Name : _____________________ Teacher: ______________________ Acids, bases and salts – an introduction! Hydrogen, hydrochloric acid, pH, water, pure water, neutral, hydroxide ions, hydrogen, An example of an acid is _____________ _________. When acids dissolve in water they form ______ ions (H +). Alkalis are bases when dissolved in _______. Alkalis form __________ (OH-) when dissolved in water. The _____ scale tells us which kind of ion is present. pH stands for the % _________ in solution. A ________ solution has a pH of 7 An example of a neutral solution is _____ _______. In the space below write a symbol equation to describe what happens when hydrochloric acid is mixed with water. In the space below write a symbol equation to describe what happens when sodium hydroxide is mixed with water. Challenge yourself: What do you think happens when we add equal quantities of acid and base together? 1 Acid and alkali strength You probably used universal indicator to test acids and alkalis. This solution (or paper) is really useful as it allows us to tell where on the pH scale something is. You are going to test some solutions and work out whether they are acid or alkaline. But first we need to look at how universal indicator (UI) works. Can you colour in this chart to show the COLOUR that UI turns in different solutions? pH 1 Colour 2 3 4 5 6 7 8 9 10 11 12 Anything with a pH of ………………………………….. is an acid Anything with a PH of …………………………………… is an alkali pH …………………… is neutral What happens to the strength of an acid as the pH decreases? ……………………………………………………………………………………………………………………………. What happens to the strength of an alkali as the pH increases? ……………………………………………………………………………………………………………………………. I would describe pH 5 as a …………………… …………………………….. I would describe pH 14 as a …………………… …………………………….. 2 13 14 Experiment: For this experiment you are going to use red and blue litmus paper and either universal indicator solution or paper. You need to test each solution and match the colour change to the pH scale to discover the pH of the solution. Record your results in the table below. Substance Red Blue Universal pH Red Type of litmus litmus indicator cabbage substance Distilled water Bicarbonate of soda Hydrochloric acid Salt solution Sodium hydroxide Lemon juice Sulphuric acid Orange juice Stomach powder solution Toothpaste Toilet cleaner Tap water Vinegar 3 Don’t forget that everyday substances are acidic. This is why you need to clean your teeth kids… so that the acid in the food you eat does not erode your tooth enamel away. What do you notice about the pH of toothpaste?................................................................................. Why do you think this might be?............................................................... ……………………………………………………………………………………………………………………….. Information Main Laboratory Acids Acids found at home: Citric acid Vinegar (acetic acid) Coke (phosphoric acid) Vitamin C (ascorbic acid) Name Formula Hydrochloric Acid Nitric Acid Sulphuric Acid HCl(aq) HNO3(aq) H2SO4(aq) Acids taste SOUR Acids contain HYDROGEN IONS H + (aq) Main Laboratory Alkalis Alkalis found at home: Name Sodium Hydroxide Potassium Hydroxide Calcium Hydroxide Ammonium Hydroxide Formula NaOH(aq) KOH (aq) Ca(OH)2(aq) NH4OH(aq) Alkalis feel SOAPY Alkalis contain HYDROXIDE IONS OH – (aq) Soap Toothpaste Shampoo 4 Past paper question 5 Summary of the things that you have learnt this lesson- in your own words 6 Acids and Metals Do you remember the metal reactivity series? Write down as many metals as you can think of with the most reactive at the top and the least reactive at the bottom: Try and do it WITHOUT looking at your Periodic table Your list Actual list Now compare this with the list that your teacher comes up with and write these in the right hand column . Are there any surprises? 7 Experiment: You are going to use hydrochloric acid and a selection of metals and see what happens when you react them together. Wear goggles! Use about 1 cm depth of acid in the test tube and half a spatula of metal. Write down everything that you observe (you may want to feel the tubes). Also test the gas that is produced. Metal Observations Reactivity Copper Magnesium Iron Zinc Aluminium Once you have finished write down the order of the reactivity of the metals. Use 1 for the most reactive. What gas is produced in this reaction?......................................................... How do you test for this gas?........................................................................ 8 Equations: We need the equations to explain what is happening First of all we need to know what we have in order to be able to write equations....... Metals are easy, they are on the left hand side of the periodic table. What do all acids contain?......................................................................... When a metal and an acid react together they make salts. SALT - a SALT is formed when the Hydrogen of an Acid is replaced by a metal Naming SALTS Remember metals (except copper and some others) push out (displace) the hydrogen of acids to make SALTS. ACID TYPE of SALT made Hydrochloric acid HCl(aq) CHLORIDES e.g. sodium chloride NaCl(s) Sulphuric acid H2SO4(aq) SULPHATES e.g. magnesium sulphate MgSO4(s) Nitric acid HNO3(aq) NITRATES e.g. potassium nitrate KNO3(s) Carbonic acid H2CO3(aq) CARBONATES e.g. zinc carbonate ZnCO3(s) Phosphoric acid H3PO4(aq) PHOSPHATES e.g. calcium phosphate Ca3(PO4)2(s) 9 