Johnson Matthey Metal Joining - High Temperature Brazing Alloys Index Page About Johnson Matthey 4 About Johnson Matthey Metal Joining 5 Pallabraze Alloys 6 Orobraze Alloys 7 Silver Brazing Alloys 8 Nickel Based Alloys 9 Argentel and Bronze Alloys 10 Copper Based Alloys 11 High Temperature Brazing Fluxes 12 Product Availability 13 Precious Metal Brazing Materials Reference Chart 14 3 Johnson Matthey plc Johnson Matthey is a world leader in all aspects of precious metals technology. Building on 180 years of expertise in assaying and refining, the name of Johnson Matthey has become synonymous with the highest levels of quality and customer service. Today Johnson Matthey has worldwide businesses in Chemicals and Catalysts, Precious Metals and Colours and Coatings. The Company is continually changing and developing new technologies to meet the current and future needs of our customers. Johnson Matthey is a key supplier to many of the worlds automotive and aerospace companies. Johnson Matthey Metal Joining High Temperature Brazing Processes Johnson Matthey use global sourcing and manufacturing capabilities to offer the widest range of High Temperature Brazing Alloys. These materials have a many applications. They are used for aerospace, automotive or electronic components. Some have found special applications in mining or drilling equipment or in chemical and engineering industries. 4 About Johnson Matthey - Metal Joining Johnson Matthey have over 70 years experience in the brazing and soldering industry and have a global manufacturing capability. Our aim is to provide our customers with value for money whilst maintaining our renowned product quality and service. We recognise that customers face ever increasing challenges, and we intend to offer full technical product support. When you buy our products, you will receive not only the best quality, but also a solution to your brazing and soldering requirements. We serve customers in all industry sectors, from aerospace and electronics to mining and drilling. Our product range has evolved to meet their needs. We actively look to work in partnership with customers, the goal often being to increase the efficiency of their brazing and soldering processes. Johnson Matthey constantly monitor advances in materials technology using the expertise of our sites worldwide as well as that of our partners in the industry. This combined expertise enables us to offer the best solutions to metal joining problems and in many cases significantly reduces process costs. Johnson Matthey - Metal Joining Quality All branches of Metal Joining have been accredited with ISO 9002 and numerous customer quality approvals. Certification to national and international standards is available and all our products are supported by full COSHH documentation. High Temperature Brazing Processes 5 Pallabraze Alloys Palladium based brazing alloys Introduction Johnson Matthey’s Pallabraze range of alloys are manufactured to ‘vacuum grade’ purity standards. In addition to traditional aerospace and electronics applications they have been used in the glass and chemical industries where increased resistance to corrosion and chemical attack makes them a good choice. Physical Properties of the Alloys Composition (%) Melting Standards Name Pd Ag Cu Ni Range °C BS1845:1984 EN 1044:1999 Pallabraze 810 5 68.5 26.5 - 807 - 810 PD1V PD106 Pallabraze 840 10 67.5 22.5 - 834 - 840 PD3V PD104 Pallabraze 850 10 58.5 31.5 - 824 - 850 PD2V PD105 Pallabraze 880 15 65 20 - 856 - 880 PD4V PD103 Pallabraze 900 20 52 28 - 876 - 900 PD5V PD102 Pallabraze 950 25 54 21 - 901 - 950 PD6V PD101 Pallabraze 1010 5 95 - - 970 - 1010 PD7V PD204 Pallabraze 1090 18 - 82 - 1080 - 1090 PD8V PD203 Pallabraze 1225 