1.0 ABSTRACT This experiment is to observe the relationship between the pressure and temperature of a saturated steam in equilibrium with water and also to demonstrate the vapour pressure curve. This experiment is carried out by using Marcet Boiler. Marcet Boiler is use for the understanding of basic properties of saturated steam. Set the temperature controller and observe the steam temperature rise as the water boils. The steam temperature and different readings is record as the boiler is heated or cooled. As the result, the temperature increases as the pressure increase. Some of the values are not the same at the certain point. This is because some of the errors occur along the experiment. 2.0 INTRODUCTION Thermodynamics is a branch of study of physics that deals with the interchange of energies such as work and heat between a system and a surrounding when the system undergoes a process which are either cooling or heating. The loss or gain of energy of the system during a process has a direct impact on the thermodynamics properties. Two of the most important thermodynamics properties that are being investigated in this experiment are absolute pressure and temperature that are both changes during the process in the system. The data from the experiment will be compared with the theoretical value obtained from the steam table. For the purpose of this experiment, we will be using SOLTEQ®Marcet Boiler (Model: HE169) which is the bench top unit designed for the demonstration of the basic principal in thermodynamics which is boiling. SOLTEQ®Marcet Boiler (Model: HE169) are the most common device used for students in the laboratory in order for them to have a better understanding the relationship between absolute pressure and temperature of saturated steam in equilibrium with water. 3.0 OBJECTIVE The main objective of this experiment isto determine the saturation pressure curve at the pressure within 10bar (150lb/in2). This experiment is also carried out to investigate between the pressure and temperature of saturated steam in equilibrium with water. Then, by using the data from the experiment, construct a graph for a function of temperature against the absolute pressure and calculate the slope of the curve (dT/dP). Next, the results from this experiment will be compared with the theoretical value obtained from the steam table. However, we may not be able to get an accurate value of data as it might have errors during the experiment. 4.0 THEORY The use of Marcet Boiler is to investigate the relationship between a saturated pressure and the temperature of water between ranges of 0-14 bar. By using the Marcet Boiler, we can observe that as the temperature of water increases, the pressure also increases. Thus, the temperature of water is said to be directly proportional with the pressure. Thermodynamics is a study related between energy and entropy, which is also deal with heat and work. It is a set of theories that related to macroscopic properties, visible with naked eye which we can measure the volume, pressure and temperature. Ideal gas law is a law in which related to pressure, temperature and also volume of an ideal gas. Ideal gas law is originally derived experimentally measured from Charles’s Law and Boyle’s Law. Let P is pressure of a gas, V is a volume it occupies and T is it temperature which is in Kelvin, K. The ideal gas law state that PV = nRT Where, P = Absolute pressure, kPa V = Volume, m³ n = Amount of substances, moles R = Ideal gas constant, kJ/kg.K T = Absolute temperature, K The measured value of the slope of a graph (dT/dP)SAT can be obtained from the data of result from the experiment done and compare it with corresponding values calculated from the steam tables. � � � � SAT = �Vfg fg � �f − �g SAT = f− g And hf + hfg= hg Hence, hfg = hg – hf As Vg>>Vf Where , Vf Vg hf hg hfg � � SAT = � �f − �g fg = specific volume of saturated liquid = specific volume of saturated vapour = enthalpy of saturated liquid = enthalpy of saturated vapour = latent heat of vaporization = �Vg fg 5.0 APPARATUS AND MATERIAL Material : Distilled water Apparatus : 6 1 2 7 3 8 4 9 10 5 Figure 1 : Unit Construction for Marcet Boiler (Model : HE169) No 1. Apparatus Pressure Transducer 2. Pressure Indicator 3. Temperature Indicator/Controller 4. Control Panel 5. Bench 6. Bourdon Tube Pressure Gauge 7. Temperature Sensor 8. Pressure Relief Valve 9. Heater 10. Water Inlet Port & Valve 6.0 METHODOLOGY General Operating Procedures General Start-up Procedures 1) Perform a quick inspection to ensure that the unit was in a proper operating condition. 2) Connect the unit to the nearest power supply. 3) Inspect whether water was already filled in the boiler. If water had been filled in the boiler, skip step no 4 and 5. 4) Open the valves at the feed port and the level sight tube (V1, V2 and V3). 5) Fill in the boiler with distilled water through the feed port and make sure that the water was at about half of the boilers height. Then, close the valves, V1 and V2 at the level sight tube. 6) Turn on the power supply switch. 7) Carry out the experiment. General Shut-down Procedures 1) Switch off the heater and allow the boiler temperature to drop until room temperature. 2) When the temperature had dropped down to a room temperature, switch off the main switch and the main power supply. 3) Retain the water for the next use. 4) To drain off the water, open the upper part of the level sight tube, V3 and then open V1 and V2 to drain off the water. Note : Do not open the valve at the water inlet port as it was highly pressurized at a higher temperature. Experimental Procedure 1) Perform the general start-up procedures 2) If the boiler was initially filled with water, open the valves at the level sight tube (V2 and V3) to check the water level. Pour in additional distilled water if necessary. Then, close the valves. 3) Set the temperature controller to 185.0 °C which was slightly above the expected boiling point of the water at 10.0 bar (absolute pressure). 4) Open the vent valve, V3 and turn on the heater.It is always important to ensure that the valves at the level sight tube are closed before turning on the heater as the level sight tube is not designed to withstand high pressure and temperature. 5) Observe the steam temperature rise as the water boils. 6) Allow the steam to come out from the valve, V3 for about 30 seconds, and then close the valve. This step was important to remove air from the boiler as the accuracy of the experimental results will be significantly affected when air is present. 7) Record the steam temperature and pressure when the boiler is heated until the steam pressure reaches 10.0 bar (absolute pressure). (Make the intervals of pressure data for 0.1 initially, followed by 0.2 and 0.5 for the following data). 8) Then, turn off the heater and the steam temperature and pressure will begin to drop. Start to record the steam temperature when the boiler is cooled down until the steam pressure reaches atmospheric pressure. 9) Allow the boiler to cool down to a room temperature. 10) Record the steam temperatures at different pressure readings when the boiler is heated and cooled. Warning : Never open the valve when boiler is heated as pressurized steam can cause severe injury. 7.0 RESULT Pressure, P (bar) Temperature, T Gauge Absolute Increase (ᵒC) Decrease (ᵒC) Average Tavc (ᵒC) Average Tavc(K) 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00 1.10 1.20 1.30 1.40 1.50 1.60 1.70 1.80 1.90 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2.0 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0 7.5 8.0 8.5 9.0 9.5 10.0 100.60 101.70 102.20 104.90 107.00 109.10 111.30 113.20 115.0 116.80 118.40 120.10 121.60 123.10 124.50 126.00 127.30 128.60 129.90 131.00 132.20 137.6 142.50 146.80 150.80 154.40 157.80 161.00 164.00 166.80 169.50 172.00 174.50 176.90 179.10 99.90 102.60 