Study Guide – CHEM 1015 These are examples of skills you should have in preparing for exams! This list is not exclusive. Please note that exam questions may ask you to apply several of these skills within one question J Chapter 1 1. Describe the scientific method 2. Describe the subatomic particles that make up an atom 3. Sketch a picture of an atom, labeling the nucleus 4. Understand that opposite charges cancel one another 5. Identify an atom from its atomic number (using periodic table) 6. Determine the chemical symbol of an element given its name or atomic number 7. Identify the groups of the periodic table that contain halogens, alkali metals, alkaline earth metals, chalcogens, and noble gases 8. Recognize that elements in the same group have similar properties 9. Identify an element as a metal, nonmetal, or metalloid using a periodic table 10. Identify an element as a main-group or transition element 11. Define isotope 12. Determine whether two atoms are isotopes of one another, given the number of protons and neutrons present in each 13. Determine the isotope (nuclear) symbol for a given isotope of an element 14. Determine the number of protons, neutrons, and electrons in a given species 15. Calculate the atomic mass of an element given the abundance and masses of its isotopes 16. Identify the isotope of higher abundance given a periodic table and the masses of the element’s isotopes. Chapter 2 1. Sketch the Bohr model of the atom 2. Recognize the relationship between n levels and energy 3. Define “excited state” in terms of the Bohr model of the hydrogen atom 4. Understand that transitions in an atom give off light of specific wavelengths 5. Differentiate between absorption and emission of light by an atom 6. Define the term “atomic orbital” 7. Describe the shapes of the s, p, and d orbitals 8. Describe the number of orbitals present in each sublevel of an atom 9. Identify the maximum number of electrons that could be present in each sublevel 10. Identify legitimate combinations of level and sublevel (2s, 1p, 2d?) 11. Write the electron configuration for a given element 12. Draw the orbital diagram for a given element 13. Write the electron configuration for a given element, using a noble gas core 14. Identify the valence electrons present in a given atom or ion 15. Describe the atomic size trend of main-group elements 16. Arrange elements in order of increasing/decreasing atomic size 17. Arrange elements in order of increasing/decreasing ionization energy (ease of losing electron) 18. Describe the metallic character trend of elements 19. Arrange elements in order of increasing/decreasing metallic character 20. Write the electron configuration for a main-group ion 21. Predict the charge on the ion formed from a main-group element 22. Draw the Lewis dot structure for a main-group atom or ion 23. Define anion and cation Chapter 3 1. Describe the three states of matter and their properties 2. Differentiate between heterogeneous and homogeneous mixtures 3. Differentiate between chemical and physical properties 4. Determine the chemical formula for a binary ionic compound formed from two given elements 5. Deduce the charge on the metal ion given an ionic compound formula 6. Determine the name of an ionic compound given the chemical formula 7. Recognize the presence in an ionic compound of a metal that forms more than one ion 8. Determine the name of a binary molecular compound from its chemical formula 9. Determine the chemical formula of a binary molecular compound from its name 10. Determine whether a compound is ionic or molecular 11. Differentiate between ionic bonding and covalent bonding 12. Determine an empirical formula from a molecular formula 13. Determine a chemical formula given a molecular model 14. Write the name and chemical formula, including charge, of common polyatomic ions 15. Recognize simple acids 16. Determine the name for an acid 17. Determine the chemical formula of an acid given its name Chapter 4 1. Define base units in the SI system 2. Define metric prefixes and their abbreviations 3. Write the metric conversion factor between base unit and any other metric prefix 4. Convert between the three temperature scales 5. Write a very small or very large number in scientific notation 6. Determine the number of significant figures in a given value 7. Determine the number of significant figures to report in a measurement 8. Determine the number of significant figures in the answer to a calculation 9. Round a given value to a smaller number of digits 10. Recognize the 4 different ways of writing the same metric conversion factor 11. Convert between any base unit and metric prefix 12. Convert between two metric units, neither of which is a base unit 13. Convert between nonmetric base units given relationship 14. Recognize the physical relationship (sink/float/suspend) between two substances with different densities 15. Determine density from mass and volume 16. Convert between density, mass, and volume 17. Convert derived units into another set of units 18. Convert squared or cubed units into another set of squared or cubed units Chapter 5 1. Define the mole and Avogadro’s number 2. Convert between moles of element and number of atoms 3. Determine the molar mass of an element or compound 4. Convert between mass, moles, and atoms of an element 5. Convert between mass, moles, and molecules (or formula units) of a compound 6. Determine the number of atoms, mass, or moles of a specific element present in a given mass or number of moles of a compound 7. Determine conversion factors between moles of substances using a chemical