Nomen Dies Recitation Magistra 1. In a redox reaction, how does the total number of electrons lost by the oxidized substance compare to the total number of electrons gained by the reduced substance? 7. Base your answer to the following question on the diagram below which represents a chemical cell at 298 K and 1 atmosphere. A) The number lost is always greater than the number gained. B) The number lost is always equal to the number gained. C) The number lost is sometimes equal to the number gained. D) The number lost is sometimes less than the number gained. 2. In an electrolytic cell, to which electrode will a positive ion migrate and undergo reduction? A) B) C) D) the anode, which is negatively charged the anode, which is positively charged the cathode, which is negatively charged the cathode, which is positively charged 3. Given the redox reaction: 2 Cr(s) + 3 Sn2+(aq) B) Sn2+ 2 Cr 3+(aq) + 3 Sn(s) C) Cr 3+ D) Sn 4. What is the oxidation number of sulfur in Na2S2O3? A) –2 B) +2 C) +6 D) 0 5. An oxidation-reduction reaction involves the A) B) C) D) A) Zn B) Zn2+ C) Cu D) Cu2+ 8. What occurs during the reaction below? 4 HCl + MnO2 ® MnCl2 + 2 H2O + Cl2 Which species serves as the reducing agent? A) Cr Which species represents the cathode? A) The manganese is reduced and its oxidation number changes from +4 to +2. B) The manganese is oxidized and its oxidation number changes from +4 to +2. C) The manganese is reduced and its oxidation number changes from +2 to +4. D) The manganese is oxidized and its oxidation number changes from +2 to +4. sharing of electrons sharing of protons transfer of electrons transfer of protons 6. Which half-reaction can occur at the anode in a voltaic cell? A) Ni 2+ + 2e - ® Ni C) Zn ® Zn2+ + 2e - B) Sn + 2e - ®Sn2+ D) Fe 3+ ® Fe 2+ + e - Version 1 9. Base your answer to the following question on the equation and diagram below represent an electrochemical cell at 298 K and 1 atmosphere. 13. In a chemical cell composed of two half-cells, ions are allowed to flow from one half-cell to another by means of A) B) C) D) electrodes a voltmeter an external conductor a salt bridge 14. Which energy conversion must occur in an operating electrolytic cell? A) B) C) D) electrical energy to chemical energy electrical energy to nuclear energy chemical energy to electrical energy chemical energy to nuclear energy 15. The overall reaction in a electrochemical cell is Zn(s) + Cu2+(aq) ® Zn2+(aq) + Cu(s). As the reaction in this cell takes place, the Which species is oxidized when the switch is closed? B) Mg 2+ (aq) D) Ag+ (aq) A) Mg(s) C) Ag(s) 10. What is the oxidation state of nitrogen in the compound NH 4Br? A) –1 B) +2 C) –3 electrical energy spontaneously chemical energy spontaneously electrical energy nonspontaneously chemical energy nonspontaneously 12. Given the reaction: Cu(s) + 4 HNO 3(aq) H2O( ) mass of the Zn(s) electrode decreases mass of the Cu(s) electrode decreases Cu2+(aq) concentration remains the same Zn2+(aq) concentration remains the same 16. Given the balanced equation representing a redox reaction: D) +4 11. During the operation of a voltaic cell, the cell produces A) B) C) D) A) B) C) D) 2Al + 3Cu2+ ® 2Al3+ + 3Cu Which statement is true about this reaction? A) B) C) D) Each Al loses 2e – and each Cu 2+ gains 3e–. Each Al loses 3e– and each Cu 2+ gains 2e–. Each Al3+ gains 2e– and each Cu loses 3e –. Each Al3+ gains 3e– and each Cu loses 2e –. 17. Which energy conversion occurs in a voltaic cell? Cu(NO 3) 2(aq) + 2 NO2(g) + 2 As the reaction occurs, what happens to copper? A) It undergoes reduction and its oxidation number decreases. B) It undergoes reduction and its oxidation number increases. C) It undergoes oxidation and its oxidation number decreases. D) It undergoes oxidation and its oxidation, number increases. A) B) C) D) chemical energy to electrical energy chemical energy to nuclear energy electrical energy to chemical energy nuclear energy to electrical energy 18. Given the balanced equation representing a reaction: 2KClO 3(s) 2KCl(s) + 3O 2(g) The oxidation state