Oilfield Resins for Plug and Abandonment Paul Jones, PhD., Principal Scientist © 2016 Halliburton. All rights reserved. Challenge: Place barriers to isolate formations from each other and from the surface Appropriate selection of materials and elements to form the barrier(s) 30 CFR part 250 – pg 263-264 describes cement UK Oil & Gas describes alternative materials Individual operator requirements generally more stringent Key parameters Permeability Fluid interaction Dimensional stability Mechanical properties Other (material dependent) Design and Deliver Dependable Barriers Tailored to Minimize Risk and Maximize Production © 2016 Halliburton. All rights reserved. 2 Solution: Resin (WellLock® Resin) and Resin/Cement Composites (LockCem™ Cement) WellLock® Resin usage in abandonment operations LockCem™ Cement usage in abandonment operations © 2016 Halliburton. All rights reserved. 3 Halliburton Resin Usage Recommendation for Plugging Job designs using the lowest volume of resin to achieve maximum results is recommended to be employed. The length of the resin portion of the plug is recommended to be no more than 20% of the total plug length, while the remaining 80% of the total plug length is recommended to be a Portland-based cement, composite cement (LockCem™ Cement) or equivalent. If a leak is located, it is recommended to contact the leak pathway with the resin and to squeeze the resin into the leak pathway as part of the job procedure. © 2016 Halliburton. All rights reserved. 4 Microfluidic Flow of Epoxy Sealant ΔP × D2 ν= 32 × µ × ΔL Q=ν×A ν = fluid velocity ΔP = pressure drop = 7 bar D = diameter = 67 µm µ = fluid viscosity 70F = 549 cP Mass collected = 0.18 gm Collection time = 4:41 (h:mm) Fluid velocity = 9.89 m/hr Volumetric flow rate = 0.035 mL/hr ΔL = length = 20 cm Q = volumetric flow rate Calculated ν (m/hr)𝐴 = 𝑐𝑐𝑐𝑐𝑐 𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠𝑠 3.22 𝑎𝑎𝑎𝑎 Q (mL/hr) © 2016 Halliburton. All rights reserved. 5 Measured 0.011 9.89 0.035 Resin Applications in P&A Squeezes for annular fluid flow Shut-off gas source Squeeze a previously leaking plug © 2016 Halliburton. All rights reserved. 6 LockCem™ Cement Oil well cement containing resin Regulatory approval under 30 CFR part 250 Increase bonding Reduce stiffness Maintain strength Reduce density Non-shrinking formulations © 2016 Halliburton. All rights reserved. 7 LockCem™ Cement Reduced Permeability Maintain compressive strength while reducing Young’s modulus Volume Fraction of Resin Increased Shear Bond Volume Fraction of Resin © 2016 Halliburton. All rights reserved. 8 WellLock® Resin and LockCem™ – 400+ Case Histories Other Primary Isolation Casing Repair 8% 23% 11% 21% 37% Annular Gas Remediation Abandonment Operations PERCENTAGES BASED ON FIRST 100 JOBS © 2016 Halliburton. All rights reserved. 9 Resin Cement Composite Case Study Challenge Rig less abandonment, no cementing equipment, only wireline Small slurry volumes (2.5 to 5 bbls total) Abandon bottom part of well and perforate new intervals in close proximity Solution Dump bailer run on wireline used to place slurry on top of mechanical base Small volumes mixed using hand mixer Resin cement composite system (20% resin and 80% cement by volume) Results © 2016 Halliburton. All rights reserved. Dump bailer minimized contamination of small volume in specialized applications Increased shear bond of LockCem™ Cement allowed shorter plugs Plug length ranged from 100 to 200 feet 100% success rate on all wells 10 Publications Devesh Bhaisora, Ahmed Aly, and Ahmed Morsy, Halliburton; Hesham Shamma, Radi EI Nashar, and Salah EldinEldin El0Sayed Karim, Gulf of Petroleum Company (GUPCO), “Innovative Application of Ultra-Lightweight Epoxy Resin-Cement Slurry Mixture Achieved Zone Isolation Objectives and secured Well Integrity: Case History From Offshore Gulf of Suez”, IPTC-18504-MS, (2015). P.J. Jones, J.D. Karcher, D. Bolado, Halliburton, “OFFSHORE PLUG AND ABANDONMENT USING SYNTHETIC RESIN TECHNOLOGY”, delivered at RAO/CIS Russia (2013) Kay A. Morris, Jay P. Deville, and Paul Jones, Halliburton, “Resin-Based Cement Alternatives for Deepwater Construction”, SPE 155613, (2012). P.J. Jones, B.A. London, L.B. Tennison, and J.D. Karcher, Halliburton, “Unconventional Remediation in the Utica Shale Using Advanced Resin Technologies”, SPE 165699, (2013). P.J. Jones, J.D. Karcher, A. Ruch, A. Beamer, P. Smit, S. Hines, “Rigless Operation to Restore Wellbore Integrity using Synthetic-based Resin Sealants”, SPE 167759, (2014). I. Foianini, G. Frisch, and P. Jones, Halliburton, “SUCCESSFUL IDENTIFICATION AND BOND ASSESSMENT OF EPOXY-BASED RESIN CEMENT BEHIND PRODUCTION CASING: INTEGRATING CEMENTING TECHNOLOGY WITH NEW LOG INTERPRETATION METHODOLOGY TO PROVIDE AN INNOVATIVE WELL INTEGRITY SOLUTION”, SPWLA 55th Annual Logging Symposium, May 18-22, 2014. Pardeshi, M.; Wilke, A.; Jones, P.J.; Gillies, J., Halliburton; Jedlitschka, V., OMV New Zealand Ltd., 2016. “Novel Use of Resin Technology for Offshore Pilot Hole Abandonment” Paper OTC-26565-MS presented at the Offshore Technology Conference Asia, Kuala Lumpur, Malaysia, 22-25 March. © 2016 Halliburton. All rights reserved. 11 © 2016 Halliburton. 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