formula 8. Determine the number of ions present in a given mass or number of moles of an ionic compound 9. Determine the mass or number of moles of an ionic compound present with a given number of ions 10. Determine the mass percent composition of a given compound 11. Determine an empirical formula given the mass percent composition of a compound 12. Determine a molecular formula, given an empirical formula and molar mass Chapter 6 1. Draw the Lewis structure of a diatomic molecule 2. Draw the Lewis structure of a simple molecule with a central atom 3. Draw the Lewis structure of a polyatomic ion 4. Draw a Lewis structure of a molecule that contains double or triple bonds 5. Recognize exceptions to the octet rule 6. Draw resonance structures when necessary 7. Determine electron geometry and molecular shape of a given compound 8. Define electronegativity 9. Arrange several elements in order of increasing/decreasing electronegativity 10. Determine whether a bond is polar or nonpolar 11. Determine whether a compound is polar or nonpolar 12. Arrange compounds in order of increasing/decreasing polarity 13. Determine bond angles in a compound 14. Arrange compounds in order of increasing/decreasing bond angle Chapters 6-7 (these topics are introduced in Chapter 6 and applied in Chapter 7) 15. Define dispersion, dipole-dipole, and hydrogen bonding forces 16. Sketch dispersion, dipole-dipole, and hydrogen bonding forces between two species 17. Determine the intermolecular forces present in a given compound 18. Arrange several substances in order of increasing/decreasing strength of intermolecular forces Chapter 7 1. Describe the differences between ionic, molecular, and atomic solids 2. Identify a substance as an ionic, molecular, or atomic solid 3. Describe the relationship between vapor pressure and intermolecular force strength 4. Describe the relationship between boiling point and intermolecular force strength 5. Describe the relationship between melting point and intermolecular force strength 6. Describe the relationship between viscosity and intermolecular force strength 7. Describe the relationship between surface tension and intermolecular force strength 8. Describe the relationship between substances with similar or different types of intermolecular forces 9. Arrange several substances in order of increasing/decreasing boiling point 10. Arrange several substances in order of increasing/decreasing melting point 11. Arrange several substances in order of increasing/decreasing vapor pressure 12. Arrange several substances in order of increasing/decreasing surface tension 13. Arrange several substances in order of increasing/decreasing viscosity 14. Write the chemical equation to describe a physical change: melting/freezing, vaporizing/condensing, and sublimation/deposition 15. Describe the states of matter present at the boiling point/freezing point/sublimation point 16. Draw a sketch to represent the physical change of an element or compound Chapter 8 1. Describe Kinetic Molecular Theory and its four assumptions 2. Describe the physical properties of the gaseous state 3. List the common elements that exist as gases at room temperature 4. Define pressure 5. Convert between pressure units of atmospheres, torr, mmHg, and psi (pounds per square inch) 6. State the ideal gas equation, including the value/units of the constant 7. Recognize the relationship between two variables in the ideal gas law, keeping the other two constant 8. Solve for a variable in the ideal gas equation, given the other three 9. State the combined gas equation 10. Solve for one variable in the combined gas equation, given the remainder 11. Recognize STP (standard temperature and pressure) and its definition 12. Solve for molar mass or gas density, using the ideal gas equation 13. State Dalton’s law of partial pressure 14. Determine the partial pressure of one gas in a mixture of gases given mole fraction and total pressure 15. Determine the partial pressure of one gas in a mixture of gases given mole fraction and the pressure(s) of other gases in the mixture 16. Determine the partial pressure of one gas in a mixture of gases given moles, temperature and volume 17. Draw a sketch before and after a change in the conditions of a gas sample Chapter 9 1. Define a solution, including solute and solvent 2. Describe solubility in an aqueous solution 3. Describe the differences between unsaturated, saturated, and supersaturated solutions 4. Draw a sketch to represent a saturated or supersaturated solution 5. Use the solubility chart to determine the solubility of an ionic compound in water 6. State the percent by mass concentration equation 7. Determine the concentration of a solution in percent by mass 8. Determine the mass of solute present, given a mass of solution and the concentration in percent by mass 9. State the molarity equation 10. Determine the concentration of a solution in molarity 11. Use molarity to either determine the volume of solution or moles of solute 12. Sketch two solutions with the same molarity, but different volumes 13. Determine the concentration of a stock solution from its volume and the volume and concentration of a diluted solution 14. Determine the volume of a stock solution from its concentration and the volume and concentration of a diluted solution 15. Determine the concentration of a diluted solution from its volume and the volume and concentration of a stock solution 16. Determine the volume of a diluted solution from its concentration and the volume and concentration of a stock solution 17. State the molality equation 18. Determine the concentration