ZEOCA WATER FILTRATION By: TANTIANA M. P. 1415100053 RAFIKA AMALIA 1415100059 AZIFA DYAH A. 1415100066 GILBERT 1415100072 Lecturer: RATNA RINTANINGRUM, S.S., M.Ed., Ph.D. SEPULUH NOPEMBER INSTITUTE OF TECHNOLOGY SURABAYA 2016 i PREFACE Thanks to Almighty God who has given His blessing to the writers for finishing this English Paper assignment entitled “Zeoca Water Filtration”. This Paper is about Water Filtration to solve some problems because of pollution. We use ‘Water Filtration’ as our main theme because we want to applicate our Chemistry knowledge to people around us who needs our help. We realize that this paper is not only about assignment, but also to expand our knowledge more and even more. We also wish to express our deep and sincere gratitude for those who have guided in completing this paper, especially: 1. Prof. Ir. Joni Hermana, M.ScES., Ph.D. as Rector of Sepuluh Nopember Institute of Technology; 2. Prof. Dr. Ir. Heru Setyawan, M.Eng. as Vice Rector I of Sepuluh Nopember Institute of Technology 3. Ratna Rintaningrum, S.S., M.Ed., Ph.D. as our English Lecturer; 4. Parents who support us; and 5. All people who help us to complete this paper whom we can’t mention one by one. Last but not least, we hope this English Paper assignment can help the readers to expand their knowledge about science. From the proverb “No Rose without Torn”, we realized this paper is not perfect and we apologize for any mistake in this paper. Thank You. Surabaya, April, 11, 2016 Author ii TABLE OF CONTENTS PREFACE ........................................................................................................................ i TABLE OF CONTENTS ............................................................................................... ii CHAPTER 1.................................................................................................................... 1 1.1 Background of Information ............................................................................ 1 1.2 Problem Statement .......................................................................................... 2 1.3 Purpose of The Study ...................................................................................... 2 1.4 Contribution of The Study .............................................................................. 2 CHAPTER 2.................................................................................................................... 3 2.1 What Zeoca Is ................................................................................................... 3 2.1.1 Water Pollution ......................................................................................... 3 2.1.2 Zeoca Water Filtration ............................................................................. 5 2.2 The Function of Zeoca ..................................................................................... 5 2.3 Function of Each Component of Zeoca Water Filtration ............................ 6 2.4 How Zeoca Works ............................................................................................ 7 2.4.1 Waste Water Garden ............................................................................... 8 2.4.2 Water Treatment ...................................................................................... 8 CHAPTER 3.................................................................................................................... 9 3.1 How to make Zeoca .......................................................................................... 9 3.1.1 Tools and Materials .................................................................................. 9 3.1.2 The Step Making ZEOCA Prototype ................................................... 10 3.2 TEST OF ZEOCA (RESULTS).................................................................... 11 3.3 Advantages and Disadvantages .................................................................... 14 CHAPTER 4.................................................................................................................. 16 4.1 Conclusion ...................................................................................................... 16 REFERENCES ............................................................................................................. 