30 70 - - 1150 - 1225 Pallabraze 1237 60 - - 40 1237 - 1237 PD14V PD201 Impurity levels – Refer to EN1044:1999 or Johnson Matthey technical department for more details. Features of the range • Joints brazed with Pallabraze alloys have good oxidation resistance and improved mechanical strength at elevated temperatures. For example Pallabraze 810 shows resistance up to 500°C and Pallabraze 1237 offers effective oxidation resistance up to 700°C. • Pallabraze alloys offer good corrosion resistance and show excellent resistance to interfacial corrosion when brazing ferritic and austenitic stainless steels. • Pallabrazes exhibit minimal errosion on ferrous and nickel-bearing alloys during brazing. 6 • Palladium-bearing alloys do not cause 'stress cracking' and are recommended on iron-nickel-cobalt alloys. • Pallabrazes are free from volatile constituents making them particularly useful in vacuum applications such as electronic valve and power tube construction. • The narrow melting ranges of the Pallabraze alloys enables complex components to be assembled by a step brazing. • Pallabrazes have excellent flow and penetration qualities but are also capable of filling joint gaps up to 0.5mm. Orobraze Alloys Gold based brazing alloys Introduction Johnson Matthey supplies a wide range of high purity Gold brazing alloys. These are manufactured to the highest quality to meet the needs of the aerospace and electronics industries. In addition to the alloys shown below JM are able to supply most gold bearing brazing materials available today. Physical Properties of the Alloys Melting Standards Name Composition (%) Au Cu Ni Other Range °C BS1845:1984 EN 1044:1999 Orobraze 845 60 20 - 20Ag 835 - 845 - - - Orobraze 910 80 19 - 1Fe 908 - 910 AU1V AU101 - Orobraze 940 62.5 37.5 - - 930 - 940 AU2V AU102 - Orobraze 950 82 - 18 - 950 - 950 AU5V AU105 4787/BAu-4 Orobraze 970 50 50 - - 955 - 970 - - Orobraze 990 75 25 - 950 - 990 AU6V AU106 - Orobraze 998 37.5 62.5 - - 980 - 998 AU3V AU103 BAu-1 Orobraze 1005 35 65 - - 970 - 1005 - Orobraze 1018 30 70 - - 996 - 1018 AU4V AU104 - Orobraze 1030 35 62 3 - 1000 - 1030 - - BAu-3 Orobraze 1040 70 - - 30Ag 1030 - 1040 - - - - AMS/AWS A5.8 Impurity levels – Refer to EN 1044:1999 or Johnson Matthey technical department for more details. Features of the range Gold-Copper Orobrazes Gold-NickeI Orobrazes • Gold-copper Orobrazes exhibit exceptional resistance to corrosion and • Nickel-bearing Orobrazes exhibit increased high temperature strength and strength at elevated temperatures. • Gold-copper Orobrazes can produce ductile joints without excessive resistance to oxidation at elevated temperatures compared to gold-copper alloys. inter-alloying between the brazing alloy and the parent material. This is • These alloys offer good corrosion resistance in many chemical environments. advantageous when brazing thin-walled structures. • Alloys such as Orobraze 950 find extensive application in the manufacture of • Gold-copper Orobrazes exhibit good wetting on copper, nickel, iron, cobalt, molybdenum, niobium, tungsten and their alloys. • The gold-copper Orobrazes are ideal for use in vacuum devices that operate at elevated temperatures as they contain no volatile elements. aeroengine components. • Gold-nickel Orobrazes exhibit flow characteristics superior to the gold-copper Orobrazes on nimonics, super-alloys and stainless steel. • Orobraze alloys exhibit a number of well-defined melting ranges which make them suitable for step brazing. 