Electrify Europe, Vienna Austria 2018, Revisiting IGCC Technology Koichi SAKAMOTO, Takashi FUJII, Tetsuya KIZU Mitsubishi Hitachi Power Systems, Inc. Carlos KOENEKE Mitsubishi Hitachi Power Systems Americas, Inc. Abstract: Considerable Integrated Gasification Combined Cycle (IGCC) research has been funded by several governments and large companies for several decades; however, deployment of the technology has not materialized despite large coal resources in many countries around the world. This is evident by the construction of only eleven coal based IGCC plants since 1994. Environmental concerns surrounding coal based generation, high initial costs and low reliability of many of the existing assets have worked against investment and development of new plants. Mitsubishi Hitachi Power Systems (MHPS) has continued the design and development of the technology in a progressive and conservative way that has resulted in the reliable operation of a 250 MW Air-blown gasification demonstration plant called Nakoso. This facility was converted into a commercial plant called Joban Nakoso # 10 power plant upon completion of exhaustive validation and thorough testing. The construction of a 166 MW Oxygen-blown plant named Osaki Coolgen was completed in March, 2017 and is now under demonstration operation. Based on the above mentioned successful projects, MHPS has started the construction of two 540 MW Air-blown IGCC projects in Japan. These projects leverage Nakoso’s experience; incorporating high efficiency 50Hz class gas turbines for 48% net plant efficiency. This technology enables the new plants to operate with several advantages compared to UltraSuper-Critical applications, including capability to burn a diverse range of coals, lower ash volumes and generation of residue that can be used in civil construction projects, and others. The use of Air-blown gasification enables high reliability operation by eliminating the requirements of gasifier internal refractory insulation allowing elimination of the requirement for a spare gasifier. This paper will explain MHPS IGCC Technology and presents an update on the status of construction of the two plants mentioned above, scheduled to start commercial operation in 2020 and 2021. 1 Introduction: A total of 31 large or medium scale IGCC power plants have been built around the world in more than three decades (1). Thirteen of those 30 have been retired leaving only 18 of them in operation. The decommissioning motivation for these plants varies, but it typically includes low reliability associated to issues in the gasification and/or gas cleaning processes and high cost of generation compared to other energy sources, especially in countries where natural gas is abundant and cheap. Construction delays and cost overruns in recent projects have also casted a negative image on the technology. MHPS has dedicated considerable resources to IGCC for more than three decades and the gasification technology development has been focused on power generation rather than based on petrochemical industry applications. Low Heating Value Gas Turbine Experience: Firing low heating value gases in gas turbines designed for natural gas can be challenging. Figure 1 below shows the combustibility range covered by MHPS industrial gas turbines ranging from low heating value Blast Furnance Gas (BFG) to oxygen blown syngas applications. Figure 1. Low Heating Value Combustibility in Gas Turbines 2 MHPS experience firing low heating value gases in gas turbines dates back to 1958 when an 850 kW unit burning Blast Furnace Gas (BFG) was commissioned as a prime mover for a blast furnace blower at Yawata Steel Corporation (present Nippon Steel Corporation). A 4 MW gas turbine was later delivered for the same client. A 15 MW gas turbine was supplied to Sumitomo Metal Industries, Ltd. Wakayama Works in 1965. These efforts were followed by extensive development of gas turbines capable of firing low heating value in the 1970’s. MHPS pioneered the use of high efficiency gas turbines firing low heating value syngas in 2003 with the introduction of one F Class M701FV gas turbine at the 430 MW single shaft at Nippon Petroleum Refining CO. Ltd. Negishi Refinery IGCC power plant located in Yokohama, Japan. This IGCC unit features other OEMs gasification equipment. Negishi’s M701FV experience with low heating value gas was followed by the introduction of the first F class gas turbine firing BFG at 1,300 °C (2372 °F) Turbine Inlet Temperature in 2004. This 300 MW combined cycle named Kimitsu Power Station (Figure 2) includes a 56 meter long single