Chapter 7: Chemical Bonding A) Ionic Bond 1. Use Lewis dot structure to represent the formation of following ionic compounds: Example: Formation of NaCl = a.) KF b.) Na2O c.) Li3N d.) MgO e.) CaCl2 f.) Al2O3 2. Predict the chemical formula of following compound formed by: a.) X element (Group IA) and Y element (Group VA) b.) A element (Group IIA) and B element (Group VIIA) c.) M element (Group IIIA) and N element (Group VIA) B) Covalent Bond 1. a) Draw the Lewis dot structure of the following molecules. b) Predict the shape of the molecules. c) Determine the polarity of the molecules. (is it a polar molecule or non-polar molecule?) i) CH4 vi) O2 ii) NH3 iii) H2O vii) PCl3 viii) H2S iv) SiCl4 v) HCl ix) CH2O x) HCN 2. Draw the Lewis electron dot structures for the following molecule and ion, showing any coordinate covalent bonds present. a) Al2Cl6 b) SO2 c) H3O+ 3. Draw the Lewis electron dot structure for the following molecules which do not obey the octet rule. a) BF3 b) BeCl2 c) SF6 C) Intermolecular Forces 1. Identify the main intermolecular forces of following molecules: Choose between van der Waals (Dipole-Dipole Attraction) van der Waals (London Dispersion Force) hydrogen bond i) H2 vi) CH3Cl ii) HI iii) H2O vii) BH3 iv) H2S v) CO2 viii) NH3 2. Below are some wrong statements regarding hydrogen bond, correct the mistakes. a.) Hydrogen bond is one type of covalent bond. b.) There are two hydrogen bonds within each water molecules. D) Types of Crystalline Structure and their Properties. 1. Complete the table below: Substances sodium chloride Type of Crystal ionic crystal Component Particles Na+ and Cl- ions Force between Particles ionic bond diamond atomic crystal C atoms covalent bond hydrogen gas molecular crystal H2 molecules van der Waals hydrogen fluoride molecular crystal HF molecules hydrogen bond sodium powder metallic crystal Na+ ions and electrons metallic bond silicon dioxide magnesium cube calcium oxide ammonia dry ice aluminium foil distilled water silicon potassium sulfate aluminium chloride 2. Given following substances: CCl4, NaOH, Na2O2, H2O2, (NH4)2S, CO2, NaCl, C2H2, SiO2 a.) An ionic compound having only ionic bond is ______________ b.) An ionic compound having ionic bond as well as polar covalent bond is ______________ c.) An ionic compound having ionic bond, polar covalent bond and coordinate bond is ____________ d.) An ionic compound having ionic bond and non-polar covalent bond is ____________ e.) A non-polar molecule having only polar covalent bond is ___________ (2 ans) f.) A non-polar molecule having non-polar covalent bond and polar covalent bond is ____________ g.) A polar molecule having non-polar covalent bond and polar covalent bond is _____________ h.) An atomic crystal having only covalent bond is __________