www.ngk-alloys.com Beryllium Copper Alloys Security Reliability Performance Beryllium Copper Introduction Offers unique combinations of mechanical and electrical properties The Berylco Beryllium Copper alloys are the most versatile of all copper alloys. They combine a wide range of properties that make our alloys the ideal materials to meet the exacting requirements of many products demanding high specifications that are used in the most diverse markets. ADVANTAGES High strength High fatigue life Good conductivity Good formability Corrosion resistance Stress relaxation Wear & abrasion resistance Wide temperature range Non-magnetic Non-sparking All manufacturing technologies such as casting, forging, extrusion, cold drawing, cold rolling, stamping, machining, soldering, plating, and many others, can be used to produce any beryllium copper parts. Meet tomorrow’s technological challenges The Berylco alloys offer a wide combination of mechanical and electrical properties, combining with excellent formability which is unique for copper alloys. Demands for cost, quality, miniaturisation, reliability, safety, environmental protection and high-end general performance require suitable high-performance alloys such as beryllium copper. The mechanical strength achieved after a simple heat treatment, at low temperature, ranks highest amongst all the copper-based alloys, and combined with a high electrical conductivity outperforms any bronze alloys. The available data is to be referred to by the user in order to select the correct alloy and temper and the alloy which will provide optimum properties and yet be compatible with the forming of the part. Our alloys exhibit a wide range of desired properties such as high fatigue strength, excellent corrosion, wear and abrasion resistance. For a given problem we can investigate the possibility of improving the formability while retaining the desired mechanical properties. For these special investigations NGK Berylco offers the services of its engineers and technical advisors. They are also non-magnetic and non-sparking. Automotive Aerospace Electrical & Electronic Telecommunication Home appliances Nuclear energy Offshore Biomedical & Medical Photovoltaic Watch making Defence & Military Railway … Electrical conductivity (%IACS) MARKETS High Bending Formability Formability (R/t ; 90° Transversal bending) High Strength & Electrical Conductivity PRODUCT RANGE The Berylco alloys product range including strips, rods, wires, foundry alloys (ingots, master alloys to 4%), Chill-Vents, forged rods, plates, profiles and safety tools. INDUSTRIAL HYGIENE When supplied in solid form, beryllium copper alloys are non-hazardous, because Beryllium has been completely dissolved into copper. General handling, stamping, forming, most machining operations, pickling, surface treatment, plating and heat treatment are nonhazardous and do not require any special precautions. discharge