Hull Cell Brochure - A-Gas Electronic Materials

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1
For improvement of your plating quality
Hull Cell Test Kit
What can be identified through a“Hull Cell Test”?
In plating process, proper maintenance of bath is very important to keep the quality and to obtain demanded function of plated
film. However, the state of bath changes with the passage of time during actual plating process. Therefore, it is necessary to
maintain the state of bath by regularly test with various ways. The test for plating is mainly classified into two category. The first
category is quantitative test such as chemical analysis and physicochemical measurement such as pH, specific gravity and so on.
The second category is qualitative test with actual electrodeposition, such as Hull Cell test, Harling Test and so on. Among them,
Hull Cell Test, which allows to show the state of bath with only small amount of solution and short time, is very useful tool for
actual plating field. Particularly, by preparing standard plated sample in advance, Hull Cell test allows to predict the occurrence
bath troubles. You can check the “Wellness” of bath very easily by using Hull Cell test.
.
.
The current density distribution on a test-piece can be calculated using the following formula:
C.D = I (5.10 -5.24 logL)
C.D : Current Density (A/dm ) I : Total Current (A) L : Distance from the edge of high current side on cathode plate
2
( Please note that values measured are based on average current distribution and therefore, slight changes must be considered depending on the type of plating-bath. )
1
2
3
4
5
6
Range of optimal current density for the plating-bath
Range of burnt deposit for determining limiting current density
Covering power ( to what extent can current density be lowered to obtain satisfying plating fim )
Evaluation of plating-bath composition balance
Lack or excess of brightener and additives
Mixture and/or effect of impurities
7
8
9
Evaluation of levelling power by making polishing flaws on Hull Cell plates
Determination of alloy composition for alloy plating *1
Evaluation of dummy plating effect, etc. in eliminating impurities
10 Effects of activated carbon treatment and filtering treatment
11 Prediction of bath-trouble occurrence *2
12 Estimation of optimal timing for adding various chemical solutions *2
*1 : Current density dependence of alloy composition can be determined through combining Hull Cell test and other methods such as XRD.
*2 : Prediction can be made through periodic sample comparisons or by conducting repeated Hull Cell tests.
2
Test result example
Nickel Plating ( Watts bath )
Full-Scale ( 100mm×67mm )
The left side of the photo is the high current density area close to the anode and the right side is the low current density area. Example A , where it appears blackened, is9 the “burnt
deposit” area and because of the scorched plating film, it can not be applied to actual products.
Example B is the “dull-plating” area and tiny bubbles can be observed. In this case, the optimal current density condition would be the condition applied in Example C where
brightness has been obtained.
The full-scale picture shown right is the example in which the difference of
appearance in different current density is emphasized. In Hull Cell test, various
useful information such as, presence of inorganic impurity, balance of
compositions in solution, whether pH is appropriate or not, effect of additives
and so on are appears on one test-piece. Repeating Hull Cell test many times,
various know-how are accumulated, and you will be able to predict the
occurrence of trouble in advance and to find out the solution for it in a short time.
High
A
A Burnt deposit
B Dull plating
Low
Current Density
B
C
C Brightness
3
Usage Examples of Hull Cell Test Kit
Usage
Example
1
Test for the amount of brightener or
inorganic contamination in Ni plating.
Test conditions such as current with/without agitation and
so on, should be determined by “What you want to know.”
Usage
Example
2
Long Hull Cell whose length is twice of that of Standard
Hull Cell makes it much clear to show “Throwing power”
and “Deposition ratio for each current density”.
Sn-Ag Plating 2A, 5min with agitation ( Paddle )
Conditions should be changed
according to a purpose of test.
Test for the amount of
brightener and composition
balance of solution
Test for inorganic
contamination
( 3A, 5min, without agitation )
( 1A, 5min, with air agitation )
Test for deposition ratio in alloy plating
with “Long Hull cell”
Use with
standard Hull Cell
Use with Hull Cell (Long-Type)
40μm
Solution surface
Only tin is
deposited
Usage
Example
3
Reference
Reference
Excessive Brightener
contaminated with Zn
Saving of expensive solution for noble
metal plating with“Tenori Hull Cell”
Usage
Example
4
Test for agitation in alloy plating and
high speed plating
Patent-Registered
Smart Hull Cell
Test of Sn Plating and Alloy
plating with agitation using
“Smart Hull Cell”.
Smart cell is placed on the stirrer,and
rotate a stirring bar. Solution flows in the
direction of the arrow in this figure,
It will begin overflow circulation.
“Tenori Hull Cell” makes it possible to test with only 33mL
of solution. Required amount of solution is 1/8 of that in the
case using standard Hull Cell.
Tenori Size
Standard Size
4
Result of Pd-Co Plating Test
(Photo provided by
EEJA : Palladex PC-100)
High speed plating Hull Cell and
Agitation Effect Testing Kit
Test of high speed plating (max ~130A/
dm 2 , ~75m/min), using “High Speed
Plating Hull Cell” and “Agitation Effect Test
Equipment”.
Hull Cell Test Procedures ( Test Processes )
If it is not clear what to prepare for a Hull Cell test, first confirm the instruments and testing conditions required by referring to the general testing
samples listed below. Tests should be conducted by setting conditions to match the actual operation environment, taking into account the purpose
of testing. Please read the details of testing procedures thoroughly so as to be aware of precautions that must be followed during the testing
process. Since chemical solutions will be used in testing, careful attention should be paid in the handling and storage of such solutions.
[ Example of Testing Specification : Bright Nickel Bath ]
Testing to determine the effect of additives/bath-composition: Effect on composition itself can be observed by setting the following plating
specifications: 3A / 5-minutes / No agitation.
Testing to identify metal impurities: Metal impurities can be more easily identified in low current density areas by setting the following
plating specifications: 1A / 5-minutes / agitation.
Examples of Testing Specification by Plating Solution Type
Hull Cell
Anode
Cathode
( test-piece )
ThermostaticControl-Type
Oxygen-free
Copper
Iron
Copper Sulfate
Air-Agitation-Type
Diaphragm-Type
Phosphorous
Copper Iridiumplated Titanium
Copper
Pyrophosphate
ThermostaticControl-Type
Oxygen-free
Copper
Types of Plating Solution
Copper Cyanide
Copper
Nickel
Nickel
Chromium
( Watts-bath based )
Nickel
Sulfamate
HexavalentChromium
ThermostaticControl-Type
Chromium
Brass
SK Nickel
Copper
Lead with 5%
Tin Content
Time
( min. )
2~3
5~10
Brass
Electrolytic
Nickel
( Sulfur depolarized nickel )
Specification Examples
Total Current
(A)
Brass
Nickel Plated
Brass
2
5
1
5
2~3
5
5~10
1~3
1
Standard-Type
Zincate
Zinc
Iron
Zinc Chloride
Tin
Standard-Type
Tin
Silver Cyanide
ThermostaticControl-Type
Silver
Standard-Type
Noble
Metal
Rhodium
Alkaline Gold
Acid Gold
5
2
Tin Sulfate
Tenori
Platinum plated
Titanium
ThermostaticControl-Type
Carbon
Platinum plated
Titanium
Smart
Smart
Tenori
Iron
Nickel Plated
Brass
20~60
Air
40~60
*2
None
None/
20~30
Hull Cell
Cathode Rocker
Hull Cell
Cathode Rocker
0.5~1
5~10
20~30
5
40~60
1~3
50~65
3~5
20~50
*1
Air/ None
40~60
18~20
Platinum plated
Titanium
Hull Cell
Cathode Rocker
50~60
5
Remarks
Air/
20~30
1
1
Agitation
20~35
Zinc Cyanide
Zinc
Temp.
