See discussions, stats, and author profiles for this publication at: https://www.researchgate.net/publication/326348662 High Temperature Erosion of Dense Refractory Castables for CFBC Boilers Article in InterCeram: International Ceramic Review · March 2017 DOI: 10.1007/bf03401198 CITATIONS READS 3 734 4 authors, including: Prasad Kannan L N N Satapathy Bharat Heavy Electricals Limited Bharat Heavy Electricals Limited 3 PUBLICATIONS 28 CITATIONS 3 PUBLICATIONS 3 CITATIONS SEE PROFILE Some of the authors of this publication are also working on these related projects: Refractories for CFBC boilers View project All content following this page was uploaded by L N N Satapathy on 17 February 2020. The user has requested enhancement of the downloaded file. SEE PROFILE REFRACTORIES 019 1, V.G. Kadirvell1, L.N.Satapathy 3 K. PrasadTemperature R. Sanakaranarayana High Erosion2, of Dense Refractory Castables for CFBC Boilers Temperature Erosion of Dense Refractory Castables High for CFBC Boilers K. Prasad1, V.G. Kadirvell1, L.N.Satapathy2, R. Sanakaranarayana3 1 Bharat Heavy Electricals Ltd., Process and Captive Power Systems, Tiruchirappalli, Tamil Nadu (India) 2 Bharat Heavycirculating Electricalsfluidized Ltd., Ceramic Technological Institute, Corporate R&D, Bengaluru, Karnataka KEYWORDS: bed combustor (CFBC), fluidization, refractories, bed material, dense bricks, low cement castable, plastic ramming mix, erosion resistance » Interceram 66 (2017) [1–2] 3 (India) National Institute of Technology, Dept. of Metallurgical and Materials Engineering, Tiruchirappalli, Tamil Nadu (India) and systems, heat transfer nanofluids for close circuit cooling, selective catalytic reduction catalysts for power plants, wear resistant ceramic The corresponding author, K. Prasad, received his components, special refractories and high temperature characterization Bachelor of Technology from A.C. College of Technol- of materials at Bharat Heavy Electricals Limited in Bangalore (India). ogy, Guindy, Chennai, Tamilnadu (India) in the field of Dr. S. Raman Sankaranarayanan obtained his Bachelor of Engiceramic technology in 2006. Since 2012 he has been neering (Metallurgical Engineering) from P.S.G. College of Technology, working as Deputy Manager in the Process and Captive Coimbatore, Tamilnadu and his M.Sc. (Materials Engineering) and Ph.D. Power Systems group of Bharat Heavy Electricals Ltd. (Materials Engineering) from Drexel University, Philadelphia (USA). He (BHEL), Tiruchirappalli (India). Prior to this he worked has been with the National Institute of Technology, Tiruchirappalli, InThe corresponding author, K. Prasad, received his Bachelor of Technology from A.C. College of in the Refractory Engineering Department of the Visakhapatnam Steel dia since 1998. His areas of interest are process metallurgy and quality Technology, Guindy, Chennai, Tamilnadu (India) in the field of ceramic technology in 2006. Since 2012 he Plant. Currently he is involved in the design engineering and analysis of management. has been working as Deputy Manager in the Process and Captive Power Systems group of Bharat Heavy refractory lining and insulation for pulverized fuel fired boilers, circulatElectricals Tiruchirappalli Prior to this generahe worked in the Refractory Engineering ing fluidizedLtd. bed(BHEL), combustion boilers and (India). heat recovery steam ABSTRACT Department of the Visakhapatnam Steel Plant. Currently he is involved in the design engineering and tors. He provides field engineering support to resolve refractory problems at various powerlining plantand sites. He is presently pursuing Master of circulating The erosion resistance of dense refractory bricks or castables used in analysis of refractory insulation for pulverized fuelhis fired boilers, fluidized bed combustion Science in Metallurgical andsteam Materials Engineering Nationalfield Institute CFBCsupport boilers tois resolve tested asrefractory per ASTM C 704. This method of testing deboilers and heat recovery generators. He at provides engineering of Technology (NIT), Tiruchirappalli, Tamilnadu (India) inpursuing the field his of retermines the relative erosion of a refractory at room temperature only. problems at various power plant sites. He is presently Master of Science in Metallurgical and fractories for CFBC boilers. E-Mail: kprasad@bheltry.co.in Hence, solid particle erosion at elevated temperatures is desired in seMaterials Engineering at National Institute of Technology (NIT), Tiruchirappalli, Tamilnadu (India) in the field V.G. Kadirvell received his Master of Technology (Energy Engineer- lecting the suitable refractory quality for boiler applications. The dense of refractories for CFBC boilers. E-Mail: kprasad@bheltry.co.in ing) from the National Institute of