of chlorine in this reaction changes from A) –1 to +1 C) + l to –1 B) –1 to +5 D) +5 to –1 Version 1 19. Which balanced equation represents a redox reaction? A) B) C) D) AgNO3 + NaCl ® AgCl + NaNO 3 BaCl2 +K2CO 3 ® BaCO 3 +2KCl CuO + CO ® Cu + CO2 HCl + KOH ® KCl + H 2O 20. Given the balanced ionic equation: 24. Given the balanced equation representing a reaction: 2Fe + 3Cu2+ ® 2Fe 3+ + 3Cu When the iron atoms lose six moles of electrons, how many moles of electrons are gained by the copper ions? A) 12 moles C) 3 moles B) 2 moles D) 6 moles 25. Which is the oxidizing agent in the reaction Which equation represents the oxidation half-reaction? A) B) C) D) 2e– Zn2+(aq) Zn(s) + Zn(s) Zn2+(aq) + 2e– Cu2+(aq) Cu(s) + 2e– Cu2+(aq) + 2e– Cu(s) 21. The diagram below shows a key being plated with copper in an electrolytic cell 2 Fe2+ + Cl2 ® 2 Fe3+ + 2 Cl– ? A) Fe 2+ B) Cl 2 C) Fe 3+ D) Cl – 26. According to Reference Table J, which metal will react with Zn 2+ but will not react with Mg2+? A) Al(s) B) Cu(s) C) Ni(s) D) Ba(s) 27. Base your answer to the following question on the information below. During a laboratory activity, a student reacted a piece of zinc with 0.1 M HCl(aq). Based on Reference Table J, identify one metal that does not react spontaneously with HCl(aq). Given the reduction reaction for this cell: Cu2+(aq) + 2e- Cu(s) This reduction occurs at A) B) C) D) A, which is the anode A, which is the cathode B, which is the anode B, which is the cathode 22. Which reaction occurs spontaneously? A) B) C) D) Cl 2(g) + 2NaBr(aq) Br2( ) + 2NaCl(aq) Cl 2(g) + 2NaF(aq) F2(g) + 2NaCl(aq) I 2(s) + 2NaBr(aq) Br 2( ) + 2NaI(aq) I 2(s) + 2NaF(aq) F2(g) + 2NaI(aq) 23. During which process does an atom gain one or more electrons? A) transmutation C) oxidation B) reduction D) neutralization Version 1 28. Base your answer to the following question on the following redox reaction, which occurs spontaneously. Which species loses electrons and which species gains electrons? Base your answers to questions 29 and 30 on the information below. Metallic elements are obtained from their ores by reduction. Some metals, such as zinc, lead, iron, and copper, can be obtained by heating their oxides with carbon. More active metals, such as aluminum, magnesium, and sodium, can not be reduced by carbon. These metals can be obtained by the electrolysis of their molten (melted) ores. The diagram below represents an incomplete cell for the electrolysis of molten NaCl. The equation below represents the reaction that occurs when the completed cell operates. 29. Identify one metal from the passage that is more active than carbon and one metal from the passage that is less active than carbon. 30. Identify the component required for the electrolysis of molten NaCl that is missing from the cell diagram. Version 1 Base your answers to questions 31 through 33 on the information below. A student constructs an electrochemical cell during a laboratory investigation. When the switch is closed, electrons flow through the external circuit. The diagram and equation below represent this cell and the reaction that occurs. 31. Determine the number of moles of Al(s) needed to completely react with 9.0 moles of Ni 2+(aq) ions. 32. State, in terms of energy, why this cell is a voltaic cell. 33. Write a balanced half-reaction equation for the oxidation that occurs when the switch is closed. 34. Zinc metal reacts with hydrochloric acid to produce zinc chloride and hydrogen gas according to the reaction below: Zn(s) + HCl(aq) ZnCl2 + H2(g) a Explain why this reaction is classified as an oxidation-reduction reaction. b Which reactant is oxidized? Explain your answer. c What is the oxidation number of zinc in zinc chloride? Version 1 Base your answers to questions 35 and 36 on the information below. Underground iron pipes in contact with moist soil are likely to corrode. This corrosion can be prevented by applying the principles of electrochemistry. Connecting an iron pipe to a magnesium block with a wire creates an electrochemical cell. The magnesium block acts as the anode and the iron pipe acts as the cathode. A diagram of this system is shown below. 