• Metamorphic Grade a. General term for describing the relative T and P conditions under which metamorphic rocks form. b. Metamorphic Rocks can be formed in labs but not naturally occurring minerals or rocks c. High P—Low T= Subduction d. Low P—High T=Contact Metamorphism (Intrusion) • Role of Temperature a. Rocks heat up as they are buried/pushed deeper in the Earth’s crust (Burial, plate tectonics) b. Rocks may heat up locally due to igneous intrusions or lava c. Plate tectonics is an important aspect in metamorphism or temperature. Plate tectonic (regional metamorphism) transport rocks and sediments into hot depth of the crust o Subduction o Continent-continent d. Proximity to igneous intrusions (localized metamorphism) e. Geothermal Gradient, is the increase in temperature with increasing depth in Earth’s interior o Shallow/Smaller (20ºC / km) where the lithosphere is thick o Steep/Greater (50ºC / km) where the lithosphere is thin or where magma is rising o Instrument for measuring is Geothermometer Gradient which is the use of a rock’s mineral composition to gauge the temperature at which it was formed Clay minerals recrystallize into micas, which then recrystallize into garnet. The Role of Pressure (stress) a. Two Types of Pressure o Confining Pressure, the force applied equally in all directions in proportion to the weight of overlying rocks. o Directed Pressure/Differential Stress, the force exerted in a particular direction; usually concentrated within particular zones or along discrete planes (Ex. Continent-continent collision) b. Average pressure at depth of 15km is about 4000x the pressure at the surface • Metamorphic Rocks are products of processes acting on rocks at depths ranging the upper to the lower crust • Changes in heat, pressure, and the chemical environment of rocks can alter mineral compositions and crystalline textures, making them metamorphic. • Metamorphic changes occur in the solid state, so there is no melting. • Meta (change); Morph (Form) -- (Greek) • Under metamorphism, a rock will change its minerals and/or textures until it is in equilibrium with its new Temperature and Pressure (or new fluids) • Through metamorphism, limestone like Fossiliferous when heated and pressurized will recrystallize forming bigger crystals and losing the fossils (textural change) and it will turn into marble. • Clay minerals contain a lot of water, through metamorphism and with increased pressure it will remove the water and then form micas (Mineralogical and textural change) a. Shale—Slate—phyllite—schist—gneiss (Increasing metamorphism) Significance of Metamorphic Rocks • To understand how the Earth’s crust evolved through time—most metamorphism happens deep in the crust • Commercial reasons (gemstone) • • • • Factors include: a. Temperature b. Pressure c. Fluid Phases d. Time Driven by or causes of metamorphism: a. Internal heat of Earth b. Internal pressure of Earth c. Fluid composition inside Earth Temperature increases with depth a. rate = 20º to 60ºC per km b. at 15 km depth: 450ºC Pressure and temperature increase with depth in all regions a. Pressure (P) increases with depth at about the same rate everywhere b. Temperature (T) increases at different rates in different regions c. Both P and T might increase locally due to magmatic intrusions, plate tectonics, and etc. • • c. Rate of increase = 0.3 to 0.4 kbar / km d. Minerals are measured by geobarometers Role of Fluids a. It can alter rock’s mineralogy by introducing or removing chemicals components that are soluble in heated water b. Accelerated chemical reaction o Hydrothermal fluid- carries dissolve CO2, Na, K, silica, Co, and Zn—soluble in hot water under pressure c. Metasomatism o Changing rock’s composition by fluid transport of chemical substances into or out of it. d. Reactive fluids o Are from minute pores (spaces between grains) i.e. Chemical bound water in clays (Mica and amphibole crystal structure); CO2 in hydrothermal fluids is largely derived from sedimentary carbonates—limestone and dolostones. • Type of Metamorphism a. Shock Metamorphism o Results from the heat and shock waves of a meteorite impact, transforms rock at impact site. o Shock metamorphism, also called impact metamorphism, occurs when high heat and pressures generated during an impact deform the underlying rock layers. b. Regional Metamorphism o Mineralogy and texture of rocks are changed over a wide area by deep burial and heating associated with the largescale forces of plate tectonics. o At convergent plate boundaries occurs at moderate to deep levels under moderate to ultra-high pressures and high temperatures. o Example: Himalayas, produces schist and gneiss metamorphic rocks c. High-pressure Metamorphism o Usually found in along active trenches, subduction zones, linear belts of volcanic