Technology, Tiruchirappalli (Formerly refractory materials for CFBC boilers are usually eroded at operating known as Regional Engineering College, Tiruchirappalli). He has more temperature (~900 °C) by hot circulating solids at high temperatures. V.G. 25 Kadirvell Technology (Energyinsulation Engineering) fromwork, the low National Institute of than years of received experiencehisinMaster design of engineering of lining, In this cement castable–45, low cement castable–80 and an Technology, Tiruchirappalli (Formerly known as Regional Engineering College, Tiruchirappalli). He has more and refractory for pulverized fuel fired boilers, circulating fluidized bed 80 % alumina-based plastic refractory castable, three varieties of dense combustion boilers and heat inrecovery generators. He isinsulation currentlyand refractory castables usedfuel in CFBC than 25 years of experience design steam engineering of lining, refractory for pulverized fired boilers, were selected for testing of working as Senior Deputy General Manager (SDGM) Heavy steam erosiongenerators. properties.He Theiserosion tests were conducted at room temperaboilers, circulating fluidized bed combustion boilerswith and Bharat heat recovery currently Electricals Ltd Senior (BHEL), Tiruchirappalli, (India). andElectricals boiler operating temperature of 900 °C at three different anworking as Deputy General Manager (SDGM) with Bharat ture Heavy Ltd (BHEL), Dr. Lakshmi Narayan Satapathy obtained his post-graduate de- gles of impingement (30°, 45° and 90°) using specially developed high Tiruchirappalli (India). grees in chemistry, materials science, ecology and environment and temperature erosion test equipment following the ISO 16349 (2015) management, prior to his Ph.D. in Materials Engineering from the Indian standard. The erosion loss result values (in cm3) were compared, and Dr. Lakshmi Narayan Satapathy obtained his post-graduate degrees in chemistry, materials science, Institute of Science, Bangalore. He has more than 25 years of R&D ex- this comparison is useful in selection of suitable material for various ecology and environment ceramics, and management, to his Ph.D. in Materials Engineering from the boiler. Indian erosion prone zones of the perience in alumina-based microwaveprior processing of materials AUTHOR Institute of Science, Bangalore. He has more than 25 years of R&D experience in alumina-based ceramics, 1. Introduction Circulating fluid bed combustors (CFBCs) are steam generating boilers that use fuels like lignite, pet coke and solid wastes. The operation of CFBC boilers involves the circulation of hot, high-velocity solids containing a mixture of refractory bed material and fuel at temperatures around 900 °C. Fuel is burnt in the vertical combustion chamber furnace in fluidized condition at a temperature around 900 °C in a reducing atmosphere with slight positive pressure. The mixture of bed material and fuel is fluidized by preheated primary air introduced through air nozzles at the bottom of the combustor bed, and by the flue gas generated during combustion. The air (primary and secondary) and gas flow upwards with a relatively high velocity, filling the entire combustor with suspended solids. The combustion gas entrains a considerable portion of the solids in the combustor and carries them over to the recycling cyclone where the entrained bed materials are separated from the gas. The bed material separated by the recycling cyclone is collected in the fluidized seal pots and is then returned directly into the furnace's lower part at higher pressure through the return leg of the seal pot. The refractory forms an integral part of several of these components 1 Bharat Heavy Electricals Ltd. Process and Captive Power Systems, Tiruchirappalli, Tamil Nadu (India) 2 Bharat Heavy Electricals Ltd., Ceramic Technological Institute, Corporate R & D, Bengaluru, Karnataka (India) 3 National Institute of Technology, Dept. of Metallurgical and Materials Engineering Tiruchirappalli, Tamil Nadu (India) 01–02|17 020 Table 1 · Properties of dense refractories used in CFBC applications Low cement castable–45: LCC–45 Low cement castable–80: LCC–80 Alumina plastic mix (80 %) : 80(P) - 1550 1500 1650 Al2O3 / mass-% Fireclay Bauxite Bauxite 46.0 min 80.5 min 82.0 min Fe2O3 / mass-% 1.0 max 0.72 max 1.3 max CaO / mass-% 3.0 max 0.9 max - P2O5 / mass-% - - 4.5 max Bulk density / g/cm3 110 °C 2.30 min 2.5 min 2.75 min Cold crushing strength / N/mm2 110 °C 1200 °C 110 min 90 min 76 min 45 min 60 min Thermal conductivity / W/mK 500 °C 1.10 max 1.65 max - 1000 °C 1.15 max 1.60 max - - Minimal vibration / rodding Minimal vibration / rodding Pneumatic Ramming Property Max. service temperature / °C Raw material base Chemical analysis Application like