INTRODUCTION TO CHEMISTRY Specific learning objectives Define Chemistry Explain Chemistry as a Science Mention the branches of Chemistry Highlight the career opportunities in Chemistry List the apparatus in the Chemistry laboratory Meaning of Chemistry Chemistry is the science of the composition, properties, structure, and uses of matter as well as the changes associated with matter. Chemistry as a Science Science as an organized body of knowledge adopts some steps in the course of an inquiry. This process of inquiry is known as the Scientific Method or Scientific Approach. It begins with an observation and ends with a law as shown below. Hence the reason Chemistry is a science. Observation Hypothesis Experiment Theory Law To make observations means to state the problem and collect data. Observations may be qualitative or quantitative. A qualitative observation does not involve a number. For instance, colour and state of matter (solid, liquid, gas). A quantitative observation is a measurement and does involve a number and a unit. An observation is something that is witnessed and can be recorded. To formulate hypothesis means to provide a possible explanation for the observation. To perform experiments means to test the hypothesis. During experimentation, new information is gathered which enables decision on whether the hypothesis is supported by the new information learned from the experiment. Experiments always produce new observations and this starts or initiates the process of inquiry as depicted above. To explain the behaviour of a given part of nature, the first three steps (observation, hypothesis, experiment) are repeated many times and gradually knowledge necessary to understand things accumulate. Once a set of hypotheses agrees with the various observations, they are assembled into a theory. A theory is a set of tested hypotheses that gives an overall explanation of some parts of nature. Theories are human inventions. They represent human attempts to explain observed natural behaviour in terms of human experiences. A theory is an interpretation – a possible explanation of why nature behaves in a particular way. Theories inevitably change as more information becomes available. This implies that questions will continue to be asked about nature even after explaining the behaviour of nature; experiments will continue to be conducted to refine theories. This is done by using the theory to make a prediction and then doing experiments (making a new observation) to see whether the results bear out this prediction. Scientists must continue to do experiments and refine theories to be consistent with new knowledge if we hope to approach a more nearly complete understanding of nature. As scientists observe nature it is noticed the same observation applies to many different systems. For example, studies of a large number of chemical changes have shown that the total mass of materials involved is the same before and after the change. Such generally observed behaviour is formulated into a statement called law. The observation that the total mass of materials is not affected by a chemical change in those materials is called the law of conservation of mass. Differences between a law and theory A law is a summary of observed behaviour whereas a theory is an explanation of behaviour. A law tells what happens; a theory is a human attempt to explain why it happens. What type of science is Chemistry? Chemistry is a pure science because its inquiry is carried out in a laboratory. Branches of chemistry Physical Chemistry is the branch that deals with the structure of matter and how energy affects it. Inorganic Chemistry is the branch that deals with the study of elements, their compounds and their chemical reactions. Organic Chemistry is the study of carbon compounds with the exception of its oxides, sulphides, carbonates and hydrogen carbonates. Analytical Chemistry is the branch concerned with the techniques used to identify and quantify the composition of matter. Industrial Chemistry is the branch concerned with the methodology and other related aspects of commercial preparation of various compounds. Environmental Chemistry is concerned with natural and synthetic substances in the environment and their impact on the environment. Career Opportunities in Chemistry Chemistry as a science has paved way for numerous careers such as Biochemist, industrial chemist, environmental chemist, food chemist, clinical chemist, petroleum chemist, chemical engineer, pharmacy, subject teacher in a college, lecturer in a higher institution among other careers. Familiarization of laboratory apparatus in the Chemistry laboratory Name of apparatus Description Use of apparatus Test tube It is made of glass and available in various sizes. It is used to perform chemical tests and to boil the solutions Boiling tube It is made of hard glass (pyrex) and wider than a test tube It is used for strong heating Diagram Beakers It is a cylindrical glass container containing a beak at the upper side. It is available in various volumes such as 1 000 cm3 , 600 cm3, 500 cm3, 250 cm3, 100 cm3 It is used to pour liquid from one container to another Filter Funnel It is made of glass (glass funnel) or plastic (plastic funnel). It is conical in shape with a hollow tube. It is available in various sizes. It is used for filtration and sublimation. It is cylindrical in shape with graduated marks. It is made of glass or plastic and available in various volumes It is used to the measure