7 Silver Brazing Alloys For Special Brazing Applications Introduction Johnson Matthey Metal Joining supply a range of special silver brazing alloys. In this range are a number of alloys which are designed for or can be used in furnace brazing applications. Some like Silver Copper Eutectic, IN10 and IN15 are designed to meet the high purity requirements of the electronics industry, whilst others are designed for specific applications. Physical Properties of the Alloys Composition (%) Ag Cu Melting Alloy Specification In other Range °C EN1044:1999 / BS1845:1984 / AWS A5.8 - Silver 99.9 - - - 960 Standard Silver 92.5 7.5 - - 805-890 - Silver-Copper Eutectic 72 28 - - 778 EN1044:1999 AG401 / BS1845:1984 AG7V* IN 10 63 27 10 - 685 - 730 * IN 15 61 24 15 - 630 - 705 * RTSN 60 10 - 10 Sn 602 - 718 AMS4773 / B-Ag 18 85/15 Ag/Mn 85 - - 15 Mn 960 - 970 EN1044:1999 AG501 / BS1845:1984 AG19 / B-Ag 23 DHE310 54 40 - 5Z n,1 Ni 718 - 857 AMS4772 / B-Ag 13 *Impurity levels – Refer to EN 1044:1999 or Johnson Matthey technical department for more details. Features of the range Silver Alloys Silver and Standard Silver can be used for the furnace brazing of Titanium. Silver Copper Eutectic commonly used metals are Nilo K (Kovar) type alloys which are used because their thermal expansion closely matches that of alumina. Silver Copper Eutectic is widely used for the brazing of metal to metallized alumina ceramics used in electronic components. The most These alloys are prone to intergranular penetration by Silver-Copper Eutectic. This tendency is generally avoided by nickel plating the components or by using a silver-copper-palladium alloy such as Pallabraze 810. Silver copper eutectic has excellent flow characteristics. IN 10 The flow characteristics of IN10 and IN15 are more sluggish than Silver-Copper Eutectic and liquation (a separation of the metallurgical IN 15 Eutectic. They are used where a lower brazing temperature is desirable, or step brazing with Silver-Copper Eutectic is required RTSN RTSN is an alloy for furnace or vacuum brazing with good corrosion resistance in marine environments. 85/15 Ag/Mn 85/15 Ag/Mn is used for the joining of steel and stainless steel assemblies in contact with ammonia, where copper containing materials phases of the brazing alloy) may occur if a protracted heating cycle is used. IN10 and IN15 have similar applications to Silver-Copper are not acceptable. DHE 310 8 DHE 310 is used in furnace brazing where fast heating rates are possible to avoid liquation. Nickel Based Alloys High Temperature Furnace Brazing Introduction Nickel based brazing alloys provide exceptional resistance to chemical corrosion and oxidation coupled with high strength at elevated temperatures. The alloys in this range have a variety of compositions that result in differing melting ranges, alloy flow, brazing and joint characteristics. These alloys are widely used particularly within the Aerospace and Nuclear industry. Vacuum brazing and controlled atmosphere brazing (pure dry Hydrogen or Argon) are the most common heating methods used. They are often used to join stainless steel (300 and 400 series) as well as nickel and cobalt base alloys. In addition carbon and low alloy steels and copper can be brazed with selected nickel based brazing alloys. Physical Properties of the Alloys Alloy Composition Melting Specifications Name Ni Cr Fe B Others Range ˚C BS1845 1984 AMS / AWS EN1044 1999 HTN1 Bal 14 4.5 3.1 Si 4.5,C 0.7 980-1060 HTN1 4775/BNi-1 NI101 HTN1A Bal 14 4.5 3.1 Si 4.5 980-1070 HTN1A 4776/BNi-1a NI1A1 HTN2 Bal 7 3.0 3.1 Si 4.5 970-1000 HTN2 4777/BNi-2 NI102 HTN3 Bal - 0.5 3.1 Si 4.5 980-1040 HTN3 4778/BNi-3 NI103 HTN4 Bal - 1.5 1.8 Si 3.5 980-1070 HTN4 4779/BNi-4 NI104 HTN5 Bal 19 - - Si 10.1 1080-1135 HTN5 4782/BNi-5 NI105 HTN6 Bal - - - P 11 875 HTN6 BNi-6 NI106 HTN7 Bal 14 - - P10.1 890 HTN7 BNi-7 NI107 Alloys are available in powder and paste form. Melt spun foils, tapes and preforms can be supplied. Aerospace