shaft configuration that also drives an 87.3 MW centrifugal BFG compressor through a step-up gear box (2). Figure 2. Aerial view of Kimitsu BFG Power Station Since 1990, MHPS has manufactured and delivered 59 low-Btu gas fired gas turbines, totaling more than 7,000 MW of generating capacity and accumulating more than 3 million hours of operation as shown in Figure 3 below. Seven additional units are currently in production. They will add another 665 MW. 3 Figure 3. Low Heating Value Gas Turbine Experience installations since 1990 Air and Oxygen-blown Gasification Experience: IGCC System Features Key features of IGCC power generation that makes it most attractive include: High Thermal Efficiency. Through the application of more efficient combined cycle power generation equipment, IGCC can achieve higher overall net plant efficiency than conventional pulverized coal-fired steam (Rankine cycle) plants. IGCC offers potential for substantial improvements in plant efficiency by applying advanced state-of-the-art gas turbines featuring 1,600°C (2,912°F) TiT. MHPS J fleet operates at this temperature level since 2011 and has accumulated more than 500,000 Actual Operating Hours (AOH). The next-generation 1,700°C (3,092°F) class higher temperature gas turbines are being developed with funding from the Japanese government. This technology is expected to further improve the efficiency of future IGCC designs. 4 Coal Flexibility. While issues with ash slagging, and other operational limitations, make low-rank coal largely unsuitable for conventional coal-fired plants, high temperature slagging gasification processes, as typically used for IGCC plants, can use a wider range of coals including low-rank types as shown in Figure 4. Figure 4. MHPS IGCC experience of wide variety of coal Environmental Performance. Higher plant efficiency achieved with IGCC vs. conventional coal-steam plants involves further CO2 emission reduction. SOx and particulate emissions are greatly reduced by virtue of the pre-combustion gas cleanup processes inherent in the IGCC plant design. CO2 emission’s reductions could approach 10-20% compared to most advanced ultra-supercritical plants. Significant NOx reduction is achieved due to the dilute nature of the syngas inherent in air-blown gasification, and via dilution with nitrogen in the oxygen-blown case. Compared to a traditional steam-only power cycles, the circulating water required for plant cooling in case of gas turbine combined cycle system is reduced by 30 percent. Easier Ash Disposal. MHPS design features slagging gasification, allowing coal ash discharge in a form of non-leaching glassy slag, with only half the volume of fly ash from conventional coal-fired plants. This slag is much more easily disposed of, and even has the possibility for sale as a byproduct for commercial applications, such as road paving materials or as a fine aggregate for concrete. 5 IGCC Plant Experience: MHPS air-blown IGCC technology has been proven by the successful long-term continuous operation at the Nakoso 250MW IGCC plant. Larger, more sophisticated, highly efficient and highly reliable air-blown IGCC commercial plants projects are now being implemented. Two separate 500MW-class plants, each utilizing a M701F gas turbine operating on low heating value syngas, are now under construction. They are scheduled start operation in September, 2020 and September, 2021. MHPS has also developed oxygen-blown IGCC technology. A plant named Osaki CoolGen was developed and started demonstration testing in March, 2017. This initial phase of the project will be followed by demonstration testing with CO2 capture equipment, starting in 2019. A third project step will include demonstration of an Integrated Gasification Fuel Cell (IGFC) with CO2 capture, in 2021. Nakoso 250MW Air-Blown IGCC Plant MHPS, in collaboration with the Japanese Government, nine electric utility companies, J-Power and the Central Research Institute of Electric Power Industry (CRIEPI) developed an air-blown IGCC demonstration plant optimized for electric power generation. The 1,700 ton/day, 250 MW Nakoso IGCC plant (Figure 5), utilizing an M701DA gas turbine, was constructed as the final step in a long and methodical development process before commercialization. It is noteworthy that the 1,700 ton/day Nakoso IGCC demonstration project itself was the culmination of almost 20 years of gasification process development. This started with a 2 t/day process development unit (PDU) phase operated by CRIEPI during the 1980s, followed by a 200 t/day pilot plant at Nakoso which operated from 