.5~75㎛ V-0 06.02 200℃ 06.06 Plan 20 Conclusion • 30 year old plastic film expert “SKC” starts to supply Pl film in the name of “SKC PI film” with its accumulated and advanced technology • SKC has invested vastly in the PI film R&D for 5 years, and can supply fast and proper technical support satisfying customer’s demands • SKC will invest continuously in PI film business and will grow up as a major global player in the near future • With SKC PI film, you’ve got the best quality of products and services. Your best choice is SKC Customer OK! SKC 21