105.00 107.40 109.40 111.70 113.70 115.50 117.30 119.00 120.60 122.10 123.6 125.10 126.50 127.80 129.10 130.30 131.50 132.80 133.90 139.20 143.90 148.30 152.20 155.80 159.20 162.40 165.50 168.30 170.90 173.40 175.80 177.80 179.10 100.25 102.15 103.60 106.15 108.20 110.40 112.50 114.35 116.15 117.90 119.50 121.10 122.60 124.10 125.50 126.90 128.20 129.45 130.70 131.90 133.05 138.40 143.20 147.55 151.50 155.10 158.50 161.70 164.75 167.55 170.20 172.70 175.15 177.35 179.10 373.25 375.15 376.60 379.15 381.20 383.40 385.50 387.35 389.15 390.90 392.50 394.10 395.60 397.10 398.50 399.90 401.20 402.45 403.70 404.90 406.05 411.40 416.20 420.55 424.50 428.10 431.50 434.70 437.75 440.55 443.20 445.70 448.15 450.35 452.10 Measured slope, dT/dP Calculated slope, Tvg/hfg 0.190 0.145 0.255 0.205 0.220 0.210 0.185 0.180 0.175 0.160 0.160 0.150 0.150 0.140 0.140 0.130 0.125 0.125 0.120 0.115 0.107 0.096 0.087 0.079 0.072 0.068 0.064 0.061 0.056 0.053 0.050 0.049 0.044 0.035 0.2800 0.2600 0.2413 0.2257 0.2128 0.1997 0.1904 0.1809 0.1725 0.1653 0.1579 0.1522 0.1464 0.1412 0.1365 0.1318 0.1279 0.1255 0.1203 0.1171 0.1137 0.1004 0.0902 0.0821 0.0755 0.0700 0.0653 0.0613 0.0578 0.0547 0.0520 0.0496 0.0474 0.0455 0.0436 8.0 CALCULATION Calculation for measured slope, (dT/dP) :Pressure, Pabs (bar) dP (kPa) Average Tavc (K) dT (K) (dT/dP) (K/kPa) 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2.0 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0 7.5 8.0 8.5 9.0 9.5 10.0 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 50 50 50 50 50 50 50 50 50 50 50 50 50 50 373.25 375.15 376.60 379.15 381.20 383.40 385.50 387.35 389.15 390.90 392.50 394.10 395.60 397.10 398.50 399.90 401.20 402.45 403.75 404.90 406.05 411.40 416.20 420.55 424.50 428.10 431.50 434.70 437.75 440.55 443.20 445.70 448.15 450.35 452.10 1.9 1.45 2.55 2.05 2.20 2.10 1.85 1.80 1.75 1.60 1.60 1.50 1.50 1.40 1.40 1.30 1.25 1.25 1.20 1.15 5.35 4.80 4.35 3.95 3.60 3.40 3.20 3.05 2.80 2.65 2.50 2.45 2.20 1.75 0.190 0.145 0.255 0.205 0.220 0.210 0.185 0.180 0.175 0.160 0.160 0.150 0.150 0.140 0.140 0.130 0.125 0.125 0.120 0.115 0.107 0.096 0.087 0.079 0.072 0.068 0.064 0.061 0.056 0.053 0.050 0.049 0.044 0.035 Sample calculation for average temperature, Tavg :- Average Temperature, Tavg =T increase + T decrease 2 = 100.6 ᵒC + 99.9 ᵒC 2 = 100.25 ᵒC = 100.25 ᵒC + 273 K = 373.25 K Sample calculation for dP :- dP 2.1 bar = Pabs @ 2.1 bar – Pabs @ 1.1 bar = 2.1 bar – 1.1 bar = 1.0 bar = 1.0 bar × 100 kPa 1 bar = 100 kPa Sample calculation for dT :dT2.1 bar = Tavg @ 2.1 bar - Tavg @ 1.1 bar = 394.10 K – 374.56 K = 19.54 K Sample Calculation for (dT / dP) :- (dT / dP) 1.5 bar = (dT 1.5 bar / dP 1.5 bar) = 2.20/10 =0.22 K/kPa Sample Calculation for Vf :- 150 kPa – 125 kPa = 175 kPa – 125 kPa Vf Vf m³ / kg – 0.001048 m³ / kg 0.001057 m³/kg – 0.001048 m³/kg = 0.0010525 m³ / kg Sample Calculation for vg :- 150 kPa – 125 kPa 175 kPa – 125 kPa Vg = = Vg m³ / kg – 1.3750 m³ / kg 1.0037 m³ / kg – 1.3750 m³ / kg 1.18935 m³ / kg Sample Calculation for Vfg :- Vfg = = Vfg = Vg – Vf 1.18935 m³ / kg – 0.0010525 m³ / kg 1.1882975 m³ / kg Sample Calculation for enthalpy, hfg :- 150 kPa – 125 kPa = 175 kPa – 125 kPa hfg hfg kJ/kg – 2240.6 kJ/kg 2213.1 kJ/kg – 2240.6 kJ/kg = 2226.85 kJ/kg Sample Calculation for Calculation Slope, (Tvfg / hfg) :- (Tvfg / hfg) = (383.40 K) (1.1882975 m³ / kg) 2226.85 kJ/kg = 0.20459 m³ K / kJ X 1 kJ 1 kPa.m³ = 0.20459 K / kPa Calculation for calculated slope, (�� / ) :- Pressure, P (bar) Temperature,T (K) Specific volume, v (m3/kg) Enthalphy, h (kJ/kg) Gauge Absolute Average Tavc Vg hfg 373.25 375.15 376.60 379.15 381.20 383.40 385.50 387.35 389.15 390.90 392.50 394.10 1.6941 1.5540 1.4340 1.3320 1.2456 1.1594 1.0971 1.0348 0.9801 0.9329 0.8858 0.8488 2257.50 2250.14 2243.78 2237.68 2231.84 2226.00 2220.84 2215.68 2210.80 2206.20 2201.60 2197.36 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00 1.10 