and aero-engine approved materials. Special alloys and product forms are possible. Features of the range HTN 1 HTN1 produces high strength, oxidation and corrosion resistant parts and is useful in highly stressed components. Typical joint gaps are 0.05-0.12mm. HTN 1a HTN1a has a restricted carbon content and is used for similar applications to HTN1. Typical joint gaps are 0.15mm. HTN 2 HTN2 is the first choice for many applications except very thin walled assemblies. Good alloy flow allows joint clearances of 0.025-0.1mm. HTN 3 HTN3 is again similar to HTN1 but finds applications in marginal brazing atmospheres offering good flow where tight joint tolerances are encountered. HTN 4 HTN4 has a wide melting range which can produce large, ductile fillets. Suitable for brazing components where tight joint tolerances are not possible. HTN 5 HTN5 is used for high strength, oxidation resistant joints that can operate at elevated temperatures. Joint gaps up to 0.1mm. HTN 6 HTN6 is a free flowing alloy that can be used on Fe and Ni alloys and low chromium steels in exothermic atmospheres. Contact joint gaps are required. HTN 7 HTN7 is used on thin walled structures and on high temperature components. It shows low erosion on Fe and Ni alloys. Contact joint gaps are required. 9 Argentel and Bronze Alloys Base metal brazing alloys Introduction JM Argentel alloys are used in the braze or bronze welding processes. In this process some penetration of the filler metal may be obtained into the capilliary gaps between the components being joined. However strength is achieved in the joint by building up a fillet of the braze metal. Today the widest use for these alloys is in ‘brazing’ of steels and tungsten carbide. JM Bronze alloys are a range of special alloys designed for high temperature brazing of steel and carbide components. Each has specific alloy characteristics and uses. Physical Properties of the Alloys Melting Standards Alloy Nominal Composition Cu Zn Mn Ni Other Range ˚C BS1845:1984 Argentel No 1 60 Bal - - 0.2Si 875-895 CZ6 CU301 Argentel 48 42 - 10 - 920-980 CZ8 CU305 B-Bronze 97 - - 3 0.03 B 1081-1101 CU7 CU105 C-Bronze 86.5 - 11 2.5 - 965-995 - - F-Bronze 57.5 38.5 2 - 2 Co 890-930 - - D-Bronze 86 10 - - 4 Co 980-1030 - - EN1044:1999 Features of the Range JM Argentel Range of Brazing Alloys Argentel No 1 Argentel No. 1 is widely used in the joining of mild steel, galvanised steel, cast iron and some copper alloys. Argentel Argentel is a nickel containing alloy and gives extremely strong joints on stainless and mild steels and cast iron. JM Bronze Range of Brazing Alloys B Bronze C Bronze B Bronze – see page 11 for details of this alloy. C Bronze - has good gap-bridging properties in the range 0.025 mm up to 0.75 mm and offers excellent resistance to interfacial corrosion when used on ferritic or austenitic stainless steels. Due to the manganese content the alloy requires a furnace atmosphere with a dew point better than - 40°C. It is also used in vacuum brazing provided a partial pressure of argon is applied. If required C Bronze can be brazed in air using Tenacity 125 as a flux. D Bronze D Bronze is used in the brazing of rock drills where its good wetting properties and strength coupled with an ability to allow heat treatment of the drill shank at temperatures between 800 - 1000°C. The alloy is frequently induction brazed in air with Tenacity 125 flux. F Bronze F Bronze is used to braze tungsten carbide into rock drills or similar equipment. It is harder than D Bronze and is used where the heat treatment of the steel drill shank is temperature critical. Induction or flame heating with Tenacity 125 flux are usually used. 10 Copper Based Alloys High Temperature Furnace Brazing