(℃)
Hull Cell
Cathode Rocker
*3
*4
*1 Metal impurities in bright nickel plating solution can be identified at the low-current density side ( Air-agitation is essential )
*2 Mixture of chloride ions can be determined by observing bare spots and the rear side,
*3 Hull cell test alone may not be sufficient to identify the brightness range or to determine existence of metal impurities. In such cases, another
method for identification is to wash the test-piece with water, dry it well, dip it ( to about 1/2 the length of the test-piece ) in 0.5% nitric acid and
then further conduct chromate treatment to 1/2 of the dipped part.
*4 Tenori : Tenori Hull Cell ( Small-sized )
Videos of Hull Cell Test are available.
QR Code is registered trademark of
DENSO WAVE INCORPORATED
in Japan and other countries.
You can see the videos of experiment and experimental results and so on.
Check this QR code or URL shown bellow.
http://www.yamamoto-ms.co.jp/en/movie/index.html
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Various Types of Hull Cell
13
14
11
12
9
8
5
10
7
6
1
2
3
4
According to purpose of use, there are various types of hull cell tanks, anode plates, cathode plates, etc.
Hull Cell Tanks
No. Product No.
Product Name
Features
For noble metal plating. It is eco-friendly since hull cell test can be performed with one eighths(⅛)of the tank’s volume(approx. 33mL).
Air-agitation is also possible.
1
B-54-HW
2
B-55-H
3
B-55-HG
4
B-55-G
Hull Cell (Standard-Type, Glass)
5
B-53W
Hull Cell (Thermostatic-Control-Type) Air-agitation and heating by use of heater.
6
B-54W
Hull Cell (Air-Agitation-Type)
Air-agitation is possible.
Hull Cell (Standard-Type)
Without air agitation and heating
Tenori Hull Cell (Air-Agitation-Type)
Tenori Hull Cell (Standard-Type)
Optimal for noble metal plating since hull cell test can be performed with one eighths (⅛)of standerd tank’s volume (approx.
)
(
)
Tenori Hull Cell (Standard-Type Glass) 33mL . Heating by use of thermostatic water bath warming in hot water is possible.
Same type as B-55, but made of glass. Heating by use of thermostatic bath (warming in hot water) is possible.
7
B-55
8
B-54-DW
9
B-55-L
10
B-55-LG
11
B-53-LW
By extending the length of cathode-side in Hull Cell in horizontal direction, more detailed observation with
Hull Cell (Thermostatic-Control/Long-Type) very wide current-density range become possible.
12
B-54-LW
Hull Cell (Air-Agitation/Long-Type)
13
B-56
Diaphragm-type Hull Cell (Air-Agitation-Type) Hull cell designed to reduce decomposition of additives caused by use of insoluble anodes.
Hull Cell (Standard/Long-Type)
Hull Cell (Standard/Glass Long-Type)
Hull Cell (Chromium)
14 B-53-SMW Smart Hull Cell
PAT.
For chromium plating. To prevent sharp rise in temperature, perforated hull cell is fixated inside a 1L rectangular-type tank. (Made of PVC).
In addition to heating by use of heater and air agitation, air agitation by overflow method can also be performed. Therefore, can be used for plating
for which air agitation can not be applied. Can also be used for composite plating.
Anode / Cathode Plates
Product No.
Anode Plates
Product No.
B-60-P01A
Sumitomo Electrolytic Nickel
B-59-P04
Zinc
B-60-P02
B-59-P06
Stainless-steel (SUS304)
B-60-P03
Brass
B-59-P07
Sumitomo SK Nickel ( Sulfur depolarized nickel )
B-60-P04
Aluminum (A1085P)
B-59-P08
Phosphorus Copper
B-60-P05
Copper
B-59-P10
Oxygen-free Copper
B-60-P06
Phosphor Bronze
B-59-P11
5% Tin-contained Lead
B-60-P07
Stainless-steel (SUS316) 50pcs. included
B-59-P12
High-Purity Tin
B-60-P01LA
Iron for Hull Cell Long Tank (67×200mm)
Iron
Stainless-steel (SUS304)
B-59-P15
Carbon
B-60-P03L
Brass for Hull Cell Long Tank (67×200mm)
B-59-P17
Silver
B-60-P05L
Copper for Hull Cell Long Tank (67×200mm)
B-59-P18
Titanium Platinum
B-61-E
B-61-L-E
6
Cathode Plates (100pcs. included)
B-59-P02
Hull Cell Scale
Hull Cell Scale (Long-Type)
B-61-E Hull Cell Scale
※ English Version is available & picture shown here is
Japanese Version.
※Please request for information of other products, as we
provide a wide range of products other than those listed.
Hull Cell Test Kit
B-52W-YTC300
Hull Cell Test Kit YTC300
Hull cell test is a simple and effective testing-method, by which electroplating
characteristics can be examined. Since plating-film of a wide range of cathode
current densities can be observed on a single test-piece, it is possible to conduct
studies of optimal plating conditions and effects from lack or excess of chemicals
( such as additives ) , existence of trace amount of impurity and deposition
distribution on alloy films.
※ Air pump is sold separately.
1
※
1
2
4
5
3
5
2
3
4
No. Product No.
Product Name
Unit No. Product No.
1 B-93-YTC300 Thermostat YTC300 (AC100-230V, 300W)
B-52-P03
2 B-53W
3 B-58W
B-52-P05
B-55
4 B-59-P02
4 B-59-P04
4 B-59-P07
1 unit.
Thermostat Stand (w/clamp)
1 pc.
Hull Cell (Thermostatic-Control-type Tank) MODEL 3w
Hull Cell Heater (DC48V,100W)
1 pc.
1 pc.
Hull Cell 10A Model-2 Lead Wire 2 pcs. (Length:1m /Anode-side clip made of titanium) 1 unit.
Hull Cell (Standard-type Tank) 250mL/267mL
1 pc.
