Chemistry Name _________________________ NB#3 Unit 11—Solutions Factors affecting solvation The Solvation Process _______________________ forces exist among the particles of all substances Examples: ___________________________________, ____________________________________, and ______________________________________________ If the attractive forces between the solute and the solvent are _____________________ than the attractive forces holding the solute particles together, the solute _______________________in the solvent _______________________is the process of surrounding solute particles with solvent particles to form a _______________________. Solvation in water is called _______________________ For ionic compounds that dissolve in water, the attraction between _______________________ (partially charged ends) of a water molecule and the _______________________ (charged particles) of a crystal are _______________________than the attraction among ions of a crystal. How do you know if a substance will dissolve? The general rule is “_________________dissolves _____________________.” Polar will dissolve _______________________ (or ionic) Nonpolar will dissolve _______________________ Is oil polar or nonpolar? Since it does not dissolve in water, and water is ___________________, oil is _____________________ Sucrose (sugar) molecules have several O–H bonds, which become sites for _____________________________with water molecules. That’s why sugar _______________________in water. During solvation, the solute must separate into particles and move apart, which requires _______________________ The overall energy change that occurs during solution formation is called the heat of _______________________. When energy is released, it is an _______________________process and feels _______________________. When energy is absorbed, it is an _______________________process and feels _______________________. Factors that affect rate of dissolving of solid in liquid 1. Agitation _______________________or _______________________moves dissolved particles away from the contact surfaces more quickly and allows new _______________________to occur. This is why you _______________________your tea after you put sugar in it. 2. Surface area Breaking the solute into small pieces increases ___________________________and allows more _______________________to occur. This is why you use _______________________sugar instead of sugar cubes 3. Temperature As temperature increases, rate of solvation _______________________. Particles are moving _______________________. This is why sugar dissolves _______________________in hot tea than in iced tea. Solubility Solubility depends on the nature of the _______________________and _______________________. Solubility is affected by increasing the temperature of the solvent because the _________________________________ of the particles increases. Solubility of solids in liquids Generally _______________________with an increase in temperature (some exceptions) Not affected by _______________________ Solubility of gases in liquids _______________________with an increase in pressure (Henry’s Law) This is how _______________________beverages are made and why they go ___________ if left open Scuba diving o As the diver goes deeper in the water, pressure _______________________, allowing ______________gases (N2) to dissolve in his blood o If the diver goes to the surface too quickly, the gases will un-dissolve in his _______________________________instead of his _______________________ o This results in the bends (decompression sickness, caisson’s disease. . .) How is the solubility of gases affected by temperature? Solubility of gases _______________________with an increase in temperature This is why soda at room temperature goes flat _______________________than soda in the refrigerator Thermal pollution What do fish breathe? If these cooling towers dump hot water into the lake, what happens to the temperature of the water? What happens to the O2 dissolved in the water? What happens to the fish? There are now regulations on how much the temperature of water can be affected by dumping hot water that was used for cooling Summary of factors that affect solubility: Solubility of solids in liquids Increase temperature Increase pressure p. 511 127-129, 86-88, 93, 94 Solubility of gases in liquids