Reading the Periodic Table Review – Current Atomic Model Protons Electron cloud nucleus Neutrons Electron Introduction There are 118 known elements in the universe. The periodic table organizes all of the elements in a way that is understandable and useful. REMEMBER! Elements differ by the number of protons (#p) each has in its nucleus. Introduction The current periodic table has 118 squares. Each square shows the elements name, symbol, atomic number and atomic mass. Information in Each Square Take the element Helium, for example: CHEMICAL SYMBOL ELEMENT NAME ATOMIC NUMBER (p) or (e) ATOMIC MASS (p + n) Example – 1 Atom of Helium (p) or (e) (2p + 2n) Atomic Math Calculate the # of protons, electrons & neutrons. p = _____ p = _____ p = _____ e = _____ e = _____ e = _____ n = _____ n = _____ n = _____ Atomic Math Calculate the # of protons, electrons & neutrons. p=3 p = 11 p = 30 e=3 e = 11 e = 30 n=4 n = 12 n = 35 Something Strange There’s something strange about mass numbers. Mass numbers are not whole numbers, but are decimals instead. How can you have a decimal proton or neutron? This can be explained by isotopes. What are Isotopes? Every atom of each element has the same # of protons, but the # of neutrons can change. Isotopes are elements with the same # of protons but a different # of neutrons. This gives each isotope a different mass number (p+n) Example 1 There are 3 natural isotopes of carbon. 6 NEUTRONS 7 NEUTRONS 8 NEUTRONS Each isotope has 6 protons; they are all carbon! How many neutrons does each isotope have? Example 2 There are 3 natural isotopes of oxygen 7 NEUTRONS 8 NEUTRONS 10 NEUTRONS Each isotope has 8 protons; they are all oxygen! How many neutrons does each isotope have? Why Decimals? In the universe, the C-12 isotope is much more abundant than C-13 and C-14 isotopes. Atomic mass is a weighted average of all of an elements natural isotopes. A weighted average takes into account each isotope’s mass and its natural abundance (%). Why Decimals? In the universe, the C-12 isotope is much more abundant than C-13 and C-14 isotopes. Atomic mass is a weighted average of all of an elements natural isotopes. NOTE: The weighted average is always closest to the mass of the most abundant natural isotope! Abundance Example 1 The atomic mass number of oxygen is 15.999. MOST ABUNDANT What’s the most abundant oxygen isotope? This is because 15.999 is closest to O-16. Abundance Example 2 The atomic mass number of chlorine is 35.45. MOST ABUNDANT What’s the most abundant chlorine isotope? This is because 35.45 is closest to Cl-35. Before the Periodic Table Before the periodic table was invented, the field of chemistry was a mess! The roughly 63 elements were not organized. It was very difficult to locate information on all the elements and to predict how elements would react with each other. Dmitri Mendeleev (1869) Dmitri Mendeleev created the periodic table. Mendeleev was a chemist and professor who found a new way to organize the elements. While writing a textbook, Mendeleev wanted to find a way to organize the 63 known elements at the time. While doing this, he made a famous discovery that ultimately solved the problem of the disorganized elements. A Game of Cards Mendeleev was a fanatical card player, and he used his talents to solve the element puzzle. I spent time collecting information about all of the known elements and then made cards for them, similar to a deck of playing cards. A Game of Cards Mendeleev was a fanatical card player, and he used his talents to solve the element puzzle. On each card I wrote the element’s name, chemical symbol, atomic mass, physical and chemical properties and bonding power. A Game of Cards Mendeleev was a fanatical card player, and he used his talents to solve the element puzzle. When I placed the elements in order of increasing atomic mass, I began to notice clear patterns in their properties and reactivity... I placed the first 7 element cards in a row by increasing atomic mass. I placed the next 7 in a new row. Their properties repeated perfectly! I placed the next 7 in a new row. Their properties repeated perfectly! I filled the rest of the table but left gaps where the pattern didn’t fit. I claimed that the missing elements