1992 to 1996. In 1999, MHPS had also installed a 24 t/day verification test unit at its own facilities in Nagasaki. The Nakoso IGCC demonstration project was led by Japan’s Clean Coal Power R&D Co. (CCP), which was founded in June 2001. MHPS signed a turn-key EPC contract for the entire IGCC plant, and supplied the air-blown gasifier, syngas cleanup system, gas turbine (model M701DA), steam turbine and heat recovery steam generator (HRSG). Table 1 below summarizes the results of the series of verification tests that started in 2007. The plant reached its rated load of 250 MW and completed 2,000 hours of continuous operation in 2008, less than one year from initial startup – testimony to the high reliability of MHPS’s airblown IGCC design. Follow-on demonstration testing culminated with the successful running of a 5,000-hour long-term durability test, completed in June 2010. 6 Figure 5. Nakoso 250MW IGCC plant In the spring of 2013, the plant was taken over by Joban Joint Power Company and renamed Nakoso #10 plant, representing the first coal-based IGCC commercial operation in Japan. In December 2013, record breaking 3,917 hours of continuous IGCC operation was achieved. All key performance measures for the Nakoso plant such as net thermal efficiency, environmental performance and start-up time, achieved or well exceeded target values. (Note: 42.9% LHV efficiency is equivalent to approximately 41.5% HHV efficiency, substantially higher than the typical conventional coal-fired steam plant and comparable to the most advanced ultra-supercritical plants.) Tests burning 10 different kinds of coal, including 6 ranks of sub-bituminous confirmed the flexibility of the MHPS air-blown gasification process. Japan imports its coal, so that this ability to operate over such a wide range of coal properties is essential to flexibly operate as a commercial plant under the imported coal diversity. Output (Gross) (Net) Performance Efficiency (Net, LHV) Carbon Conversion Emission SOx NOx (@dry, 16%O2) Dust Targets Achievements 250MW 220MW 250MW 225MW > 42.0% 42.9% > 99.9% > 99.9% < 8 ppm < 5 ppm < 4 mg/m3N 1.0 ppm 3.4 ppm < 0.1 mg/m3N Chinese, Canadian Coal Kinds Operational Flexibility Reliability Start-up Time Note 10 kinds of coal in total Bituminous 6 Sub-bituminous 2 US (including PRB) Indonesian (Adaro, etc.) 4 Bituminous Sub-bituminous 3 Colombian, 2 Russian have been used. < 18 hr 15 hr Minimum Load 50% 36% Ramping Rate Long-term Continuous Operation 3%/min 3%/min 2,000 hr 3,917 hr Cumulative operating hours : > 38,000 hrs. Table 1 Targets & Achievements of 250MW Nakoso IGCC Plant 7 Osaki 166MW Oxygen-Blown IGCC Plant The Osaki CoolGen IGCC demonstration plant features a MHPS oxygen-blown single-chamber, two-stage, swirl-flow entrained-bed type of gasifier (see sidebar of Figure 6) with a coal feed rate of 1,180 t/day. The 166MW (gross) IGCC plant was completed in March, 2017 and is currently undergoing demonstration testing. For the CoolGen project, MHPS signed a comprehensive contract to design, manufacture, install and test the gasification/gas clean-up train -- including turnkey supply of the combined cycle power generation equipment based an H-100 gas turbine – in addition to overall engineering and general management of the project. The demonstration test program aims to verify the scale-up technology of the gasifier, establishing the control technology for operating the gasifier, and the complete oxygen-blown IGCC system (refer to Figure 7). Following this first demonstration phase, the second phase planned for the project involves demonstration testing with CO2 capture equipment, starting in 2019. And, as the third step, it is planned to demonstrate Integrated Gasification Fuel Cell (IGFC) with CO2 capture, in 2021. (Note: The CoolGen project is sponsored by the New Energy and Industrial Technology Development Organization.) Due to the more concentrated nature of syngas produced with an oxygen-blown gasification process (essentially a 50/50 mixture of CO and H2), the pre-combustion removal of CO2 via conventional gas processing equipment is more practical than with air-blown gasification, where the syngas is highly diluted with the nitrogen from the air used in the gasification process. Figure 6. Osaki CoolGen IGCC demonstration project 8 FY 2012 2013 2014 2015 2016 Work to be implemented Detailed design and construction of oxygen-blown IGCC units a nd facilities Design & manufacturing Design & manufacturing Design & manufacturing Design & manufacturing Equipment & electrical work Civil & architecture work Civil & architecture work Civil & architecture work Civil & architecture work Gasification operation Equipment & electrical work Equipment & electrical work Comletion of equipment work Hydraulic tests Power reception 2017 2018 De monstration Verification of basic performance Plant performance Environmental performance Verification of coal variety compatibility Verification of plant reliability Prolonged endurance test Verification of controllability & operability Load change rate Starting/stoppingtimes Economy evaluation Figure 7. Schedule for Osaki oxygen-blown IGCC demonstration (Phase I) Current Projects under construction in Japan: Based on success of the 250MW Nakoso IGCC Plant, a consortium led by MHPS is now implementing a very significant commercial power generation project in Japan comprising two similar 500MW-class IGCC plants; one plant will be for Nakoso IGCC Power GK and the other for Hirono IGCC Power GK (GK stands for Godo Kaisha in Japanese, a type of Limited Liability Company or LLC). This project will result in the development of industrial infrastructure and economic recovery in the area. The new Nakoso IGCC plant will be built on property adjacent to Joban Joint Power’s Nakoso Power Station in Iwaki City and the Hirono IGCC plant will be built on the site of TEPCO Fuel & Power’s Hirono Thermal Power Station in Fukushima’s Futaba District. (See artist concepts of each plant in Figures 8 and 9.) Figures 8 and 9. Fukushima Revitalization Power Project: Nakoso IGCC Power (L) Hirono IGCC Power (R) 9 Each air-blown IGCC plant will have a generating capacity of 540MW, utilizing M701F gas turbines. The process design for the gasification island (gasifier, gas cleanup, etc.) will use the same concept, scaled approximately 2:1, as used at the 250MW Nakoso IGCC Plant. Nakoso began construction in April, 2017 and Hirono will begin in April 2018 with start of operation scheduled in September 2020 and September 2021, respectively. MHPS, as project leader, is working closely with its three consortium partners: Mitsubishi Heavy Industries Ltd., Mitsubishi Electric Corporation, and Mitsubishi Hitachi Power Systems Environmental Solutions, Ltd. “In the process of building these two plants, every effort will be made to further improve IGCC technologies, to enable even more efficient coal-based power production, and further reduce environmental impact”, say MHPS project managers. Following the successful demonstration and commercialization of the Nakoso 250MW airblown IGCC plant based on M701DA gas turbine, MHPS is now offering commercial plants using both M501GAC (60Hz) and M701F (50Hz) gas turbines. Expected net plant efficiency for both designs is 48% (LHV), as represented in Figure 10. Major Specification Output Gasifier Gas Clean-Up Gas Turbine Project Schedule Operation Start 540 MW (gross) 480 MW (net) Air-blown MDEA M701F GT (1 on 1) 2020 (Nakoso site) 2021 (Hirono site) Figure 10. Specifications of the Fukushima Revitalization Power IGCC plants 10 Summary: MHPS has the largest low heating value gas turbine fleet in the industry, including 59 gas turbines with more than 7,000 MW installed base with an accumulated experience in excess of 3 million hours. Seven additional units are currently in manufacturing for additional 665 MW. MHPS has consistently worked on the development and testing of air- and oxygenblown gasification process focusing on high plant efficiency while targeting high reliability. The air-blown gasification design successfully completed its demonstration and commercial scale. Two air-blown 540MW IGCC plants are currently under construction aiming at COD in 2020 and 2021. The Oxygen-blown gasification operation is ongoing and being analyzed for future deployment combined with CCS and/or fuel cell technology References: (1) Gas Turbine World 2018 Handbook reference to EPRI information. Page 25 and 26. (2) Katsunori TANAKA, Koichi NISHIDA, Wataru AKIZUKI, Toyoaki KOMORI, Carlos KOENEKE; Update on synthetic gas and low calorie gas applications to M701F Gas Turbines; PowerGen International 2005. (3) Toyoaki KOMORI, Katsunori TANAKA, Wataru AKIZUKI, Carlos KOENEKE; Update on Design and Operating Experience of Low Calorie Gas Firing Gas Turbine for Steel Works; PowerGen International 2007. (4) Toyoaki KOMORI, Katsunori TANAKA, Wataru AKIZUKI, Carlos KOENEKE; Update on Design and Operating Experience of Low Calorie Gas Firing Gas Turbine for Steel Works; Association For Iron and Steel Technology Conference, Pittsburg, 2018. (5) Koichi SAKAMOTO; Building on success: MHPS takes on two 500MW-Class IGCC projects; Gas Turbine World 2018 Handbook. 11