arcs and was produced by continent-continent collision. Example. Past of Surigao (Philippine or Pacific plate underneath Mindanao). o Ultra/high-pressure metamorphism refers to the metamorphism of crustal rocks (both continental and oceanic) brought to pressures high enough to crystallize the index minerals like coesite and/or diamond. (8-12 kbar or greater than 28 kbar) d. Contact Metamorphism o Occurs adjacent to igneous intrusions and results from high temperatures associated with the igneous intrusion. Affects a thin zone of country/surrounding rock around the igneous intrusion. o This happens when the temperature of the existing rocks rises and is also infiltrated with the magma fluid. e. Burial Metamorphism o Transforms sedimentary rocks at progressively increasing temperature and pressure o Occurs when sediments are buried (deposition) deeply enough that the heat and pressure cause minerals to begin to recrystallize and new minerals to grow f. Seafloor Metamorphism o Occurs at mid-ocean ridges, where intruding magma drives seawater circulation (makes it hotter) and ethe effect have a direct change to the surrounding basalt. 3) • • • • • • Texture of metamorphic rocks is determined by a. Size (Grains) b. Shape c. Arrangement of its constituent crystals (Grains) Some texture depends on the particular kinds of minerals formed Grain size increases as metamorphic grade increases Each textural variety tells us something about the metamorphic process that created it Two major textural classes: a. Foliated rocks b. Granoblastic rocks or non-foliated rocks Two major textural classes: Foliation/Foliated Rocks a. A set of flat or wavy parallel cleavage planes produced deformation of sedimentary or igneous rocks under directed pressure b. Foliation planes may cut through the bedding of the original sedimentary rock at any angle or be parallel to the bedding. (Ex. Cracks or parallel lines in bedding planes caused by directed pressure and other factors) c. As the grade of regional metamorphism increases, formation becomes more pronounced. d. Creating Bedding planes is an example to determine the foliation (definition of beds depends on the person to make the sketch either through grains, colors, structure and etc.) e. Foliation and Cleavage Illustration (Bedding plane) • • • • • 1. Directed pressure causes sedimentary rocks, such as shale, to form cleavage planes that may differ from their bedding plane. 2. The original bedding in a sample of shale is marked by the thin sandstone layers. 3. Regional metamorphosed rocks show foliation caused by compressive force 4. Rocks develop elation when they contain platy minerals (sheets of minerals) that align along with a preferred orientation depending on their preferred orientation, compressive forces cause the mineral crystals in the rock to grow or to a line perpendicular to the compressive forces. Preferred orientation of the minerals a. Planes of all the platy crystals are aligned to the foliation b. As platy minerals crystallize, the preferred orientation is usually perpendicular to the main direction of forces squeezing the rock during metamorphism. c. Crystals of resisting minerals may contribute to the foliation by rotating until they also lie parallel to the developing foliation plane. Slaty Cleavage (different from perfect cleavage of sheers silicates like mica) a. Develops at small, regular intervals in the rock b. Rock splits into thin sheets along smooth, parallel surfaces Elongated, needlelike crystals habit a. Also tend to assume a preferred orientation b. Crystals normally line up parallel to the foliation plane c. Example are rocks with abundant amphiboles (mafic rocks) Foliated Rocks are classified on: a. Metamorphic Grade o Range of metamorphic change a rock undergoes, progressing from low (little metamorphic change) grade to high (significant metamorphic change) grade b. Crystal Size c. Type of Foliation o Type of foliation are: slate, phyllite, schist, and gneiss d. Banding o Rock consists of alternating, thin layers of two different mineral compositions. Same mineral but different proportions. Foliated Rock Names/Type of Foliation (Increasing Metamorphism) a. Slate o Metamorphosed shale or volcanic ash deposit. Dark gray to black from small amount of organic matter in the parent shale; very fine-grained. b. Phyllite o More or less glossy sheen from the crystal of mica and chlorite that have grown a little larger than those of slates. Also tend to split into thin sheets, but less perfectly than slates c. Schist o Platy crystals grow large enough to be visible and minerals tend to segregate into lighter and darker bands = coarse, wavy foliation known as schistosity. o Among the most abundant metamorphic rocks types. It has >50% platy minerals (mica, muscovite and biotite) and thin layers of