Chemistry: Solubility Inquiry Question Ever wonder why Gatorade or other drink crystals don’t always dissolve fully? How do different conditions affect the rate of compounds going into solution? How is the concentration of a substance related to its solubility? Name: ___________________________ Date: ____________ Image in public domain. Have you ever become frustrated when trying to dissolve drink crystals such as Gatorade Powder, ice tea crystals, chocolate milk or hot chocolate powders, or similar? What can you do to make it dissolve better? Do some thing dissolve better than others? Does the liquid you are dissolving in make a difference? These all revolve around the topic of solubility and solutions. The characteristics of different solvents and solutes strongly impacts the ability for things to dissolve. In this project you will further explore the concept of ‘concentration’ and how different substances can dissolve better than others. Though a simulation and some calculations we will see how ion concentrations are related to solution concentrations etc. Page 1 of 6 2021-07-14 Chemistry: Solubility Instructions The goal for this project is to use a PHET simulation to learn more about solutions. Specifically how changing various factors will affect the concentration (Molarity) of the solution. You will also explore the concepts of saturation, ion concentration and dilution further. Begin by defining a series of solubility related terms and learning about two important concentration formulas. Explore the PHET simulation where you can try out different substances and learn about different factors affecting solubility. Finally, engage in a series of exploration questions and calculate saturated solution concentrations, ion concentrations, and how dilutions work. This Project will be graded according to the marking rubric. Definitions: Start by looking up definitions for the following words: 1. Solution: 2. Solute: 3. Solvent: 4. Molarity: 5. Dilution: Formulas: There are two important formulas for solutions. The first is how you calculate molarity. The second is the dilution formula. Complete them below. Note: M = molarity. V = Volume. Molarity = Dilution: M1V1 = Page 2 of 6 2021-07-14 Chemistry: Solubility Exploration: Ctrl-Click on the link to the right to open the PHET simulation. Solutions Try each of the following to get a feel for how the sim works then answer the questions below 2. Add different amounts of the solute “drink mix” to the beaker. There are two ways to add a solute. You can shake in solid from the shaker, which comes out in small grains, or you can add a concentrated solution using the dropper. You may switch between the “solid” shaker or “solution” dropper. 3. Measure the concentration by sliding the purple meter tool into the solution. 4. Observe what happens to the concentration when water is added or taken out of the tank. This is done by sliding the blue knob on the top or bottom faucet. 5. Explore the above options but change the type of solute. Exploration Questions: 1. What are the visual changes to the solution in the beaker when a solute is first added? 2. What happens visually and to the concentration as more and more solute is added? 3. What happens visually and to the concentration when water is added to the beaker? 4. What happens visually and to the concentration when liquid is drained from the beaker? 5. What happens visually and to the concentration when water is evaporated? Page 3 of 6 2021-07-14 Chemistry: Solubility Saturated Concentrations: As you continue to add drink mix, eventually you reach a point where no more will dissolve. This is called saturation. Determine the concentration at which saturation is reached for dink mix and then repeat that process for each solute and fill in the table below. Solute Concentration Solute Concentration Drink Mix Molarity Calculations: Using the simulation and the formula for Molarity, complete the table below. Moles of Compound (mol) Liters of Solution (L) 0.53 0.79 0.86 0.34 0.88 1.0 0.20 3.5 0.67 0.67 Molarity of Solution (M) Moles of Compound (mol) Liters of Solution (L) Molarity of Solution (M) 0.78 0.59 1.8 8.4 6.4 8.5 Ion Concentrations: Just as an entire solution has a concentration, so does each individual ion. For instance, since there are three ions when a Calcium Chloride (CaCl2) molecule dissolves into solution, a 3.0 M solution of CaCl2 is 3.0 M with respect to Ca2+ ions and 6.0 M with respect to Cl- ions. An analogy for this would be taking 3 bikes apart. You would end up with 3 frames and 6 wheels. Copy the saturated concentrations from above and then determine the concentration of each ion in solution. Compound Saturated Concentration (from Part 3) Cation Molarity Co(NO3)2 CoCl2 K2Cr2O7 K2CrO4 NiCl2 CuSO4 KMnO4 Page 4 of 6 2021-07-14 Anion Molarity Chemistry: Solubility Dilution: Adding water to a solution will dilute it which lowers the concentration. We're going to use the simulation to do some dilution activities and calculate new concentrations. 1. Complete the table below, using in an empty beaker. Begin by changing the button at the top right to read solution. You should see a dropper like the one shown the right except it will read CoCl2 instead of drink mix. Click on the red button until you have 0.20L of solution. Copy the concentration reading into the first box of the table below. Next click the spout on the left to add 0.20L of water. This will give you a total of 0.40 L of solution. Copy the new concentration and then continue adding water 0.20L at a time and copying the concentration. .20L of dropper .20L dropper+.20L .20L dropper+.40L .20L dropper+ solution water water .60Lwater Repeat the exercise, using .20L of dropper .20L dropper+.20L solution water in an empty beaker. .20L dropper+.40L water .20L dropper+ .60Lwater 2. What do you notice about the concentration change as each addition of .25L of water is added to the concentrated spigot solution? 3. The formula M1V1 = M 2V2 is a great way to calculate the concentration of a solution that undergoes dilution. M1V1 refers to the concentration and volume of the original solution, and M 2V2 refers to that solution after it has been diluted. 0.20 L of has a concentration of 5.0 M. (M1 = 5.0 M and V1 = 0.20 L) If the solution’s volume, V2 is increased with water to .50 L, calculate the new concentration, M 2. Show your work below and then check your work in the sim AFTER your calculation. Your Calculated M2: Page 5 of 6 2021-07-14 Chemistry: Solubility New concentration shown in the simulation: Page 6 of 6 2021-07-14