Chapter #5 Nomenclature NOMENCLATURE I. Binary Ionic compounds Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal name using the “ide” suffix. Step 2 If the metal is to the right of group IIA, then a Roman numeral is used after the metal to to describe the charge of the metal. Except Ag, Zn,and Al Examples NaCl Al2O3 FeCl2 FeCl3 NOMENCLATURE I. Binary Ionic compounds Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal name using the “ide” suffix. Step 2 If the metal is to the right of group IIA, then a Roman numeral is used after the metal to to describe the charge of the metal. Except Ag, Zn,and Al Examples NaCl Sodium chloride Al2O3 FeCl2 FeCl3 NOMENCLATURE I. Binary Ionic compounds Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal name using the “ide” suffix. Step 2 If the metal is to the right of group IIA, then a Roman numeral is used after the metal to to describe the charge of the metal. Except Ag, Zn,and Al Examples NaCl Sodium chloride Al2O3 Aluminum oxide FeCl2 FeCl3 NOMENCLATURE I. Binary Ionic compounds Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal name using the “ide” suffix. Step 2 If the metal is to the right of group IIA, then a Roman numeral is used after the metal to to describe the charge of the metal. Except Ag, Zn,and Al Examples NaCl Sodium chloride Al2O3 Aluminum oxide FeCl2 Iron(II) chloride FeCl3 NOMENCLATURE I. Binary Ionic compounds Binary means two different elements Ionic means metal and nonmetal Step 1 First give the name of the metal, followed by the nonmetal name using the “ide” suffix. Step 2 If the metal is to the right of group IIA, then a Roman numeral is used after the metal to to describe the charge of the metal. Except Ag, Zn,and Al Examples NaCl Sodium chloride Al2O3 Aluminum oxide FeCl2 Iron(II) chloride FeCl3 iron(III) chloride II. Nonbinary Ionic compounds Nonbinary means more than two different elements Step 1 First give the name of the metal, followed by the memorized polyatomic ion name. Step 2 If the metal is to the right of group IIA, then a Roman numeral is used after the metal to describe the charge of the metal. Except Ag, Zn, and Al. Examples NaOH FeSO4 Fe(NO3)3 Zn(C2H3O2)2 Memorized Polyatomic Ion List Formula Name Formula Name NH4+ C2H3O2CO32- Ammonium Acetate Carbonate O22NO3NO2- Peroxide Nitrate Nitrite HCO31- SO42- Sulfate ClO4- Hydorgen carbonate Perchlorate SO32- Sulfite ClO3ClO2- Chlorate Chlorite PO43PO33- Phosphate Phosphite ClOCNOH- Hypochlorite Cyanide Hydroxide CrO42Cr2O72- Chromate Dichromate II. Nonbinary Ionic compounds Nonbinary means more than two different elements Step 1 First give the name of the metal, followed by the memorized polyatomic ion name. Step 2 CO If the metal is to the right of group IIA, then a Roman numeral is used after the metal to describe the charge of the metal. Except Ag, Zn, and Al. Examples NaOH FeSO4 Sodium hydroxide Fe(NO3)3 Zn(C2H3O2)2 II. Nonbinary Ionic compounds Nonbinary means more than two different elements Step 1 First give the name of the metal, followed by the memorized polyatomic ion name. Step 2 If the metal is to the right of group IIA, then a Roman numeral is used after the metal to describe the charge of the metal. Except Ag, Zn, and Al. Examples NaOH Sodium hydroxide Fe(SO4)2 Fe(NO3)3 Iron(III) nitrate Zn(C2H3O2)2 II. Nonbinary Ionic compounds Nonbinary means more than two different elements Step 1 First give the name of the metal, followed by the memorized polyatomic ion name. Step 2 If the metal is to the right of group IIA, then a Roman numeral is used after the metal to describe the charge of the metal. Except Ag, Zn, and Al. Examples NaOH Sodium hydroxide Fe(SO4)2 Iron(II) sulfate Fe(NO3)3 Iron(III) nitrate Zn(C2H3O2)2 II. Nonbinary Ionic compounds Nonbinary means more than two different elements Step 1 First give the name of the metal, followed by the memorized polyatomic ion name. Step 2 If the metal is to the right of group IIA, then a Roman numeral is used after the metal to describe the charge of the metal. Except Ag, Zn, and Al. Examples NaOH Sodium hydroxide Fe(SO4)2 Iron(II) sulfate Fe(NO3)3 Iron(III) nitrate Zn(C2H3O2)2 Zinc acetate III. Binary molecular Compounds Molecular means nonmetals Step 1 First give the name of the first nonmetal, followed by the nonmetal name using the “ide” suffix. Step 2 Give each nonmetal a Latin prefix describing the number of atoms present in the compound. Examples CO P2O5 CO2 CCl4 You will need to learn the Greek numerical prefixes (Table 4.6): Number 1 2 3 4 Prefix Mono-* DiTriTetra- 5 6 7 8 PentaHexaHeptaOcta- 9 Nona- 10 Deca- *Note 1 Compound names never start with mono Note 2 When adding a prefix two vowls cannot next to each other III. Binary Molecular Compounds Molecular