Training Session on Energy Equipment Industry Sectors Presentation to Energy Efficiency Guide for Industry in Asia Chapter 15 1 © UNEP GERIAP Training Agenda: Industry Sectors 1) Iron & Steel 3) Cement • Sector description • Process flow • Energy conservation • Sector description • Process flow • Energy conservation 2) Chemical 4) Pulp & Paper • Sector description • Process flow • Energy conservation • Sector description • Process flow • Energy conservation 2 © UNEP 2005 Iron & Steel Industry Sector Description Two categories: 1. Primary steel production • Manufactured right from the basic iron and steel ore to final product 2. Secondary steel production • Conversion metal scrap, ignots and metal scraps manufactured through various routes 3 © UNEP 2005 Iron & Steel Industry Process Flow Basic primary steel process • High grade iron ore is crushed for sizing and to produce both fine and lump ore • Pelletizing is a process that mixes very fine ground particles of ore with limestone, dolomite etc Figure: Primary steel making4 process Source: JFE © UNEP 2005 Iron & Steel Industry Process Flow Basic secondary steel process • Raw material • Re-heating furnace • Melting • Rolling mill • Refining • Cooling • Casting • Shearing • Rolling • Inspection dispatch • Re-rolling 5 © UNEP 2005 Iron & Steel Industry Process Flow Steel foundry • Can be classified into a) melting, b) moulding, c) fettling and d) heat treatment Arc furnace • Melting of scrap by application of intense heat generated by the arc Induction furnace • Transfers energy through a magnetic field and its 6 intensity decides the amount of absorbed energy © UNEP 2005 Iron & Steel Industry Process Flow Energy flows Raw material • Rolling Electricity • Thermal energy Fuel Electricity Cutting Reheating Furnace • Electrical energy Electricity Rolling • Steel foundry Electricity Cooling • Arc melting Electricity Shearing • Induction melting Finished Product Figure: Energy flow in rolling 7 © UNEP 2005 Iron & Steel Industry Process Flow Material & energy balance 8 Figure: Energy balance in reheating furnace © UNEP 2005 Iron & Steel Industry Energy Conservation Opportunities CP-EE measures: 9 Figure: Reheating furnace © UNEP 2005 Iron & Steel Industry Energy Conservation Opportunities CP-EE measures in reheating: Table: CP-EE measures in reheating and heat treatment furnaces Improvement Area Energy-Saving Measure Energy Saving Potential Efficient Combustion Maintain minimum required free oxygen in combustion products. 2% to 10% Efficient Combustion (burners) Eliminate formation of excessive amount of CO or unburned hydrocarbons. Also eliminate or minimize air leak-age. 2% to 10% Flue Gas Heat Recovery Preheat and/or dry combustion air and the charge/load. After-burn the combustibles and cascade the exhaust gas heat. 5% to 25% Heat Loss Reduction Use optimum insulation for equipment and maintain it regularly. Employ furnace pressure control. 1% to 5% 10 © UNEP 2005 Iron & Steel Industry Energy Conservation Opportunities CP-EE measures in reheating: Table: CP-EE measures in reheating and heat treatment furnaces Improvement Area Energy-Saving Measure Energy Saving Potential Design of Furnaces and Heating Select proper burner and furnace design to enhance heat transfer to the load. 5% to 10% Furnace Operation Clean heat transfer surfaces frequently. 5% to 10% Furnace and Heating System Heat Transfer Replace indirect heat systems with direct heat systems where possible. 5% to 10% Improved Scheduling and Load Management Operate with full load; minimize idle time, shutdowns, and start-up cycles. 2% to 5% Use of Process Simulation Use models to optimize temperature settings to avoid long "soak" times or overheating. 5% to 10% Equipment Design Materials Use advanced and improved materials. 11 2% to 5% © UNEP 2005 Iron & Steel Industry Energy Conservation Opportunities CP-EE measures in arc furnace melting: • • • • Scrap preparation Scrap segregation Use of oxygen lancing Temperature control CP-EE measures in induction melting: • • • • Idling periods Charge metals Optimizing heel Radiation losses 12 © UNEP 2005 Iron & Steel Industry Energy Conservation Opportunities Energy efficient technologies: • Melting • Ceramic recuperator • Ceramic fiber • Ceramic coatings • Regenerator 13 © UNEP 2005 Iron & Steel Industry Energy Conservation Opportunities Energy efficient technologies: Figure: Regenerative burner system operating principle 14 © UNEP 2005 Training Agenda: Industry Sectors 1) Iron & Steel 3) Cement • Sector description • Process flow • Energy