of a solution in molality 19. Use molality to determine mass of solution or moles of solute 20. Describe the difference between an electrolyte and nonelectrolyte 21. Sketch a solution composed of an ionic compound dissolved in water 22. Sketch a solution composed of a molecular compound (as a nonelectrolyte) dissolved in water 23. Determine the molarity of a particular ion in solution, given the mass or moles of ionic compound present 24. Determine the new molarity of a solution following dilution with water 25. Describe the impact on water’s freezing point, boiling point, or osmotic pressure after addition of a solute Chapter 10 1. Recognize when a chemical reaction has taken place 2. Select a sketch that represents a chemical reaction vs. a physical change 3. Write a chemical equation to represent a chemical reaction described in words 4. Balance a chemical equation 5. Understand the symbols used in a chemical equation and identify reactants and products 6. Use a solubility table to predict whether an ionic compound is aqueous or solid 7. Classify a reaction as a precipitation, acid-base, gas-evolution, or oxidationreduction (redox) reaction 8. Recognize combustion reactions 9. Predict the products of a precipitation, acid-base, or gas-evolution (producing) reaction 10. Predict whether or not a reaction will occur 11. Define neutralization reaction 12. Write a molecular, complete ionic, and net ionic equation for a precipitation reaction 13. Write a molecular, complete ionic, and net ionic equation for an acid-base reaction 14. Determine the oxidation number (state) of an element, alone, in a polyatomic ion, or in a compound 15. Determine the substance undergoing oxidation in a given redox reaction 16. Determine the substance undergoing reduction in a given redox reaction 17. Recognize a gas-evolution (gas-producing) reaction involves the quick decomposition of products H2SO3, NH4OH, H2CO3 18. Recognize that heat is a reactant or product in most reactions Chapter 11 1. Write mole to mole conversion factors from a balanced chemical equation 2. Use a balanced chemical equation to determine moles of a reactant needed, or product formed, from moles of one reactant or product 3. Use a balanced chemical equation to determine mass of a reactant needed, or product formed, from moles or mass of a reactant or product 4. Define limiting reactant 5. Determine the limiting reactant when given moles, mass, volume/concentration (solution), or pressure/volume/temperature (gas) of two reactants 6. Define theoretical and actual yield 7. Determine the amount of remaining excess reactant, given moles, mass, volume/concentration (solution), or pressure/volume/temperature (gas) of two reactants 8. Determine percent yield given actual yield 9. Determine a volume of acid (or base) needed to neutralize a given quantity of a base (or acid) 10. Determine the volume of a gas formed (or needed), given a chemical equation and the conditions of the gas 11. Use a balanced thermochemical equation that includes heat of reaction to determine the amount of heat energy needed (or given off) during a reaction 12. Use a balanced thermochemical equation to determine the moles or mass of a reactant or product when a given amount of heat is released (or absorbed) Chapter 12 1. Recognize Arrhenius acids and bases 2. Define Arrhenius acid, base and Bronsted acid, base 3. Define hydronium ion 4. Define conjugate acid-base pair 5. Identify a conjugate acid-base pair 6. Define the term amphoteric 7. Write a chemical equation to represent the autoionization of water 8. State the product of hydronium ion concentration and hydroxide ion concentration in water at 25°C 9. Given either hydronium or hydroxide ion concentration, determine the other 10. Identify the strong acids 11. Identify the strong bases 12. Describe the properties of a strong acid using a chemical equation 13. Calculate [OH–] or [H3O+] given the concentration of either a strong acid or strong base 14. State the pH equation – the relationship between pH and [H3O+] 15. Calculate pH given the concentration of either a strong acid or strong base 16. Determine [H3O+] from pH 17. Describe the difference between a strong acid and weak acid 18. Describe the difference between a strong base and weak base 19. Illustrate the behavior of a strong acid in water 20. Illustrate the behavior of a weak acid in water 21. Illustrate the behavior of a strong base in water 22. Illustrate the behavior of a weak base in water 23. Estimate the pH value of a weak acid or weak base solution 24. Define the terms titration and equivalence point 25. Calculate the concentration of an unknown acid or base, given titration data 26. Describe a buffer and how it works 27. Recognize solutions that exhibit buffer properties Chapter 16 1. Describe alpha, beta, and gamma radioactivity 2. 3. 4. 5. 6. 7. 8. 9. Differentiate between chemical and nuclear reactions Write nuclide symbols for atoms and subatomic particles Balance nuclear equations Write a balanced nuclear equation for a given radioactive process Describe the relationship between radioactive decay and ionizing power Describe the relationship between radioactive decay and penetrating power Arrange radioactive decay in order of increasing/decreasing ionizing power Arrange radioactive decay in order of increasing/decreasing penetrating power 10. Describe the process defined by half-life 11. Calculate the amount of product present after a given number of half-lives 12. Calculate the amount of starting material present after a given number of half-lives 13. Describe nuclear fission 14. Describe nuclear fusion