FREEZE CRYSTALLISATION
Based on an
Environmentally Friendly Technology
By
Frederick Simon Oosthuizen
All Rights Reserved - © 2010 Frederick Simon Oosthuizen
Treating of Complex Waters
Freezing out the Water Part from a Solution with Dissolved Chemicals.
Principle
Method of Utilizing the Refrigeration Energy by Freezing out Water
in a Contaminated Fluid without the Addition of Chemicals.
Theory
When a Solution Freezes, the Ice Crystals Reject the Solute. The Dissolved
Substances increase in Concentration, allowing an Operating
Factor Ranging from 1 to 40 in the Remaining Water.
Technology
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The HybridICE Technology consists of a Water Freeze Crystallisation Plant
and a Filter System to separate the clean water from the contaminated concentrate.
All Rights Reserved - © 2010 Frederick Simon Oosthuizen
MINING & INDUSTRIAL SECTOR
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The HybridICE Technology is based on the principles of conventional
refrigeration. HybridICE can be integrated into an existing infra structure
typically found in both the Mining and Industrial Sector. The technology is ideal
for Retrofitting and Modernising existing Refrigeration plants.
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Deep Cast Mines have large refrigeration capacities. Existing cooling systems can
be retrofitted for water treatment and in the process improve the existing
refrigeration performance.
BRINE STREAM TREATMENT FOR REVERSE OSMOSES
Membrane technologies are widely installed and used by Industry. The produced
Brine Streams from a Reverse Osmoses (RO) is a critical issue in many countries.
The treatment of Brine Streams is energy intensive and therefore extremely costly
to operate, as these steams are predominantly being fed into Evaporation ponds.
All Rights Reserved - © 2010 Frederick Simon Oosthuizen
TYPICAL COMPLEX WATER
Complex Waters such as Acid Mine Drainage (AMD) and Brine Steams contain
Freezing Point Depressant Substances (FPDS) such as chlorides and sulphur.
Both AMD and Brine Streams can be used as efficient and environmentally
friendly secondary refrigerant in the HybridICE Process without the need for
Glycol .
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All Rights Reserved - © 2010 Frederick Simon Oosthuizen
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SCHEMATIC OF THE HybridICE FREEZE CRYSTALLISATION
C
COMPLEX WATER
A
LIQUID ICE
B
INLET: COMPLEX WATER
A:
B:
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HybridICE FREEZE CRYSTALLISATION PLANT
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HybridICE FILTER SYSTEM
D
OUTLET:
C:
D:
ICE / CLEAN WATER
CONTAMINATED CONCENTRATE
All Rights Reserved - © 2010 Frederick Simon Oosthuizen
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PRINCIPLE HybridICE FILTER
A:
B:
C:
D:
E:
F:
INLET ICE / COMPLEX WATER
FILTER ELEMENT
ICE / CLEAN WATER
CONTAMINATED CONCENTRATE
WATER RESERVOIR
HEAT EXCHANGER
C
B
C
E
F
A
D
All Rights Reserved - © 2010 Frederick Simon Oosthuizen
HybridICE FILTER SYSTEM – HIF SERIES
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All Rights Reserved - © 2010 Frederick Simon Oosthuizen
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HybridICE FREEZE CRYSTALLISATION PLANT
All Rights Reserved - © 2010 Frederick Simon Oosthuizen
ADVANTAGES FOR MINING & INDUSTRAL SECTOR
Conventional Cooling Technology can used to treat AMD or Brine Stream
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The HybridICE Process requires No Chemical Addition
Process recovers clean and usable water from Complex Waters
Significantly Reduces the Volume of Contaminated Fluids
Quality Air for a Healthy & Safer Working Environment for Mineworkers
Recovers Water with high Cooling Capacity
Thermal Energy well suited for High Peak Cooling Loads
Flexible Operating Strategies Possible
Cheaper Off-Peak Energy – Load Shift
All Rights Reserved - © 2010 Frederick Simon Oosthuizen
WASTE BRINE TREATMENT FROM REVERSE OSMOSES (RO) PLANTS
Excellent Energy Management Strategy
Low Temperatures reduce Scaling and Corrosion
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Unlike Membrane Technologies, HybridICE is not Sensitive to
Impurities such as mud or Heavy Metals
Waste heat from for heating the Evaporation Ponds
Up to four times higher concentration than membrane-based RO
The High Concentrate and reduced Brine Stream from the HybridICE
Process can reduce the evaporation cost by up to 75%
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Significantly increases the capacity of existing Evaporation Ponds
No Chemicals Required
All Rights Reserved - © 2010 Frederick Simon Oosthuizen
ADVANTAGES FOR INDUSTRIES
Feasible Solution for reducing Toxic Fluids
Energetic and Safety Advantages
Cost reduction by using Off-Peak Operations
Environmentally Friendly
Ecologically-Efficient
All Rights Reserved - © 2010 Frederick Simon Oosthuizen
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FEATURES OF HybridICE COMPONENTS
Retrofitting existing Refrigeration Systems
Significantly reduces HFC
Optimisation of Energy Consumption
Containerized Plug & Play Modules
Small Refrigerant Charge
Service Friendly & Easy to Maintain
All Rights Reserved - © 2010 Frederick Simon Oosthuizen
ENERGY AND COST ENHANCEMENT
HybridICE - offers itself as an economically feasible solution to Recover Fresh
Water were Energy is Critical and Disposal of Contaminated Fluids are Costly.
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Process is not sensitive to impurities e.g. mud / metals unlike membrane
technology.
HybridICE Process requires no chemical addition.
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Waste heat from the refrigeration cycle can be utilized to heat the concentrate.
The thermo-physical Properties of contaminated fluid as secondary refrigerant
makes it an ideal medium for thermal energy storage, transport and transfer of
cold energy.
The Process is ideal to reduce air temperature and humidity in the mines.
All Rights Reserved - © 2010 Frederick Simon Oosthuizen
FEASIBILITY
Contaminated Fluid is an efficient two-phase Secondary Refrigerant
Retrofitting and Utilizing of existing Refrigeration Equipment possible
Significantly reduces the amount of Primary Refrigerant
Usable Water can be recovered without addition of Chemicals
All Rights Reserved - © 2010 Frederick Simon Oosthuizen
Eco-MeRe™ ENHANCEMENT TECHNOLOGY
Acid Mine Drainage (AMD) often contain high levels of metals
apart from other harmful and toxic substances. When a
HybridICE System is installed, the contaminated fluid is
concentrated.
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This concentrated fluid can contain valuable metals such as
Cobalt, Copper, Nickel and Uranium. These Metals can be
recovered with the eco-MeRe™ System, a complimentary
product of HybridICE .
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The eco-MeRe™ is an electro-coagulation technology. This
System has been designed to salvage valuable metals and
remove iron and other harmful substances effectively. The
combination of the eco-MeRe™ and HybridICE can ensure
that the recovered water can be used as industrial water or
returned safely back into the environment.
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All Rights Reserved - © 2010 Frederick Simon Oosthuizen
SOLUTIONS IN PARTNERSHIP
All Rights Reserved - © 2010 Frederick Simon Oosthuizen