machining, melting or welding, then an inhalation hazard could arise. If they are subsequently processed in any way which might give rise to airborne dust or fumes, for instance by dry grinding, abrading, electro- For more information concerning the non hazardous use or to request our product safety information sheets (SIS), please contact us. www.ngk-alloys.com Any such process requires suitable air extraction 3 and filtration to maintain Be level of 2 µg/m of air per working day, value set up by the Ministry of Labour as the average Permissible Exposure Limit (PEL) has not to be exceeded. Beryllium Copper alloys High Strength alloy Berylco alloys Properties Designation Chemical composition (%) Product form Characteristics BERYLCO 25 Be : Co : Co + Ni + Fe : Cu + additions : 1,8-2,0 % 0,3 % max. 0,6 % max. 99,5 % min. Strip Rod Wire B25 alloys offer a wide combination of properties ranging from good electrical conductivity, good formability, and very high mechanical and electrical properties after heat treatment. Be : Co : Co + Ni + Fe : Pb : Cu + additions : 1,8-2,0 % 0,3 % max. 0,6 % max. 0,2 % min. 99,5 % min. Rod Wire Free machining very high strength alloy. Its small addition of lead gives a very good machinability index. Its properties are identical to Berylco 25. Be : Ni : Cu + additions : 0,2-0,6 % 1,8-2,2 % 99,5 % min. Strip Rod Wire B14 alloys combine good mechanical properties and high electrical conductivity. B14S mill hardened strip product offers an excellent formability superior to any other copper alloys. Be : Ni : Cu + additions : 0,2-0,6 % 1,4-2,2 % 99,5 % min. Strip B8 alloys combine very high electrical conductivity (>60 %IACS) and good mechanical properties. It is recommended for products exposed to high temperature. Be : Ni + Co : Al : Cu+Be+Ni+Co+Al : 0.2-0.4 % 1.8-2.5 % 0.6 % max. 99.5 % min. Strip B7 alloys offer an excellent combination of mechanical, formability and electrical properties, and are recommended for large production batch applications. ISO EN UNS CuBe2 CW 101 C C17200 BERYLCO 33/25 ISO EN UNS CuBe2Pb CW 102 C C17300 High Conductivity alloys BERYLCO 14 ISO EN UNS CuNi2Be CW 110 C C17510 BERYLCO 8 ISO EN UNS CuNi2Be CW 110 C C17510 BERYLCO 7 ISO UNS CuNi2Be C17530 Physical properties after precipitation hardening Melting point (°C) 3 Berylco 25 Berylco 33/25 Berylco 14 Berylco 8 Berylco 7 865-980 865-980 1030-1070 1005-1070 1050-1085 Density (g/cm ) at 20°C 8,26 8,26 8,75 8,75 8,71 Specific heat (Cal/(g.°C)) at 20°C 0,1 0,1 0,1 0,1 0,1 Coefficient of linear expansion -6 at 20° to 200°C 17,3 17,3 18 17,6 17,6 Electrical resistivity ρ (maxi) -8 (10 Ω.m) at 20°C 7,9 7,9 3,8 3,1 5,4 Thermal conductivity (W/m.K) at 20°C 84-130 84-130 167-260 167-260 148-194 Electrical conductivity (% IACS) at 20°C Modulus of elasticity (x10 /°C) 25 25 50 63 38 2 130 000 130 000 132 000 132 000 127 000 2 50 000 50 000 52 000 52 000 49 000 0,3 0,3 0,3 0,3 0,3 1.000042 