the combustor, the inlet duct connecting the combustor and the cyclone, the cyclone, the seal pot and ducts connecting the seal pot and the combustor. The components are lined with a dense refractory comprised of brick shapes made from fireclay and andalusite and low cement castable containing 45–80 % of alumina and backup insulation comprised of shaped insulation bricks, calcium silicate blocks and a vermiculite / pearlite / grog-based insulation castable depending on the operating condition inside. The dense refractory bricks and castable lining take care of the erosive environment generated due to the hot circulating bed's solids at higher velocities and at high temperatures. Hence, among various properties for dense refractory like bulk density, porosity, thermal shock resistance, thermal conductivity, CO resistance etc., erosion resistance has a major role in selecting the suitable grade of dense brick or castable quality. The various challenges that are thrown at the refractory in a CFBC boiler have been well documented [1–5]. The demands of quantity and quality of refractories that were used in industrial boiler technologies have been low. However in CFBC technology, the design of boilers involve the usage of high quality and quantities of refractory [2]. With a target of reducing refractory material in the boiler and increasing heat transfer areas by introducing steam cooled walls, CFBC technology has evolved from external hot cyclone technology, involving layers of refractories at temperatures around 900–950 °C to internal steam cooled cyclone technology operating at around 450–550 °C with a single erosion protection layer of the refractory, as mentioned in the literature [6, 7]. In both cases, the dense refractory used must possess adequate abrasion resistance to withstand the high velocity circulating solids of up to 6 mm in size and hot gases. Moreover, with the transition of refractory material technology from multi-layered brick design to double-layered castable design the current CFBC technology has also adapted well to the market conditions. In a CFBC boiler, the risk of refractory failure to erosion of dense refractories by solid particles travelling at high speeds at elevated temperatures is a serious threat to the lifetime of the equipment. A failure in refractory due to poor erosion resistance also disrupts continuous operation of the boiler, thereby leading to interruption of the power gen- eration. The cause of erosion wear of the refractory surface may include both physical erosion by solid particles and chemical corrosion due to fuel quality / hot gas / slags and physical wear due to particles circulating at high velocity at high temperatures [8]. There is a requirement in understanding the erosion rate of refractory castable at elevated boiler operating temperatures of dense refractories used in abrasive environments like that of the cyclone inlet duct's sidewalls and roof. Although a number of studies [9, 10, 11] are available on the solid particle erosion of metals and ceramics at elevated temperatures, very little work on erosion resistance of refractories can be found in the literature. Bakker et al. studied the erosion resistance of refractory materials used in CFBC boilers with respect to the effect of the bed material that is circulated inside a circulating fluidized bed combustor [12]. The selection of refractory for water cooled cyclones based on erosion testing of various refractory bricks and castables has also been studied elsewhere [6]. For hot cyclone technology of CFBCs, the high temperature erosion behaviour of refractory brick materials comprised of coarse and fine aggregates have been studied [8]. There is also a study done on the hot erosion behaviour of alumina-based low cement castables and phosphate bonded plastic refractories for FCCU applications in petrochemical industry [13]. Information in the literature on the hot erosion test results for dense castable varieties used in CFB applications is scarce. This paper refers only to the physical erosion of dense refractory castables commonly used in CFBC boilers with hot cyclone technology in erosion prone areas like the cyclone inlet ducts' long and short walls and its inlet duct roof. In CFBCs, there is an increasing trend to use dense monolithic castables for their ease of application and improved application techniques by saving the boiler's down time. However, the inherent problem of calcium aluminate cement (CAC)-bonded refractories is that they attain better density and better high temperature properties including high erosion resistance at temperatures above 1200 °C, due to mullite formation [14, 15]. In a CFBC boiler, the operating temperatures are well below 900–950 °C. Hence, this work involves