Hull Cell Anode Plate Sumitomo Electrolytic Nickel (for Watts-Bath) 1 pc.
Hull Cell Anode Plate Zinc
1 pc.
Hull Cell Anode Plate Sumitomo SK Nickel (for Sulfamate Bath)
4
4
4
5
5
5
Product Name
Unit
B-59-P10
Hull Cell Anode Plate Phosphorous Copper (for Copper Sulfate Bath) 1 pc.
Hull Cell Anode Plate Oxygen-free Copper (Electrolytic Copper)
1 pc.
B-59-P12
1 pc.
B-59-P08
Hull Cell Anode Plate High-Purity Tin
B-60-P01A Hull Cell Cathode Plate Iron (film coating type ) /100 pcs.
Hull Cell Cathode Plate Brass /100 pcs.
B-60-P03
1 Box.
1 Box.
B-60-P05
Hull Cell Cathode Plate Copper /100 pcs.
1 Box.
B-61-E
Hull Cell Scale English Ver.
1 pc.
B-52-TIB-E Hull Cell Techical Information Book (English)
1 Vo.
1 pc.
B-52W-YTC300-G1
1
Use for tests not being able to apply air agitation, such as gold, silver and solder plating.
This new Paddle Cathode Rocker is more compact than our conventional product,
Hull Cell Cathode Rocker (B-69A). This Cathode Rocker Set can be apply for not
only Thermostatic-Control-type but also Air-Agitation-type and Standard-type.
※ This set cannot apply for Long-type and Chromium Hull Cell.
※ Air Pump is sold separately.
7
※
5
4
3
Hull Cell Test Kit YTC300
Paddle Cathode Rocker Set
1
2
3
4
5
6
2
6
No. Product No.
1 B-93-YTC300
2 B-53W
3 B-58W
B-55
4 B-59-P02
4 B-59-P04
4 B-59-P07
4 B-59-P08
4 B-59-P10
4 B-59-P12
Product Name
Thermostat YTC300 (AC100-230V, 300W)
Hull Cell (Thermostatic-Control-type Tank) MODEL 3w
Hull Cell Heater (DC48V,100W)
Hull Cell (Standard-type Tank) 250mL/267mL
Hull Cell Anode Plate Sumitomo Electrolytic Nickel (for Watts-Bath)
Unit No. Product No.
Product Name
1 unit. 5 B-60-P01A Hull Cell Cathode Plate Iron (film coating type ) /100 pcs.
1 pc. 5 B-60-P03 Hull Cell Cathode Plate Brass /100 pcs.
1 pc. 5 B-60-P05 Hull Cell Cathode Plate Copper /100 pcs.
1 pc.
B-61-E
Hull Cell Scale English Ver.
1 pc.
B-52-TIB-E Hull Cell Techical Information Book (English)
Hull Cell Anode Plate Zinc
1 pc. 6 B-75-P14A Speed Controler
Hull Cell Anode Plate Sumitomo SK Nickel (for Sulfamate Bath)
1 pc. 7 B-69SW
Hull Cell Paddle Cathode Rocker Set
Hull Cell Anode Plate Phosphorous Copper (for Copper Sulfate Bath) 1 pc.
B-69SW-P01 Hull Cell Paddle Cathode Rocker Lead Wire ( black : 2 wires, 1.5m, w / Titanium Clamp)
Hull Cell Anode Plate Oxygen-free Copper (Electrolytic Copper)
1 pc.
B-52-P05-4 10A Lead Wire w/Titanium Clip (Red)
Hull Cell Anode Plate High-Purity Tin
1 pc.
Unit
1 Box.
1 Box.
1 Box.
1 pc.
1 Vo.
1 unit.
1 unit.
1 pair.
1 pc.
7
Hull Cells
B-53W
Hull Cell (Thermostatic-Control-Type)
B-53-SMW
Hull cell designed to fit a heater into the
base part and to agitate with air.
Recommended for plating requiring both
heating and agitation.
Avoid use of hexavalent-chromium
plating solution.
Heater ( B-58W ) is sold separately.
Hull cell designed to let the solution
overflow and circulate, by use of a stirrer.
Recommended for composite plating
with powders, etc.
Stirrer ( W/Stand ) and heater are sold
separately.
( Avoid use of hot stirrer. )
specification
Material
Acryl
Outer (Installation) 117 ( D ) × 150 ( W )
× 95 ( H )
Dimensions
specification
Tank Volume
500mL
Material
Acryl
Outer (Installation) 160 ( D ) × 210 ( W )
× 95 ( H )
Dimensions
Heatproof Temp 65℃
Heatproof Temp 65℃
B-54W
Hull Cell (Air-Agitation-Type)
B-54-DW
Diaphragm-type Hull Cell (Air-Agitation-Type)
Hull cell designed to agitate with air.
Recommended for plating requiring air
agitation without heating.
Optimal for copper sulfate plating.
When using insoluble anodes such as
iridium oxide, the oxygen generated from
the anode causes additives to decompose
excessively. Diaphragm-type hull cell is
designed to greatly reduce the
decomposition of additives. Optimal for
copper sulfate plating and chromium plating.
specification
Tank Volume
250mL / 267mL
Material
Acryl
Outer (Installation) 101 ( D ) × 145 ( W )
× 80 ( H )
Dimensions
specification
Tank Volume
250mL / 267mL
Material
Acryl
Outer (Installation) 111 ( D ) × 143 ( W )
× 82 ( H )
Dimensions
Heatproof Temp 65℃
B-55
Heatproof Temp 65℃
B-55-G
Hull Cell (Standard-Type)
Hull Cell (Standard-Type Glass)
Classic type of hull cell. Recommended
for plating that does not require either
heating or agitation.
Mainly for plating of solder, tin, etc.
Hull cell for use with thermostatic tank.
Recommended for high-temperature
plating of 65℃ or over.
specification
Tank Volume
250mL / 267mL
Material
Acryl
Outer (Installation) 71 ( D ) × 128 ( W )
× 68 ( H )
Dimensions
specification
Tank Volume
250mL / 267mL
Material
Glass
Outer (Installation) 73 ( D ) × 134 ( W )
× 69 ( H )
Dimensions
Heatproof Temp 65℃
B-53-LW
Hull Cell (Thermostatic-Control / Long-Type)
Heatproof Temp 450℃
B-54-LW
Hull Cell (Air-Agitation / Long-Type)
Hull cell with longer cathode plates than standard
hull cells, making it easier to observe the lowcurrent-density areas.Optimal for barrel plating
and alloy plating. The length of the cathode is
twice that of the standard-type ( 200mm ) .
Designed to fit a heater into the base part and to
agitate air. Heater ( B-58W ) is sold separately.
Hull cell with longer cathode plates than
standard hull cells, making it easier to
observe the low-current-density areas.
