Thermal Analysis of Single Walled and Double Walled Beverage Containers by Peter Tu An Engineering Project Submitted to the Graduate Faculty of Rensselaer Polytechnic Institute in Partial Fulfillment of the Requirements for the degree of MASTER OF ENGINEERING Major Subject: Mechanical Engineering Approved: _________________________________________ Professor Ernesto Gutierrez-Miravete, Project Adviser Rensselaer Polytechnic Institute Hartford, Connecticut December, 2014 i © Copyright 2014 by Peter Tu All Rights Reserved ii CONTENTS LIST OF TABLES ............................................................................................................ iv LIST OF FIGURES ........................................................................................................... v SYMBOLS ....................................................................................................................... vi ACKNOWLEDGMENT ................................................................................................. vii ABSTRACT ................................................................................................................... viii 1. INTRODUCTION ......................................................................................................... 1 2. Theory & Methodology ................................................................................................. 3 2.1 Theory ................................................................................................................... 3 2.2 Methodology ......................................................................................................... 4 3. Results & Discussion ..................................................................................................... 7 3.1 COMSOL Heat Transfer in Solids Model – Single Walled Cup............................... 13 4. Conclusions.................................................................................................................. 39 5. References.................................................................................................................... 40 6. Appendices .................................................................................................................. 43 iii LIST OF TABLES iv LIST OF FIGURES Figure 1: Left - Single walled cup; Right - Double walled cup Figure 2: Left – Plastic with straw, Center – Titanium with handle, Right – Ceramic Figure 3: Schematic of the heat transfer process: 1. Thermal conduction through inner wall, 2. Convection via trapped gas, 3. Thermal conduction through outer wall, 4. Energy lost to environment v SYMBOLS 𝑄 𝑡 = heat transferred over time 𝑘 = thermal conductivity of the material 𝐴 = area of the interface 𝑇 = temperature 𝑑 = thickness of the interface vi ACKNOWLEDGMENT I would like to acknowledge my family for their constant support and encouragement throughout my career and studies. I would also like to acknowledge Professor Ernesto Gutierrez-Miravete for his guidance and council as I conducted this final study. vii ABSTRACT This project documents the analytical simulations that were performed along with the collection of empirical data to confirm the validity of the claim that double walled beverage cups keep hot liquids hotter for longer periods of time than single walled cups. viii 1. INTRODUCTION The traditional cup is typically a single walled container formed to hold liquids which result can result in a rapid loss or gain of thermal energy depending on the geometry and materials used. The need for cups that were less prone to rapid heat transfer has been addressed by the invention of double walled cups. The first double walled cup patent was issued on July 22, 1969 under number 3456860 to William L. Janninck. The original design featured plastic inner and outer walls supported by circumferential and axial ribs that maintained structural integrity of the cup while minimizing heat transfer from the inner to outer wall. Modern day manufacturers now make double walled cups from a variety of materials, shapes, and sizes to distinguish their products in terms of aesthetics and functionality. Figure 1 depicts a single walled cup next to a double walled cup. Figure 1: Left - Single walled cup; Right - Double walled cup 1 Figure 2 provides examples of products from various manufacturers to illustrate diverse range of double walled cups. Figure 2: Left – Plastic with straw, Center – Titanium with handle, Right – Ceramic Based on similarity of double walled beverage cups to double paned windows, double walled cups are expected to retain heat longer than single walled cups. The feature that makes double walled cups effective at slowing the transfer of thermal energy is the layer of trapped gas that modifies the path of transfer from only conduction to two instances of conduction