conservation • Sector description • Process flow • Energy conservation 2) Chemical 4) Pulp & Paper • Sector description • Process flow • Energy conservation • Sector description • Process flow • Energy conservation 15 © UNEP 2005 Chemical Industry Sector Description • Production of graphite for brake linings and lubricants, chemical catalysts for plastics, elastomers and pharmaceuticals and more • Most chemical applications require spray drying or milling why particle size is important • Most milling processes comprise a grinder, a classifier, a cyclone and a blower • The formed material size needs to be measured 16 © UNEP 2005 Chemical Industry Process Flows Fertilizer industry • 85% of the world’s ammonia production is used for making chemical fertilizer • Fertilize production accounts for 2% of total global energy consumption • Fertilize production accounts for 1% of global carbon dioxide emissions • Ammonia manufacture is expensive and is about 70-80% of the production costs • Natural gas is the most commonly used hydro17 carbon feedstock for new fertilizer plants © UNEP 2005 Chemical Industry Process Flows Primary reforming • The natural gas that leaves the desulphurization tank is mixed with process steam • It is preheated in the primary reformer Secondary reforming • Only 30-40% of the hydrocarbon feed is reformed in the primary reformer • In a secondary, the temperature is increased to increase conversion 18 © UNEP 2005 Chemical Industry Process Flows Energy balance • Compared to natural gas, ammonia manufacturing with heavy oil is 30-40% more energy intensive and with coal route 80% more • Steam reforming ammonia plants have surplus heat available for steam production and modern plants can be energy self sufficient • The theoretical minimum energy consumption for ammonia manufacture through steam reforming is ~21.6 GJ/t of ammonia (HHV) 19 © UNEP 2005 Chemical Industry Process Flows Natural gas ZnS Material balance Sulphur Removal ZnS H2O, Fuel Reformer (Primary) Air, Power Reformer (Secondary) Heat Shift conversion Heat • Emissions from Heat, Power ammonia plants include SO2, NOx, CO, CO2, VOCs, particles, hydrogen sulfide, Power methane, Power hydrogen cyanide and ammonia Carbon dioxide Removal Condensate CO2 Methanation Compression Ammonia synthesis NH3 20 Figure: Material balance for an ammonia plant © UNEP 2005 Chemical Industry Energy Conservation Opportunities Areas for CP-EE measures in ammonia plants: • Primary reformer • Shift conversion • Excess air reforming • • Heat exchange auto terminal reforming Carbon dioxide removal section • Leakage of CO2 from compressors • Flue gas from the furnace • Cogeneration • Reformer catalyst • Reformer tubes • Furnace design 21 © UNEP 2005 Chemical Industry Energy Conservation Opportunities Areas for CP-EE measures in ammonia plants: • Ammonia converter • Pre-reformer • Carbon dioxide removal section • Ammonia synthesis converter • Leakage of CO2 from compressors • Absorption refrigeration system • Compressors • • Better purification techniques Cooling of synthesis gas • Desulphurization 22 © UNEP 2005 Chemical Industry Energy Conservation Opportunities Energy efficiency technologies: • Gas heated reformers • Selectoxo unit • Lower syngas inert level • Heat exchange auto terminal reforming • Purge gas recovery unit 23 © UNEP 2005 Chemical Industry Energy Conservation Opportunities Energy efficiency technologies: • Pre-reformer • Improved catalyst • Carbon dioxide removal processes 24 © UNEP 2005 Training Agenda: Industry Sectors 1) Iron & Steel 3) Cement • Sector description • Process flow • Energy conservation • Sector description • Process flow • Energy conservation 2) Chemical 4) Pulp & Paper • Sector description • Process flow • Energy conservation • Sector description • Process flow • Energy conservation 25 © UNEP 2005 Cement Industry Sector Description • Cement is produced by grinding, blending and burning limestone, sand, clay, bauxite or laterite • These contain a suitable mixture of calcium oxides, silicon oxides, aluminum oxides and iron oxides • Two types of CO2 emissions occur: 1. 