the study of the erosion properties of samples of commonly used refractory castables like low cement castable–45, low cement castable–80 and 80 % alumina plastic mix us- REFRACTORIES ing a high temperature erosion tester at a boiler operating temperature of 900 °C. A comparison of the erosion behaviour of the various samples has been carried out at two different temperatures viz., 27 °C (ambient temperature) and boiler operating temperature 900 °C. The selection of impingement angles for testing is pivotal in getting more meaningful results. Although the existing test standards for testing erosion resistance for refractories are the involves impact of the erodent at a 90° angle in highly erosive zones of boilers like cyclone inlet ducts, cyclone target walls, roof etc., the tangential or low angle impact by solids flowing through causes erosion of refractories. The importance the low angle of impact of solids inside a cyclone of CFBC boilers has also been emphasized in the literature [6]. Based on these, in this study angles of 30° and 45° were chosen for erodent impingement and a 90° impact angle along with existing room temperature testing for erosion resistance of refractories using the ASTM C704 [16] test method. 2. Materials and testing 021 1 Fig. 1 • Erosion tester used for measuring the erosion resistance of refractory test pieces at elevated temperature High temperature erosion tests were carried out on refractory samples of low cement castable–45, low cement castable–80 and 80 % alumina plastic refractory mix, which were sourced from an Indian refractory 2 (a) (b) supplier for boilers. The material data sheets of these samples are listed in Table 1. The sizes of the test samples were 100 mm x 100 mm x 25 mm. The samples were casted in moulds using a castable mix. These samples were then air cured for 24 h, preheated to 110 °C for 24 h and then prefired to 900 °C for 3 h before being subjected to tests. They were then tested using the “high temperature erosion tester” facility developed in tester house is used measuring the erosion resistance at the for Ceramic Technological Institute located at Bharat Heavy of refractory test pieces at elevated Electricals Limited –ofBengaluru Division in accordance with the regulating ISO , and mainly consists blasting devices, a pressure chamber, a sample chamber and 16349 (2015) standard. erosion tester is used1. forThe measuring erosion resistance of re- in the sample chamber with the square nents, asThe depicted in Fig. testthe sample was placed fractory test pieces at elevated temperature, and mainly consists of mm x 100blasting mm devices, perpendicular (at a chamber, 90° angle) orchamber at lowand angles of 30° or 45° to the protective tube. a pressure regulating a sample components, depicted in Fig. 1. The test sample wasto placed ature wasother raised fromas the ambient temperature 900in °C at a rate of 5–8 K/min. The material the sample chamber with the square face of 100 mm x 100 mm perpen(at a 90° or at low angles of 30° or 45° toThen the protective held fordicular 30 min at angle) the testing temperature. the abrasive media of 1000 g ± 5 g of black tube. The temperature was raised from the ambient temperature to 900 °C Fig. 2 • 2a) Samples of refractory castables before testing, 2b) Samples of refracde grainsat of particle sizeThe 300–850 μm was washeldimpinged theafter charging funnel of a suitable tory castables testing a rate of 5–8 K/min. material sample for 30 min atthrough the testing temperature. Then the abrasive media of 1000 g ± 5 g of n 900 ± 10 at 16 kPa pressure inside theμmsample chamber. After completion of the test, the blackssilicon carbide grains of particle size 300–850 was impinged immersion method.dust Photographs samples before through the test charging funnelwas of a suitable orifice from within 900 10 s at wateraccumulated cooled and the piece removed the± chamber, blownof off and thesubjection to 16 kPa pressure inside the sample chamber. After completion of the test, the erosion test and after erosion testing are shown in Figs. 2a and 2b, respectively the furnace wasin cooled and the test piece was removed the cham- room Similarly, temperature testing for the sample oss was measured cubic centimetres (cm3).from ber, accumulated dust blown off and the volumetric loss was measured ° angle impingement raisingtesting the for temperature inside the testing chamber. The Similarly,without room temperature the in cubic centimetreswas (cm3). done sample at 90° or 30° angle impingement was done without raising the 3. Results and discussion rosion loss (ΔV) of material by erosion from each of the test samples was calculated using the temperature inside the testing chamber. The volumetric erosion loss Three types of castable