35. Explain, in terms of reactivity, why magnesium is preferred over zinc to protect underground iron pipes. Your response must include both magnesium and zinc. 36. State the direction of the flow of electrons between the electrodes in this cell. Version 1 Version 1 Chemistry[2015-2016 Redox Practice Test[4/27/2016]]- New York Total Questions: 36 3. Matter is made up of particles whose properties determine the observable characteristics of matter and its reactivity. (22) 3.2. Use atomic and molecular models to explain common chemical reactions. (22) 3.2.d. An oxidation-reduction (redox) reaction involves the transfer of electrons (e-). (4) 3.2.l. An electrolytic cell requires electrical energy to produce a chemical change. This process is known as electrolysis. (2) 3.2.i. Oxidation numbers (states) can be assigned to atoms and ions. Changes in oxidation numbers indicate that oxidation and reduction have occurred. (5) 3.2.j. An electrochemical cell can be either voltaic or electrolytic. In an electrochemical cell, oxidation occurs at the anode and reduction at the cathode. (3) 3.2.k. A voltaic cell spontaneously converts chemical energy to electrical energy. (5) 3.2.h. A half-reaction can be written to represent oxidation. (2) 3.2.e. Reduction is the gain of electrons. (1) Exam Question Summary 2015-2016 Redox Practice Test # QID# Ans Thinking Skills 1 5419 2 4/27/2016 Difficulty Standards B Intermediate 3.2.d. 1009 C Basic 3.2.l. 3 4290 A Unassigned 4 2456 B Intermediate 3.2.i. 5 7051 C Unassigned 3.2.d. 6 5527 C Intermediate 3.2.j. 7 894 C Intermediate 3.2.k. 8 4339 A Intermediate 3.2.i. 9 2382 A Basic 3.2.j. 10 6725 C Advanced 3.2.i. 11 7475 A Unassigned 12 4836 D Unassigned 3.2.i. 13 43 D Basic 3.2.k. 14 7563 A Unassigned 15 1921 A Intermediate 3.2.j. 16 5930 B Intermediate 3.2.d. 17 6290 A Basic 3.2.k. 18 6476 D Unassigned 3.2.i. 19 5842 C Intermediate 3.2.h. 20 5615 B Unassigned 3.2.h. 21 5273 B Unassigned 3.2.l. 22 6639 A Intermediate 3.2.k. 23 6537 B Intermediate 3.2.e. 24 6535 D Advanced 3.2.d. 25 276 B Basic 26 4453 A Basic 27 6044 n/a Unassigned 28 4931 n/a Intermediate 29 7437 n/a Unassigned Applying 3.2.k. Version 1 Exam Question Summary 2015-2016 Redox Practice Test # QID# Ans Thinking Skills Difficulty 30 7436 n/a Unassigned 31 7354 n/a Unassigned 32 7355 n/a Unassigned 33 7353 n/a Unassigned 34 4723 n/a Unassigned 35 6581 n/a Advanced 36 6580 n/a Advanced 4/27/2016 Standards Version 1 Answer Key 2015-2016 Redox Practice Test 1. B 30. –source of electrical energy –battery 2. C 3. A 31. 6.0 mol. 4. B 32. 5. C 6. C 7. C 8. A 9. A —A spontaneous reaction converts chemical energy to electrical energy. —A battery is not required to provide energy for the cell to operate. 10. C 33. 11. A 12. D —Al ® 3e – + Al 3+ — 2Al ® 2Al 3+ + 6e – 13. D 34. 14. A 15. A 16. B 17. A 18. D a) There is a transfer of electrons. or The oxidation states changed. b) The zinc is oxidized because it lost electrons. or The zinc because it went from a zero oxidation state to a +2. c) +2 19. C 35. 20. B 21. B 22. A 23. B 24. D 25. B Examples: – Magnesium atoms lose electrons more easily than zinc atoms. – Mg oxidizes more readily than Zn. – Mg is more active than Zn. 26. A 36. Examples: – Electrons flow from the magnesium block to the iron pipe. – Electrons flow from the Mg to the Fe through the wire. – Electrons flow from the anode to the cathode in a voltaic cell. – from the block to the pipe 27. Examples: –Cu –Ag –gold 28. Zn (not Zn2+ ) loses electrons and Cr3+ (not Cr) gains electrons. 29. –More active than carbon: aluminum, Mg, or Na –Less active than carbon: zinc, Pb, Fe, copper Version 1 Question ID's in Test Order 1. 5419 2. 1009 3. 4290 4. 2456 5. 7051 6. 5527 7. 894 8. 4339 9. 2382 10. 6725 11. 7475 12. 4836 13. 43 14. 7563 15. 1921 16. 5930 17. 6290 18. 6476 19. 5842 20. 5615 21. 5273 22. 6639 23. 6537 24. 6535 25. 276 26. 4453 27. 6044 28. 4931 29. 7437 30. 7436 31. 7354 32. 7355 33. 7353 34. 4723 35. 6581 36. 6580 Version 1