SCH3U ATOMIC STRUCTURE & PERIODIC TABLE PRACTICE TEST Name____________________ Part A 1. Which one of the following conclusions did Rutherford’s gold foil experiment lead to? A. atoms are incredibly small B. atoms are mostly empty space C. electrons exist only in discrete energy levels D. protons are positively charged and electrons are negatively charged _____ 2 . Isotopes of an element have different numbers of A. protons B. neutrons C. electrons D. electrons, protons and neutrons 3. Which term applies to the number of protons in an atom? A. atomic mass B. mass number C. atomic mass unit D. atomic number 4 How many neutrons does the isotope A. 92 B. 146 C. 238 D. 7 _____ ____ 238 U92 have? 5. An atom of lead has an atomic number of 82 and a mass number of 207. How many protons are in this atom of lead ? A. 207 B. 26 C. 82 D. 125 ____________ ____ 6. What does the period number on the periodic table represent? A. number of protons in an atom B. number of neutrons in an atom C. number of valence electrons in an atom D. number of electron shells in an atom ___ 7. A. 2 B. 3 C. 5 ____ 8. In the periodic table, what happens to the atomic radius as you move from left to right across a period? A. The radius increases. B. The radius decreases. C. The radius does not change appreciably. D. The radius varies at random. _____ 9. The above atomic model is the A. Hard sphere model B. Plum pudding model C. Rutherford model D. Bohr model 10. Relative atomic masses are A. are same as mass numbers B. weighted averages of isotopes masses C. always expressed in whole numbers D. fixed in comparison to oxygen ____ _____ 11. What was the major contribution of Niels Bohr to the current model of the atom? A. Electrons may enter the nucleus for brief periods of time. B. Electrons only occupy specific energy levels. C. An electrons has a mass much smaller than the mass of a neutron. D. The charge of an electron is negative. ___ 12. The current model of the atom suggests that A . electron clouds surround the nucleus. B. proton clouds surround the nucleus. C . electrons travel in definite paths around the nucleus. D . the exact path of a moving electron can be predicted. _____ 13. The amount of energy required to remove an electron from an atom is called A. ionization energy B. electron affinity C. atomic energy D. electronegativity ___ 14. If Thomson's model of the atom were correct, then the particles in Rutherford's experiment would have A . bounced directly back to the source. B. been deflected to the left. C . been deflected to the right. D. continued in a straight line. ____ 15. An unknown element has an atomic mass of 45.7 u. Which two isotopes (written from most to least abundant) are likely the most abundant for this element? A. 46, 45 B. 47, 46 C. 45, 46 D. 44, 45 __ 16. Why did Thomson change Dalton's atomic theory? A . Thomson had experimental evidence of atoms, and Dalton did not. B . Thomson's discovery that atoms were made up of even smaller particles showed that part of Dalton's theory was wrong. C. Thomson's discovery of the nucleus showed that Dalton's plum-pudding model was wrong. D. none of the above ____ 17. Neutrons are particles that A. help make up the nucleus and have no charge. B. help make up the nucleus and are positively charged. C. are located outside of the nucleus and are negatively charged. D. are located outside of the nucleus and have no charge. ____ 18. In the cathode-ray tube experiment, a positively charged plate attracted a beam. This showed that the beam was made of A. molecules. B. positively charged particles. C. atoms. D . negatively charged particles. ______ 19. Niels Bohr was able to explain the line spectrum of A. helium B. hydrogen C. oxygen D. neon ________________ 20. What is the mass number of this atom? A. 1 B. 3 C. 4 D. 7 _____ 21. In Bohr’s model when an electron changes its orbit from an outer orbit to a lower orbit , energy is A. released B. absorbed C. unchanged ____ 22. If an atom contains exactly 79 protons, then it's an atom of _____ A. lithium B. silver C. gold D. carbon 23. Which one of the following atoms has the largest radius? A. O B. F C. S D. Cl ________________ ____ 24. Which one of the following has the smallest radius? A) Na B) Cl C) P D) Li _____ 25. Which of the following correctly lists the five atoms in order of increasing size (smallest to largest)? A. O < F < S < Mg < Ba B. F < O < S < Mg < Ba C. F < O < S < Ba < Mg D. O < F < S < Ba < Mg _____ 26. Which of the elements below has the largest electronegativity? E) Si F) Mg G) P D) S ______ 27. Of the following atoms, which has the largest ionization energy? H) Br I) O J) C K) P _____ 28. Below is an outline of the periodic table with a number of elements represented only by the letters A to I is shown. Use these letters when answering this question. Which of the following elements has the highest ionization energy? A. element A B. element H C. element I D. element B 29. The graph shown could represent the trend in which of the following properties? A. atomic radius B. ionization energy C. electronegativity D. electron affinity ____ 30. The following diagram is a Bohr-Rutherford diagram of one element from the periodic table To which group and period does this element belong? A) Period 3 group 