Introduction Johnson Matthey supply a series of high temperature copper base alloys. These alloys are used for brazing in reducing atmosphere belt furnaces and in vacuum furnaces. They are available in a variety of forms and are designed to meet the needs of a range of customers from commercial jobs to more demanding automotive or aerospace applicatons. Physical Properties of the Alloys Alloy Pure Copper JM Bronze Alloys Copper Tin Alloys Composition Melting Specification Cu Ni Sn Other Range °C EN1044:1099 / AWS A5.8 / BS1845:1984 Copper 99.9 - - - 1085 CU101 / BCu-1 / CDA 110 / CU2 Copper 99.95 - - - 1085 CU102 / CU3 B Bronze 97 3 - 1081-1101 CU7 C Bronze 86.5 2.5 - 11 Mn 965-995 - 92/8 91.75 - 8 0.25 P 882-1027 CDA 521 97/3 97 - 3 - 980-1070 - 96/4 96 - 4 - 950-1060 - 0.03 Boron Some Features of the Range Copper Alloys Copper Alloys can be supplied as rings washers, pastes or preform shapes to speed up furnace brazing. B Bronze B Bronze was developed for furnace brazing of stainless steel under reducing atmospheres where the joint gaps involved cannot be closely controlled. It will penetrate joint gaps ranging from an interference fit up to 0.5 mm. The joints produced with this alloy in both ferritic and austenitic steels exhibit excellent resistance to interfacial corrosion. B Bronze is ideal for the brazing of mild steels where the gaps are too large for the use of copper (i.e. over 0.025 mm). Copper Tin Alloys Copper Tin Alloys are used in the furnace brazing of mild steel and offer good gap filling properties. A variety of copper-tin compositions are available. Copper Brazepastes Johnson Matthey supply a range of copper brazepastes in addition to those shown below. They have been designed operate in different furnace atmospheres and have different brazing characteristics. Consult a technical representative for more details and product datasheets. CU 503 Brazepastes CU 503 Brazepastes is a Copperpaste loaded with Copper Oxide, this is to help the flow in difficult atmospheres and also may help to prevent "sooting". JM CU 521 is an alternative to CU 503 filling gaps up to 0.10mm. CU 510 Brazepastes CU 510 Brazepastes is used for most applications, normally used in atmospheres of Nitrogen and/or Hydrogen. 11 High Temperature Brazing Fluxes Introduction Flux plays a vital role in virtually all air brazing processes. Use of the wrong flux or a poor application technique can have a dramatic effect on joint quality. Johnson Matthey produce a range of fluxes suitable for most air brazing operations. Many of the brazing alloys in this booklet are designed for furnace brazing operations where an inert or protective atmosphere means that no flux is required. For high temperature brazing operations in air a JM Tenacity flux can be considered. The information shown here is intended to help the user select the most suitable Johnson Matthey High Temperature Flux for a particular application. Details of Johnson Matthey Metal Joining’s complete range of fluxes including general purpose and medium temperature fluxes can be found in the Silver Brazing Alloys and Fluxes Booklet. High Temperature Fluxes Flux Form Working EN 1045 Range ºC* Standard Flux Residue Removal Packaging (kg) Tenacity 5 Powder 600-900 FH10 0.25 0.5 5.0 Tenacity No.125 Powder 750-1200 FH21 0.4 4.0 Tenacity No. 125 Paste 750-1200 FH21 0.7 Tenacity No. 12 Powder 800-1300 FH21 0.5 Tenacity No.20 Powder 750-1100 FH21 0.5 Residues are insoluble in water. Remove using NaOH solution or mechanical methods. Residues are insoluble in water. Grit blasting or mechanical removal is necessary. Residues are insoluble in water. Grit blasting or mechanical removal is necessary. 