Optimal for barrel plating and alloy plating.
The length of the cathode is twice that of
the standard-type ( 200mm ).Air agitation
function is available.
specification
Tank Volume
510mL
Material
Acryl
Outer (Installation) 115 ( D ) × 300 ( W )
× 95 ( H )
Dimensions
Heatproof Temp 65℃
specification
Tank Volume
430mL
Material
Acryl
Outer (Installation) 115 ( D ) × 300 ( W )
× 80 ( H )
Dimensions
Heatproof Temp 65℃
B-55-LG
Hull Cell (Standard-Type, Glass Long-Type)
B-55-L
Hull Cell (Standard / Long-Type)
Long-type hull cell for use with
thermostatic tank for high-temperature
plating of 65℃ or over.
Hull cell with longer cathode plates than
standard hull cells, making it easier to
observe the low-current-density areas.
Optimal for barrel plating and alloy plating.
The length of the cathode is twice that of
the standard-type ( 200mm ). Air agitation
function is not available.
specification
Tank Volume
430mL
Material
Glass
Outer (Installation) 73 ( D ) × 247 ( W )
× 69 ( H )
Dimensions
specification
Tank Volume
430mL
Material
Acryl
Outer (Installation) 75 ( D ) × 250 ( W )
× 70 ( H )
Dimensions
Heatproof Temp 450℃
8
Patent-Registered
Smart Hull Cell (500mL)
Heatproof Temp 65℃
Hull Cells
B-55-H
B-54-HW
Tenori Hull Cell ( Standard-Type )
Tenori Hull Cell ( Air-Agitation-Type )
Hull cell designed to conduct hull cell
test with 1/8 fluid volume compared to
standard types.
Hull cell designed to conduct hull cell
test with 1/8 fluid volume compared to
standard types. Optimal for noble metal
plating. Air agitation function is available.
specification
Tank Volume
33mL
Material
Acryl
Outer (Installation) 47 ( D ) × 78 ( W )
× 45 ( H )
Dimensions
specification
Tank Volume
33mL
Material
Acryl
Outer (Installation) 65 ( D ) × 83 ( W )
× 73 ( H )
Dimensions
Heatproof Temp 65℃
B-55-HG
Tenori Hull Cell ( Standard-Type Glass )
Heatproof Temp 65℃
B-56
Hull Cell ( Chromium-use ) 1L
Hull cell designed to conduct hull cell
test with 1/8 fluid volume compared to
standard types.
Hull cell for using with thermostatic tank.
Recommended for high-temperature
plating of 65℃ or over.
Hull cell dedicated for chromium plating,
during which the temperature rises
rapidly.
A perforated hull cell is placed inside a
1L square tank.
specification
Tank Volume
33mL
Material
Glass
Outer (Installation) 37 ( D ) × 68 ( W )
× 35 ( H )
Dimensions
specification
Tank Volume
1000mL
Material
Heat-resistant PVC
Outer (Installation) 140 ( D ) × 180 ( W )
× 110 ( H )
Dimensions
Heatproof Temp 80℃
Heatproof Temp 450℃
B-61-E
B-61-L-E
Hull Cell Current-Density Scale ( Long-Type )
Hull Cell Current-Density Scale
Current-density can be easily read by
just placing the scale against hull cell
cathode plate, eliminating the need for
cumbersome calculations.
( The product shown in this photo is
Japanese version )
Material
Current-density can be easily read by
just placing the scale against the long
hull cell cathode plate, eliminating the
need for cumbersome calculations.
( The product shown in this photo is
Japanese version )
specification
Acryl
Material
specification
Acryl
B-52-TIB-E
HULL CELL TECHNICAL INFORMATION BOOK
Hull cell test has been used as a powerful tool for on-site test in the field of electroplating. In order to further utilize Hull
Cell test, we recommend to refer to our “HULL CELL TECHNICAL INFORMATION BOOK”. This booklet is filled with a
lot of useful information, not only basic instruction, but also easy-to-understand electrochemical concepts, examples of
actual test results with full-color photographs etc.
Content
1 About the Hull Cell Test 2 Hull Cell Test Procedures (Test Processes) 3 Saving and Controlling Methods
4 Monitoring of Hull Cell Test Results 5 Test Panel Evaluation Examples ( Experiment Conditions of Various Evaluation Examples )
Nickel Plating Bath
Copper Plating Bath
Zinc Plating Bath
Tin Plating Bath
Hexavalent-Chromium Plating Bath
Trivalent Chromium Plating Bath
6
Hull Cell Test Troubleshooting
7
Specialized Hull Cells
8
Related Topics
9
Plating Test Kits
A-45W
Patent-Registered
High Speed Plating Hull Cell Testing Kit
New-type of Hull Cell Test Kit for high-speed plating, enabling hull cell data to be obtained for
various agitation speeds.
The High Speed Plating Hull Cell and Agitation Effect Testing Equipment assembly can be used for
almost all kits, with some exceptions, and can also be applied for control of regular plating
solutions.
7
.Plating is performed by rotating test-pieces (Φ8 [mm]×100 [mm] rod-type) by motor.
.Distribution of current density can be easily obtained by calculation using a formula.
.The state of deposited film (bright, burnt, or dull) can be judged from exterior appearance.
.Optimal anode position for a hoop line can be examined through administering control of
6
agitation speed, electrical quantity and electricity power-up speed.
5
.Also applicable for control of plating solutions in barrel plating and regular plating.
.Rotating unit can be selected from two motor-types: 3000rpm and 300rpm.
※ Several test-piece types are available such as brass, copper or iron. Prices of anode-plates
differ by type.
8
1
specification
4
3
2
Tank Volume
5L
Outer (Installation) Dimensions
420 ( D ) × 460 ( W ) × 1010 ( H )mm
Main Unit Weight
20kg
Rotator Capacity
70W
No. Product No.
1
2
4
5
High Speed Hull Cell Main Tank MODEL Ⅰ (incl. jigs)
2
A-45-P02W
High Speed Hull Cell, Agitation Effect Testing Kit 5L Outer-Tank
1 unit.
used for both HC/Agitation units MODEL Ⅰw
A-45-P05W
High Speed Hull Cell, Agitation Effect Testing Kit Standard Cathode
1 set
Connection Jigs
A-45-P07
High Speed Hull Cell Cathode Fixation Bar (w/Teflon Coating)
1 pc.
A-45-P08
High Speed Hull Cell, Agitation Effect Testing Kit Lead Wires
1 pc.
3
A-45-P11
Various Anode Plate Types for High Speed Hull Cell
1 pc.
4
A-45-P12
High Speed Hull Cell Cathode Test Bar incl. 50 bars
1 Box
5
B-93-YTC300 Thermostat YTC300 (AC100-230V, 300W)
1 unit.