2. From the energy consumption As a by product from the calcination process • The global cement industry contributes to ~20% of all man made CO2 emissions • The energy consumption in the cement industry is about 2% of the global primary energy consumption 26 © UNEP 2005 Cement Industry Process Flows Production processes • Mining - surface mining is more eco-friendly • Crushing - size is reduced to 25 mm • Raw material preparation - roller mills for grinding and separators or classifiers for separating ground particles • Coal milling - provides dried pulverized coal to the kiln and precalciner 27 © UNEP 2005 Cement Industry Process Flows Production processes • Pyro processing - transform the raw material mix into gray clinkers in the form of spherically shaped nodules • Pre heater and pre calciner - from the preheater/precalciner process 60 % of flue go to the raw mill and 40 % to the conditioning tower • Clinker cooler - heat recovery from the hot clinker and temperature reduction of the clinker • Finish milling - grinding of clinker to produce a fine grey powder 28 © UNEP 2005 Cement Industry Process Flows Diesel Limestone Mining for loaders, dozers and compressors Diesel for dumpers and trucks/ Electrical energy for ropeway Energy flows • • Energy consumption nearly 40-40% of production costs Mill drives, fans and conveying systems are major energy consumers Electrical Energy for crushers Electrical Energy for Mill drive and fans Heat Energy from kiln off gases Heat Energy from fuel input Transport Figure: Energy flows in a cement plant Crushing Bauxite, Ferrite Raw Milling Pre calcination Electrical Energy for mill drive and fans Coal Milling Electrical Energy for Kiln drive, fans and ESP Pyro Processing Heat Energy from fuel input Electrical Energy for fans, drive and clinker breaker Electrical Energy for Mill drive and fans Heat Energy from fuel input/waste heat from clinker cooler Clinker Cooling Gypsum Cement Grinding 29 Packing & Dispatch © UNEP 2005 Cement Industry Process Flows Electrical energy flows • Clinker burning: ~30% • Finish grinding: ~30% • Raw mill circuit: ~24% Thermal energy flows • 50% of the energy costs • The kiln and precalciner are major users 30 © UNEP 2005 Cement Industry Process Flows Material & energy balance • Important for optimized operation of the cement kiln, diagnosing operational problems, increasing production and improving energy consumption • In a cement plant processes involve gas, liquid and solid flows with heat and mass transfer, the combustion of fuel, reactions of clinker compounds and any undesired chemical reactions • Parameters to consider include velocity, static 31 pressure, dust concentration, surface © UNEP 2005 Cement Industry Energy Efficiency Opportunities CO2 reductions involves a two pronged strategy: 1. Improving energy efficiency 2. Promoting blended cements that can decrease the clinker percentage in the cement 32 © UNEP 2005 Cement Industry Energy Efficiency Opportunities Table: Classification of CP-EE measures in three steps Raw material process Clinker burning process Finish process First step 1) Selection of raw material 2) Management of fineness 3) Management of optimum grinding media 1) Prevention of stoppages 2) Selection of fuel 3) Prevention of leak 1) Management of fineness 2) Management of optimum grinding media Second step 1) Use of industrial waste material 2) Replacement of fan rotor 3) Improvement of temperature and pressure control system 4) Improvement of mixing & homogenizing system 1) Use of industrial waste material 2) Recovery of preheater exhaust gas 3) Recovery of cooler exhaust gas 4) Replacement of cooler dust collector 1) Installation of closed circuit dynamic separator 2) Installation of feed control system Third step 1) From wet process to dry process 2) From ball and tube mills to roller mill 1) From wet process to dry process 2) Conversion of fuel 3)From SP to NSP 4)Use of industrial waste 5)From planetary and under coolers to grate cooler 33 © UNEP 2005 Cement Industry Energy Efficiency Opportunities CP-EE measures: 10 -20 % electrical energy reductions have been achieved in a cement plant by: a) b) c) d) e) f) g) h) Raw meal mix design change Elimination of run-on equipment Finish Mill Optimization Avoidance of air supply leakage Installation of more efficient fan motors Employees’ awareness Power monitoring and targeting Process Replacement Measures 34 © UNEP 2005 Cement Industry Energy Efficiency Opportunities CP-EE measures: • Capacity utilization -Essential for energy efficiency -Brings down the fixed energy loss component -At least 90% required to achieve low specific energy consumption • Fine tuning equipment -Only requires marginal investment -Can yield 3-10% energy savings if efficiently performed • Technology upgrades 35 © UNEP 2005 Cement Industry Energy Efficiency Opportunities Energy efficient technologies: • Process control and management systems • Raw meal homogenizing systems • Conversion from wet to dry process • Conversion