MOLES REVIEW, MAY 28 2 Al2O3 3 O2 + 2 4 Al O2 = Al = 6 2 4 6 Al = 4 2 O2 = 2 Al2O3 3 O2 + 4 Al a) What is the mole ratio of O2 to Al? O2 Al = 3 4 THE MOLE RATIOS OF SUBSTACES IN A REACTION ARE THE BALANCED REACTION COEFFICIENTS. 2 Al2O3 3 O2 + 4 Al b) If 6 mol of O2 is produced, how many moles of Al are produced? O2 = Al 3 = 6 4 X X = 8 MOL of Al 2 Al2O3 3 O2 + 4 Al c) If 6 mol of O2 is produced, how many grams of Al are produced? Moles = mass 8 = mass = 215.2g Al GFM 26.9 2 Al2O3 3 O2 + 4 Al d) What is the % by mass composition of Al2O3 ? NEVER USE COEFFICENTS FOR MOLAR MASS CALCULATION S SUBSCRIPTS ELEMENT % COMP (MASS) = PART X 100 WHOLE MULTIPLY ATOMIC MASS 26.98g/ = mol 15.99g/ = mol Al 2 X O 3 X First you need to find the molar mass (gfm) of the substance EQUALS MASS SUBTOTAL 53.96 g 47.97 g + 101.93 g/mol % COMP (MASS) = PART X 100 WHOLE % COMP Al = 53.96 g X 100 = 52.93 % 101.93 g ELEMENT SUBSCRIPTS MULTIPLY ATOMIC MASS Al 2 X O 3 X 26.98g/ = mol 15.99g/ = mol EQUALS MASS SUBTOTAL 53.96 g 47.97 g 101.93 g/mol REVIEW CLASS MULTIPLE CHOICE QUESTIONS, FRIDAY JUNE 1 2007 #7) CALCULATE THE MOLECULAR FORMULA OF A COMPOUND THAT IS CH, GIVEN MOLECULAR MASS IS 78 G/MOL. ELEMENT SUBSCRIPTS MULTIPLY ATOMIC MASS C 1 X H 1 X 12.01g/ = mol 1.007g/ = mol THIS IS THE MASS (GFM)OF THE EMPIRICAL FORMULA EQUALS MASS SUBTOTAL 12.01 g 1.007 g + 13.017 g/mol REVIEW CLASS MULTIPLE CHOICE QUESTIONS, FRIDAY JUNE 1 2007 GIVEN IN PROBLEM #7)CONTINUED MOLAR MASS 78. g/mol = EMPIRICAL MASS CH X 6 = C6H6 = 13.017 g/mol 5.99 = 6 THIS MEANS THAT THE MOLECULAR(TRUE) FROMULA IS 6 TIMES AS LARGE AS THE EMPIRICAL(SIMPLEST) FORMULA. MULTIPLY THE SUBSCRIPTS OF THE EMPIRICAL FORMULA BY 6. REVIEW CLASS MULTIPLE CHOICE QUESTIONS, FRIDAY JUNE 1 2007 #10) CALCULATE THE FORMULA OF A COMPOUND THAT IS 85% SILVER and 15% FLUORINE BY MASS. ELEMENT MASS Ag 85 g / 107.86g/mol =0.7880 F 15 g / 18.99 g/mol =0.7898 / 0.7880 = 1.0 / ATOMIC MASS Assume 100g of the sample, this will allow you to assume 85% is 85 grams. Total mass does NOT affect % composition. RAW RATIO DIVIDE BY SMALLEST SUBSCRIPT RATIO / 0.7880 = 1.0 Ag1F1 AgF #23) CALCULATE THE LITERS OF AMMONIA (NH3) GAS FORMED FROM 20 LITERS OF N2 GAS REACTED in the reaction given below. 3 H2 (g) + N2 (g) 2 NH3 (g) NH3 (g) N2 (g) = 2 1 X liters = 20 X = 40 Liters of ammonia gas GAS VOLUMES CAN EXIST IN A RATIO AS DEFINED BY THE COEFFICIENTS OF THE BALANCED EQUATION, RATIO AS YOU WOULD RATIO MOLES! THIS ASSUMES P AND T ARE CONSTANT. #28) WHAT IS THE MOLARITY OF A SOLUTION OF KNO3 (MOLECULAR MASS=101) THAT CONTAINS 404 GRAMS OF KNO3 IN 2.00 LITERS OF SOLUTION? MOLES = MASS GFM MOLES = 404. g = 4mol KNO3 101. g/mol MOLARITY = MOLES VOLUME MOLARITY = 4 mol 2.00L = 2.00M #15) The density of a gas is 3.00 g/L at STP, WHAT IS THE GFM OF THE GAS? 3.00 g 1 LITER DENSITY RATIO, GIVEN X = 22.4 LITERS 1 MOLE = 22.4L THE MASS OF 22.4 L IS THE MOLAR MASS AT STP = 67.2 g/mol