separated by convection. This project characterizes analytically quantifies how much more effective a double walled cup is when compared to a single walled cup. 2 2. Theory & Methodology Double walled beverage cups are promoted as being able to keep hot drinks hot and cold drinks cold for longer periods of time than single walled beverage cups. Much like double pane windows, double walled mugs capture an insulating layer of air between two layers of material and prevent thermal energy from being readily conducted through to the other side. 2.1 Theory The process of heat transfer can be simplified as follows: 1. The inner most wall of the window obtains thermal energy and transfers the energy to towards the second wall via thermal conduction 2. The gas in between the two walls then transfer the thermal energy to the second wall through convection 3. The energy is then conducted through the second wall 4. Lost to the environment via convection Figure 3 is a schematic of this heat transfer process. Figure 3: Schematic of the heat transfer process: 1. Thermal conduction through inner wall, 2. Convection via trapped gas, 3. Thermal conduction through outer wall, 4. Energy lost to environment 3 2.2 Methodology Heat transfer is the process where thermal energy is exchanged between neighboring systems in response to a temperature difference. This is in accordance to conservation of energy theory where the total energy of an isolated system remains constant and the first law of thermodynamics where the change in internal energy of a system is equal to the heat added to the system minus the work done by the system. Heat transfer is further categorized into three modes: conduction, convection, and radiation. Heat conduction is heat transfer across a medium without any motion of the material as a whole. In a solid, the mechanism of conduction is the atomic activity in the form of lattice vibration which contribution of the translational motion of electrons if the solid is electrically-conducting. Heat conduction in a liquid or gas is due to the random motion and interaction of the molecules. Examples of conductive heat transfer: the transfer of heat energy down the axis of a metal rod when one end is a higher temperature than the other; and the transfer of heat energy from a stove element through a metal pan into the contents within. The rate of heat conduction can be expressed as follows: 𝑄 𝑘𝐴(𝑇ℎ𝑜𝑡 − 𝑇𝑐𝑜𝑙𝑑 ) = 𝑡 𝑑 Where: 𝑄 𝑡 = heat transferred over time (watts) 𝑘 = thermal conductivity of the material (𝑊 ⁄𝑚 ∙ 𝐾) 𝐴 = area of the interface (𝑚2 ) 𝑇 = temperature (K) 𝑑 = thickness of the interface (m) Convective heat transfer occurs between systems by moving fluid past a wall of a different temperature. Convection can be forced or natural - for the purposes of this discussion and project, only natural will be described and used in the analysis model. 4 Natural convection occurs in accordance to the Ideal Gas Law, where a liquid that increases in temperature also decreases in density and rises. Due to the resulting internal buoyancy force, circulating currents then transport the heat energy away from the energy source. The convective heat transfer model in this study will be simplified into natural convection from a horizontal and vertical plate. The assumption is that the cup is on a level surface and the cup geometry can be approximated by a vertical wall. For a time dependent study, the natural convection across a vertical or horizontal plate is represented by the following equation: −𝑛 ∙ (−𝑘∇𝑇) = ℎ ∙ (𝑇𝑒𝑥𝑡 − 𝑇) Where: ℎ = ℎ𝑎𝑖𝑟 (𝐿, 𝑝𝐴 , 𝑇𝑒𝑥𝑡 ) (𝑊 ⁄𝑚2 ∙ 𝐾) L = plate height, length, or diameter (m) 𝑝𝐴 = Absolute pressure (Pa) 𝑇𝑒𝑥𝑡 = Externals temperature (K) Thermal radiation is a form of energy emitted by matter at a nonzero temperature and can be considered to be the propagation of electromagnetic waves or particles. For the purpose of this project, this form of heat transfer will be considered insignificant. The following inputs and assumptions were used: 1. Initial temperature of the glass, air, and surrounding environment: 70 degrees Fahrenheit or 21 degrees Celsius or 294.261 Kelvin 2. Initial temperature of the water: 212 degrees Fahrenheit or 100 degrees Celsius or 373.15 Kelvin 3. Thermal conductivity of water @ 300 Kelvin: 0.609 𝑊 ∙ 𝑚−1 ∙ 𝐾 −1 4. Thermal conductivity of glass @ 300 Kelvin: 0.8 𝑊 ∙ 𝑚−1 ∙ 𝐾 −1 5 5. Natural convection heat transfer of a horizontal plate in air at 300 Kelvin: 11.26 𝑊 ∙ 𝑚−2 ∙ 𝐶 −1 6. Natural convection heat transfer of a vertical plate in air at 300 Kelvin: 7.03 𝑊 ∙ 𝑚−2 ∙ 𝐶 −1 6 3. Results & Discussion The test specimen obtained for this project is the Kiran Tea Glass distributed exclusively by Teavana. The cup is double walled, made from borosilicate glass, and holds 8 ounces or 235 milliliters of liquid. The cup can be procured from any Teavana retail store or from the