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2.0 2.1 Calculated slope, (�vg/ fg) 0.2800 0.2600 0.2413 0.2257 0.2128 0.1997 0.1904 0.1809 0.1725 0.1653 0.1579 0.1522 1.20 1.30 1.40 1.50 1.60 1.70 1.80 1.90 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0 7.5 8.0 8.5 9.0 9.5 10.0 395.60 397.10 398.50 399.90 401.20 402.45 403.75 404.90 406.05 411.40 416.20 420.55 424.50 428.10 431.50 434.70 437.75 440.55 443.20 445.70 448.15 450.35 452.10 0.8118 0.7784 0.7486 0.7187 0.6942 0.6696 0.6470 0.6264 0.6058 0.5242 0.4624 0.4139 0.3748 0.3426 0.3156 0.2926 0.2728 0.2555 0.2404 0.2269 0.2149 0.2041 0.1944 2193.12 2189.04 2185.12 2181.20 2177.52 2173.84 2170.30 2166.90 2163.50 2147.70 2133.40 2120.30 2108.00 2096.60 2085.80 2075.50 2065.80 2056.40 2047.50 2038.80 2030.50 2022.40 2014.60 0.1464 0.1412 0.1365 0.1318 0.1279 0.1255 0.1203 0.1171 0.1137 0.1004 0.0902 0.0821 0.0755 0.0700 0.0653 0.0613 0.0578 0.0547 0.0520 0.0496 0.0474 0.0455 0.0436 Sample calculation for percentage error, % :� ,% = = � − � � 0.1130 − 0.1518 � 100% 0.1130 � � 100% = -34.34% Calculated slope, � fg fg (K/kPa) Measured slope, � � � �� (K/kPa) 0.2800 0.2600 0.2413 0.2257 0.2128 0.1997 0.190 0.145 0.255 0.205 0.220 Percentage error (%) -36.84 -66.41 11.49 -3.80 9.23 0.1904 0.1809 0.1725 0.1653 0.1579 0.1522 0.1464 0.1412 0.1365 0.1318 0.1279 0.1255 0.1203 0.1171 0.1137 0.1004 0.0902 0.0821 0.0755 0.0700 0.0653 0.0613 0.0578 0.0547 0.0520 0.0496 0.0474 0.0455 0.0436 0.210 0.185 0.180 0.175 0.160 0.160 0.150 0.150 0.140 0.140 0.130 0.125 0.125 0.120 0.115 0.107 0.096 0.087 0.079 0.072 0.068 0.064 0.061 0.056 0.053 0.050 0.049 0.044 0.035 9.33 2.22 4.17 5.54 1.31 4.88 2.40 5.87 2.50 5.86 1.62 -0.4 3.76 2.42 1.13 6.17 6.04 5.63 4.43 2.78 3.97 4.22 5.25 2.32 1.89 0.80 3.27 -0.03 Measured slope against Calculated Slope 0.3 0.25 Slope 0.2 0.15 measured slope 0.1 calculated slope 0.05 0 1 1.2 1.4 1.6 1.8 2 2.2 2.4 2.6 2.8 3 4 5 6 7 8 9 10 Absolute Pressure,P, (Bar) Average Temperature (K) against Absolute Pressure,P,(bar) 500 450 350 300 250 200 150 100 50 0 1 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 3 3.5 4 4.5 5 5.5 6 6.5 7 7.5 8 8.5 9 9.5 10 Average Temperature (K) 400 Absolute Pressure,P,(bar) 9.0 DISCUSSION 1. Before the experiment is conducted, it is vital to remove the air from the boiler. This is because, air might affects the accuracy of the experimental results. If the air is not removed, the correct equilibrium measurements between the steam and the boiling water will not be obtained. Due to the partial pressure of air, a lower water temperature will be required to raise the pressure. Besides, the air trapped in the boiler could lead to boiler failure. 2. Measured slope against Calculated Slope 0.3 0.25 Slope 0.2 0.15 measured slope calculated slope 0.1 0.05 0 1 1.2 1.4 1.6 1.8 2 2.2 2.4 2.6 2.8 3 4 Absolute Pressure,P, (Bar) 5 6 7 8 9 10 Average Temperature (K) against Absolute Pressure,P,(bar) 500 450 Average Temperature (K) 400 350 300 250 200 150 100 50 0 1 1.11.21.31.41.51.61.71.81.9 2 2.12.22.32.42.52.62.72.82.9 3 3.5 4 4.5 5 5.5 6 6.5 7 7.5 8 8.5 9 9.5 10 Absolute Pressure,P,(bar) 3. The error percentage should not cross or exceed 10% as the experiment was done in enclosed surface and no volume of experimenting samples are allowed to escape from the system. However, based on the data obtained from experiment, the percentage of errors is within the range of -35 % – 41 %. The percentage error for the experiment shows that the experimental yield was too much when the percentage error is negative. Differ when the percentage of error is positive, it shows that the experimental yield less than the theoretical yield. This might happen due to the present of air in the boiler and the measurements reading errors that happen during the experiment. There are several sources of error of the experiment:I. Measurement reading accuracy. II. Room temperature and pressure. III. The stability of the material. IV. The calculations of the data obtained. In order to make sure the accuracy of the data obtained, we must avoid the measurements reading errors. 