SELECTION AND APPLICATIONS OF WROUGHT ALUMINUM AND ALUMINUM ALLOYS Arif Uddin Prio – 1511001 S.M Farhaduzzaman - 1511015 Wreet Sarker - 1511016 Wrought Aluminum Alloys Wrought aluminum alloys can be broadly classified into two basic types: •Non Heat-treatable alloys •Heat-treatable alloys Non Heat-treatable alloys ◦ Various grades of pure aluminum ◦ Alloys that derive their strength from: Solid solution strengthening Cold-work or strain hardening Heat-treatable alloys ◦ Alloys that contain one or more of the elements of copper, magnesium, silicon and zinc. ◦ Have the characteristics of increasing solubility in aluminum with increasing temperature. ◦ Examples: 1xxx, 3xxx, 4xxx, 5xxx and few belonging to 7xxx and 8xxx series. ◦ Generic characteristics for precipitation hardening. ◦ Examples: 2xxx, 6xxx, 7xxx and few of 4xxx and 5xxx series. Non Heat-treatable alloys ◦ Various grades of pure aluminum ◦ Alloys that derive their strength from: Solid solution strengthening Cold-work or strain hardening Heat-treatable alloys ◦ Alloys that contain one or more of the elements of copper, magnesium, silicon and zinc. ◦ Have the characteristics of increasing solubility in aluminum with increasing temperature. ◦ Examples: 1xxx, 3xxx, 4xxx, 5xxx and few belonging to 7xxx and 8xxx series. ◦ Generic characteristics for precipitation hardening. ◦ Examples: 2xxx, 6xxx, 7xxx and few of 4xxx and 5xxx series. Non Heat-treatable alloys Non Heat-treatable alloys exhibit very low yield and tensile strength in the annealed state and therefore are easily formable(workable) to different shapes. 1xxx Alloys ◦ 99.00% or more pure aluminum ◦ Large application in electrical and chemical industry ◦ Properties: Excellent corrosion resistance High thermal and electrical conductivities Low mechanical properties Excellent workability Applications ◦ Typical uses: chemical equipment, reflectors, heat exchangers, electrical conductors and capacitors and so on. ◦ One of the important applications of pure aluminum is as a cladding material to: Improve the corrosion resistance of heat-treatable alloys Improve the finishing characteristics of non heat-treatable alloys 3xxx Alloys ◦ Manganese is the major alloying element of this group. ◦ Have about 20% more strength than 1xxx alloys due to dispersion and solid solution hardening. ◦ Manganese content is limited to 1.5% in these alloys. ◦ Few alloys contain magnesium as an extra alloying element. Applications ◦ Alloys 3003, 3004 and 3105 are used as general purpose alloys for moderate strength application which require good workability. ◦ Other applications include beverage cans, cooking utensils, storage tanks, highway signs etc. ◦ They constitute most used aluminum alloys, tonnage wise. 4xxx Alloys ◦ Silicon is the major alloying element in these group. ◦ Silicon can be added in a substantial amount (up to 12%) to cause a dramatic lowering of melting range without producing brittleness. Hence, are not characterized by their mechanical properties. ◦ Normally non heat-treatable but when used to heat the heat treatable alloys will pick some constituents of heat treatable alloys and will respond to heat treatment to a limited extent. Applications ◦ Major use of aluminum-silicon alloys is as welding wires and brazing alloys in the joining of aluminum alloys. ◦ Alloys which have high amount of silicon become dark gray to charcoal when surface anodized and thus have great demand in architectural applications. ◦ Alloy 4032 is used to produce forged engine pistons. 5xxx Alloys ◦ Magnesium is the major alloying element along with some manganese. ◦ Produces moderate to high strength alloys that can be cold worked or strain hardened. ◦ Magnesium is highly effective as a hardener. ◦ Were developed as marine alloys due to high resistance in salty marine environment and good weldability. ◦ Certain restrictions are placed on the amount of cold work and the operating temperature to avoid susceptibility to stress corrosion cracking. Applications ◦ Uses include architectural, ornamental, decorative trim, can and can ends. ◦ Also used in boats and ships, cryogenic tanks, crane parts and automotive structures. 