5.0 Residues are insoluble in water. Grit blasting or mechanical removal is necessary. Residues are insoluble in water. Grit blasting or mechanical removal is necessary. * The lower figure is the temperature at which the flux is capable of removing metal oxide. The upper figure is the maximum temperature at which the flux will remain effective long enough to make a sound brazed joint Features of the Range Tenacity No 5 Powder Tenacity No 125 Powder & Paste Tenacity No 12 Powder Tenacity No 20 Powder Flux Application Tenacty 5 is active at 600ºC above which temperature it spreads and cleans rapidly and is effective with alloys with a liquidus up to 850˚C. Tenacity No. 5 is particularly recommended when brazing stainless steel at temperatures above 700ºC and also for brazing large assemblies in steel or copper wherever prolonged heating is necessary. Tenacity No. 125 is high temperature flux which is effective on copper and copper based alloys, mild and low alloy steels and tungsten carbide with alloys melting between 800-1100˚C. It can therefore be used with the JM Argentel and Bronze alloys shown on page 10. Tenacity No. 12 is effective on copper and copper based alloys, mild steel and tungsten carbide when used with brazing alloys melting between 850-1200˚C. Tenacity 20 is used for brazing or bronze welding of mild steel components using Argentel alloys. It is recommended that flux should be applied as a paste to the parts to be joined. Powders can be made into pastes by stirring in water until the mixture has the consistency of thick cream. A few drops of liquid detergent added to the mixture will often improve the wetting of flux onto clean parent metals.The flux should be applied to both joint surfaces before assembly. Application of flux after assembly places great demands on the fluidity of the molten flux and its ability to penetrate capillary joints. Brushing is an effective method of applying a thin film of paste to the joint itself and to surrounding component surfaces. 12 More information on fluxes is available in ‘Silver Brazing Alloys and Fluxes’ or on www.jm-metaljoining.com. Product Availability Johnson Matthey hold a very broad range of products in stock at our sales offices. However many of the items detailed in this booklet are manufactured to customers orders. If we don’t carry an item that you use regularly please let us know. The brazing alloy ranges can be manufactured in a variety of different product forms. Wire Wire is available either in loose coils or on reels. (Not applicable to Nickel Brazing alloys). Foil Foil can be supplied on lose coils or on reels. Sizes can usually be made to order. Nickel based brazing alloys can also be supplied as tapes. Rods Brazing alloys can be supplied in rod form. (Not applicable to Nickel Brazing alloys). Strips Strips can be made to order. (Not applicable to Nickel Brazing alloys). Washers and preformed shapes All pre-formed shapes are made to order. A wide range of shapes including washers, clips, blocks and many foil shapes are possible. Rings All brazing rings are manufactured to order. (Not applicable to Nickel Brazing alloys). They are made ‘butt ended’ or more commonly with ends offset. Rings can be made in a vast range of sizes and from a wide range of wires. Brazepastes and Powders 10 JM supply a complete range or brazepastes. All alloys can be produced as paste or powder. Refer to JM booklet ‘Brazepastes and Solderpastes’ for more details. Product packaging JM brazing materials can be packed according to customer requirements. Quality Proceedures All branches of Metal Joining have been accredited with ISO 9002 and numerous customer quality approvals. Certification to national and international standards is available and all our products are supported by full COSHH documentation. Please contact your local JM office to discuss any matter relating to quality of our products or services. 