1.000042 1.000031 1.000031 1.000027 ≥ 300 ≥ 300 ≥ 240 ≥ 240 ≥ 250 (N/mm ) Modulus of rigidity (N/mm ) Poisson’s ratio Magnetic permeability µ (µ=1+4πk) 2 Fatigue resistance (N/mm ) 8 at 10 cycles Reference Specifications Authority Strip Rod and Wire EN 1652, 1654 12163, 12164, 12165, 12166, 12167 ASTM B194, B534 B196, B197, B442, B441 CDA and SAE C17200, C17000, C17510, C17530 C17200, C17300, C17510 JIS H3130 C1720 P.R, H3130 C1751 P.R H3270 C1720 B.W (1) AFNOR (1) A51.109 A51.114(1), A51.414(1), NFL14.709 DIN(1) 17666(1), 17670(1), 1777(1) 17666(1), 17672(1) British Standard(1) BS 2870(1) BS 28731, BS 2874(1) Federal USA(2) QQ-C-533(2) QQ-C-530(2) ■ Specifications replaced by the EN (1) and ASTM (2) specifications. Withdrawn and superseded specifications are listed for reference only, and are not to be used for purchasing. ■ Please contact NGK Berylco to determine the appropriate replacement specification. www.ngk-alloys.com Berylco Strip Strip Properties High Conductivity High Strength Alloy B25 B14 B8 B7 Temper TS (N/mm²) YS 0,2% (N/mm²) Elongation A50 mini (%) Age hardenable A 410 – 540 190 – 380 1/4H 510 – 610 400 – 560 1/2H 590 – 690 510 – 660 H 690 – 830 650 – 800 Age hardened AT 1130 – 1350 960 – 1210 1/4HT 1210 – 1400 1020 – 1280 1/2HT 1260 – 1450 1090 – 1350 HT 1310 – 1520 1130 – 1420 Mill hardened (standard) 1/4HM 750 – 870 550 – 760 1/2HM 830 – 960 650 – 850 HM 930 – 1080 750 – 980 SHM 1030 – 1150 860 – 1020 XHM 1100 – 1250 930 – 1180 XHMS 1200 – 1320 1030 – 1230 Mill hardened Type B (high formability) 1/2HMB 830 – 930 660 – 860 HMB 930 – 1030 760 – 930 XHMB 1070 – 1210 930 – 1170 Mill hardened Type S (very high formability) HM-TypeS 960 – 1040 790 – 940 XHM-TypeS 1060 – 1220 930 – 1070 Age hardenable A 250 – 380 140 – 300 1/2H 410 – 530 340 – 480 H 480 – 600 370 – 560 Age hardened AT 680 – 870 550 – 690 1/2HT 750 – 900 650 – 850 HT 750 – 950 670 – 900 Mill hardened (high formability) S780 780 – 930 680 – 850 S880 880 – 1020 780 – 950 Mill hardened (standard) HT 700 – 870 600 – 780 Mill hardened (standard) 1/2HT 670 – 800 550 – 760 HT 765 – 900 685 – 830 EHT 870 – 1000 750 – 930 Hardness (HV) Electrical Conductivity (% IACS) Heat Treatment Formability R/t at 90° bending Long. Trans. 35 15 8 2 90 – 150 130 – 190 180 – 220 215 – 270 15 – 19 15 – 19 15 – 19 15 – 19 --------- 0,0 0,0 1,0 2,0 0,0 0,0 2,0 5,0 3 3 1 1 350 – 410 360 – 430 370 – 440 380 – 450 21 – 28 21 – 28 21 – 28 21 – 28 3h at 315°C 2h at 315°C 2h at 315°C 2h at 315°C ----- ----- 15 12 9 9 4 3 235 – 280 260 – 310 290 – 350 310 – 360 345 – 395 365 – 420 19 – 28 19 – 28 19 – 28 19 – 28 19 – 28 19 – 28 M M M M M M 1,3 1,5 2,3 2,5 3,0 4,0 1,8 2,0 2,5 3,0 4,0 6,0 12 9 6 255 – 310 280 – 340 330 – 390 17 – 26 17 – 26 17 – 26 M M M 0,0 1,0 2,0 0,0 1,0 2,0 9 6 285 – 370 315 – 395 17 – 26 17 – 26 M M 0,5 1,0 0,5 1,0 20 5 2 60 – 130 125 – 160 140 – 185 22 – 25 22 – 25 22 – 25 ------- 0,0 1,5 2,0 0,0 2,0 3,0 8 5 5 190 – 250 