company’s internet website. Figure 4 is a picture of the cup. Figure 4: Kiran Tea Glass by Teavana The reason for selecting this cup model is due to its design being simple, axisymmetric, and being made from a clear glass material. This simplifies not only the analysis, but also eliminates complications from the analysis model. A two-dimensional sketch and three-dimensional model of the cup was created using NX 6.0, the computer-aided design software package formerly known as NX 7 Unigraphics. The inputs used to model the cup were gathered using a scale, digital caliper, and radius gages. All dimensions were gathering in the United States customary system units then converted to metric using NX. Figure 5 is a picture of the tools used to gather the dimensions of the cup being analyzed. Figure 5: Scale, digital caliper, and radius gages 8 Figure 6 is a picture of the two-dimensional sketch of the cup created using NX. Figure 6: 2D Sketch of the Kiran Tea Glass Figure 7 is a picture of the three dimensional model of the cup created using NX. Figure 7: 3D model of the Kiran Tea Glass 9 To facilitate the analysis model, a two-dimensional sketch and three-dimensional model of the water and air were also created using the curves from the two-dimensional cup sketch. As with the cup, the air and water were created in the United States customary system units then converted to metric using. Figure 8 is a picture of the two-dimensional of the air model created using NX. Figure 8: 2D sketch of the air within the Kiran Tea Glass 10 Figure 9 is a picture of the two-dimensional sketch of the water model created using NX. Figure 9: 2D Sketch of the water within the Kiran Tea Glass Figure 10 is a picture of the three-dimensional model of the air created using NX. Figure 10: 3D model of the air within the Kiran Tea Glass 11 Figure 11 is a picture of the three-dimensional model of the water created using NX. Figure 11: 3D Model of the water within the Kiran Tea Glass Figure 12 is a picture of the cup, air, and water three-dimensional models nested and cross-sectioned using NX. Figure 12: The 3D models of the cup, air, and water nested and cross-sectioned 12 While the three-dimensional models of the cup, air, and water was not necessary for the study, it was useful for predicting what the two-dimensional-axisymmetric thermal model would look like based on the two-dimensional NX model. COMSOL Multiphysics 4.2a was then used to create and solve the finite element analysis model. The geometry created using NX was imported into COMSOL via a Drawing Exchange Format (DXF) file. The heat transfer module was used to perform the heat transfer simulations. 3.1 COMSOL Heat Transfer in Solids Model – Single Walled Cup The first thermal model created in COMSOL was a time-dependent Heat Transfer in Solids study. The cup, air, and water geometry were imported into COMSOL then united and repaired to compensate for any approximations that were made when the NX files converted measurement systems and file formats. The default relative repair tolerance function in COMSOL was utilized to perform the geometry repair. The repair tolerance was set to 1e-3 millimeters. Figure 13 is a picture of the cup, air, and water after being imported and repaired in COMSOL. 13 Figure 13: The 2D sketches after importing and repairing in COMSOL Note that the same models created for the double walled cup will be used. For this singled walled cup study, the geometry that would normally be air domain was set to the same properties as the cup domain thereby creating what would be a single walled cup with the same profile as the double walled cup. This was done to eliminate any potential discrepancies a single walled cup of different geometry would have when drawing comparison conclusions between single and double walled cups. The material properties for both the glass and water were added to their respective domains from the built-in library in COMSOL. Silica glass and liquid water were the two library entries selected for this study. Figure 14 is a picture of the cup, air, and water where domains 1 and 2 are both set to silica glass and domain 3 set to liquid water. 14 Figure 14: COMSOL Built-in Materials applied to the cup, air, and water domains The thermal model is two-dimensional axisymmetric. The axis of symmetry is shown in Figure 15 by the solid blue line. Figure xyz is of the thermal model with the axis of symmetry highlighted. 15 Figure 15: COMSOL model with the axis of symmetry highlighted A thermal insulation boundary condition was added to the bottom of the cup, where it would normally rest on a surface. In this thermal model, zero heat energy was lost to the surrounding environment. Figure 16 is of the thermal model with the thermal insulation boundary condition highlighted. 