Answers to end-of-chapter questions Chapter 5 Acids, bases and salts 1 4 a pH 3 [1] b Add blue (or neutral) [1] litmus [1]; if it turns red, it is acidic [1]. [3] c i calcium carbonate + hydrochloric acid → calcium chloride + carbon dioxide + water [1 mark for each product] [3] ii in a blast furnace for producing iron [1] iii lime/calcium oxide, or slaked lime/ calcium hydroxide [1] [2] d Fe + 2HCl → FeCl2 + H2 [Total = 11] 5 a acidic: < 7, any appropriate e.g. SO2 basic: > 7, any appropriate e.g. CaO neutral: 7, any appropriate e.g. H2O [6] b i an oxide/substance that will react with/ dissolve in both acids and alkalis. [1] ii any strong acid (e.g. HCl) + any strong alkali (e.g. NaOH) [2] [Total = 9] 6 Step 2: Filter to remove excess solid [1] Step 3: Evaporate to crystallisation point [1] Step 4: Leave solution to cool [1]; dry crystals on filter paper [1] [2] [Total = 4] 7 a first row: sodium hydroxide; nitric acid [2] second row: copper oxide [1] third row: silver nitrate; hydrochloric acid (or soluble chloride salt) [2] fourth row: zinc sulfate [1] [2] b i Ag+(aq) + Cl−(aq) → AgCl(s) ii ZnCO3 + H2SO4 → ZnSO4 + CO2 + H2O [2] [Total = 10] The process of dissolving takes place when the molecules of water are able to break up the lattice structure of the ions in the solid salt. If the bonding between the ions in the solid is too strong, then the water molecules are not able to break up the structure. The strength of the bonding in an ionic solid depends on the size and charge of the ions. There are some guidelines that help us know which salts are soluble in water and which are not. 2 In understanding the different uses of the word ‘strong’ in these cases, we have to focus on the way the adjective is being applied. In the first case, the term is being applied to the solution – ‘the coffee is strong’ means that it is concentrated. A weak cup of coffee would have a low concentration of coffee. In the second case, the word is applied to the nature of the acid itself – not the solution – the strong acid is fully ionised in water. It is therefore possible to have a dilute solution of a strong acid. Remember, in chemistry, to use the words ‘concentrated’ and ‘dilute’ when talking about how concentrated a solution is. 3 a pH 11 [1] b slaked lime [1] c i to help plants grow better (or words to that effect) [1] ii sulfur dioxide [1] from power stations [1] or nitrogen oxides [1] from car exhausts [1]; dissolves in rain [1] [3] d i neutralisation [1] ii Measure the calcium hydroxide/alkali with a pipette [1], add indicator [1] and add acid from burette until there is a colour change [1]. [3] [Total = 10] © Cambridge University Press 2014 IGCSE Chemistry Answers to end-of-chapter questions: Chapter 5 1