17 1 CHAPTER 1 INTRODUCTION 1.1 Background of Information Water is an important element of nature resources. Water is used in every aspect of human lives such as husbandry, fishery, animal husbandry, industry, mining, etc. Water is a prior need for human in this planet. Human can survive even without having their meal in several weeks, but not with water. Human even can die if they don’t consume water in a day due to dehydration. In modern economics application, water is a constituent part for agriculture, industry, electricity power plant and transportation application. Human, plants and animal might die lacking in water. Water affects widely in human lives, moreover it’s used for us to eat and drink (Honimb, 2007). Water pollution can be caused by the house hold water waste disposal, industry waste and could even be caused by the pesticide and fertilizer utilizing. Those pollutions affect the organism and even environment in the form of liquid, colloid and other forms of particle. Another effects caused by the water pollution is sickness. Due to the bad condition of the environment itself, human willingly or unwillingly could be sick (Dery Firdaus, 2008). The quality of water in metropolitan cities especially Surabaya is not even up to the water quality standards based on Peraturan Pemerintah Number 82 Year 2001 and Perda Kota Surabaya Number 2 Year 2004 about Quality Of Water Processing And Controlling (Badan Lingkungan Hidup, 2009). One of the possible ways to make out the water pollution problem in Surabaya is by having the recycle technology and water filtration of Zeoca. Zeoca is a technology which uses a filter instrument and active carbon in its application. This kind of technology can be used to recycle the water waste disposal of wudhu (in the mosque) and purify them. This technology consists of 2 elements, they are waste water garden and water treatment. The Waste Water Garden Component contain of gravel and water hyacinth. The water hyacinth itself is used to catch the serious metal pollutant. While the Water Treatment contains silica, zeolite and active carbon. The silica is used to filter the soil and mud in 2 the waste water. Zeolite is for changing the nature ion and also bonding the oxygen molecules in the waste water. Meanwhile, the active carbon function is in removing the released chlorine and other organic compounds to move away the odor, taste and color of the water. 1.2 Problem Statement Based on the information background, the problem statement of this paper are: 1. What is Zeoca Water Filtration? 2. What is Zeoca Water Filtration for? 3. What are the functions of each component of Zeoca Water Filtration? 4. How does Zeoca Water Filtration work? 5. What results can be obtained from Zeoca Water Filtration? 6. What are the advantages and disadvantages of Zeoca Water Filtration? 1.3 Purpose of The Study This paper of study purposes to know about: 1. What Zeoca Water Filtration is; 2. The function of Zeoca Water Filtration; 3. The function of each component of Zeoca Water Filtration; 4. The way how Zeoca Water Filtration works; 5. Results that can be obtained from Zeoca Water Filtration; 6. The advantages and disadvantages of using Zeoca Water Filtration. 1.4 Contribution of The Study 1. This study is an application of chemistry, biology, chemistry engineering and physics 2. This study is done for people lived in polluted water area 3 CHAPTER 2 ZEOCA AND HOW IT WORKS 2.1 What Zeoca Is 2.1.1 Water Pollution Water is the most common liquid on Earth. It covers about 71.4% of the Earth. Pure water has no smell, taste, or color. Lakes, oceans, and rivers are made of water. Water is very important for life. Plants and animals (including people) are mostly water inside, and must drink water to live. It gives a medium for chemical reactions to take place, and is the main part of blood. It keeps the body temperature the same by sweating from the skin. Water helps blood carry nutrients from the stomach to all parts of the body to keep the body alive. Water also helps the blood carry oxygen from the lungs to the body. Saliva, which helps animals and people digest food, is mostly water. Water helps make urine. Urine helps remove bad chemicals from the body. The human body is between 60% and 70% water. Though a human being can survive for up to a three weeks without food, they can only survive for a day or two without water. However, some studies suggest that by 2025 more than half of the people around the world will not have enough water. Its happen because as earth's population continues to grow, people are putting ever-increasing pressure on the planet's water resources. In a sense, our oceans, rivers, and other inland waters are being "squeezed" by human activities—not so they take up less room, but so their quality is reduced. Poorer water quality means water pollution. We know that pollution is a human problem because it is a relatively recent development in the planet's history: before the 19th century Industrial Revolution, people lived more in harmony with their immediate environment. As industrialization has spread around the globe, so the problem of pollution has spread with it. When Earth's population was much smaller, no one believed pollution would ever present a serious problem. It was once popularly believed that the oceans were far too big to pollute. Today, with around 7 billion people on the planet, it has become apparent that there are limits. Pollution is one of the signs that humans have exceeded those limits. 