16 Figure 16: COMSOL model with the thermal insulation boundary highlighted In heat transfer in solids models, any curves between materials are set to conductive heat transfer by default. The heat transfer properties were all set to the default values built into the COMSOL library. The natural convection boundary conditions were the applied. Figure 17 is of the thermal model with the natural convection past a vertical wall applied to the highlighted cup surfaces. 17 Figure 17: COMSOL model with the natural convection past a vertical wall boundaries highlighted Figure 18 is of the thermal model with the natural convection past a horizontal wall applied to the water surface. 18 Figure 18: COMSOL model with the natural convection past a horizontal plate boundary highlighted The initial temperature value of the water was set to 373.15 Kelvin. The initial temperature value of the cup was set to 294.26 Kelvin. An extra fine mesh of the thermal model was created. The mesh consists of 5917 elements. Figure 19 is of the mesh of the thermal model. 19 Figure 19: Extra fine mesh of the thermal model in COMSOL A stepped time dependent study was performed. The duration was for thirty minutes and with a minute for each step. Figure 20 is of the results of the thermal model at time = zero minutes. 20 Figure 20: Thermal model at time = zero minutes 21 Figure 21 is of the results of the thermal model at time = ten minutes. Figure 21: Thermal model at time = ten minutes in COMSOL 22 Figure 22 is of the results of the thermal model at time = twenty minutes. Figure 22: Thermal model at time = 20 minutes in COMSOL 23 Figure 23 is of the results of the thermal model at time = thirty minutes. Figure 23: Thermal model at time = 30 minutes in COMSOL After thirty minutes, the water temperature dropped approximately 40 degrees and the cup temperature rose approximately 40 degrees. Also notice that the cup temperature was at its hottest at 20 minutes, being approximately 50 degrees higher than its initial temperature. The thermal analysis model appears to be well behaved and utilizes the applied boundary conditions appropriately. 3.2 COMSOL Heat Transfer in Solids Model – Double Walled Cup The second thermal model created in COMSOL was another time-dependent Heat Transfer in Solids study. The same cup, air, and water geometry used in the single walled study were imported into COMSOL then united and repaired. The default relative 24 repair tolerance function in COMSOL was utilized to perform the geometry repair. The repair tolerance was set to 1e-3 millimeters. The material properties for the glass, air, and water were added to their respective domains from the built-in library in COMSOL. The cup, air, and water are domains 1, 2, and 3 respectively. Figure 24 is a picture of the cup, air, and water where domains 1, 2, and 3 are set to silica glass, air, and liquid water, respectively. Figure 24: COMSOL Built-in Library Materials applied to the cup, air, and water domains The thermal model is two-dimensional axisymmetric. Figure 25 is of the thermal model with the axis of symmetry highlighted. 25 Figure 25: Double Walled thermal model with the axis of symmetry highlighted A thermal insulation boundary condition was added to the bottom of the cup, where it would normally rest on a surface. In this thermal model, zero heat energy was lost to the surrounding environment. Figure 26 is of the thermal model with the thermal insulation boundary condition highlighted. 26 Figure 26: Thermal model with the thermal insulation boundary condition highlighted In heat transfer in solids models, any curves between materials are set to conductive heat transfer by default. The heat transfer properties were all set to the default values built into the COMSOL library. The natural convection boundary conditions were the applied. Figure 27 is of the thermal model with the natural convection past a vertical wall applied to the highlighted cup surfaces. 27 Figure 27: Thermal model with the natural convection past a vertical wall boundary conditions highlighted 28 Figure 28 is of the thermal model with the natural convection past a horizontal wall applied to the water surface. Figure 28: Thermal model with the natural convection past a horizontal wall boundary condition highlighted The initial temperature value of the water was set to 373.15 Kelvin. The initial temperature value of the cup was set to 294.26 Kelvin. An extra fine mesh of the thermal model was created. The mesh consists of 5917 elements. Figure 29 is of the mesh of the thermal model. 29 Figure 29: Extra fine mesh of the thermal model A stepped time dependent study was performed. The duration was for thirty minutes and with a minute for each step. Figure 30 is of the results of the thermal model at time = zero minutes. 