Lipids/Fats By Jennifer Turley and Joan Thompson © 2016 Cengage Overview Categories, Chemistry, Functions & Foods of: • Fats/Lipids • Triglycerides – Fatty Acids • Phospholipids • Sterols Lipids - Fats Composition: Fats contain Carbon, Hydrogen, Oxygen • Lipids are organic compounds • Lipids are soluble in fat Categories of Lipids: 1. Triglycerides 2. Phospholipids 3. Sterols Triglycerides “Fats”, Part 1 • Energy Yield: Fats provide 9 Calories/gram. – Fats are the only type of lipid that the body can convert to ATP or produce energy from. – Fats are the most Calorically Dense energy-producing nutrient. Triglycerides “Fats”, Part 2 • Caloric density: Refers to the Calories yielded per weight of the substance. – Triglycerides (dietary fats) provide 9 Calories per gram while proteins and digestible carbohydrates provide 4 Calories per gram and alcohol provides 7 Calories per gram. Triglyceride Model Actual Triglyceride Categories of Fatty Acids Dietary fats are defined by the composition of the fatty acids in the triglyceride. 1. Saturated fat food sources are comprised of mostly saturated fatty acids (SFAs). 2. Monounsaturated fat food sources are comprised mostly of monounsaturated fatty acids (MUFAs). 3. Polyunsaturated fat food sources are comprised mostly of polyunsaturated fatty acids (PUFAs). Examples of Fatty Acids Saturated Fatty Acids (SFA) • Have 0 double bonds between the carbons. • Are found in animal products, hydrogenated vegetable fats, & tropical oils (palm & coconut oils). • Are solid at room temperature & unhealthy when consumed in excess. Monounsaturated fatty acids (MUFA) • Have 1 double bond in the carbon chain • Are healthy • High levels are in olive oil, canola oil, almonds, & avocado • Become semisolid when refrigerated • Are liquid at room temperature Polyunsaturated fatty acids (PUFA) • Have >1 double bond in the carbon chain. • Some are essential for the body. • Are found in plant oils like corn, cottonseed, safflower, and sunflower oil. • Are liquid at room temperature. • Too much can promote cancer. Fat Food Sources • Oils, butter, cream, lard, margarine, dressings, cream cheese, olives, nuts & seeds are all examples of foods high in dietary fat. • Try to chose healthy fats from plant sources, like those shown on the right. Fatty Acid Composition of Common Fats Essential Fatty Acids, Part 1 • The body cannot make the essential fatty acids (EFAs). • Linoleic Acid & Alpha-Linolenic Acid. • These EFAs are found in plant oils & plant foods. • Deficiency characteristics develop when they are lacking in the diet. Essential Fatty Acids, Part 2 • The AMDR level for adults that will optimize health are: – 5-10% of Calories from Linoleic Acid – 0.6-1.2% of Calories from Alpha-Linolenic Acid • Linoleic Acid is an omega 6 fatty acid. • Alpha-Linolenic Acid is an omega 3 fatty acid. Essential Fatty Acids, Part 3 Created in food processing when PUFAs or MUFAs are partially hydrogenated. Trans Fatty Acids Functions of Fats • • • • • • Increase satiety value of a meal. Improve texture, flavor & aroma of foods. Required for fat soluble vitamin absorption. Provide the body’s major energy stores. Cushion vital organs. An essential structural component of cell membranes. • Provide insulation. Fat: Dietary Recommendations • 20-35% of total dietary Calories should come from fats. This is the AMDR. <7% should come from SFA. Limit trans fatty acids. • All excess Calories consumed whether from carbohydrates, proteins, or fats are converted to fat & stored in fat cells. • Fat is the storage form of energy in mammals. Phospholipids (lecithin), Part 1 • Non-Energy Yield: 0 Calories per gram. Phospholipids are non-energy-producing (noncaloric) lipid substances. • Sources: Lecithin is found in egg yolk and soy products and is the most common phospholipid consumed in the diet. Phospholipids (lecithin), Part 2 Functions: 1. Phospholipids like lecithin are emulsifiers that allow water soluble & fat soluble substances to mix (like oil & vinegar). 2. Lecithin provides choline which is a component of the neurochemical acetylcholine. 3. Phospholipids are used to make cell membranes. Lecithin: A Phospholipid Actual Structure of Lecithin Cell Membrane Sterols Cholesterol is the most popular dietary sterol Non-Energy Yield: Noncaloric, 0 Calories/gram Sources of Cholesterol: 1. Exogenous: From outside the body. Cholesterol is made by animals. It is only found in animal foods & byproducts. 2. Endogenous: Made inside the human body. Exogenous Sources • Egg yolk provides ~275 mg each. • Organ meats & crustaceans such as crab, shrimp & lobster provide ~190 mg per 3 ounces. • Much smaller amounts are in the fat portions of animal meats & products like milk. Endogenous Sources • Cholesterol is a very important molecule in the body. • Cholesterol is made inside the human body, primarily in the liver, from SFA. • Usually about 1 gram (1,000 milligrams) of cholesterol per day is produced in the body. • It is a very waxy substance. Cholesterol is used to make … Part 1 Cholesterol is used to make … Part 2 • Myelin sheath that covers nerve cells. • Cell membranes. Cholesterol Recommendation • Cholesterol can be deposited in the artery walls leading to plaque buildup & heart disease. • To maintain heart health, the dietary recommendation is to limit intake to < 300 mg/day. • To improve heart health, limit intake to < 200mg/day. Some Summary Points, Part 1 • Fats/Lipids are organic compounds. • Fats/Lipids are categorized as triglycerides, phospholipids, and sterols. • Triglycerides provide 9 Calories per gram. • Triglycerides contains fatty acids that are categorized as SFA, MUFA, & PUFA. • There are 2 EFAs that are PUFAs (linoleic acid and alpha-linolenic acid). • AMDRs, omega 6 and 3 fatty acids • Triglycerides have many important functions. Some Summary Points, Part 2 • Consume 20-35% of Calories from fats & limit SFAs to <7% of Calories. • Phospholipids like lecithin, emulsify and help make up cell membranes and acetylcholine. • Cholesterol is found in animal foods. It is not essential and can be made in the liver. It has many important functions in the body but intake should be limited to less than 300 mg/day. References for this presentation are the same as those for this topic found in module 1 of the textbook