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plastics (2)

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Resistant Materials
Plastics
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© Boardworks Ltd 2005
Learning objectives
Learning objectives
To understand the differences between
thermoplastic and thermosetting plastics.
To become familiar with the properties of different
types of plastic, and know what each is typically
used for.
To be aware of the origins of plastics and with the
range of industrial processes used to manufacture
plastic products.
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© Boardworks Ltd 2005
Plastics
There are two main groups of plastics:
thermosetting plastics
thermoplastic plastics.
Thermoplastic plastics:
The word
What does
the
‘plastic’
means
word ‘plastic’
‘easily
shaped
or mean?
moulded’.
Formed by heat
Soften when heated
Made of long
polymer chains
with few cross links
Can be reheated
and reshaped
Mostly recyclable
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© Boardworks Ltd 2005
Plastics
Thermosetting plastics:
Initially set by heat
Consist of polymer
chains with strong
bonds between
each chain
Strong and durable
Cannot be
reshaped once set
Common in powder
or resin forms
What items do you have in your possession that are
made of plastic? Are they made from thermoplastic
or thermosetting plastics?
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© Boardworks Ltd 2005
Plastics
Thermoplastic plastics are made of long chains of polymers
which don’t cross over very often. When heated, the molecules
slip easily over one another.
Thermosetting plastics also have lots of long chain molecules,
but there are links between them. These cross links prevent the
molecules from moving over one another.
individual monomer molecule
individual monomer molecule
Which of these diagrams depicts a thermoplastic
and which depicts a thermosetting plastic?
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© Boardworks Ltd 2005
Thermoplastic plastics
The majority of common plastics are thermoplastics.
Thermoplastics can be heated and reshaped because of the
ways in which the molecules are joined together.
This can be repeated many times (as long as no damage is
caused by overheating).
Heat
Harden
Soften
Cool
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© Boardworks Ltd 2005
Thermoplastic plastics
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© Boardworks Ltd 2005
Thermosetting plastics
Thermosetting plastics are those which are set with heat and
have little elasticity. Once set, they cannot be reheated and
reformed.
Burn
They are heated and moulded
during manufacture.
Once cooled, they will not
soften again when heated.
This breaks the potentially
unending cycle that
thermoplastic plastics are
capable of.
If heated too much, they burn.
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Heat
Harden
Soften
Cool
© Boardworks Ltd 2005
Thermosetting plastics
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© Boardworks Ltd 2005
Uses of plastics (thermoplastics)
Here are some common products made from thermoplastics. Can
you say which type of thermoplastic each one is made of?
Polystyrene
Polypropylene
High density
polythene
Low density polythene
ABS
Acrylic
Why do thermoplastics make good materials for
What other usesthese
do these
thermoplastics have?
products?
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© Boardworks Ltd 2005
Uses of plastics (thermosets)
Thermosets have different qualities to thermoplastics. Can you
say which thermoset each of these products is made from?
Epoxy
resin
Melamine
formaldehyde
Phenol
formaldehyde
Urea
formaldehyde
GRP
Why are thermosets good materials for these
What other uses do these thermosets have?
particular products?
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© Boardworks Ltd 2005
Working with plastics – considerations
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© Boardworks Ltd 2005
Why do we use plastics?
Think of five reasons why we use plastics. How many of
them are mentioned below?
They can be
shaped into very
complex shapes.
They are soft to the touch.
They are tough and durable.
They are strong.
They can be shaped easily,
quickly and cheaply.
They are light in weight.
They are available in a large range of colours.
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Early and modern plastics
Plastic materials were first used at around 2000BC.
Plastics can occur naturally in trees or even milk;
amber is an example (a resin from trees and
insects). Amber was used by early Egyptians to make
jewellery and is still used for this purpose today.
Today, numerous different plastics are
available. Some are still made from natural
materials but most modern plastics are
manufactured from chemicals obtained
from crude oil. Plastics manufacturers
convert chemicals into plastics.
What implications do you think this has for the
environment?
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© Boardworks Ltd 2005
Oil - the raw material for plastics
Pump
Pipeline
Oil well
Layers
of rock
Gas
Oil
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We obtain crude oil from
under ground, either on
land or at sea.
After it has been pumped,
it is heated in a
fractioning tower and
broken down into
chemicals.