215 – 265 220 – 270 ≥ 45 ≥ 45 ≥ 45 3h at 480°C 2h at 480°C 2h at 480°C -1,5 2,0 -2,0 2,0 12 10 220 – 270 250 – 310 ≥ 48 ≥ 48 M M 0,3 0,7 0,3 0,7 5 210 – 260 ≥ 60 --- 1,0 1,0 10 8 4 195 – 250 220 – 275 250 – 310 ≥ 38 ≥ 33 ≥ 30 ------- 0,0 0,5 1,0 0,0 1,0 1,5 from 50 to 100 ± 0.10 ± 0.06 ± 0.15 > 100 ± 0.20 ± 0.20 ± 0.20 ■ Strip Properties – Values are applicable to thickness 0.1mm and over. ■ M – “Mill Hardened” M indicates that the metal has been submitted to a treatment facility designed especially to give characteristics falling within a guaranteed range specific properties. Note ■ Formability – The formability R/t ratio allows a bending radius at 90° without cracking in the direction of rolling (longitudinal and transverse bending ways), for the various tempers. Typical R/t values are applicable for strip of 0.25mm thick or less. R = radius of bending ; t = thickness of the strip. Strip Dimensional Tolerances Thickness tolerances (mm) Thickness < 0.099 0.10 – 0.149 0.15 – 0.199 0.20 – 0.249 0.25 – 0.299 0.30 – 0.399 0.40 – 0.499 0.50 – 0.599 0.60 – 0.799 0.80 – 0.999 1.00 – 1.199 1.20 – 1.499 1.50 – 2.000 Standard ± 0.004 ± 0.005 ± 0.006 ± 0.007 ± 0.008 ± 0.009 ± 0.010 ± 0.013 ± 0.015 ± 0.030 ± 0.035 ± 0.045 ± 0.050 Width tolerances (mm) Precision ± 0.003 ± 0.004 ± 0.004 ± 0.005 ± 0.006 ± 0.007 ± 0.008 ± 0.009 ± 0.010 On demand On demand On demand On demand ■ If supplied A temper, only standard tolerances are possible. Thickness ≤ 0.80 mm > 0.80 mm Width standard precision standard from 3 to 49.9 ± 0.08 ± 0.05 ± 0.10 Camber tolerances max. / 1m (mm) Ratio : Width / Thickness (mm) Straightness tolerances fo (mm) 8 – 15 15.1 – 30 30.1 – 60 60.1 – 120 > 120 8 6 4 3 2 ■ If the measurement is made over a length l1 other than 1 m, the value for f1 is established by the formula: f1 = fo × I1² (l1 is in mm). www.ngk-alloys.com Berylco Rod & Wire Rod Properties High Strength & Conductivity Alloy Temper Diameter (mm) Age hardenable A All dimensions H Ø ≤ 25 mm H Ø > 25 mm Age hardened AT All dimensions HT Ø ≤ 25 mm HT Ø > 25 mm Age hardened AT All dimensions HT All dimensions B25 & B33/25 B14 TS (N/mm²) YS 0,2% (N/mm²) Elongation A50 mini (%) Hardness (HV) Electrical Conductivity (% IACS) Heat Treatment 420 – 600 620 – 900 600 – 800 170 – 270 550 – 800 500 – 750 35 3 5 90 – 150 200 – 250 180 – 240 15 – 19 15 – 19 15 – 19 ------- 1150 – 1350 1300 – 1500 1200 – 1500 1000 – 1250 1150 – 1400 1050 – 1400 3 1 2 360 – 410 390 – 440 380 – 430 21 – 28 21 – 28 21 – 28 3h at 315°C 2h at 315°C 2h at 315°C 650 – 800 740 – 900 500 – 670 640 – 800 10 8 190 – 250 210 – 270 48 – 60 48 – 60 3h at 480°C 2h at 480°C Rod Dimensional Tolerances Dimensional tolerances (Age hardenable) Berylco 25 Ø (mm) 1,4 – 3.0 3,1 – 6.0 6,1 – 10.0 10,1 – 18.0 18,1 – 25.0 25,1 – 30.0 30,1 – 50.0 50,1 – 60.0 Length / Diameters Berylco 33/25 ± (mm) Ø (mm) h9 : +0, -0,025 h9 : +0, -0,030 h9 : +0, -0,036 h10 : +0, -0,070 h10 : +0, -0,084 