quartz, feldspar, or both depending on the quartz content of parent shale. d. Gneiss o Gneiss—gneissic foliation= segregation of lighter colored quartz and feldspar from darker and tables and other mafic minerals o Ratio of granular to plate in minerals is higher than in slate or schist = poor foliation and thus little tendency to split e. Migmatite o Surrounding parts of country-rock begin to melt. Melt then migrates short instances before they solidify again o Rocks are badly formed and contorted, penetrated by veins, small pods, and lenses of melted rocks: resulting in a mixture of igneous and metamorphic rock • • • Two major textural classes: Granoblastic rocks or non-foliated rocks a. Composed mainly of crystals that grow in equant shapes (cubes or spheres) (ex. Garnet) b. Contact metamorphism where directed pressure is absent. c. All except hornfels are defined by their mineralogy rather than texture because all of them have a homogeneous granular texture (no identifiable feature; identifiable only by mineralogy) Non-foliated (granoblastic) rocks names: a. Hornfels o High-temperature contact metamorphism; uniform grain size; little or no deformation; parent rock is sedimentary or any rock with abundant silicate minerals; granular overall texture, not foliated, and it's platy or elongated crystals are oriented randomly (or all directions). b. Quartzite o From quartz-rich sandstone; homogeneous, unbroken by preserved bedding and foliation, other have thin bands of slate or schist—relics of former interbedded layers of clay or shale. c. Marble o Products of heat and pressure acting on limestone and dolomites. d. Greenstone o Metamorphosed mafic volcanic rocks; low-grade metamorphic rocks form by seafloor metamorphism; large areas of seafloor are covered with basalts that have been slightly or extensively altered • • • in this way at mid-ocean ridges; greenish due to abundance of chlorite. e. Amphibolite o Amphibole and plagioclase feldspar; medium to high grade metamorphism of mafic volcanic rocks; foliated amphiboles are by directed by pressure f. Granulite (Granofels) o High grade metamorphism; homogeneous granular texture; medium to coarse grained rocks in which the crystals are equant and has faint foliation at most; form metamorphism of shale, impure sandstone, and many kinds of igneous rocks. Classification of Metamorphic Rocks by Texture Grade of Metamorphism a. Low b. Intermediate c. High Mineral Isograds (zone of charge) a. Index minerals reflect pressure and temperature conditions o Index minerals are abundant minerals that each from under a limited range of temperature and pressure o Marks the point at which we move into a new zone with a higher metamorphic grade o Make a map of the boundaries (isograds) between metamorphic zones o Reflect pressure and temperature conditions b. Groups of 2 to 3 index minerals form an Isograds Index Minerals Define Metamorphic Zones • o Increasing Metamorphism Grade • • Changes in the mineral composition of shale during metamorphism; Changes in the mineral composition of mafic rock during metamorphism • • • • Contact Metamorphism around intruding plutons d. Transform plate margins o Seafloor metamorphism o Metamorphism by shearing forces along transform faults Metamorphic Pressure-Temperature Paths a. Metamorphic grade in forms of the maximum pressure or temperature to which the metamorphic rock has been subjugated but nothing about where the rocks encountered those conditions b. Does not tell us about how the rock was exhumed, or transported back to earth’s surface P-T Path a. Sensitive recorder of many factors: and rates of tectonic transport (burial and exhumation) that changes pressures b. Characteristics of particular plate tectonic settings Garnet (common porphyroblasts) a. Grow steadily during metamorphism b. As P and T of the environment changes, the chemical composition of the garnet changes. c. Core (oldest), edge (youngest): yields the history of metamorphic conditions under which it is formed Tectonic Plates in response to the correlation between pressure and temperature of Metamorphic Facies Metamorphism occurs in or near a. Continental Plate interiors o Contact Metamorphism o Burial Metamorphism o Regional Metamorphism b. Divergent plate margins o Seafloor Metamorphism o Contact Metamorphism is likely to be best preserved c. Convergent plate margins o Regional Metamorphism o High-pressure and ultra-high-pressure Metamorphism • Metamorphic pressure-temperature paths a. History of burial and exhumation b. Prograde and retrograde paths • The garnet crystal initially grows in a schist but ends up growing in a gneiss. • • Rapid erosion (exhumation) rates of mountain ranges show a relationship between a. Tectonics (Orogeny) b. Climate Controls the flow of metamorphic rocks to the surface.