So, a SALT contains: And a CATION e.g. Na+ (usually from a METAL) an ANION e.g. Clfrom an ACID e.g. hydrochloric acid HCl(aq) We will not write an equation for copper as it doesn’t react. The first one has been done for you as an example 1. magnesium + hydrochloric acid magnesium + hydrogen …chloride.... Mg + 2. Iron 2HCl MgCl2 + H2 + hydrochloric acid ……………………….. + …………………………… ………………………. Fe + 3. Zinc HCl ……………………….. + …………………………… + hydrochloric acid ……………………….. + …………………………… ………………………. Zn + HCl ……………………….. + …………………………… 4. aluminium + hydrochloric acid ……………………….. + …………………………… ………………………. Al 5. + tin HCl ……………………….. + …………………………… + hydrochloric acid ……………………….. + …………………………… ………………………. Sn + HCl ……………………….. + …………………………… 10 Past paper question The reactions of metals with acids can show the reactivity trend amongst the metals. Remember back to your metals topic.... why do you think that you were not given sodium to react with the hydrochloric acid today? ......................................................................................................................... Write out the general equation for the reaction of a metal with an acid: ..................... + ...................... ..................... ................. + ................................ 11 Extension Equations: You did equations for hydrochloric acid, now what if you had a different starting acid? You may need to look back at your notes to check that you get the formulae of these compounds correct 1. magnesium + nitric acid ……………………….. + …………………………… ………………………. Mg 2. Iron + HNO3 + nitric acid ……………………….. + …………………………… ……………………….. + …………………………… ………………………. Fe + 3. Zinc HNO3 + nitric acid ……………………….. + …………………………… ……………………….. + …………………………… ………………………. Zn + HNO3 4. aluminium + nitric acid ……………………….. + …………………………… ……………………….. + …………………………… ………………………. Al 5. + tin HNO3 + nitric acid ……………………….. + …………………………… ……………………….. + …………………………… ………………………. Sn + HNO3 ……………………….. + …………………………… 12 6. magnesium + sulphuric acid ……………………….. + …………………………… ………………………. Mg 7. Iron + H2SO4 ……………………….. + …………………………… + sulphuric acid ……………………….. + …………………………… ………………………. Fe + 8. Zinc H2SO4 ……………………….. + …………………………… + sulphuric acid ……………………….. + …………………………… ………………………. Zn + H2SO4 9. aluminium + sulphuric acid ……………………….. + …………………………… ……………………….. + …………………………… ………………………. Al 10. + tin H2SO4 + sulphuric acid ……………………….. + …………………………… ……………………….. + …………………………… ………………………. Sn + H2SO4 ……………………….. + …………………………… 13 Neutralisation Method: 1. Use a measuring cylinder to measure out 20cm3 of acid and pour into the burette. 2. Measure 20cm3 of sodium hydroxide into a flask/beaker 3. Add 2-3 drops of Universal indicator with a pipette. 4. Slowly open tap on burette and let the acid drop out. 5. Stop when solution turns green. 6. Pour solution into a petri dish and leave overnight. 7. Note the volume of acid used to neutralise the alkali. 8. Repeat experiment. Results: Burette readings Accurate titrations Rough titration End point Start of titration Volume of acid used 1st 2nd 3rd cm3 cm3 cm3 cm3 0.0 cm3 0.0 cm3 0.0 cm3 0.0 cm3 cm3 cm3 cm3 cm3 1.Give the word equation for the neutralization reaction of an acid and a base. ___________ + ___________→_____________+___________ 2. Complete the equation for this neutralization reaction: a) In symbol form HCl b) In word form + NaOH → _________ + _________→___________+________ 3. A _______________ is a laboratory method used to determine the concentration of an acid or a _______________ in solution by performing a _______________ reaction with a standard solution. 14 4. At the ______________ of the titration, the indicator changes color, which indicates neutralization. Once neutralized, number of _____________ and number of ____________ are equal. 5.What colour did the solution turn when just enough acid was added? _____________ 6.What colour did the solution turn when too much acid was added?____________ Possible words to use: yellow, sodium hydroxide, titration, NaCl ,salt, green, neutralization, acid, H20, alkali, water, end, hydrogen ions, hydroxide ions Reviewing Neutralisation We did lots of equations for the reactions of metals with acids and now we need to look at equations for neutralisation. Word equation: hydrochloric + sodium acid …………………………….. + ……………………………… hydroxide …..……………………….. Symbol equation: HCl + NaOH …………………………….. + ……………………………… What if we changed the acid? Word equation: sulphuric acid + sodium hydroxide …………………………….. + ……………………………… …..……………………….. 15 Symbol equation: H2SO4 + NaOH …………………………….. + ……………………………… sodium …………………………….. + ……………………………… Word equation: nitric + acid hydroxide …..……………………….. Symbol equation: HNO3 + NaOH …………………………….. + ……………………………… And what if we change the alkali? Word equation: sulphuric + acid potassium …………………………….. + ……………………………… hydroxide …..……………………….. Symbol equation: H2SO4 + KOH …………………………….. + ……………………………… 16 And what if we changed both? Word equation: hydrochloric + lithium acid hydroxide …………………………….. + ……………………………… …..……………………….. Symbol equation: HCl + LiOH …………………………….. + ……………………………… Preapring a soluble salt -Practical You are going to make some soluble salt from a largely insoluble base. Copper oxide is what we can describe as a base. This is because it is not acidic…. and it acts the same as an alkali when it reacts. If your exam talks about a base they probably mean a metal oxide. NB some bases are soluble. This one is not Collect: A beaker Measuring cylinder Filtration apparatus Bunsen burner, heatproof mat and tripod Evaporating basin Test tube rack Stirring rod Hydrochloric acid Copper oxide and a spatula 1. Put 50 cm3 of acid into the beaker. Warm and stir while adding copper oxide until all the acid has been used up. Your teacher will help you recognise this point. 