Lesson 1: The states of matter Matter • Anything that has mass and takes up space. • There are three physical states: solid, liquid and gas. • Every pure substance has its own melting and boiling point. This is a distinguishing property for this substance. Sublimation • • A volatile liquid is one which evaporates easily and hs a relatively low boiling point. Ethanol (b.p. 78 C) is a more volatile liquid than water (b.p. 100 C). Lesson 2: Pure substances and purity Pure substances • • • • • A pure substance consists of only one substance. There is nothing else in it; it has no contaminating impurities. We can use melting and boiling points to test the purity of a substance. MP and BP can also be used to check the identity of an unknown substance. MP can be measured using and electrically heated melting point apparatus. The effect of impurities • • Seawater is impure water. It contains salt and other minerals. Seawater freezes well below the the freezing point of water (0 oC) and boils at a temperature above the boiling point of water (100 oC) The presence of an impurity in a substance: lowers the melting point raises the boiling point of the substance. • Why do you think salt is sprinkled to the roads in snowy days? Measuring melting point in laboratory A powdered solid is put in a narrow melting-point tube so that it can be heated easily. Heating curves • • • Naphthalene melts at precisely 80 C. Notice that, while the solid is melting, the temperature stops rising. Generally, the heating curve for a pure solid stops rising at its melting point. The heating curve of a wax, which is a mixture of substances, shows the solid wax melting over a range of temperatures. Heating curve of ice Cooling curves Important ❗️ When a pure solid is melted, or a pure liquid is boiled, the temperature stays constant until the process is complete. The same is true in reverse when a gas condense or a liquid freezes. Purity is very important in pharmacy. Lesson 3: Types of mixtures Mixtures Homogeneous Heterogeneous Solutions Suspensions Solid in liquid : Salty water Liquid in liquid : alcohol+water Gas in liquid : fizzy drinks Gas in gas : air Chalk + Water Sand + Water Emulsions Oil + Water Solutions • • • • • They seem as one phase. For example salty water looks like pure water. Solutions have two parts. Solute : the substance that is dissolved in another substance (minor part) Solvent : the substance that dissolves the other substance (major part) Solution : Solvent + solute Miscible and immiscible liquids • • Alcohol and water are miscible in each other. They can be dissolved in each other and they form a solution (homogeneous mixture). Oil and water are immiscible liquids. One can not dissolve the other. So they form an emulsion which heterogeneous. We can see two layers. Suspensions • • If a solid is not soluble in a liquid, the solid is dispersed as large lumps in the liquid. So a cloudy substance will form. You can see different phases. For example : chalk is not soluble in water. The large lumps are suspended in water. Fizzy drinks • Carbon dioxide is dissolved in water under high pressure. Lesson 4 Separating and purifying substances • The most useful separation method for a particular mixture depends on: The type of mixture, and Which substance in the mixture we are most interested in. • Separation depends on the physical differences of the substances in the mixture. Separating insoluble solids from liquids (suspension) • • If the particles of solid are large enough, we can use a process called decanting. Once the solid has settled to the bottom, the liquid can be carefully poured off. • A more generally useful method is for separating solids from liquids is filtration. Separating immiscible liquids (emulsions) • Mixtures of two immiscible liquids can be separated if the mixture is placed in a separating funnel and allowed to stand.