h11 : +0, -0,130 h11 : +0, -0,160 h11 : +0, -0,190 Berylco 25 ± (mm) 0,9 – 2,3 2.4 – 3.0 3.1 – 6.0 6.1 – 10.0 10.1 – 13.0 13.1 – 18.0 18.1 – 25.4 25.5 – 30.0 30.1 – 40.0 h8 : +0, - 0.014 h8 : +0, - 0.014 h8 : +0, - 0.018 h8 : +0, - 0.022 h8 : +0, - 0.027 h9 : +0, - 0.043 h9 : +0, - 0.052 h10 : +0, - 0.084 h10 : +0, - 0.100 Berylco 33/25 Ø (mm) ± (mm) Ø (mm) < 25,4 25,5 – 45 45,1 – 50,8 50,9 – 60 3 m ± 100mm 2 m min. 1,5 m min. 1 m min. ≤ 3.0 3,1 – 18 18,1 – 25 25,1 – 40 ± (mm) 3 m ± 10mm 3 m ± 50mm 3 m ± 100mm 2 m min. ■ Remarks: For Berylco 33/25 alloys, CuBe2Pb, rods are pointed and chamfered up to Ø16 mm before shipment. ■ Rods can be delivered centerless ground. Contact us ■ NGK Berylco can also supply some profile rods (square, rectangular and hexagonal) cold drawn or hot worked, and some non-standard sizes. Wire Properties Alloy Temper Diameter (mm) TS (N/mm²) High Strength Age hardenable A Ø ≥ 0.30 390 – 540 1/2 H Ø ≥ 0.10 550 – 780 B25 H Ø ≥ 0.10 750 – 1140 & Age hardened B33/25 AT Ø ≥ 0.30 1130 – 1300 1/2 HT Ø ≥ 0.10 1200 – 1450 HT Ø ≥ 0.10 1270 – 1550 ■ Elongation and electrical conductivity are for design guidance only. YS 0,2% (N/mm²) Elongation A50 mini (%) Hardness (HV) Electrical Conductivity (% IACS) Heat Treatment 140 – 250 470 – 750 610 – 960 35 10 2 ------- ------- ------- 980 – 1200 1100 – 1350 1200 – 1460 3 2 1 ------- > 22 > 22 > 22 3h at 315°C 2h at 315°C 2h at 315°C Wire Dimensional Tolerances Diameter (mm) 0.10 – 0.25 0.26 – 0.30 0.31 – 0.50 0.51 – 2.00 2.01 – 3.50 3.51 – 4.50 4.51 – 9.50 Standard Tolerances ± 0.005 ± 0.008 ± 0.010 ± 0.020 ± 0.030 ± 0.040 ± 0.050 Precision Tolerances On demand On demand ± 0.005 ± 0.010 ± 0.015 ± 0.020 ± 0.030 ■ Other wire dimensions available on demand. 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Passeroni, 6 20135 MILANO, Italia Tel: +39 02-45506240/1 Fax: +39 02-39304926 Email: tecnicom@mclink.it ASIA JAPAN CHINA CHINA NGK INSULATORS Ltd New Metal Division, Marunouchi Bldg.25F, 2-4-1, Marunouchi, Chiyoda-ku, Tokyo, 100-6235, Japan Tel: +81 (0)3-6213-8913 Fax: +81 (0)3-6213-8973 www.ngk.co.jp NGK INSULATORS Ltd Shanghai Office, Dawning Centre Tower A Room 1902, No.500 Hongbaoshi Road, Shanghai 201103, China Tel: +86-021-3209-8870 Fax: +86-021-3209-8871 www.ngk.co.jp/cn NGK INSULATORS Investment Co Ltd Shenzhen Branch Room.8, Level.15, Tower 2, Kerry Plaza, No.1 Zhong Xin Si Road, Futian District Shenzhen 518048, China Tel : +86-755-3304 -3178 AMERICA INDIA USA INDIA NGK METALS Corporation 917 U.S. Highway 11 South, Sweetwater, TN 37874, USA Tel: +1 (800) 523-8268 Fax: +1 (877) 645-2328 www.ngkmetals.com NGK INSULATORS Ltd New Delhi Liaison Office, 601, 6th floor, DLF Place, A-4, District Centre, Saket New Delhi 110 017, India Tel: +91-11-4170-4020 www.ngk.co.jp For more information, please visit our website www.ngk-alloys.com Distributed by : EN 9100 ISO 14001 Edition 06/2014 Copyright © 2014 by NGK Berylco Europe