4. When the water in the boiler is heated up, the liquid molecules started to gain heat and move faster. As they move around so fast that they can not even hold on to each other anymore, all the molecules started to flying apart and becoming gas. As the liquid absorbed enough heat energy, it changes from liquid form to vapour form. However, as the steam is not allowed to exit, the pressure in the boiler increases. Thus, causing the temperature rise. The liquid (water) undergoes evaporation and becomes gas (steam). 5. The boilers in the industries include : Power plant boiler The boiler generates high pressure steam by transferring heat of combustion in various heat transfer sections. Volume of one unit mass of steam is thousand times that of water. When water is converted to a steam in a closed vessel, the pressure will increase. Heat the water from a cold condition to a boiling point or saturation temperature. Water boils at saturation temperature to produce steam. Heating steam from saturation temperature to higher temperature called superheating to increase the power plant output and efficiency. Food steamer used by food industries There are two types of food steamers used by the food industry to heat food in large quantities. The traditional design uses steam trays connected to a central boiler. Newer technology uses individual heating systems to create the steam on each set of steam trays. The newer technology offers significant advantages in both energy and water efficiency. The boiler-based steamers utilize a boiler to inject (through pipes) steam into the heating compartment containing the food trays. Steam that does not condense on the food product escapes as a mixture of steam and hot condensate through a drain at the bottom of the set of steam trays. Not only is water wasted in the rejected steam, but also a substantial amount of additional water is required to condense this steam and cool the condensate water to an acceptable temperature before it enters the sewer system Fluidized bed reactor The fuel is fluidized in oxygen and steam or air. The ash is removed dry or as heavy agglomerates that defluidize. The temperatures are relatively low in dry ash gasifiers, so the fuel must be highly reactive; low-grade coals are particularly suitable. The agglomerating gasifiers have slightly higher temperatures, and are suitable for higher rank coals. Fuel throughput is higher than for the fixed bed, but not as high as for the entrained flow gasifier. The conversion efficiency can be rather low due to elutriation of carbonaceous material. Recycle or subsequent combustion of solids can be used to increase conversion. Fluidized bed gasifiers are most useful for fuels that form highly corrosive ash that would damage the walls of slagging gasifiers. Biomass fuels generally contain high levels of corrosive ash. Steam engines Steam engines are external combustion engines, where the working fluid is separate from the combustion products. Non-combustion heat sources such as solar power, nuclear power or geothermal energy may be used. The ideal thermodynamic cycle used to analyse this process is called the Rankine cycle. In the cycle, water is heated and transforms into steam within a boiler operating at a high pressure. When expanded through pistons or turbines, mechanical work is done. The reduced-pressure steam is then condensed and pumped back into the boiler. 