13 Reference Chart High Tempreature Brazing Materials Reference Chart Palladium Based Brazing Alloys Pd Ag Cu Pallabraze 810 5 68.5 26.5 Pallabraze 840 10 67.5 22.5 Pallabraze 850 10 58.5 31.5 Pallabraze 880 15 65 20 Pallabraze 900 20 52 28 Pallabraze 950 25 54 21 Pallabraze 1010 5 95 Pallabraze 1090 18 82 Pallabraze 1225 30 70 Pallabraze 1237 60 - Others - Melting Range°C 807-810 834-840 824-850 856-880 876-900 901-950 970-1010 1080-1090 1150-1225 1237-1237 BS1845:1984 PD1V PD3V PD2V PD4V PD5V PD6V PD7V PD8V PD14V EN1044:1999 PD106 PD104 PD105 PD103 PD102 PD101 PD204 PD203 PD201 Others 20Ag 1 Fe 30 Ag Melting Range°C 835-845 908-910 930-940 950-950 955-970 950-990 980-998 970-1005 996-1018 1000-1030 1030-1040 BS1845:1984 AU1V AU2V AU5V AU6V AU3V AU4V - AMS /AWS 4787/BAu-4 BAu-1 BAu-3 - Precious Metal Brazing Alloys - 1100-1300°C Ag Au Cu Ni Pd Other 92 8 - Melting Range°C 1200-1270 Comment For brazing W, Mo, Ta, and superalloys. It is oxidation resistant and ductile. 48.5 - 30 50 19 - 1219 910-1179 1135-1169 1102-1121 For For For For Precious Ag 75 90 - Metal Au 25 70 70 20 25 73.8 Brazing Alloys Cu Ni 31 18 30 22 78 37 10 26.2 - 1000-1100°C Pd Other 20 5 Mn 10 15 11 Mn 8 2 In 15 13 Mn - Melting Range°C 1008-1072 1025-1070 1017-1052 960-1050 1005-1037 975-1025 970-1013 980-1010 Comment For brazing superalloys and tungsten carbide. For brazing Ni, Mo, W, stainless steel and fast braze cycles on titanium. For brazing super alloys and tungsten carbide. Excellent wetting, flow, strength, oxidation resistance, ductility. For brazing superalloys and stainless steel. AMS-4786 Alternative to Orobraze 1030 and higher gold content Au-Cu alloys. For brazing of superalloys and tungsten carbide. For brazing of stainless steel and superalloys. For loose tolerances. Precious Ag - Metal Au 35 40 72 31 81.25 81.5 60 Brazing Alloys Cu Ni 31.5 14 60 22 Bal Bal Bal 9.75 18 16.5 2 37 - - 900-1000°C Pd Other Melting Range°C 10 9.5 Mn 971-1004 980-1000 6 Cr 975-1000 30 10.5 Cr, 2.4 B 941-977 36 10.5 Cr, 0.5 Si 3B 820-960 9.75 16 Mn 927-949 0.75 Ti 945-960 910-925 3 In 860-900 Comment For brazing of super alloys and tungsten carbide. For brazing of Cu, Ni, Kovar and Mo-Mn metallised ceramics. For brazing of diamond to stainless steel. It is corrosion resistant. Better creep resistance than Orobraze 950 at elevated temps. Better creep resistance than Orobraze 950 at elevated temps. For brazing of super alloys and tungsten carbide. Excellent for difficult to wet materials. For brazing Cu, Ni and Mo-Mn metallised ceramics. Remains ductile. Lower brazing temperatures than Au/Cu series. Precious Ag 5 82 68.8 95 Metal Au 75 - Brazing Alloys Cu Ni 20 Bal 47 26.7 - - below 900°C Pd Other Melting Range°C 885-895 45.5 5 Co, 5 Si, 4.5 Mo 847-895 9 9 Ga 845-880 47 6 Si 810-851 4.5 Ti 830-850 5 Al 780-830 Comment Narrow melting range useful in step brazing. Available as a melt spun foil only. For brazing of Ti to Ti and stainless steel. Ductile and corrosion resistant. Better creep resistance than Orobraze 950 at elevated temps. Wets almost every material including ceramics metals and graphite. Forms ductile joints particularly with alloys containing Aluminium. Gold Based Brazing Alloys Au Cu Orobraze 845 60 20 Orobraze 910 80 19 Orobraze 940 62.5 37.5 Orobraze 950 82 Orobraze 970 50 50 Orobraze 990 75 Orobraze 998 37.5 62.5 Orobraze 1005 35 65 Orobraze 1018 30 70 Orobraze 1030 35 62 Orobraze 1040 70 - 14 Ni 18 25 3 - 10 36 25 65 22.5 34 25 Ni 40 35 Co - EN1044:1999 AU101 AU102 AU105 AU106 AU103 AU104 - brazing stainless steel, Mo, W, Ni. and superalloys. High strength, brazing stainless