B-50-KTSG121513 Stainless-steel G-type Clasp (Width: 12mm×15 ,φ13)
2 pcs.
6
B-83W2
7 8 Agitator (IKA) ,Stand (IKA) , stirrer (IKA) is not included.
7 8
Principle of Hull Cell Test for High Speed Plating ( HCHS )
Hull Cell Test kit for High Speed plating (HCHS) is specially developed for the test of high speed plating, by
Yamamoto-MS. In HCHS, as a cathode, rotational rod is used, instead of cathode plate in normal Hull cell. The
structure of HCHS resembles a standard Hull Cell turned sideways in vertical position. This structure allowed to
obtain very wide-range of current density distribution simultaneously on one cathode rod, that is, high current
density is obtained at the region close to anode and low current density is obtained at the region far from anode.
In HCHS, by rotating cathode rod with motor, high speed agitation, which is required in high speed plating, is
achieved. For example, with test piece of 8mm diameter, if the test piece (cathode rod) is rotated at 40rpm, agitation
speed on cathode surface become 1m/min. In the range of 10 ~ 3000 rpm, current density distribution on cathode
rod is independent to rotational speed, and given by the formula shown below.
[ Basic cathode current density distribution formula ]
Dk = I ( a - b log x ) ................................. Formula (1)
Dk: cathode current density ( A/dm2 )
I : total current ( A )
a,b : constant determined by plating solution type and cathode
current efficiency
x : distance from tip of test-piece ( cm )
( provided, 1cm x 9cm )
[
Cathode current density distribution formula for
nickel plating solution in HCHS
10
Dk = I ( 5.35 - 2.39 log x ) ...................... Formula (2)
]
1 unit.
300W Quartz Small Drop-in Heater ( Diam. φ15×310mm, Heater
2 pcs.
Section 150mm)
B-50-KTSG122016 Stainless-steel G-type Clasp (Width: 12mm×20 ,φ16)
Unit
A-45-P01
3
6
Product Name
1
Example of Test Result
( according to the difference of agitation speed )
Example of current distribution
on cathode in HCHS
2 pcs.
Plating Test Kits
A-46W
Agitation Effect Testing kit
Patent-Registered
New testing method for high speed plating. The effect of agitation speed can be measured while
applying constant current-density on a single test piece. The kit's High Speed Plating Hull Cell and
Agitation Effect Testing Equipment can be used for almost all kits, with some exceptions, and can
also be applied for control of regular plating solutions.
7
.Plating is performed by rotating test-piece (Φ64 [mm]×t0.3 [mm] disk-type) by motor.
.Uniform current density distribution can be obtained by use of a shied-plate (accessory). Film
with uniform current density, but varied agitation speed, can be obtained on a single test-piece.
6
5
.Agitation speed (peripheral speed) proportional to the diameter is generated over the test-piece.
.Also applicable for control of plating solutions in barrel plating and regular plating.
.Also applicable for basic experiments of precision plating, such as plating on to silicon wafers.
.Agitation Effect Testing kit can be selected from two motor-types: 3000rpm and 300rpm.
※ Several test-piece types are available such as brass, copper or iron. Prices of anode plates
differ by type.
8
specification
4
3
2
1
Tank Volume
5L
Outer (Installation) Dimensions
420 ( L ) × 460 ( W ) × 1010 ( H )mm
Main Unit Weight
20kg
Rotator Capacity
70W
No. Product No.
1
1
2
3
5
6
4
5
6
2
3
4
Product Name
Unit
A-45-P02W
High Speed Hull Cell, Agitation Effect Testing Kit 5L Outer-Tank used
1 unit.
for both HC/Agitation units MODEL Ⅰw
A-45-P05W
High Speed Hull Cell, Agitation Effect Testing Kit Standard Cathode
1 set
Connection Jigs
A-45-P08
High Speed Hull Cell, Agitation Effect Testing Kit Lead Wires
1 pc.
B-93-YTC300 Thermostat YTC300 (AC100-230V, 300W)
1 unit.
B-50-KTSG121513 Stainless-steel G-type Clasp (Width: 12mm×15 ,φ13)
1 pc.
B-83W2
300W Quartz Small Drop-in Heater ( Diam. φ15×310mm, Heater
2 pcs.
Section 150mm)
B-50-KTSG122016 Stainless-steel G-type Clasp (Width: 12mm×20 ,φ16)
2 pcs.
A-46-P01
Agitation Effect Testing Kit Jig
1 pair.
A-46-P07
Agitation Effect Testing Kit Cathode Fixation Bar (w/Teflon Coating)
1 pc.
A-46-P11
Various Anode Plate Types for Agitation Effect Testing Kit
1 pc.
A-46-P12
Agitation Effect Testing Kit Cathode Plate incl. 50 pcs.
1 Box.
7 8 Agitator (IKA) ,Stand (IKA) , stirrer (IKA) is not included.
7 8
Principle of Agitation Effect Test for High Speed Plating ( AEHS )
Agitation Effect Testing kit for High Speed plating (AEHS kit) is the equipment applying Hull Cell Test for
High Speed Plating, HCHS. HCHS is the method to observe the difference of plated result according to
current density with same agitation speed (rotational speed). On the other hand, AEHS is the method to
observe the plated result according to agitation speed with same current density. In AEHS, low agitating
speed and high agitating speed are achieved at the same time, on one rotating cathode disc, though
current density is almost same. By the effect of shield plate, almost uniform current density is achieved in
the region of r = 0.5 ~ 2.5 cm, r is the distance from rotational axis. The diameter is test-pieces is 64 mm,
the effective area for plating is 0.31 dm2, respectively. The rear side (rear of plating surface) of test-piece
is coated by green insulating film.
Comparison of the results of
HCHS and AEHS
[ Basic cathode current density distribution formula ]
Agitation Speed
Dk = a . I ................................. Formula (3)
100rpm
400rpm
1600rpm
2400rpm
Dk : cathode current density ( A/dm )
2
I : total current ( A )
60A / dm2
a : constant determined by plating solution type and
cathode current efficiency
valid in the region of r = 0.5 ~ 2.5 cm.
( r is distance from the rotational axis. )
120A / dm2
[ Current density distribution in Ni plating solution ]
Dk = 2.11 × I ........................... Formula (2)
Structure of AETHS
Example of Results in AEHS
11
Anode
B-59
Hull Cell Anode Plates
A wide variety of materials are available for anode
plates (i.e., phosphorous copper, oxygen-free
copper (electrolytic copper), nickel, SK nickel
(Sulfur depolarized nickel ), lead, zinc, tin, iron,
solder, brass, carbon, stainless-steel, platinum
plated titanium, silver, iridium-plated titanium )
enabling the user to select the anode appropriate
for the purpose of the Hull Cell test.
