ENGINEERING CHEMISTRY 3 (AAECH3A) ASSIGMENENT 1: ALCOHOLS, ETHERS AND EPOXIDES SUBMITION DATE: 17 APRIL 2023 TOTAL: 95 MARKS Question 1 1. Give the IUPAC name of the following alcohols and state if the alcohol is 1⁰, 2⁰ or 3⁰ alcohol. (a) OH CH3CHCH2CH2CH3 (4) OH H3CHC (b) (4) OH (c) CH3 (4) 2. Predict the products of the following reactants: (a) CH3CH2CH2CH=CCH2CH3 CH3 (b) 1. BH3 2. NaOH, H2O2 (3) 1.Hg(OAc)2, H2O 2. NaBH4 (3) (c) CH2CH=CHCH2CH2CH2CH3 1. OsO4 2. NaHSO4, H2O (3) 3. What reagent would you use to accomplish each of the following reactions? (a) OH O CH3CH2CH2CH ? CH3CH2CH2CH2 (2) O (b) CH3CH2CH2CH2CH2COH 4. ? CH3CH2CH2CH2CH2CH2OH (2) What carbonyl compound would give the following alcohols on reduction with LiAlH4 (a) CH3CH2CH2OH + CH3CH2OH (3) OH CH2CCH3 (b) (3) 5. Predict the product of the product of the following reactants. O (a) CH3CH2CH2CH2CH 1. CH3MgBr 2. H2O (3) O 1. CH3CH2MgBr (b) 2. H2O (3) 6. What is the starting carbonyl compound and Grignard reagent used to prepare the following alcohols? CH3 (a) CH2=C-CH2OH (5) CH2OH (b) (5) OH (c) CH3CHCH2CH3 (5) 7. What product are formed when reacting the following: OH (a) CH CH CH CH CH 3 2 2 2 2 OH (b) (c) PCC (2) PCC CH2CCH2CH3 CH3 (2) OH CrO3 CH3CH2CH2CHCH2CH2 H O+ 3 (2) Question 2 1. (a) (b) (c) 2. (a) Draw the structure corresponding to the following IUPAC names. Ethyl 1-ethylpropyl ether Di(p-chlorophenyl) ether Cyclopentyloxycyclohexane (9) Give the IUPAC name of the following ethers and epoxides. CH3 CH3CH (b) O OCH3 OCH3 (a) O CH3 (6) 3. Using Williamson Ether Synthesis, How will the following ethers be prepare? (a) CH3CH2OCH2CH2CH3 Show all the steps (6) 4. How will the following be prepared using Williams synthesis method? (b) CH3 CH-C-OH CH3 ? CH3 CH3C O CH3 (4) Predict the products of the following ether cleavage reactions O-CH2CH3 HI (a) ? H2O CH3 OCH2CHCH3 HBr (a) ? (6) Predict the product of the following O (a) H2O ? - OH O (b) H2O H+ ? (6)