Name:_____________________________ ( ) Class:__________ Date:___________ WORKSHEET Chemical Bonding 6.1 The Stable Electronic Configuration of a Noble Gas 1. Noble gases • Elements that belong to __________ of the Periodic Table. • They are _________ (__), _________ (__), ________ (__), _________ (__), and ________ (__). • They are __________ and _____________. • They exist as ____________________ in nature. 2. The noble gases have ______ and _____________ outer shells. • Helium has a __________ configuration. • All other noble gases have an __________ configuration. 3. Atoms of most other elements are reactive because they do not _____________________ ____________________. 4. Atoms of these elements ________, ________ or ________ outer electrons to attain the ______________________________ and form _____________ or _____________. 5. Atoms ________ or ________ electrons to form substances with ionic bonding. 6. Atoms ________ electrons to form substances with covalent bonding. 6.2 Forming Ions 1. An atom ________ or ________ electrons to form ions. Ions are __________ particles because they do not have equal numbers of __________ and __________. 2. Atoms ________ electrons to form positively-charged ions called __________. 1 Example: Formation of a sodium ion sodium atom ______ _____ outer electron(s) 2, 8, 1 __________ Charge on sodium ion = ___p + ___e = (____) + (____) = _____ Example: Formation of a calcium ion calcium atom ______ ____ outer electron(s) 2, 8, 8, 2 __________ Charge on calcium ion = ___p + ___e = (____) + (____) = _____ 3. Common cations and their charges: Metallic element Electronic configuration of atom sodium 2, 8, 1 potassium 2, 8, 8, 1 calcium 2, 8, 8, 2 magnesium 2, 8, 2 aluminium 2, 8, 3 2 Formula of cation Electronic configuration of cation 4. Atoms ____________________ to form negatively-charged ions called __________. Example: Formation of a chloride anion chloride atom _____ _______ electron(s) 2, 8, 7 __________ Charge on chloride ion = ___p + ___e = (____) + (____) = ___ Example: Formation of an oxide ion oxygen atom _____ ______ electron(s) 2, 6 __________ Charge on oxide ion = ___p + ___e = (___) + (___) = ____ 5. Common anions and their charges: Non-metallic element Electronic configuration of atom chlorine 2, 8, 7 fluorine 2, 7 oxygen 2, 6 sulfur 2, 8, 6 3 Formula of anion Electronic configuration of anion 6.3 Ionic Bonds: Transferring Electrons 1. Ionic bonds occur between metals and non-metals. Examples of metals: Examples of non-metals: 2. In the formation of an ionic bond, the metal atom __________ outer electrons to the nonmetal atom. __________ ions (cations) and __________ ions (anions) are formed. 3. The oppositely charged ions are held together by strong ______________________________ called ionic bonds. 4. We can show the formation of an ionic bond by a ____________________ diagram, where • __________ (__) represent the electrons of _____ atom; • __________ (__) represent the electrons of ________atom. Steps Involved in the Formation of an Ionic Compound Example: Sodium chloride (a) The sodium atom loses ______ valence electron to the chlorine atom. Na → __________ Cl + e− → _______ Na atom Cl atom Na+ ion Cl– ion (______) (_______) (_______) (_______) (b) The electronic configuration of Na+ is the same as that of the noble gas _____. (c) The electronic configuration of Cl− is the same as that of the noble gas _____. (d) Formula of compound formed: _______ 4 NOW TRY THESE ON YOUR OWN! Ionic Bonding between Sodium and Sulfur Na atom (2, 8, 1) S atom (2, 8, 6) ________ ________ ________ ________ Name of compound: __________________ Formula of compound: _________ Ionic Bonding between Magnesium and Oxygen ________ ________ ________ ________ ________ ________ Name of compound: __________________ Formula of compound: _______ 5 ________ ________ Chemical Formulae of Ionic Compounds 1. Give the names of the following ionic compounds: Chemical formula NaCl Chemical formula ZnSO4 Name CaO KNO3 CO2 Li2CO3 Mg(OH)2 Na3PO4 Name 2. When writing the chemical formula of an ionic compound, the positive charges must __________ the negative charges. 3. The formula of an ionic compound is constructed by _____________ the charges on the positive and negative ions. All the positive charges ____________________ all the negative charges in an ionic compound. • For example, magnesium forms Mg2+ ions with a charge of ____. Chlorine forms Cl– ions with a charge of ____. There must be ____ Cl– ions to balance out the _____ positive charges of Mg2+. Hence, the chemical formula of magnesium chloride is __________. 4. The chemical formula of an ionic compound can be deduced using the following steps: (a) Write down the ions with the charges, e.g. Xm+Yn–. Xm+ Yn– Xn Ym (b) Move the values m and n diagonally (without the charges). The chemical formula is ________. 5. Write the chemical formulae of the following ionic compounds: Name Chemical formula Name Lead(II) bromide Silver sulfate Copper(II) oxide Calcium nitrate Iron(III) hydroxide Lithium hydride Sodium hydrogen carbonate Ammonium carbonate 6 Chemical formula 6.4 Structure and Physical Properties of Ionic Compounds Structure of Ionic Compounds 1. Ionic compounds form ___________________________ also known as crystal lattices. 