In most situations, anode bags are not necessary
for Hull Cell tests conducted within a short length
of time. If the need for an anode bag arises, there
is an effective method of covering the anode with
“filter paper.” ( Refer to lower figure ).
Filter
Paper
[ Thickness : 2mm ]
Various Anode Plate Types for Hull Cell ( 64 × 64 × t 2mm )
Product No.
Product
Unit
Product No.
Product
B-59-P02
Hull Cell Anode Plate Sumitomo Electrolytic Nickel ( for Watts-Bath )
B-59-P13-4 Hull Cell Anode Plate Solder 9 : 1
B-59-P03
Hull Cell Anode Plate Pure Lead
B-59-P13-5 Hull Cell Anode Plate Solder 95 : 5
B-59-P04
Hull Cell Anode Plate Zinc
B-59-P14
Hull Cell Anode Plate 5% Silver-contained Lead ( for Chromium Bath )
B-59-P05-1 Hull Cell Anode Plate Brass 6 : 4
B-59-P15
Hull Cell Anode Plate Carbon ( t 3 )
B-59-P05-2 Hull Cell Anode Plate Brass 7 : 3
B-59-P16
Hull Cell Anode Plate Cadmium
B-59-P17
Hull Cell Anode Plate Silver ( t 2 )
B-59-P06
Hull Cell Anode Plate Stainless-steel ( SUS304 )
B-59-P06-2 Hull Cell Anode Plate Stainless-steel ( SUS316 )
B-59-P07
Hull Cell Anode Plate Sumitomo SK Nickel ( for Sulfamate Bath )
( There are Variations in Thickness )
B-59-P08
B-59-P17-1 Hull Cell Anode Plate Silver ( t 1 )
B-59-P18
Hull Cell Anode Plate Platinum-plated Titanium ( for acidic noble metal Bath ) 1 pc.
Hull Cell Anode Plate Phosphorous Copper ( for Copper Sulfate Bath )
B-59-P19
Hull Cell Anode Plate Cobalt
B-59-P10
Hull Cell Anode Plate Oxygen-free Copper ( Electrolytic Copper )
B-59-P20
Hull Cell Anode Plate 5% Antimony-contained Lead
B-59-P11
Hull Cell Anode Plate 5% Tin-contained Lead ( for Hexavalent Chromium Bath )
B-59-P23
Hull Cell Anode Plate Pure Iron
B-59-P12
Hull Cell Anode Plate High-Purity Tin
B-59-P24
Hull Cell Anode Plate Titanium
B-59-P13-1 Hull Cell Anode Plate Solder 6 : 4
B-59-P25
Hull Cell Anode Plate 5% Antimony-contained Lead
B-59-P13-2 Hull Cell Anode Plate Solder 7 : 3
B-59-P28
Hull Cell Anode Plate Iridium-plated Titanium
B-59-P13-3 Hull Cell Anode Plate Solder 8 : 2
B-59-P18H Tenori Hull Cell Anode Plate Platinum-plated Titanium ( 31 × 31 × t 2mm )
1 pc.
Our Uncompromising Stance on
the Production of Anode Plates
Since more dissolving occurs on the high-current density
side than the low-current density side, gradual anode
thickness variation will occur during use. Although at first
minor, continued use will cause changes in the original
anode-cathode distance and the thicker the anode plate,
the more obvious such difference will become. If this
situation continues, depending on the solution-type used,
the proper anode-cathode distance required for hull cell
tests may not be reproduced and reliable experiments
will not be possible ( thus leading to different results
between manufacturing sites involved ). For this reason,
at Yamamoto-MS, time and effort are devoted in the
producing of thinly rolled anode plates, so as to keep
differences occurring in anode-cathode distances to an
absolute minimum.
12
Unit
At high current density
region, result is
strongly influenced.
Cathode
Test pieces polished to have glossiness
for both sides
We are the only maker providing Test
pieces applied glossy finishing for both
sides in the world.
※ As of February, 2015.
B-60
Hull Cell Cathode Plates
A variety of cathode plates such as iron, copper, brass and stainless-steel ( SUS304 . SUS316 )
is available. Depending on the purpose of the test, undercoating may be necessary.
For example, in chromium plating tests, nickel plating is sometimes applied as undercoating.
The exterior appearance of the plating film is greatly affected by the degree of polishing of the material
surface. A steady and reliable evaluation cannot be made if the surface of the material is not of uniform
smoothness. Yamamoto-MS’s cathode plates are finished to a bright surface, without performing buff
polishing, due to concerns regarding finishing patches that occur by each lot and to prevent warping.
Instead of buff polishing, special double-sided polish finish is achieved by an automatic machine, resulting
in an extremely uniform surface and brightness on both sides, while controlling patches that result from
different lots. Production and quality management are being administered by drawing fully upon our
originality and ingenuity born from our experiences of the past several ten years, along with the cooperation
of copper elongation manufacturers, who provide us with raw materials. Other factors which also contribute
to making our products special are adoption of custom-maid easy-to-peel protective sheets that maintain
an appropriate degree of viscosity, metal die and leveller technologies and storage methods.
Our products
Competitors' products
Influence of buff
polishing mark
[ Standard goods ]
The case hairline by polishing process of
plate appeared
[ Low-priced goods ]
Various Cathode Plates for Hull Cell
Product No.
Product ( Standard goods 67 × 100 × t0.3mm / 100pcs )
Unit Product No.
Product ( 67 × 200 × t 0.3mm / 100pcs )
B-60-P01A Hull Cell Cathode Plate Iron ( film coating type )
B-60-P01LA Long Hull Cell Cathode Plate Iron ( film coating type )
B-60-P02
Hull Cell Cathode Plate Stainless-steel ( SUS304 )
B-60-P03L Long Hull Cell Cathode Plate Brass
B-60-P03
Hull Cell Cathode Plate Brass
B-60-P05L Long Hull Cell Cathode Plate Copper
B-60-P04
Hull Cell Cathode Plate Aluminum ( A1085P )
Product No.
Product ( 34 × 50 × t 0.3mm / 100pcs )
B-60-P05
Hull Cell Cathode Plate Copper
B-60-P01H Tenori Hull Cell Cathode Plate Iron
1 Box
B-60-P06
Hull Cell Cathode Plate Phosphor Bronze
B-60-P03H Tenori Hull Cell Cathode Plate Brass
B-60-P07
Hull Cell Cathode Plate Stainless-steel ( SUS316 ) / 50pcs. ( t0.5mm )
B-60-P05H Tenori Hull Cell Cathode Plate Copper
Product No.