would be found and even predicted their properties in great detail. I could do this since I discovered that elements in the same vertical column have similar properties. Eventually, these elements were discovered and my predictions were nearly perfect. Hooray! Bold Predictions Dmitri Mendeleev’s table was very accurate. Mendeleev’s idea was put to the test when gallium (Ga) was discovered in France in 1875. A scientist named Paul Emile Lecoq de Boisbaudran discovered Ga and published information about the metal. Mendeleev publicly told the scientist that his measurements for gallium’s density were incorrect since it didn’t match his predictions… and was right! A Modern Equivalent Mendeleev took a huge risk when publicly challenging de Boisbaudran about gallium. The best way to imagine what Mendeleev did in 1875 is put it in a modern context. A TWITTER WAR After Mendeleev’s Table Mendeleev’s table was great, but had a few errors. Once protons were discovered by Rutherford, Mendeleev’s periodic table was rearranged. In 1913, British scientist Henry Moseley reorganized the table by atomic number (#p), which solved many issues with Mendeleev’s table; his table closely resembles today’s. A New & Improved Table MOSELY’S PERIODIC TABLE (1913) MODERN PERIODIC TABLE (NOW) Periods HORIZONTAL ROWS ARE CALLED PERIODS. THERE ARE 7 PERIODS IN TOTAL. 1 2 3 4 5 6 7 ELEMENTS IN SAME PERIOD = SAME # OF ENERGY LEVELS. Groups VERTICAL COLUMNS ARE CALLED GROUPS or FAMILIES. THERE ARE 18 GROUPS IN TOTAL. 1 18 13 14 15 16 17 2 3 4 5 6 7 8 9 10 11 12 ELEMENTS IN SAME GROUP = SAME # ELECTRONS IN OUTER LEVEL. Groups ELEMENTS IN THE SAME GROUP HAVE SIMILAR PROPERTIES. Names of Key Groups Alkali Metals Alkaline Earth Metals Transition Metals Noble Gases Halogens Metals, Nonmetals, Metalloids METALS ARE FOUND ON THE LEFT. NONMETALS ON THE RIGHT. THEY ARE SEPARATED BY A ZIGZAG LINE OF METALLOIDS. metalloids metals nonmetals Metals, Nonmetals, Metalloids METALS METALLOIDS NONMETALS Shiny Properties that are in between metals and nonmetals Dull Some metalloids have more metallic props Weak Hard Strong Dense Good conductors Malleable Ductile e.g. iron, copper Some metalloids have more nonmetal props Example: silicon is a semiconductor e.g. silicon, germanium Soft Lightweight Poor conductors Brittle Inelastic e.g. carbon, nitrogen Periodic Table Groups Recall that vertical columns are called groups. A periodic table group is like a “family”, where members may look and act similarly. Elements in the same group have similar physical and chemical properties. Let’s look at 5 key groups… Group 1 – Alkali Metals Alkali Metals 1 18 13 14 15 16 17 2 3 4 5 6 7 8 9 10 11 12 Group 1 – Alkali Metals Very reactive metals Na Shiny, silvery, soft Stored in oil to avoid reacting with the air Very low density Cut with a knife K React with water Li, Na, K, Rb, Cs, Fr Explosive in H2O Group 2 – Alkaline Earth Metals 1 Alkaline Earth Metals 18 13 14 15 16 17 2 3 4 5 6 7 8 9 10 11 12 Group 2 – Alkaline Earth Metals Slightly reactive metals Ca Shiny, silvery-white Common in rocks, plants, human body Relatively strong, malleable and ductile Be, Mg, Ca, Sr, Ba, Ra Silvery-white metal Be Found in emeralds Groups 3-12 – Transition Metals 1 18 2 Transition Metals 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 Groups 3-12 – Transition Metals Large metal group Au Shiny, metallic luster Hard, dense, malleable & ductile Oxides are used in pigments & paints e.g. Cu, Al, Zn, Fe, Au Shiny metallic luster Fe Iron oxides Group 17 – Halogens Halogens 1 13 14 15 16 17 2 3 4 5 6 7 8 9 10 11 12 18 Group 17 - Halogens Very reactive nonmetals Come in all three states of matter Br Both solid & gas form Give off colored vapors Highly toxic; used as antiseptics & cleaners F, Cl, Br, I, At Cl Poisonous green gas Group 18 – Noble Gases Noble Gases 1 18 13 14 15 16 17 2 3 4 5 6 7 8 9 10 11 12 Group 18 – Noble Gases Unreactive nonmetals He Completely “inert” Odorless, colorless gases Nonflammable gas Glow with distinct colors when electricity is run through them, as in “neon” lights He, Ne, Ar, Kr, Xe, Rn Gas-discharge lights Review of Key Groups Alkali Metals Noble Gases Alkaline Earth Metals Halogens Transition Metals metalloids metals nonmetals