CHAPTER 8- Practice Exercise Albert Kweyete 1. Use the following given atomic radii to estimate the bond lengths between elements in molecules. molecule bond bond length (A0) atomic radii(A0) PBr3 P - Br P= 1.10 NaCl Na-Cl H=0.37 CH4 C-H Cl=0.99 CH3OH C-O C=0.77 O-H O=0.7 Cl2 Cl-Cl Na=1.86 N=0.75 Br= 1.14 2. Using atomic radii table predict which will have greater (circle one) bond length. a) C-H , O-H b) H-Cl , H-Br c) P-Cl , C-N d) P-Cl , P-Br e) N-H , S-H f) N-C , N-O 3. Refering to periodic table, arrange the following atoms in order of increasing or decreasing. a) increasing atomic size: Na, F, P, Ca b) increasing first ionization energy: Li, Na, k, Rb, Cs c) increasing second ionization energy: K, Al, Mg, C d) decreasing metallic properties: Cl, K, P, Mg e) increasing nonmetallic properties: Cu, Sr, I, N f) increasing electron affinity : N, O, Be, K g) decreasing electronegativity: Cl, I, S, O h) increasing electropositivity: S, C, Mg, Al 4. Write the chemical formula for the following oxides. a) aluminum oxide b) sodium peroxide d) zinc peroxide e) phosphorous pentoxide c) sodium superoxide f) manganese dioxide 5. Identify the following oxides as acidic(non-metallic), basic(metallic) , or amphoteric oxides. a) ZnO b) Na2O c) P4O6 d) CaO e) SO3 f) Al2O3 g) NO h) CoO 1 6. Write a balance equations that predict the reactions of solid zinc with the followings: a) HCl b) H2 c) H2O d) Cl2 e) O2 f) S g) FeSO4 h) conc. HNO3 i) conc. H2SO4 j) dil. H2SO4 7. Write the balanced chemical equations for the reactions of the followings ; a) SO3 + KOH b) P4O6 + H2O c) CO2 + NaOH d) CuO + HCl e) K2O + H2O f) BaO + H2O g) ZnO + HCl h) Mg + dil.H2SO4 i) Al + Cl2 j) Ca + H2 k) Ba + O2 l) Na + O2 heat m) N2O3 + H2O n) H2O2 o) K + S p) H2 + Br2 8. Complete and balanced the following reactions. a) K + ..... KOH + H2 b) SO2+1/2O2+H2O ....... c) Ca + ..... CaO d) Fe + Cl2 FeCl3 + ...... e) .....+ H2O H3PO4 f) Na + O2 ........ g) SO2+NaOH Na2SO4 +.... h) HCl + HClO Cl2 +.... i) Mg + H2O MgO + .... j) Ca + H2O Ca(OH)2 +..... 9. Predict whether each of the following oxide is ionic or Covalent molecular. a) SiO2 b) P2O5 c) Cr2O3 d) BeO f) CoO 10. Consider the following elements: Cl, N, Mg, S . Identify : a) largest in size b) most metallic c) highest in ionization energy d) highest in electronegativity e) highest electron affinity f) most reactive with water g) with water gives basic oxide h) has 7 valence electrons i) has an ionic forms with charge of -2 2