Product ( Low-priced goods 75 × 100 × t0.3mm / 100pcs )
B-60-P03W Hull Cell Cathode Plate ( Low-priced goods ) Brass
B-60-P05W Hull Cell Cathode Plate ( Low-priced goods ) Copper
Superiority of our Cathode Plates
Unit
1 Box
Warping or burring is rarely found in Yamamoto-MS’s cathode plates.Accurate evaluation is possible since
there is close-to-zero warping of the plate or around the edges. ( Warped cathode plates cause changes in the
distribution of the electric current; this leads to inaccurate evaluation.)
Comparison of the Warp
Warp of cathode
plate interferes
correct evaluation.
( L: Yamamoto’s, R: Competitor )
Clip
Clip
Clip
Clip
Warp at
edge
( a ) Flat Plate ( Yamamoto’s )
Disturbance in current distribution due to warping of
cathode/anode plates.
Warping of the edge-parts will cause electric current to flow around to the rear side.
( b ) Warping Plate
Slight changes can be detected in testing with certainty only
when the quality of the tank and the cathode/anode plates
are stabilized.
In order to implement thorough quality management, frequent checking of both the front and the rear sides of the cathode
plates is necessary to evaluate macro-throwing power and impure substances inside the bath. However, observations
which involve delicate evaluation cannot be made unless brightness of both the rear and the front sides is stabilized.
Our Uncompromising Stance on Production of Cathode Plates
Features of YAMAMOTO-MS Hull Cell Test-pieces
with products of other companies
( [Compared
Reseached by Yamamoto-MS: March 2015 ] )
The greatest feature of Yamamoto-MS test-pieces is that the cathode plate surface condition is consistent on both sides and that there is no warping (excluding our low-priced version)
or adhesives remaining on the test-pieces. These are the features that differentiate Yamamoto-MS products with those of other companies. At Yamamoto-MS, we pride ourselves in the
severe quality management that we have been practicing for over several decades.
1 No variations observed in plating-surfaces
our regular
test-pieces,
test-piece
2 No warping
Bright
surfaced
rear side( in
(bright
finish
on bothexcludes
sides) low-priced pieces )
Varied surface conditions affect evaluations of detailed and precise test results.
Yamamoto-MS hull cell cathode plates, after the final machine process, are polished to a smooth,
hairline finish on both sides of the test-piece. By implementing thorough process management, both
the plating and the rear sides are completed to uniform surface roughness, with hardly any differences
observed in individual pieces or lots. On the other hand, cathode plates of other companies are finished
with buff polishing and although the plating-surfaces may seem flat and smooth, buff-finish patches and
individual and lot differences of the surface can be frequently observed. Yamamoto-MS places utmost
importance on the maintaining of a consistent surface condition and due care is given in this area.
※ In Japan, many domestic plating specialists administer plating control based on detailed and precise
test results and even the slightest change in the surface condition will not be accepted.
With warped
it iscell
difficult
toplates
accurately
because
Although
the rear test-pieces,
sides of our hull
cathode
are notadminister
covered by solution
adhesive control
protective
sheets,
minor
occur
currentfinish,
distribution
eachobservation
time according
the degree of
they aredifferences
also completed
to a in
consistent
thus enabling
of minortoelectrodeposition
warping.
on the rear sides. We recommend our users to compare this feature with cathode plates of other
Consistent
anode-cathode
distances
some solutions,
such as
companies.
Evaluation
of plating film
around toare
thecrucial
rear sidein(covering
power, bimetallic
ioncopper
effects)
sulfate
plating
solution.
is greatly
influenced
by the state of rear-side finish and therefore, this evaluation method can be
At Yamamoto-MS,
test-pieces
are rejected during inspection if even the slightest warping
considered
as an important
know-how.
is found. We ensure zero-warping for all our products (excluding our low-priced version, for
which inspection process is omitted). On the other hand, warping is observed in cathode
plates of other companies by each lot and the degree of warping also differs by lots.
3 No glue residue
( brightfinish
finish on
sides
)
4 Bright
Bright
surfaced
surfaced
rear
rear
side
side
(bright
onboth
both
sides)
In Yamamoto-MS, to protect the plating-surface, special adhesive sheets are used. With these
adhesive sheets, no residue remains on the plating-surface since glue is not used. Use of
protective sheets applying glue will result in glue-residue remaining on the surface, which will
frequently affect the test results.
Althoughthe
Although
therear
rearsides
sides
of of
ourour
hullhull
cellcell
cathode
cathode
plates
plates
are not
arecovered
not covered
by adhesive
by adhesive
protective
protective
sheets,
they are also
sheets,
they completed
are also completed
to a consistent
to afinish,
consistent
thus enabling
finish, thus
observation
enabling
of minor
observation
electrodeposition
of minor
on the rear sides. Weonrecommend
electrodeposition
the rear sides.
our users
We to
recommend
compare this
our
feature
userswith
to cathode
compareplates
this of
feature
other
companies.
with
cathode
Evaluation
plates of
of other
platingcompanies.
film around to
Evaluation
the rear side
of plating
(coveringfilm
power,
around
bimetallic
to theion
rear
effects)
side
is greatly influenced
(covering
power, bimetallic
by the state
ion of
effects)
rear-side
is greatly
finish and
influenced
therefore,
bythis
theevaluation
state of rear-side
method can
finish
be
considered
and
therefore,
as anthis
important
evaluation
know-how.
method can be considered as an important know-how.
13
Thermostat / Heater
B-93-YTC300
Thermostat
B-93-YTC1KL
Specially designed thermostat that fulfills international standards. Current supplied to heaters are monitored
all the time, and if abnormal current is detected, output is shut off immediately.
All of dedicated heaters equip with thermal fuses, and in case of dry-boiling, thermal fuses blow.
Model
specification
YTC-300
Rating
Rating Output
Setting Range
Outer (Installation) Dimensions
Main Unit Weight
Fuse
Transient Overvoltage
AC 100-230V±10%, 50/60Hz, 524VA
DC48V, 300W ( 25-100W, 1-3pcs. or 300W,1pcs. )
0-100℃, Resolution 0.1℃
160mm ( W ) × 200mm ( D ) × 230mm ( H )
160mm ( W ) × 350mm ( D ) × 230mm ( H )
5.4kg
Material
2
IEC60101-1
EN61326-1 ( IEC61326-1 )
EMC
Thermostat
Cabinet : SPCC / Ni-Plated, Aluminium
Temperature Sensor
Heater
Temperature Sensor
Liquid Level Sensor
Accessories
AC 250V, 16A ( Time lag-type ) / AC 250V, 16A ( Quick cutoff )
Overvoltage CategoryⅡ
Safety
Liquid Level Sensor
3.7kg
AC 250V, 5A, φ5 × 20mm HT ( Time lag-type, High breaking capacity )
Pollution Degree
Standards
YTC-1KL
AC 100-240V±10%, 50/60Hz, 1KVA
AC 100-240V,1KW ( 500W, 2pcs. or 1KW,1pcs. )
Liquid-wetted Member : PTFE
Liquid-wetted Member : PP,PTFE
DC48V, 25-300W, Exclusive Heater with Thermal Fuse
AC100-230V, 50-1000W
Pt100
Float Type ( Sepalately sold )
Temperature Sensor 1 pcs, AC cable with plug ( AC250V, 5A, C Type )
Temperature Sensor 1 pcs, AC cable with plug ( AC250V, 10A, C Type )
B-58W
Hull Cell Heater DC48V, 100W
Themal Fuse
Thermal fuse equipped near heater
element detects dry-boiling, and if it
occurs, thermal fuse blows within
1 minute.