2. Filter the mixture using the filtration apparatus and standing the funnel in a test tube rack. 3. Heat the evaporating basin until crystals begin to form 4. Filter the remaining solution to leave behind the crystals 17 Questions on the practical: 1. Describe what you saw once the acid had been used up ........................................................................................................... ........................................................................................................... ........................................................................................................... Use the terms in the box for questions 2-4 18 2. Give the property of copper oxide that allows it to be removed by filtering in Stage 2. ........................................................................................................... 3. Name the substance being removed during stage 3 ........................................................................................................... 4. Write a word equation to represent the reaction in stage 1. (hint: neutralisation) ......................... + .......................... ................................ + ............................. ......................... .......................... Past paper question ................................ 19 Extension Use the clues to find out what words you need to find in the word search. C I R O L H C O R D Y H N A A C A L C I U M A N O P V S O D I U M G W I C C A U S X C E N H H T R E T A W E I N I T O R P Q S U R I D D D Y H A R W U C D M L O E F G T T O L N K L E A S S D E H Y D R O G E N K E I I M N I T R I C E Z L C O H Y D R O X I D E M A P C I R U H P L U S N B Y 1) Hydrochloric acid + copper oxide copper chloride + _____________ (5) 2) Nitric acid + copper oxide copper ______________ + water (7) 3) ______________acid + copper oxide copper sulphate + water (9) 4) An ________________ is a soluble base (6) 5) Hydrochloric acid + _____________hydroxide sodium chloride + water (6) 6) Nitric ___________ + potassium hydroxide potassium nitrate + water (4) 7) Sulphuric acid + ________________ calcium sulphate + hydrogen (7) 8) _______________acid + magnesium oxide magnesium chloride + water (12) 9) Bases are metal hydroxides and metal ______________(6) 10) ______________acid + sodium hydroxide sodium nitrate + water (6) 11) Sulphuric acid + sodium _____________ sodium sulphate + water (9) 12) Hydrochloric acid + zinc zinc chloride + ___________________ (8) 20 Metal Carbonates and acid What do you need to put in the test tube to test for carbon dioxide? .................................................. Describe what you saw when you did this experiment …………………………………………………………………………………………………………………………… …………………………………………………………………………………………………………………………… Word equation: hydrochloric + calcium acid carbonate …………………… + …………………. + ………………… …..…………… …..……………. Symbol equation: HCl + CaCO3 …………………… + …………………. + ………………… 21 Do you notice any similarities with this equation and the ones that were done with the alkali and the base? This is another type of neutralisation….. You are now ready to write a summary of these reactions: These need to be LEARNT and you need to be able to write specific word and symbol equations for them. Neutralisation summary Base + Acid …………………………… + …………………………… Alkali + Acid …………………………… + …………………………… Metal carbonate + Acid …………………… + …………………. + ………………… …..…………… 22 …..……………. Past paper question 23 Extension 24 What is the name given to substances like water that have both acid and base characteristics? 1 2 7 6 4 5 3 11 8 9 10 12 A substance that accepts H+ ions OR a soluble base A dye that turns red in acid and blue in alkali Any dye that changes colour at different pHs The element present in all acids A substance that dissociates to form hydrogen ions Another name given to a hydrogen ion A substance that contains hydrogen and hydroxide ions in equilibrium and is neutral at pH7 8. An acid is a proton _ _ _ _ _ 9. The symbols of the elements present in an alkali 10. The colour litmus paper turns in acid 11. A solution that contains charged particles is described as _ _ _ _ _ 12. The colour litmus goes in alkali 1. 2. 3. 4. 5. 6. 7. Rearrange the shaded letters to answer the question in the title: _ _ _ _ _ _ _ _ _ _ 25 Summary Checklist Topics Red a) be able to classify substances as acidic, alkaline or neutral in terms of the pH scale, including acid/alkali strength. b) investigate the reactions of acids with metals and explain their observations in terms of the metals' position in the reactivity series. c) know that the neutralisation of dilute acids with bases (including alkalis) and carbonates and that carbonates effervesce in acid d) carry out test to identify carbon dioxide gas. e) prepare crystals of soluble salts, such as copper(II) sulphate, from insoluble bases and carbonates. f) be able to write and interpret word equations and balance chemical equations to describe the reactions of metals, bases (including alkalis) and carbonates with the following acids: hydrochloric acid, nitric acid and sulphuric acid. 26 Amber Green