30 Figure 30: Double walled cup thermal model at time = zero minutes 31 Figure 31 is of the results of the thermal model at time = ten minutes. Figure 31: Double walled cup thermal model at time = ten minutes 32 Figure 32 is of the results of the thermal model at time = twenty minutes. Figure 32: Double walled cup thermal model at time = 20 minutes 33 Figure 33 is of the results of the thermal model at time = thirty minutes. Figure 33: Double walled cup thermal model at time = 30 minutes After thirty minutes, the water temperature dropped approximately 10 degrees and the cup temperature rose approximately 15 degrees. The thermal analysis model appears to be well behaved and utilizes the applied boundary conditions appropriately. 3.2 Measured Data Boiled water was added to the Kiran Tea Glass on hand and measured incrementally as it cooled off. The data is available in Appendix 1. A graph of the measured temperature versus time can be seen in Figure 34. 34 Temperature (K) 370.00 360.00 350.00 340.00 Temperature (K) 330.00 320.00 310.00 300.00 Time (s) Figure 34: Graph of the measured temperature of boiled water in the Kiran Tea Glass The double walled thermal model was then updated to replicate the measured data by changing the ambient and initial temperatures. The results are as follows. 35 Figure 35: Double walled thermal model updated inputs at time = 10 minutes 36 Figure 36: Double walled cup with updated inputs at time = 20 minutes 37 Figure 37: Double walled cup with updated inputs at time = 30 minutes 38 4. Conclusions The water in the double walled cup exhibited a lower rate of thermal energy loss to the surrounding environment than the single walled cup. The non-wetted surfaces of the double walled cup also gained thermal energy slower than the single walled cup for the duration of the analysis. The measured data also verified that the thermal model was well behaved and a close representation of the physical specimen. In conclusion, double walled cups are indeed more effective at keeping hot liquids hot for longer periods than single walled cups. The layer of air between two walls of glass allow the double walled cups to perform in a similar fashion to double pane windows. Also, single walled cups meant for hot liquids most often feature a handle which aligns with the need for the user to have a way to hold the cup without being exposed to hot surfaces. 39 5. References Janninck, W.L. (1969). U.S. Patent No. 3456860. Washington, DC: US Patent and Trademark Office. http://www.google.com/patents?id=qJ9ZAAAAEBAJ&printsec=abstract&zoom=4#v=o nepage&q&f=false The big one 2004. (2003). Catering Update, , 25-26,29-30. Retrieved from http://search.proquest.com/docview/223152167?accountid=37764 Emily, B. Y. (2012, Mar 22). McDonald's testing paper cups for hot drinks. McClatchy Tribune Business News. Retrieved from http://search.proquest.com/docview/929381998?accountid=37764 Young, C. (2011). Building a double wall. Building Design & Construction, Retrieved from http://search.proquest.com/docview/1278116856?accountid=37764 Swiss inventor develops ornamental design for double wall cup. (2008, May 23). US Fed News Service, Including US State News. 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Vocations and Career Collection. Web. 29 Mar. 2013. Document URL http://go.galegroup.com.colelibprxy.ewp.rpi.edu/ps/i.do?id=GALE%7CA63411694&v=2.1&u=22507&it=r&p=GPS&s w=w "Mighty Jo travel mug -- 16 oz." Specialty Coffee Retailer June 2002: 54. Small Business Collection. Web. 29 Mar. 2013. Document URL http://go.galegroup.com.colelibprxy.ewp.rpi.edu/ps/i.do?id=GALE%7CA87692510&v=2.1&u=22507&it=r&p=GPS&s w=w Wolff, S. K. (1994). Double walled paper cup Retrieved from http://search.proquest.com/docview/34737338?accountid=37764 Singaporean inventors develop double-walled cup. (2009, Sep 18). Indian Patents News. Retrieved from http://search.proquest.com/docview/443239946?accountid=37764 Reflecting quality. (2006). Catering Update, , 30-30. Retrieved from http://search.proquest.com/docview/223134574?accountid=37764 Kiran Tea Glasses at Teavana | Teavana. Retrieved from http://www.teavana.com/teaproducts/tea-cups-mugs/glass-tea-cups/p/kiran-tea-glasses-8oz 41 R. Nave. Heat Transfer. Retrieved from http://hyperphysics.phyastr.gsu.edu/hbase/thermo/heatra.html#c1 https://www.thermalfluidscentral.org/encyclopedia/index.php/Heat_and_Mass_Transfer 42 6. Appendices 6.1 Appendix 1: Measured temperature data from boiled water in the double walled cup Time (s) 0 60 120 180 240 300 360 420 480 540 600 660 720 780 840 900 960 1020 1080 1140 1200 1260 1320 1380 1440 1500 1560 1620 1680 1740 1800 Temperature (F) 61 194 187 182 177 173 169 165 162 159 155 153 150 147 145 143 141 139 137 135 134 132 131 129 127 126 125 123 122 121 120 Temperature (K) 289.26 363.15 359.26 356.48 353.71 351.48 349.26 347.04 345.37 343.71 341.48 340.37 338.71 337.04 335.93 334.82 333.71 332.59 331.48 330.37 329.82 328.71 328.15 327.04 325.93 325.37 324.82 323.71 323.15 322.59 322.04 43