※ For safety, non-self-reset type
thermal fuse is used.
Product
Hull Cell Heater
14
Product No.
B-58W
Rating
AC / DC 48V,100W
Specifications
Total Length : 163mm,
Tube Diameter : 11mm,
Heater Section : 85mm
Maximum
Temperature
MAX 70℃
Specially designed structure
provides good waterproof and hardly
damaged. Heater is tightly fixed to
tank with two screws. Therefore, the
accident due to coming off of heater
dos not occurs.
Tank
Product No.
Product
B-53W
Hull Cell ( Thermostatic-Control-Type )
B-53-SMW
Smart Hull Cell ( 500mL )
B-53LW
Hull Cell ( Thermostatic-Control / Long-Type )
B-77-P01W
Haring Cell Tank
B-72-P01WJ
Spiral Contract-Meter Tank
A-53-M3-P01W
Micro Cell ( lll w ) Tank
A-56-0500W
Smart Cell 500W
B-74-M1-P02W
Micro Barrel Tank
COLUMN
Yamamoto-MS’s Progress in
Developing Hull Cell Test Kits
01 The wide variety of types we produce is our response to demands in the field.
Although Yamamoto-MS has many varieties of hull cells, all were created in response
to actual needs in the field. For example, the type for test-pieces twice as long as regular
pieces was our response to a request from a solution maker who found evaluations
difficult to make with the conventional test-piece in developing a high-performance
liquid. The type that uses a stirrer for overflow agitation was to accommodate plating
solutions for which composite plating and air agitation was unfeasible. Additionally, the
palm-sized type was created to curb costs of experiments using gold plating and other
expensive plating solutions.
02 Providing Products of Highly Stable Quality
Clear acrylic resin tanks are known for making it easy to observe how plating is applied and gas is generated.
Although tanks made from acrylic resin can be found in other Asian countries, it is known that their
dimensions can differ with every order or that they break immediately when used, along with other defects.
In Yamamoto-MS, water tank dimensions remain constant and the perforations made for air
agitation are uniformly sized. Exactly the same results can be reproduced even when experiments are
performed many times and moreover, our products are strong and long-lasting despite repeated use.
The photograph on the right shows a product we sold over 40 years ago (please note the
stamp of company’s former name) that is still actively used.
Cells from over 40 years ago that is still in active use
(Photograph taken at a Japanese public institution on Feb. 23, 2015)
03 First-rate Test-pieces Indispensable to Making Difficult Evaluations
With Yamamoto-MS test-pieces, because of the extremely small differences between
lots, it is possible to achieve the same brightness on both sides, with smooth and even
surfaces. By maintaining quality, we are able to ensure stable supply, which is crucial
to making severe evaluations. If the base brightness is unstable, minute differences
will go unnoticed. Also, any warping in the test-pieces will change the flow of the
electric current, even with the same solution, resulting in variations in the film’s external
appearance. By using Yamamoto-MS test-pieces, you can be assured that work can be
satisfactorily completed as they are expected to be done.
It is no easy feat to continue providing test-pieces of stable quality. We have been able to do so
only through the commitment of our skilled specialists who, with their wealth of experience and
technical expertise, have dedicated themselves to providing thorough support to our customers.
04 Continuing to be a Company that Strongly Supports Customers
We often hear from our customers of how Yamamoto-MS equipment has helped them in
their work such as commercialization of new products based on successful R&D or when
they were able to manufacture products that were previously difficult to plate or which
were too expensive to manufacture. As a company, nothing makes us more happy than
receiving such feedback from our customers, since it is our mission to provide products
and services that make the impossible possible for our customers or that allow them to
satisfactorily complete their work as they are expected to be done.
We intend to continue working together day by day, with a commitment to satisfying as
many customers as possible, while seeking to become a company trusted and admired all
over the world.
President Wataru Yamamoto
15
Corporate Profile
History
Line of Business
1950
Established Yamamoto-Shoten at 3-6, Hongokuchou,
Nihonbashi, Chuo-ku, Tokyo
Started distribution of Sulphameters (kit for measuring
sulphuric acid in chromium plating solution)
Admitted as a Sustaining Member of Metal Finishing
Society of Japan
(the current The Surface Finishing Society of Japan)
December 1961
Relocated to 5-28-1, Sendagaya, Shibuya-Ku, Tokyo
Specialized the company's business-line to the manufacture
of plating testing equipment and analytical reagents
August 1964
July 1975
October 2000
November 2002
May 2004
November 2004
Changed company name to Yamamoto-Shoten Co., Ltd.
Changed company name to YAMAMOTO-MS Co., Ltd.
Increased capital from JPY 42,000,000 to JPY 63,000,000
Increased capital to JPY 75,600,000
Registered ISO9001 Certification
Increased capital to JPY 80,000,000
Design, development and manufacture of wet surface
treatment equipment ( 100L Volume ), wet surface
treatment testing equipment,
wet surface treatment analyzers (excluding coating application)
Major Customers
ISO9001
Design, development and manufacture of wet surface
treatment-related products (equipment/chemicals)
Major electrics/device manufacturers
Raw/Primary Materials Manufacturer
MEMS-related laboratories & manufacturers
LIGA, MEMS-related laboratories & manufactures
Automotive industrial manufactures / aerospace affiliated
manufactureres
PCB / electronics parts manufacturing plants
Precision machinery industrial manufactures
Plating divisions / laboratories of other manufacturers
National/public laboratories
University laboratories
Plating specialists
Plating chemicals manufacturing companies
Plating Skills Assessment Committee (Japan)
*In 1998, English name has changed from YAMAMOTO
MEKKI SIKENKI to YAMAMOTO-MS Co., Ltd.
We also sell to other countries than the above. Please contact us for more information.
Price change and Specification Modification
Please be aware that in order to improve our products,
we may modify specifications or other aspects and price is subject to change without giving prior notice.
Tokyo
here
Japan
YAMAMOTO-MS Co., Ltd.
151-0051 5-28-1, Sendagaya, Shibuya-Ku, Tokyo Japan
Tel : +81-3-3352-2475 FAX : +81-3-3350- 0775
URL http://www.yamamoto-ms.co.jp/en/ E-mail info-eu@yamamoto-ms.co.jp
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