The chemicals consist of
nitrogen, carbon,
chlorine, sulfur and water.
© Boardworks Ltd 2005
The birth of plastics
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© Boardworks Ltd 2005
Acrylic
Acrylic is available in
many different colours.
It comes in sheets
or as round rods.
Acrylic is stronger
than glass, but
scratches easily.
It is also used to
make many outer
cases for toys.
These properties
make acrylic ideal
for shop signs.
Acrylic can resist the
weather very well.
It can be softened and bent, blown or
twisted into many different shapes.
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© Boardworks Ltd 2005
Polystyrene foam
Polystyrene foam can be easily shaped and is very light. This
makes it suitable for modelling three-dimensional objects.
Which other uses for polystyrene can you think of?
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© Boardworks Ltd 2005
Bakelite – a very early plastic
Bakelite was one of the first artificial plastics
and was created in 1909 by Leo Baekeland.
It is used for telephones, radios and electrical
equipment.
Bakelite is a hard, brittle plastic that
has a natural dark glossy colour.
It resists heat without softening.
It is a good thermal insulator and a
good electrical insulator.
When overheated, it burns and
smells.
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© Boardworks Ltd 2005
Melamine
Melamine plastics have similar properties to Bakelite.
However, they have the added advantage of being able to be
coloured during processing.
Melamine
formaldehyde
Urea
formaldehyde
Melamine formaldehyde and urea formaldehyde are two
types of melamine plastics.
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© Boardworks Ltd 2005
Polyester resin
Polyester resin is a
chemical hardener.
Polyester resin can be
reinforced with glass fibre.
It will set at room
temperature.
Glass-reinforced polyester resin
or glass-reinforced plastic
(GRP) is used for making motor
cycle fairings and boats.
When set, the plastic is stiff,
hard and brittle.
When working with it in
large projects, it is advised
to use gloves and a
chemical respirator to
protect yourself from the
fumes.
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© Boardworks Ltd 2005
Vacuum forming
When plastic is used to make a large number of identical
products, industrial processes are used. Specialized
machines are used to mass produce products. Press play
to see a video of the vacuum forming process.
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© Boardworks Ltd 2005
Injection moulding
What similarities and differences can you identify between
the vacuum forming and injection moulding processes?
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© Boardworks Ltd 2005
Blow moulding
What similarities and differences can you identify between
the blow moulding and vacuum forming processes?
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© Boardworks Ltd 2005
Line bending
What products can you think of that have been
manufactured using a strip heater? © Boardworks Ltd 2005
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Compression moulding
What is the difference between male and female
moulds?
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© Boardworks Ltd 2005
Extrusion
Can you think of any other products that are
manufactured using extrusion? © Boardworks Ltd 2005
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Finishing techniques
Plastics have excellent surface qualities. As they are
self-finishing, plastics require little or no surface finish.
However, when designers want a specific colour or texture,
spray paints can be used.
Use wet and dry paper (wet) to smooth the surface down
and create a ‘key’ for the primer to grip to.
Primer is used to create an undercoat to protect the plastic
and provide a good surface finish for the top coat. The
primer should be rubbed down using wet and dry paper
between coats.
Top coat is applied once the primer has completely
hardened. There are different surface textures; gloss, matt
and metallic being the most common. Top coat is applied in
several layers to build up a thick, tough surface layer on the
top of the primer.
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© Boardworks Ltd 2005
Plastics combined with other materials
Plastics are very useful materials. They are durable, easy to join,
self-finishing, easy to mould and not susceptible to rot or sust.
However, sometimes their properties are enhanced by
combining them with other materials.
Carbon fibre can be added to thermosetting plastics to improve
their strength. Golf clubs, tennis racquets, cycle frames and
fishing rods are made using carbon fibre composite.
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© Boardworks Ltd 2005
Working with plastics – keywords
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© Boardworks Ltd 2005
Key points
Key points
Plastics can come under the categories of
thermoplastic and thermosetting plastics. Both have
very different properties.
Most modern plastics are manufactured from
chemicals obtained from crude oil.
Plastic can be shaped or formed using a variety of
industrial processes such as vacuum forming,
injection moulding, blow moulding, line bending,
compression moulding and extrusion.
There are also a number of finishing techniques that
can be used to give a particular colour or texture to a
plastic.
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© Boardworks Ltd 2005
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