4 Some people believe pollution is an inescapable result of human activity: they argue that if we want to have factories, cities, ships, cars, oil, and coastal resorts, some degree of pollution is almost certain to result. In other words, pollution is a necessary evil that people must put up with if they want to make progress. Fortunately, not everyone agrees with this view. One reason people have woken up to the problem of pollution is that it brings costs of its own that undermine any economic benefits that come about by polluting. Pollution matters because it harms the environment on which people depend. The environment is not something distant and separate from our lives. The environment is everything that surrounds us that gives us life and health. Destroying the environment ultimately reduces the quality of our own lives. And that, most selfishly, is why pollution should matter to all of us. Water pollution is all about quantities, how much of polluting substance is released and may have little impact to nature and people surrounding. Water pollution can cause human illness, its happen, either directly or indirectly. Surabaya's water quality it’s not satisfy the standards of safe level. To avoid this bad problem, we had to find the idea to resolve this problem. Picture 2.1: Example of Water Pollution Cycle (valdosta.edu) 5 2.1.2 Zeoca Water Filtration From small example explained on 2.1.1, we give one of best alternative to resolve the water pollution, that is ZEOCA. ZEOCA is a technology to recycle and purify water by using a filter and activated carbon. This technology is used to recycle ablution water and recycle them, so that we can use the water again. This method can save the water pollution problem, especially in Surabaya. This technology consists of two steps, they are water garden waste and water treatment. Picture 2.2: Sketch of ZEOCA prototype (Zahra, 2015) 2.2 The Function of Zeoca Diagram 2.1: Zeoca Flow Chart Based on the diagram above, the function of Zeoca can be described below: Filtrate the dirt water from the weight metal pollutant and other dangerous pollutants Purify the water to change the muddy water into the clean water one 6 Recycle the water after being processed though filtration and purification process, so that the water can be used again 2.3 Function of Each Component of Zeoca Water Filtration In the manufacturing of Zeoca, there are 5 important components needed, they are: Gravel Gravel is needed in the water waste garden process. It is used as media for water hyacinth to optimize the water filtration process. Water Hyacinth Same goes with gravel, water hyacinth is also used in the water waste garden. The water hyacinth is used to absorb the serious metal pollutant contained in the dirt water. Metal pollutants are terribly dangerous especially for human’s health. Human who consume water that is contained metal pollutant will affect their nerve damage and physical defect on children. Lubis and Sofyan (1986) explained that Chrome (Cr) can be absorbed by the water hyacinth totally in degree 7 of pH. On their experiment as well, water hyacinth can absorb the Cr until 51.85 %. Water hyacinth is also justified can absorb the pesticide residue, such as 2.4-D residue and parquet. Based on the experiment of Chossi and Husin (1977), water hyacinth was able to absorb 0.296 ppm of 0.5 ppm 2.4-D and 0.83 ppm of 2 ppm 2.4-D for 96 hours. Up till now, water hyacinth is known as weeds to farmer. But, as is proper, water hyacinth can be well used in filtration technology and not to mention, the amount of water hyacinth itself is getting much bigger in Indonesia than anywhere in the world due to the temperature and seasons that Indonesia has. Silica Silica in the water treatment part is used to filter the soil and mud in the waste water. Silica that is contained Si (silicon) and O2 (oxygen) is found widely in the earth. Even though silica is generally found in a form of crystal, but silica in the form of sand is better and higher in compounds. Unfortunately, the silica sand manufacture needs more process and treatment. Sand or silica sand is contained some of mineral particles and hard core. Zeolite 7 Zeolite is also used Zeolite in this part is used to change the nature ion and to bond the oxygen molecules in the waste water. Zeolite is a hydrate compound of alumina-silicate with sodium, potassium and barium as cations. Zeolite is known as ‘molecular sieve’ or ‘molecular mesh’ due to its molecular pores that can separate/absorb molecules in a certain size. Zeolite has some special characteristics, they are: easily release water due to reheating and bond the water molecule back in humid temperature. Besides, zeolite can also release cation while exchanging them, for example zeolite that releases sodium and exchange it by bonding calcium or magnesium. These characteristics of zeolite is well used to mellow the water. Active Carbon Active carbon has a function to remove the released chlorine and other organic compounds to move away the odor, taste and color of the water. Active carbon is one type of carbon which is processed through many stages until results an openended pores active carbon, so that it has a high absorbing power especially to a material in a form of aqueous or vapor. 