steels. A ductile alloy for filling wide gaps. superalloys. A high strength oxidation resistant alloy. AMS-4785 superalloys. A high strength oxidation resistant alloy. AMS-4784 Silver Brazing Alloys Ag Silver 99.99 Silver-Cu Eutectic 72 IN 10 63 IN 15 61 RTSN 60 85/15 Ag/Mn 85 DHE310 54 Argo-Braze 7 7 AMS 4765 56 AMS 4774A 63 For Special Applications Cu In other 28 27 10 24 15 30 10 Sn 15 Mn 40 5Zn, 1Ni 85 8Sn 42 2Ni 28.5 2.5Ni Active Brazing Alloys Ag Gold Copper Silver 92.75 Silver / Copper 68.8 Silver / Copper 63 Argentel and Bronze Cu Argentel No.1 60 Argentel 48 B Bronze 97 C Bronze 86.5 D Bronze 86 F Bronze 58 Au 96.4 - Cu 92.75 5 26.7 35.25 Ti 0.6 2.25 1.25 4.5 1.75 Melting Range°C 960 778 685 - 730 630 - 705 602 - 718 960 - 970 718 - 857 662 - 984 771 - 893 691 - 802 EN1044:1999 / BS1845: 1984 / AWS A5.8 / AMS AG401 / AG7V B-Ag 18 AMS 4773 AG501 / AG19 B-Ag 23 AMS 4766 B-Ag 13 AMS 4772 B-Ag 13a AMS 4765 AMS 4774A Other 3 Ni Al 2 Si 3 Al 1 - Melting Range°C 1003-1030 958-1024 860-912 830-850 780-815 Base Metal Brazing Alloys Zn Others Melting Range°C 40 0.2 Si 875-895 42 10 Ni 920-980 3 Ni 0.03B 1081-1101 2.5Ni 11Mn 965-995 4 Co 10Mn 980-1030 38 2 Co 2 Mn 890-930 BS 1845:1984 CZ6 CZ8 CU7 - EN 1044 1999 CU301 CU302 CU105 - Copper Based Brazing Alloys Cu Ni Sn 92/8 91.75 8 97/3 97 3 96/4 96 4 CU 511 80 20 CU 512 88 12 Copper 99.9 Copper 99.95 CU510 / 513 99.9 CU535 / 557 99.4 0.6 CU503 32 CU521 32 0.6 - Other 0.25 P 68 Cu O 68 Cu O Melting Range°C 882-1027 980-1070 950-1060 800-980 800-890 1085 1085 1085 1085 1085 1085 EN1044 1999 / AWS A5.8 CDA 521 CU201 CU101 / BCu-1/ CDA110 CU102 CU101 / BCu-1/ CDA110 BCu-1a / BCu-2 - Brazepaste Brazepaste Brazepaste Brazepaste Brazepaste Brazepaste Nickel Based Brazing Alloys Ni Cr Fe B Others Melting Range°C BS1845 1984 AMS / AWS A5.8 EN1044 1984 HTN1 HTN1A HTN2 HTN3 HTN4 HTN5 HTN6 HTN7 3.1 3.1 3.1 3.1 1.8 - Si 4.5 Co 0.7 Si 4.5 Si 4.5 Si 4.5 Si 3.5 Si 10.1 P 11 P 10.1 980-1060 980-1070 970-1000 980-1040 980-1070 1080-1135 875 890 HTN1 HTN1A HTN2 HTN3 HTN4 HTN5 HTN6 HTN7 4775/BNi-1 4776/BNi-1a 4777/BNi-2 4778/BNi-3 4779/BNi-4 4782/BNi-5 BNi-6 BNi-7 NI101 NI101 NI102 NI103 NI104 NI105 NI106 NI107 Bal Bal Bal Bal Bal Bal Bal Bal 14 14 7 19 14 Aluminium Brazing Alloys Al Si Alu-flo HT 88 12 4.5 4.5 3.0 0.5 1.5 - 2 2 Melting Range°C 577-582 only only only only only only Specification 4047 / BAlSi-3 NOTE: Johnson Matthey PLC cannot anticipate all conditions under which this information and our products or the products of other manufacturers in combination with our products will be used. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is given in good faith, being based on the latest information available to Johnson Matthey PLC and is, to be best of Johnson Matthey PLC's knowledge and belief, accurate and reliable at the time of preparation. However, no representation, warranty or guarantee is made as to the accuracy or completeness of the information and Johnson Matthey PLC assumes no responsibility therefore and disclaims any liability for any loss, damage or injury howsoever arising (including in respect of any claim brought by any third party) incurred using this information. The product is supplied on the condition that the user accepts responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. Freedom from patent or any other proprietary rights of any third party must not be assum Acknowledgements Kepston Ltd. (Heat Treatment and Furnace Brazing) Wednesbury West Midlands for the use of Controlled atmosphere Furnace for Photographic purposes. 15 Johnson Matthey Johnson Matthey PLC Metal Joining York Way Royston Hertfordshire SG8 5HJ Tel: +44 (0)1763 253200 Fax: +44 (0)1763 253168 Email: mj@matthey.com www: jm-metaljoining.com