8xxx Alloys ◦ These alloys encompass variety of compositions, including non heat-treatable and heat-treatable. ◦ Among non heat-treatable 8001 (aluminum-nickel-iron alloy) has good corrosion resistance in water at high temperature and pressure and shows similar properties to that of 3003. ◦ 8081 containing 20% Sn and 1% Cu has bearing characteristics superior to other alloys for automotive use. Applications ◦ 8001 is used in nuclear energy applications. ◦ 8280(aluminum-tin-nickel-copper alloy) is used in bearings. Tin provides antifriction characteristics, while nickel and copper contribute to strengthening. ◦ 8090 is a heat-treatable aluminum-lithium alloy that is being develop to used in aerospace industry. Others ◦ Aluminum alloy foil is a widely used wrought product. Generally produced commercially from non heat-treatable alloys. ◦ Aluminum honeycomb core for aircraft is made of 3003-19, 5052-H39. Heat-Treatable Alloys These alloys are basically selected for structural applications because of their high strengths and for the inherent lightness and corrosion resistance of aluminum. 2xxx Alloys • Copper is the principle alloying element in these alloys. • These alloys don’t have a good corrosion resistance like most other aluminum alloys. • Under certain conditions, these alloys may be prone to intergranular corrosion. • So, to provide galvanic protection, these alloys are often claded with high purity aluminum or magnesium- silicon alloy in the form of sheets. Applications • These alloys find widespread use for parts and structures requiring high specific strengths. • Commonly used in truck and aircraft wheels, truck suspension parts, aircraft fuselage, wing skins, and other structural parts requiring good strength at temperature below 150°C. • Except for alloy 2219, these alloy have limited weldability. 6xxx Alloys • These alloys contain silicon & magnesium in the proportion to form Mg2Si. • Mg2Si precipitates out & strengthens the alloy during heat treating. • They have medium strength, good formability, weldability, machinability & corrosion resistance. Uses include architectural applications, bicycle frames, transportation equipment, bridge railings and welded structures. 7xxx Alloys • These alloys contain zinc, from 1 to 8 percent, and a small amount of magnesium to produce moderate to very high strength alloys. • High strength 7xxx alloys exhibit reduced SCC resistance. • Used in slightly over aged condition to provide better combinations of strength, corrosion resistance, and fracture toughness. • They are used in airframe structures, mobile equipment, and highly stressed parts. Tensile Properties Aircraft Alloys • Because of their high specific strengths and specific moduli, the alloys 2024 and 7075 have been the conventional aircraft structural materials. • They constitute 70-80 percent of the weight of the aircraft. • Higher toughness requirements have been met through the high purity modification of these alloys such as 2124,2224,7175,7475, and with alloy 7075. • In addition, 2219 is used for good weldability and high temperature strength, modified as 2419 for higher toughness. Aluminum-Lithium alloys • They are also heat treatable alloys but have yet to be fully commercialized. • They are targeted to replace the conventional aluminum alloys 2024 and 7075 in the aircraft. • These alloys are very lighter and yet have higher moduli than the conventional aluminum alloys. • They also exhibit better toughness and fatigue properties. Alclad & Clad Aluminum Products • Aluminum products are sometimes coated on one or both surfaces with a metallurgical bonded, thin layer of pure aluminum or aluminum alloy. • If the combination of core and alloys is selected so that the cladding is anodic to the core, the product is called alclad. • A clad product, on the other hand, is a combination in which the cladding is not intentionally made anodic to the core. • Cladding of the Alclad products protects the core at exposed edges as well as abraded or corroded areas and acts as a sacrificial anode. • Clad products are designed to provide improved surface appearance. • Brazing products are commercial example of clad products in which cladding alloy has a lower melting point than the core. This helps the subsequent joining of several parts into an assembly. • The corrosion potentials of cladding and core must be sufficiently different, with the cladding being anodic, in order to protect the core. • Pure aluminum, 1060, is about 0.15V more anodic than 2024-T3 and -T4 tempers. • So, 1060 is used for most Alclad 2xxx products.