from dry to multi stage pre-heater kiln • Conversion from dry to pre-calciner kiln • Conversion from cooler to grate cooler • 36 Optimization of heat recovery in clinker cooler © UNEP 2005 Cement Industry Energy Efficiency Opportunities Energy efficient technologies: • High efficiency motors and drives • Adjustable speed drives • Efficient grinding technologies • High-efficiency classifiers • Fluidized bed kiln • Advance comminution technologies • Mineral polymers 37 © UNEP 2005 Training Agenda: Industry Sectors 1) Iron & Steel 3) Cement • Sector description • Process flow • Energy conservation • Sector description • Process flow • Energy conservation 2) Chemical 4) Pulp & Paper • Sector description • Process flow • Energy conservation • Sector description • Process flow • Energy conservation 38 © UNEP 2005 Pulp & Paper Industry Sector Description • World production of paper and paperboard is about 323 million tons (year 2000) • World pulp and paper devours over 4 billion trees annually • The industry produces the net addition of 450 million tones of CO2 per year (IIIED) • The fuels within the sector are coal, oil, gas and bio fuels • There are significant opportunities for 39 © UNEP 2005 reduction of CO2 gas emissions Pulp & Paper Industry Process Flows Manufacturing process • Wood preparation • Pulping • Washing • Bleaching • Stock preparation • Paper making • Chemical recovery 40 © UNEP 2005 Pulp & Paper Industry Trees Bark ( fuel) Process Flows Barking Used Paper Electricity Wood Preparation Chipping Steam Pulping Electricity Bleaching Chemical Pulping Mechanical Pulping Waste Paper Pulping Bleach Plant Kneading Steam Electricity Bleach Plant Chemical Recovery Steam Electricity Liquor concentration Refiner Electricity Steam Electricity Fuel Electricity Energy Recovery Recausticization Paper making Figure: Process flow diagram of the pulp and paper industry 41 © UNEP 2005 Pulp & Paper Industry Process Flows Paper making Steam Stock Preparation Electricity Electricity Steam Forming Pressing Electricity Steam Drying Electricity Paper Figure: Process flow diagram of the pulp and paper industry 42 © UNEP 2005 Pulp & Paper Industry Process Flows Energy flows in the paper industry: • Thermal energy -mainly consumed in the drier -some mills use steam for drying the after coating • Electrical energy -used to power the rotor or impeller -also used as rotary power for the cylinder, transportation, motive power and lighting loads • Water flow -water consumption is significant both in terms of consumed quantities as well as environmental 43 aspects © UNEP 2005 Steam Line 2.5 Kg/cm2 Condensate Line 2 Kg/cm2 Showers Fan Pump Tank Drying Cylinders Calender, 52.5 Kw Vacuum Boxes Foil Boxes Couch Roll, 96 Kw Process Flows Head Box 22 Kw 22 Kw Pope, 11 Kw Press Roll I, 52.5 KwI Press Roll I, 52.5 Kw Pulp & Paper Industry 22 Kw Vacuum Pumps KVM 200 KVM 600 KVM 600 18 m3/min 60 m3/min 60 m3/min 37 Kw 75 Kw 130 Kw 50 - 200 mm Hg 400 mm Hg 200-250 mm Hg High Pressure Pump Common for PM I & II 350 m 24 m3/hr 45 Kw Condensate collection Tank Over Head Condensate Collection Tank 10 m 120 m3/hr 1.5 Kw To Cogeneration 10 m Plant 120 m3/hr 5.5 Kw 44 Figure: Energy balance in a paper machine © UNEP 2005 Pulp & Paper Industry Energy Efficiency Opportunities CP-EE measures: • Raw material preparation -Enzyme-assisted barker -Chip conditioners -Improved screening process -Belt conveyers • Mechanical pulping -Refiner improvements -Low consistency refining (LCR) -Heat recovery in thermo mechanical pulping 45 © UNEP 2005 Pulp & Paper Industry Energy Efficiency Opportunities CP-EE measures: • Chemical pulping -Continuous digesters -Continuous digester modification -Batch digester modification • Chemical recovery -Falling film black liquor evaporation • Paper making -High consistency forming -Extended nip press (shoe press) 46 © UNEP 2005 Pulp & Paper Industry Energy Efficiency Opportunities CP-EE measures: • General measures -Optimization of regular equipment -Efficient motor systems • Efficient steam production & distribution -Boiler maintenance -Improved process control -Flue gas heat recovery 47 © UNEP 2005 Pulp & Paper Industry Energy Efficiency Opportunities EE technologies: • Alcohol based solvent pumping • Bio pulping • Ozone bleaching • Black liquor gasification 48 © UNEP 2005 Pulp & Paper Industry Energy Efficiency Opportunities EE-technologies: • Impulse drying • Infrared drying • Press drying 49 © UNEP 2005 Training Session on Energy Equipment Industry Sectors THANK YOU FOR YOUR ATTENTION 50 © UNEP GERIAP