2.4 How Zeoca Works The Zeoca Water Filtration is contained of 2 parts, they are water waste garden and water treatment. Which each of them has its own ways of work. Such like the name of the filtration tools, Zeoca, which is the length of zeolite, active carbon, water hyacinth and silica, they are the compounds contained in the tools itself. Every part of ZWF (Zeoca Water Filtration) has its special compound to run its function. Diagram 2.2: The Process of Zeoca 8 2.4.1 Waste Water Garden Gravel Result <To Water Treatment> Water Hyacinth Diagram 2.3: The Water Waste Garden Flowchart The first part is water waste garden, it processes the dirt water or the first place where the input begins to be filtrated. As its function to be in contact with the dirt water directly, water waste garden has water hyacinth and gravel inside. Filter the soil and mud in the water Change nature ion and to bond oxygen molecules Active Carbon Water Treatment Zeolite Silica 2.4.2 Remove the released chlorine and other organic compound Diagram 2.4: The Water Treatment Process . From the water waste garden process, the result goes directly to the water treatment process. With silica, zeolite and active carbon in water treatment, the filtration water is already finished to be recycled. 9 CHAPTER 3 RESEARCH METHOD 3.1 How to make Zeoca 3.1.1 Tools and Materials 3.1.1.1 Tools The tools that we use in this research are: 1. Length meter 2. Hacksaw 3.1.1.2 Materials The Materials that we use in this research are: 1. Iron rod 2. Paralon pipe 2 inches and 4 inches 3. Hose 4. Gravel 5. Wheel 6. Box 7. Partition board 8. Glue 9. Silica sand 10. Zeolit 11. Activated carbon 12. Hyacinth 13. Valve Picture 3.1: Sketch of ZEOCA prototype (Zahra, 2015) 10 3.1.2 The Step Making ZEOCA Prototype There are two kind of process in this research: 3.1.2.1 The process of waste water garden 1. Make the model of prototype waste water garden 2. Prepare one box 57 cm of length, 40 cm of width, and 32 cm of height, or customize based the amount of the water that we want to get 3. Put the gravel on the base of the box as the cornerstone of the hyacinth 4. Plant the hyacinth inside the box, on the sidelines of the gravel Water Hyacinth Gravel Picture 3.2: Waste Water Garden (Zahra, 2015) 3.1.2.2 The process of water treatment part 1 and part 2 1. Part 1: Fill the 4 inches pipe sequentially; silica sand, zeolite, silica sand, with the comparison 1:3:1 2. Part 2: fill another 2 inches pipe with activated carbon until 60% of the pipe that we use is filled up 3. Set the prototype like the picture below Picture 3.3: Water Treatment Silica Zeolit e Silica 2015) Active Carbon (Zahra, 11 3.2 TEST OF ZEOCA (RESULTS) In Zeoca Water Filtration, we use 3 variables to analyse the difference between the water without filtration and the water after filtration. With those variables, we can know the best result from Zeoca Water Filtration based on the Clean Water Minimum Requirement (Red column). Those variables are: A. Ablution Water without any treatment (Yellow Column) B. Ablution Water with waste water garden process and then water treatment process (Green Column) C. Ablution Water with water treatment process, without water garden process (Blue Column) The result from Physical test analyzing: No. Parameter Unit Clean Water A B C Requirement* 1. Colour Unit PtCo 50 56,5 19,5 17,0 2. Taste - Tasteless - - - 3. Smell - Odourless Odour- Odour- Odourless less less 4. Turbidly NTU Scale 25 22,80 3,45 2,31 5. Total Dissolved mg/L 1500 508 498 474 Solid (TDS) 6. Temperature o 25 oC ± 3oC 25 25 25 7. Electrical Πmhos/cm - 849 830 791 Zeoca Water Filtration C Conductivity Table 3.1: The Physical Test Analysis of Source: Environment-Quality Laboratory of Environmental Engineering, Faculty of Civil Engineering and Planning, ITS Surabaya The result from inorganic test analyzing: 12 No. Parameter Unit Clean Water A B C Requirement* 1. pH - 6,5-9,0 7,20 8,35 8,40 2. Hardness mg/L 500 285,71 271,43 235,71 CaCO3 3. Chloride mg/L Cl- 600 76,00 92,00 72,00 4. Sulphate mg/L SO4 400 50,80 51,45 46,42 5. Nitrate mg/L NO3- 10 0,00 2,23 2,57 6. Nitrite mg/L NO2- 1 0,021 0,227 0,230 7. Ammonia mg/L NH3- - 3,35 0,32 0,30 8. Iron mg/L Fe 1 0,51 0,10 0,007 9. Manganese mg/L Mn 0,5 0,00 0,00 0,00 10. Lead mg/L Pb 0,05 0,00 0,00 0,00 11. Zinc mg/L Zn 15 0,12 0,08 0,07 12. Chromium mg/L Cr6+ 0,05 0,00 0,00 0,00 13. Fluoride mg/L F 1,5 0,46 0,42 0,45 14. Arsenic mg/L As 0,05 0,00 0,00 0,00 15. Mercury mg/L Hg 0,001 0,00 0,00 0,00 16. Cadmium mg/L Cd 0,005 0,00 0,00 0,00 17. Selenium mg/L Se 0,01 0,00 0,00 0,00 18. Cyanide mg/L CN- 0,1 0,00 0,00 0,00 Zeoca Water Filtration Table 3.2: The Inorganic Test Analysis of Source : Environment-Quality Laboratory of Environmental Engineering, Faculty of Civil Engineering and Planning, ITS Surabaya The result from organic test analyzing: No. Parameter Unit Clean Water A B C 10 11,30 1,26 17,0 0,5 0,26 0,12 - Requirement* 1. KMNO4 number mg/L KmnO4 2. Detergent mg/L 13 Table 3.3: The Organic Test Analysis Of Zeoca Water Filtration Source: Environment-Quality Laboratory of Environmental Engineering, Faculty of Civil Engineering