means nonmetals Step 1 First give the name of the first nonmetal, followed by the nonmetal name using the “ide” suffix. Step 2 Give each nonmetal a Latin prefix describing the number of atoms present in the compound. Examples CO Carbon monoxide P2O5 CO2 CCl4 III. Binary Molecular Compounds Molecular means nonmetals Step 1 First give the name of the first nonmetal, followed by the nonmetal name using the “ide” suffix. Step 2 Give each nonmetal a Latin prefix describing the number of atoms present in the compound. Examples CO Carbon monoxide P2O5 CO2 Carbon dioxide CCl4 III. Binary Molecular Compounds Molecular means nonmetals Step 1 First give the name of the first nonmetal, followed by the nonmetal name using the “ide” suffix. Step 2 Give each nonmetal a Latin prefix describing the number of atoms present in the compound. Examples CO Carbon monoxide P2O5 CO2 Carbon dioxide CCl4 II. Binary Ionic molecular Molecular means combination of nonmetals Step 1 First give the name of the first nonmetal, followed by the nonmetal name using the “ide” suffix. Step 2 Give each nonmetal a Latin prefix describing the number of atoms present in the compound. Examples CO Carbon monoxide P2O5 Diphosphorus Pentoxide CCl4 CO2 Carbon dioxide II. Binary Ionic molecular Molecular means combination of nonmetals Step 1 First give the name of the first nonmetal, followed by the nonmetal name using the “ide” suffix. Step 2 Give each nonmetal a Latin prefix describing the number of atoms present in the compound. Examples CO Carbon monoxide P2O5 Diphosphorus Pentoxide CCl4 Carbon tetrachloride CO2 Carbon dioxide III. Nonbinary Molecular Compounds Note: Do not use Latin prefixes Step 1 Write down the memorized polyatomic ions present in the compound. Step 2 Look to see if any monatomic ions are present. If so, then cations use the normal name. If it is an anion, then its name comes last with the “ide” suffix. Examples NH4Cl NH4OH III. Nonbinary Molecular Compounds Note: Do not use Latin prefixes Step 1 Write down the memorized polyatomic ions present in the compound. Step 2 Look to see if any monatomic ions are present. If so, then cations use the normal name. If it is an anion, then its name comes last with the “ide” suffix. Examples NH4Cl NH4OH Ammonium chloride III. Nonbinary Molecular Compounds Note: Do not use Latin prefixes Step 1 Write down the memorized polyatomic ions present in the compound. Step 2 Look to see if any monatomic ions are present. If so, then cations use the normal name. If it is an anion, then its name comes last with the “ide” suffix. Examples NH4Cl Ammonium chloride NH4OH Ammonium hydroxide Compounds that Start with Hydrogen Case 1 If the anion ends in “ide” and it is aqueous, then use the prefix hydro and suffix “ic acid” Case 2 If the anion ends in “ate” then drop it and add the suffix “ic acid” Case 3 If the anion ends in “ite” then drop it and add the suffix “ous acid” Case 4 If the anion ends in” ide” and is a gas, or liquid, then leave the name and do not use Latin prefiex Compounds that Start with Hydrogen Examples HCl (aq) HNO3 HNO2 H2O (l) HCl (g) Compounds that Start with Hydrogen Examples HCl (aq) chloride HNO3 HNO2 H2O (l) HCl (g) Compounds that Start with Hydrogen Examples HCl (aq) chloride HNO3 HNO2 H2O (l) HCl (g) chloric acid Compounds that Start with Hydrogen Examples HCl (aq) chloride HNO3 HNO2 H2O (l) HCl (g) chloric acid hydrochloric acid Compounds that Start with Hydrogen Examples HCl (aq) chloride HNO3 HNO2 H2O (l) HCl (g) nitrate chloric acid hydrochloric acid Compounds that Start with Hydrogen Examples HCl (aq) chloride HNO3 HNO2 H2O (l) HCl (g) nitrate chloric acid nitric acid hydrochloric acid Compounds that Start with Hydrogen Examples HCl (aq) chloride HNO3 nitrate HNO2 nitrite H2O (l) HCl (g) chloric acid nitric acid hydrochloric acid Compounds that Start with Hydrogen Examples HCl (aq) chloride chloric acid HNO3 nitrate nitric acid HNO2 nitrite nitrous acid H2O (l) HCl (g) hydrochloric acid Compounds that Start with Hydrogen Examples HCl (aq) chloride chloric acid HNO3 nitrate nitric acid HNO2 nitrite nitrous acid H2O (l) oxide HCl (g) hydrochloric acid Compounds that Start with Hydrogen Examples HCl (aq) chloride chloric acid hydrochloric acid HNO3 nitrate nitric acid HNO2 nitrite nitrous acid H2O (l) oxide hydrogen oxide HCl (g) Compounds that Start with Hydrogen Examples HCl (aq) chloride chloric acid hydrochloric acid HNO3 nitrate nitric acid HNO2 nitrite nitrous acid H2O (l) oxide hydrogen oxide HCl (g) chloride Compounds that Start with Hydrogen Examples HCl (aq) chloride chloric acid hydrochloric acid HNO3 nitrate nitric acid HNO2 nitrite nitrous acid H2O (l) oxide hydrogen oxide HCl (g) chloride hydrogenchloride The End