are extensively used in the various components uation: (ΔV) of material by erosion from each of the test samples was calculated of a CFBC boiler. They are alumina-based dense varieties, wherein the alumina mass-% varies in each variety, as demonstrated in Table 1 where using the formula in Equation (1) the material properties are shown. As can be seen in the table LCC–45 contains 45 mass-% Al2O3, LCC–80 contains 80 mass-% Al2O3 and 80(P) (1) ΔV = (1) is a plastic ramming mass that contains up to 82 mass-% Al2O3. Figure 3 shows the erosion loss (in cm3) plotted against three different angles of impingements 30°, 45° and 90°. Both LCC–45 and LCC–80 Where, ΔV is the volumetric3 loss (in cm3) of material, M1 ( in g) and showed excellent erosion resistance at a boiler operating temperature of mass material, M1 (in g) and and (in °Cg)irrespective are theofinitial and final mass of the plass the volumetric loss M2 ( in g) are the (in initialcm and )final of the samples tested BD M2 of 900 the angle of impingement. However, 3 densities and the(in ap- g/cm is the bulk of thebulk sample (in g/cm3).ofBulk tic castable showed high erosionand valuesthe at three different angles of im). Bulk densities apparent tested and BDdensity is the density the sample parent porosity of the samples were measured using the Archimedes pingement at a testing temperature of 900 °C. The test results showed he samples were measured using the Archimedes water immersion method.Images of samples ction to the erosion test and after erosion testing are shown in Fig. 2. 01–02|17 022 3 Fig. 3 • Erosion loss (in cm3) of the dense refractory castable with an impact angle at 900 °C the vulnerability of plastic refractory castables to highly abrasive environments at elevated temperature. It was noted from the extensive experiments that erosion resistance of castables does not show an increasing trend with respect to an increase in temperature. The reason is the operating temperatures to which these castable are subjected; mullite formation is not accentuated, which helps attain adequate thermal strength values [14, 15]. Among the three varieties, 80(P) exhibits poor erosion resistance compared to other two. The erosion values of refractory castables LCC–45 and LCC–80 are lower and are similar. The erosion value of plastic castable–80(P) is higher and is more than that of the LCC–45 and LCC–80 castable materials. The impact angle of 45° causes marginally lower erosion compared to angles of 30° and 90°. It was found from the experiments that the variation in erosion loss values from low to high impact angles provided no significant change for all three castables at elevated temperatures. Figure 4 shows the erosion resistance of various castable as a function of the impingement angle at room temperature. The erosion loss values are dependent on the impingement angles. The values of 80(P) and LCC–80 have a substantial increase in erosion rates at 90° impingement angles, as compared to the behaviour of the LCC–45 castable. Refractories are brittle in nature at room temperature. The impingement of erosive material at 90° caused more damage to the samples compared to the tangential impingement of 30°. The erosion behaviour is similar to the results obtained for various alumina bricks [8]. Under the given testing conditions, LCC–80 has the lowest erosion rate at room temperature at an impingement angle of 90°. The erosion loss of 80(P) at 30° is the lowest among the three varieties but it also shows high erosion loss at impact angle of 90°. With the room temperature tests, plastic castable 80(P) has the better erosion resistance. In Fig. 5, the existing method of erosion resistance testing of refractories ASTM C704 were also conducted to compare results with the testing method discussed in this paper at room temperature. The values of 90° impingement at room temperature for the prefired samples as per ASTM C704 [16] are similar and comparable to those of the 90° testing at room temperature using the high temperature test rig. From the results, it was found that the erosion loss (in cm3) of low cement castable varieties are low compared [5]. Although low cement castable–80 has a higher alumina content as mentioned in [5], low cement castables with a higher alumina content do not always have lower erosion loss. Also, the plastic refractory 80(P) is phosphate bonded and has low erosion loss values 4 Fig. 4 • Erosion loss (in cm3) of the dense refractory castable with an impact angle at room temperature 5 Fig. 5 • Comparison of erosion loss values between ASTM, C704 and IS 16349 [17] as tested by ASTM C704 [16]. The erosion resistance of plastic refractory 80(P) using ASTM C704 gives a superlative result, but from Fig. 3 it is quite obvious that at