4 B) Period 4 group 4 C) Period 3 group 1 D) Period 1 group 3 ____ 31. Which of the following atoms of elements has the greatest attraction for electrons? (a) Ge (b) As (c) Se (d) Br (e) Bi _____ 32. A fictitious element is composed of isotopes A and B with masses of 61.9887 and 64.9846 amu, respectively. The atomic mass of the element is 64.52. What can you conclude about the natural abundance of the two isotopes? a. The natural abundance of isotope A must be greater than the natural abundance of isotope B b. The natural abundance of isotope B must be greater than the natural abundance of isotope A c. The natural abundances of both isotopes must be about equal d. Nothing can be concluded about the natural abundances of the two isotopes from the given information ____ 33. What is the approximate average mass of a hydrogen atom in this sample? a. 6 amu b. 2 amu c. 1.5 amu d. 1 amu 34. Rutherford's gold foil experiment showed that the atom is mostly empty space because a. b. c. d. e. some of the alpha particles were reflected right back some of the alpha particles were deflected most of the alpha particles went straight through the foil all of the alpha particles went straight through the foil all of the alpha particles were deflected PART B-short answer questions 1. Silicon has three isotopes. From the mass of each isotope and isotopic abundance given below, calculate the average atomic mass of silicon . Show your work including the correct number of significant figures to get full marks( 5 marks) isotope atomic mass(u) isotopic abundance(%) Si-28 27.98 92.23 Si-29 28.97 4.67 Si-30 29.97 3.10 Average atomic mass of silicon = 27.98 u x 92.23 100 = 25.805954 u = + + 28.97 u 1.352899 u x 4.67 100 + + 29.97 u x 3.10 100 0.92907 u 28.087923 u = 28.1 u ( based on the least precise given quantity- in this question the least precise given quantity is the abundance which has 3 sig figs) Note : you only round after the last calculation in all multi steps chemistry problems do not round intermediate steps- show all numbers as it appears in calculator round to the least precise given quantity( i.e. the least number of sig figs) make sure your final answer has units 2. For the following elements , Arrange the elements in order of increasing radius. Explain your answer using the concepts of effective nuclear charge and shielding. C < A<D -Al three atoms have the same amount of electron shielding because they have the same number of shells C has the highest effective nuclear charge since it has the most number of protons( 18 protons) and therefore the attraction for the electrons also increases. This increased attraction pulls the electrons closer to the nucleus resulting in a smaller atomic radius D has the smallest effective nuclear charge since it has the least number of protons( 11) And therefore the weakest attraction between the nucleus and the electrons resulting in a larger atomic radius 3. Elements A, B, C and D have atomic radii of 265 pm, 160 pm, 185 pm, and 175 pm respectively. (a) Which element will have the lowest ionization energy? Why? A - Ionization energy decreases with increasing atomic radius Because there is weaker attraction between the valence electron and the nucleus in a larger atom so it requires less energy to remove an electron from a larger atom (b) Which element-A,B, C or D will have the highest electronegativity? Why? (2 marks) B - Electronegativity increases with decreasing atomic radius -Because the smaller the atom the closer is the nucleus to the bonding electrons therefore the stronger is the attraction between the nucleus and the bonding electrons (c) Which of the following entities- A atom or A2+ ion will have a larger size? Why?( 2 marks) Atom A When an atom loses an electron to form a positive ion , the attraction between the remaining electrons and the nucleus is increased. As a result, the electrons are drawn closer to the nucleus and the positive ion becomes smaller 4. (a) (b) (c) Bohr`s How did Ernest Rutherford discover the nucleus of the atom? Describe how Bohr modified Rutherford’s atomic model. State one similarity and one difference between Rutherford’s atomic model and atomic model (a) Rutherford aimed positively charged alpha particles at a gold foil. He observed that most of the alpha particles pass through the gold foil but a few of these particles were deflected at various angles From these observation Rutherford reasoned that an atom must have a small dense positively charged nucleus in the center of the atom (b) Bohr proposed that electrons only exist in certain allowed orbits around the nucleus. The electrons do not lose energy in these allowed orbits (c) similarity --- Both models have a small dense positively charged nucleus Difference - In Bohr’s model the electrons can only move in certain orbits In Rutherford’s model the electrons are moving in all orbits around the nucleus 5. . (a) How did Democritus reason for the existence of atoms? •Matter could not be divided into smaller and smaller pieces forever. Eventually the smallest possible piece would be obtained. This piece would be indivisible called the atom (b) Why was Thomson’s atomic model rejected? It could not explain the observations of the Gold Foil scattering experiment done by Rutherford