2. In sodium chloride, millions of sodium ions and chloride ions are held together by ionic bonds in a _________________ and __________ manner. 3. Each sodium ion is surrounded by ____________ ions. 4. Each chloride ion is surrounded by ____________ ions. Cl− Na+ 5. The ratio of sodium ions to chloride ions is _____. 6. Hence, the formula of sodium chloride is _______. Physical Properties of Ionic Compounds 1. Ionic compounds have very high ______________________________ because a large amount of energy is required to overcome the strong forces of attraction between ions in the crystal lattice. 2. Ionic compounds are usually soluble in _________ but insoluble in __________________. 3. Ionic compounds conduct electricity in the _________ and _________ states because the ions are ___________________________ in these states. 4. Ionic compounds do not conduct electricity in the solid state because the ions are ____________________________________. 7 6.5 Covalent Bond: Sharing Electrons 1. Covalent bonding involves the ___________________________ with no transfer or movement of electrons between two atoms. _____________ are formed, not ions. 2. This type of bonding occurs when _____________ atoms join together so as to achieve the stable electronic configuration of a ______________. Molecules of Elements 1. Hydrogen (a) Each hydrogen atom has ________________ in its outer shell. This means that each hydrogen atom needs _____ additional electron to achieve a stable _________ configuration. (b) By sharing electrons, each hydrogen atom has __________________ in its outer shell. Thus, each atom achieves the stable _________ configuration. (c) This shared pair of electrons forms a ___________________________. The hydrogen molecule has two atoms and is _________. H × H ⚫ 2. Chlorine (a) Each chlorine atom has _________ outer electrons. This means it is _____ electron short from the stable noble gas structure. It achieves stability by ______________ electron with another chlorine atom. (b) This shared pair of electrons forms a _________ covalent bond and is the reason why the chlorine molecule has two atoms and is _________. (c) The chemical formula of chlorine gas is ____. (d) Complete the ‘dot and cross’ diagram of the chlorine gas molecule below. × ⚫ Cl Cl 8 3. Oxygen (a) If two pairs of electrons are shared in order to achieve the noble gas structure, then a ___________ covalent bond results. This occurs between atoms in oxygen gas. (b) The chemical formula of oxygen gas is ____. (c) Complete the ‘dot and cross’ diagram of an oxygen gas molecule below. O O 4. Nitrogen (a) If three pairs of electrons are shared in order to achieve the noble gas structure, then a _________ covalent bond results. This occurs between atoms in nitrogen gas. (b) The chemical formula of nitrogen gas is ____. (c) Draw the ‘dot and cross’ diagram of a nitrogen gas molecule below. Molecules of Compounds 1. When atoms of different elements are joined together by covalent bonding, a ____________ compound or ____________ compound is formed. 2. Water (a) Water is made up of two elements — ___________ and ___________. (b) In a water molecule, an oxygen atom shares _____ of its outer electrons with _____ hydrogen atoms. ______ single O–H bonds are formed. (c) The chemical formula of water is ______. 9 (d) Draw the ‘dot and cross’ diagram of a water molecule below. 3. Methane (a) Methane is made up of two elements — _________ and ___________. (b) A carbon atom shares its ______ outer electrons with ______ hydrogen atoms. ______ ______________ bonds are formed. (c) The chemical formula of methane is _____. (d) Draw the ‘dot and cross’ diagram of a methane molecule below. 4. Carbon dioxide (a) Carbon dioxide is made up of two elements — carbon and oxygen. (b) A carbon atom shares its ______ outer electrons with ______ oxygen atoms. _______ _____________ bonds are formed. (c) The chemical formula of carbon dioxide is _____. (d) Draw the ‘dot and cross’ diagram of a carbon dioxide molecule below. 10 6.6 Structure and Properties of Covalent Substances 1. Most covalent substances exist as __________________. 2. Atoms in the molecules are held by ________________________. 3. Molecules are held together by weak __________________ forces of attraction. Melting and Boiling Points 1. __________________ is required to overcome the weak intermolecular forces between the molecules. 2. Thus, covalent substances have _________ melting and boiling points. 3. Covalent substances are usually _________ or ____________ liquids at room temperature and pressure. Electrical Conductivity 1. Most covalent substances _________ conduct electricity in _________ state. 2. This is because covalent substances have no ___________________________ in their solid, liquid or gaseous states. 3. However, there are some exceptions: • Solid carbon in the form of ____________ contains __________________. • __________________, __________________ and ____________ form ions when dissolved in water. Solubility 1. Covalent substances are usually _____________ in water. 2. However, some covalent substances are _________ in water, for example alcohol and sugar. 11 3. Covalent compounds are usually soluble in __________________ such as _________, ______________ and _________. 12