Reducing the risk of blasting “Hot Holes” July 2008 Why undertake this work? • Many surface operations on coal mines are moving into areas where there are underground fires • There have been incidents reported where primed holes (thankfully not charged!) have detonated prematurely • Most mines are developing operating procedures to reduce the risk associated with blasting in these hot areas – The threat is real – Precautions must be taken – Adherence to correct standards and procedures Procedures… • The procedure defines three cut off areas: – 40oC. • Below 40oC is considered a normal hole • Above treated according to procedure – Between 60oC and 80oC will be considered a hot hole and treated by cooling agent, till below 60oC – Above 80oC will not be considered for charging at all Procedures… • AEL has sat with the mines and conducted risk assessments for drafting of procedures: – Measure temperature of holes, identify number of holes to be blasted – Cool – Measure again – Charge from cold to hot holes but maintain a pattern so that blast can occur as required according to the risk – Minimum number people, equipment at distance Procedures • AEL’s recommendations have been to use emulsion based explosives, shock tube (On surface) and detonating cord & booster (Toe primed) • AEL needed to ascertain the safety issues related to explosives and initiating systems when subjected to prolonged periods of elevated temperatures Tube to keep transducer at a distance from pipe Pressure transducer Lid Testing Gasket Bolts to attach lid Pipe (Pressure + 6 bar) Data capture system Explosive Thermocouple 1 Booster Detonator Thermocouple 2 Gas burner Solenoid connected to data capture system Gas Cylinder Test Setup Test No. Description 1 Detonator only. Oil placed inside pipe for heat transfer 2 Powercord only – oil in pipe 3 Detonator only (repeat #1) – oil in pipe 4 400g Pentolite booster – no oil 5 Booster & detonator 6 Gassed P100 7 Gassed P700 8 Detonator, booster & P700 Detonator only Test #1: Detonator only (in oil) 800 Erratic behaviour of flame temperature probably because of wind 700 Temperature (degC) 600 Emuls Oil Temp 500 Flame Temp 400 Flame cools rapidly after gas turned off 300 200 Steady rise in temperature of the oil until detonator initiates at 160degC after about 15mins about 15 mins 100 0 0.00 200.00 400.00 600.00 Time (secs) 800.00 1000.00 1200.00 Emulsion only Pipe pressurised atvalue an initial value ofThis 5.5bar. This Pipe pressurised at an initial of 5.5bar. rises to about 7bar as the sample is heated. rises to about 7bar as the sample is heated. Test #8: P700, Booster & Detonator Test #6: Gassed Test #6: Gassed P100 P100 700 600 600 8 10 8 P100 Temp P100 Temp Emuls Temp Flame Temp Flame Temp Temp Pressure Pressure 9 600 500 8 300 Sample temperature rises Sample temperature rises rapidly from 40 to 200degC. 300 rapidly from 40 to 200degC. 300 200 200 100100 0 4 200 0 0 0 0 0.00 These temperature fluctuations are probably as a result These temperature fluctuations are probably as a result of cold product slumping into the zone w here the of cold product slumping into the zone w here the thermocouple is located and then being heated. thermocouple is located and then being heated. 500 500 200.00 1000 5 4 3 100 Pressure (bar) 56 400 Temp (degC) Temp (degC) 400 Temp (degC) 7 400 1000 400.00 1500 2000 2500 800.00 1500 2000 600.00 2500 3000 Time (secs) Time (secs) Tim e (secs) 3000 3500 1000.00 3500 4000 4000 1200.00 4500 had significant 6 hadWind Wind significant effect on the lame effect on the lame temperature temperature 5 4 Pressure (bar) 6 500 Pressure (bar) 500 7 7 3 Product did not detonate. did not detonate. 3 Product Detonator at material and Pinkfired granular Pink granularafter material and 205degC 2 a liquid w20 hich fudged on 2 aminutes liquid w hich fudged onThe of heating. cooling, remained after 2 cooling, remained after bulk explosive was the test as w ell as black, the test as w ell as black, partiallyburnt initiated but material. 1 1 1 burnt largematerial. amounts of unfired product remained in the pipe. 0 00 4500 1400.00 5000 5000 Detonator, Booster & Emulsion Test #8: P700, Booster & Detonator 10 700 Emuls Temp Flame Temp 9 Pressure 600 8 7 6 400 5 300 4 3 200 2 100 1 0 0.00 200.00 400.00 800.00 600.00 Time (secs) 1000.00 1200.00 0 1400.00 Pressure (bar) Temp (degC) 500 Detonator fired at 205degC after 20 minutes of heating. The bulk explosive was partially initiated but large amounts of unfired product remained in the pipe. Summary of Testing – Day 1 Test # Description Comments 1 Detonator only Detonation at 160ºC 2 Powercord No detonation. The Powercord immersed in the oil was burnt away and the tip of the remaining sample was severely melted 3 Detonator only Detonation at 180ºC 4 400g Pentolite booster No event. Could not see what had happened to the sample but suspected that the booster had melted and that the Pentolite had run into the bottom of the pipe. Pipe destroyed by detonating a new booster inside the pipe 5 Booster + detonator Detonation at 203ºC. Damage to the pipe was significantly less than that caused by an intact booster. The welds at the bottom of the pipe were blow open Summary of Testing – Day 2 Test # Description Comments 6 Gassed P100 No detonation 7 Gassed P700 No detonation 8 Detonator, booster + P700 Detonation occurred at 205ºC. Lid of the pipe was detached and the bolts sheared. Pipe remained intact and significant quantities of emulsion remained. Summary • In all three tests where a detonator was subjected to elevated temperatures, a detonation occurred – Temperatures varying between 160ºC and 205ºC • Neither the straight emulsion or the blend reacted in a vigorous manner – Significant temperatures and pressures – Explosive did not undergo a violent exothermic reaction which would have caused it to “run away” and detonate Water displaced during charging Field Tests Gassing/stemming? Equipment removal Equipment set-up Field Test 60 4 2 50 0 -2 30 -4 -6 20 -8 10 0 11:09:36 -10 11:16:48 11:24:00 11:31:12 11:38:24 11:45:36 11:52:48 12:00:00 Time Temp 1 Temp 2 Temp 3 Temp 4 Pressure 1 Pressure 2 12:07:12 -12 12:14:24 Pressure Temperature 40 Other tests • Minimum burning pressure tests • Test chamber to 70 bar • Apply instantaneous heat (+1000oC) – AEL & Competitor bulk products tested (at their request) do not detonate • Developed for pumping but applicable to the current situation – How confined will the explosives be in the hole? (Fissures, venting between holes, old workings etc) Recommendations… • A good assumption would be that if there is an initiating system with a detonator present that detonates, the bulk explosive will also be initiated • These tests show that the detonator is the component that has the lowest ignition temperature • Detonating cord, boosters and bulk explosives have a lower risk to detonate when heated under conditions resembling those found in “hot” holes in coal mines Recommendations • It would therefore seem logical that areas in the Witbank area which are deemed “hot” use detonating cord as the initiating system down the hole • AEL’s recommendations have been to use emulsion based explosives, shock tube (On surface) and detonating cord & booster (Toe primed) • A move to top priming should be considered to further reduce the risk particularly from the booster (Heat exposure)