and Planning, ITS Surabaya *Clean Water Requirement is taken from PERMENKES RI No. 416 MENKES/PER/IX/90 The first table shows that Ablution Water that has been processed by Zeoca Water Filtration (B and C) gives better results than Ablution Water with no treatment at all. We can look from the color, turbidity, and the total dissolved solids which both B and C have smaller value than the standard, so it means B and C is Clean Water. The second and third table (Inorganic and Organic test) show that Ablution water that has been processed by Zeoca Water Filtration gives better result than ablution water with no treatment at all. We can see from the hardness; the contents of ammonia, Iron, Zinc, Fluoride, KMNO4 number and the detergent, all have smaller number and fulfil the standard for Clean Water. Water B (Ablution water with water waste garden process and then water treatment process) shows that Water B is much better than Water C (Ablution water with water treatment process, but without waste garden process). But some test shows that C is better than B. It’s due to some failed mechanism and the water hyacinth wasn’t being cleaned properly so it has a lot of mud that contaminate the Waste Water Garden. 14 3.3 Advantages and Disadvantages After all the studies and analysis which have done, we found some advantages and disadvantages in the Zeoca technology application that shows in Table 3.4 and Table 3.5. Advantages Zeoca can recycle and save water Reason Because Zeoca can make water clean again. It’s useful so we don’t need to spend lots of money just for clean water (We can make it instead!). Zeoca can reduce water pollution on Because Zeoca itself contains Zeolite, this earth Silica, and Carbon which are able to absorb and remove metals ion in the water. Zeoca can remove smelly water Water with unpleasant smell is considered as Invisible Pollution and it’s bad for our bronchus and alveolus (lungs). Zeoca gives us better health Because Zeoca can remove heavy metals ion, the water is safer to be used on our body/skin. Heavy metal ion inside our body is very dangerous. Zeoca’s main component is cheap to Zeoca Water Filtration doesn’t cost lots of make money. Zeolite, Silica, and Carbon only total around Rp20,000.00/kg which can be used numerous times. Zeoca can be made by scraps item (do Zeoca’s main components are Zeolite, not have to use materials above, it can Silica, and Carbon. Other materials can be be modified) changed according to the needs. Table 3.4: The Advantages of Zeoca Water Filtration 15 Disadvantages Reason Zeoca’s main materials are not easy to It’s very difficult to find Zeolite, Silica, find and Active Carbon in village or backwoods. Those materials are uncommon seen there. After using many times, we need to clean Zeoca absorbs heavy metal ions which up everything again. are not small amounts. The ions are saved in Zeoca’s materials. After a while, Zeoca’s Materials can’t absorb ions anymore due to too much ion that over its capabilities (overlimit). Table 3.5: The Disadvantages of Zeoca Water Filtration 16 CHAPTER 4 CLOSING 4.1 Conclusion From the studies which had done, we can conclude some points below: 1. Zeoca Water Filtration Technology is a technology suggested to solve the water pollution problems which are happening especially in metropolitan city. 2. Zeoca Water Filtration Technology is made for filtrating and recycling the waste water, so that the waste water can be used again safely. 3. Zeoca Water Filtration has 5 important components in the manufacturing process. These are cobblestone, water hyacinth, silica soil, zeolite, and active carbon. 4. Zeoca Water Filtration’s way of works are based on its 2 components. Generally, the Zeoca Water Filtration Technology’s work principal is to filtrate, purify, and recycle the waste water. 5. The water result after being processed through Zeoca Water Filtration is a water which is up to the water standards applied by the country. The filtration water of ZWF can be used again to bath or wash some stuff (dishes, clothes, etc.). 6. However, Zeoca Water Technology application still has disadvantages. Although still, its advantages are ways more than its disadvtanges. 17 REFERENCES Istiqoma, Ona. 2012. “Eceng Gondok Harta Karun Bagi yang Berpikir” accessed in https://onainsight.wordpress.com/2012/12/09/enceng-gondok-harta-karun-bagi-yangberpikir/ on December 9th 2012 ADYWATER company. 2013. “Apa Itu Silika?” accessed in http://pasirsilikanusantara.blogspot.co.id/2013/03/apa-itu-silika.html on March 2013 KUG company. “Zeolit-Kandungan dan Kegunaannya” accessed in accessed in http://serbapupukorganik.blogspot.co.id/p/blog-page_1041.html on 2013 Marliati, Diah. 2012. “Efek Samping Karbon Aktif” http://www.kompasiana.com/diah_marliati_a_soeradiredja/efek-samping-karbonaktif_551932c9813311f1749de0d5 on November 14th 2012 and renewed on June 24th 2015 Arfenti, Z. S. (2015). RETTER (RECYCLE OF THE ABLUTION WATER) TEKNOLOGI RECYCLE AIR WUDHU YANG SYAR’I DAN BERSIH SEBAGAI SARANA PENGHEMATAN AIR DI INDONESIA. Diploma Chemical Engineering