10.0 CONCLUSION Marcet boiler is a device which we use to study the relationship between pressure and temperature for water at saturated liquid phase. As what we did in the laboratory, we started the experiment by heating water with constant pressure until it reached boiling point. Then, close the valve which creates a constant volume system which will forced the pressure to increase as the temperature rises. And thus enable us to study the direct relationship between pressure and temperature for water at that point. We notice that it is essential to close the valve as it reached the boiling point to ensure that we are now in a constant volume process or otherwise pressure would have never increased and this will result the experiment to be useless. We also notice that weclosed the valve exactly when we reached the boiling temperature and thus keeping the water at a saturated liquid phase. After studying the results and plotting the diagram, we find out that the relationship between pressure and temperature is directly proportional. The difference between the theoretical values and the actual values is caused by errors with certain calculated acceptable percentages. In this experiment, the relationship between pressure and temperature is found to be directly proportional. When compared to the theoretical slope, the experimental slope shows a small deviation between them because of certain errors. 11.0 RECOMMENDATIONS There are many ways for minor error can occur in the data from this lab. The first recommendation is to check and rectify any leaks at the boiler. This is to ensure an accurate reading is recorded throughout the experiment. The second recommendation is use only distilled water for this experiment. The reason is to maintain the boiler’s life from rusting and any damage. The third recommendation would be it is not necessary to drain the water from the boiler. This is because there is no rusting element in the boiler that can cause major damage to equipment. Lastly, it is recommend not to touch the hot component of the unit. Be more alert and careful when handling the boiler. This could cause some serious injury if the safety is taken for granted throughout the experiment 12.0 REFERENCES 1) Yunus A. Cengal& Michael A. Boles, “Thermodynamics – An Engineering Approach”, 3rd Edition, 4th Edition, McGraw Hill, 2002. 2) James, T., Fatigue Failure for Dummies, Made Up Press, New York, 2nd Ed (1999), pp.23 3) Davis, J., Metals Handbook, Vol 2, 10th Ed., ASM International, 1990, pp.145-165 13.0 APPENDIX Pressure, P (bar) Temperature, T Gauge Absolute Increase (ᵒC) Decrease (ᵒC) Average Tavc (ᵒC) Average Tavc(K) 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00 1.10 1.20 1.30 1.40 1.50 1.60 1.70 1.80 1.90 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2.0 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0 7.5 8.0 8.5 9.0 9.5 10.0 100.60 101.70 102.20 104.90 107.00 109.10 111.30 113.20 115.0 116.80 118.40 120.10 121.60 123.10 124.50 126.00 127.30 128.60 129.90 131.00 132.20 137.6 142.50 146.80 150.80 154.40 157.80 161.00 164.00 166.80 169.50 172.00 174.50 176.90 179.10 99.90 102.60 105.00 107.40 109.40 111.70 113.70 115.50 117.30 119.00 120.60 122.10 123.6 125.10 126.50 127.80 129.10 130.30 131.50 132.80 133.90 139.20 143.90 148.30 152.20 155.80 159.20 162.40 165.50 168.30 170.90 173.40 175.80 177.80 179.10 100.25 102.15 103.60 106.15 108.20 110.40 112.50 114.35 116.15 117.90 119.50 121.10 122.60 124.10 125.50 126.90 128.20 129.45 130.70 131.90 133.05 138.40 143.20 147.55 151.50 155.10 158.50 161.70 164.75 167.55 170.20 172.70 175.15 177.35 179.10 373.25 375.15 376.60 379.15 381.20 383.40 385.50 387.35 389.15 390.90 392.50 394.10 395.60 397.10 398.50 399.90 401.20 402.45 403.70 404.90 406.05 411.40 416.20 420.55 424.50 428.10 431.50 434.70 437.75 440.55 443.20 445.70 448.15 450.35 452.10 Measured slope, dT/dP Calculated slope, Tvg/hfg 0.190 0.145 0.255 0.205 0.220 0.210 0.185 0.180 0.175 0.160 0.160 0.150 0.150 0.140 0.140 0.130 0.125 0.125 0.120 0.115 0.107 0.096 0.087 0.079 0.072 0.068 0.064 0.061 0.056 0.053 0.050 0.049 0.044 0.035 0.2800 0.2600 0.2413 0.2257 0.2128 0.1997 0.1904 0.1809 0.1725 0.1653 0.1579 0.1522 0.1464 0.1412 0.1365 0.1318 0.1279 0.1255 0.1203 0.1171 0.1137 0.1004 0.0902 0.0821 0.0755 0.0700 0.0653 0.0613 0.0578 0.0547 0.0520 0.0496 0.0474 0.0455 0.0436