specific volume of liquid Erlenmeyer flask It is made of glass and conical in shape. It is available in various volumes such as 100 cm3, 250 cm3, 500 cm3 and 1000 cm3 It is used in volumetric analysis Round bottom flask It is made of glass and possesses a round bottom It is used in the preparation of gases Measuring cylinder Flat bottom flask It is made of glass and possesses a flat bottom. It is used in the distillation process. Volumetric flask It is made of corning glass. Its upper part is cylindrical while its lower part is conical. It is available in various volumes such as 100 cm3, 250 cm3, 500 cm3, 1000 cm3 and 2000 cm3 It is used in the preparation of standard solutions It is a hollow cylindrical tube made of glass. It has graduated marks on it. The lower portion possesses a glass tap or rubber tube with a cork. A normal laboratory burette has a volume of 50 cm3 It is used in volumetric analysis as a measuring apparatus Burette Pipette Retort stand Wire gauze Tripod stand It is a thin hollow cylindrical tube having cylindrical bulb at the middle portion. It is available in various volumes such as 1 cm3, 10 cm3, 20 cm3. 25 cm3 It is used in volumetric analysis It is made of cast iron. It has a rectangular base fitted with a vertical rod. A clamp can be adjusted on the rod with a screw It is used to hold on to materials that require support It is a flat iron mesh with a sheet of It is used to support asbestos paper the beaker and other trapped at its centre glass container so that the glass during heating over container do not a bunsen burner come in direct contact with flame and crack It is made of cast iron. It is triangular in shape fitted with three rods for support. It is used to support during heating Test tube stand Test tube holder Test tube brush Wash bottle Bunsen burner Mortar – pestle Beehive shelf It is made of plastic or wood. It possesses an iron strip fitted in a cylindrical wooden base. It is made of thick and hard iron wire with plastic bristles It is used to keep and support test tubes It is used to hold test tubes during heating It is used for cleaning test tube It is made of plastic and contains a thin tube It is used for washing and rinsing glass apparatus. It is a heating device made of metallic base and a gas inlet tube fitted with a brass nipple It is used for heating They are made of porcelain. The mortar is a thick walled vessel, hemispherical in shape and possess a base It is made of porcelain. It has holes at upper and lower part to insert the delivery tube The mortar is used for grinding salts and other substances with the help of pestle. It is used for the collection of a gas in a gas jar It is used to hold small samples of powdered substances Watch glass It is a circular, curveshaped transparent glass container Spatula It is made of metal or plastic Stirring rod It is a solid rod made of hard glass China dish Evaporating dish Made of porcelain and hemispherical in shape It is used for crystallization It is made of glass and available in various volumes. Some are transparent while others are amber (brownish) It has a small opening which is capped by glass or plastic stopper It is used to store reagent Crucible It is made of porcelain and has a lid It is used to heat solids to high temperatures Clay triangle It is made of ceramic and appears as an equilateral triangle with hollow sides through which are drawn wires It is used to support crucible during heating It is a machine with centrifuge tubes It is used to separate mixtures composed of insoluble solids in a solution Reagent bottle Centrifuge It is used to take chemicals from a container It is used for stirring or mixing solution Kipp’s Apparatus (Gas generator) It is made of glass and consists of three vertically stacked columns It is used for the production and intermittent supply of gases Dropper bottle with dropper The bottle is made of glass with plastic dropper It is used to hold and dispense liquids or solutions required in drops Pasteur pipette (Droppers or Dropping pipette It is made of glass or plastic It is used to transfer small quantity of liquids or solutions required in drops Reagent shelf It is made of wood It is used to store reagents Separating funnel It is made of glass It is used to separate immiscible liquids It is made of glass It is used to transfer gases from point of production to that of collection Delivery tube Pneumatic trough It is made of glass It is used to hold water while collecting gases Stopper It is cylindrical in shape and made of wood or rubber It is used for sealing the opening of the flask Desiccator It is a sealable enclosure that contains desiccants and made of glass It is used to dry solids They are scissors – like with two pincers They are used to grasp ot crucible They are scissors – like with two pincers coated with rubber They are used to grasp hot beakers It is a long handled spoon with a lid It is used t lower burning objects into glass vessel filled with a gas Crucible tongs Beaker tongs Deflagrating spoon Liebig condenser Nichrome wire It is made of glass It is used to cool and with a straight inner condense hot vapoir tube surrounded by a during distillation large outer jacket It is an alloy of nickel It is used in flame or chromosome or testing sometimes iron Analytical balance It is a very sensitive instrument with a draft shield (weighing chamber) It is used to accurately measure mass Gas jar It is made of glass and consist of a broad base and a broad opening It is used for collecting gases