an elevated temperature of 900 °C, the material has very poor erosion. Hence, the ASTM C704 test method will not provide realistic erosion loss data for plastic 80(P). Figure 6 shows the erosion loss of three products as measured by erosion loss (in cm3) using SiC erodent. These test results show that all three major classes of refractories used in CFBC boilers have been tested for erosion resistance at room as well as boiler operating temperature at various angles of impingement. Unlike bricks that are fired during manufacture, castables are unfired and tend to become eroded quickly. This may be attributed to the fact that mullite formation increases rapidly at 990 °C and this cannot be achieved at boiler operating temperatures. Mullite formed products like bricks have better erosion properties. A study on aluminosilicates and high temperature erosion resistance for prefired products has already been undertaken [8]. At elevated temperature (boiler operating temperature), low cement castable LCC–80 has better erosion resistance followed by low cement castable–45 and then the plastic refractory castable. To understand the microstructure of the three alumina-based castables selected, SEM observations were carried out on the polished surfaces. REFRACTORIES 023 8 6 (a) (b) Fig. 6 • Erosion loss of dense castables – a comparison 7 (a) Fig. 8 • 8a) Erosion photo of LCC–80 at 900 °C enlarged, 8b) Erosion photo of 80(P) at 900 °C enlarged (b) (c) Fig. 7 • 7a) SEM image of eroded surface of LCC–45 at 900 °C at 90° impingement angle, 7b) SEM image of eroded surface of LCC–80 at 900 °C at 90° impingement angle, 7c) SEM image of eroded surface of 80(P) at 900 °C at 90° impingement angle The images of the three samples tested at 900 °C at a 90° angle of impingement are shown in Fig. 7a, 7b and 7c for LCC–45, LCC–80 and 80(P), respectively. The erosion in all three samples had a similar pattern. The weak, porous binder phase first undergoes dislodgement and thus further causes loosening and then exposure of aggregates of alumina to impact erodent material. The brittle erosion mechanism is clearly evident on the SEM photographs of the three materials tested. In Fig. 8a of the LCC–80 900 °C testing, the aggregates have cracked. The cracks further cause pulling or breakage of grains due to the impact of erodent materials. LCC–80, which has the better erosion resistance, has lower binder materials and strong aggregates, as shown in Fig. 8a. The poor erosion resistance values of 80(P) are justified by the presence of more binder pull out and a greater extent of damage to the aggregates, as shown in Fig. 8b. 4. Conclusions From test results we can see the following: 1. The room temperature ambient erosion tests are sufficient for LCC–45 and LCC–80 castables. 2. In the case of plastic refractories, the room temperature and 900 °C operating temperature test results vary greatly. Hence, it is proposed to conduct high temperature erosion testing in the case of plastic refractories and rammables. 3. The ASTM C704 test method will not provide realistic erosion loss data for plastic 80(P). During ASTM C704 testing, plastic shows a very good erosion resistance value but on testing at elevated temperature they show very high erosion loss when compared to LCC–45 and LCC–80. Also, during room temperature testing at various angles the behaviour of the plastic is similar to LCC–45 or LCC–80 but in real time high tem- 01–02|17 024 perature testing they have the greatest loss. 4. Although low angle impingement results are more relevant to the operating conditions prevalent inside the boiler but the results indicate that the erosion loss difference between low and high angles are not much for the three different samples tested. 5. LCC–80 possess adequate erosion resistance compared to the other two castables and hence can continue to be used in highly erosive zones of cyclone inlet ducts. Acknowledgment The authors are grateful for the encouragement, support, guidance and facilities extended for the research by Bharat Heavy Electricals Ltd (BHEL), Tiruchirappalli, India, The Ceramic Technological Institute (CTI), Bharat Heavy Electricals Ltd (BHEL), Bengaluru India and the National Institute of Technology (NIT), Tiruchirappalli, India. References [1] Anand Arjunwadkar, Prabir Basu, Bishnu Acharya: A review of some operation and maintenance issues of CFBC boilers. Appl. Therm. Eng. 102 (2016) 672–694 [2] Snyder, G.E.D., Ehrlich, S.: Refractories in CFB applications. Proc. 12th Int. Conf. Fluidised Bed Combustion, 09.05.–13.05.1993, ASME 2 (1993) 967–982 [3] Crowley, M.S., Bakker, W.T., Stalling, J.: Refractory applications in circulating fluid bed combustors. Proc. 11th Int. Conf. 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