PRINT NEATLY Alias Name_________________ Real Name (Optional) ___________________ ____ ____ ____ ____ ____ ____ ____ ____ ____ ____ Total Score:_____ _____________________________________________________________ Chemistry 1201 Section 4 Spring 1999 Professor Russo Exam #1 Type of exam: Take-home. You can work with anyone on this exam, including me! You better know how to do these problems, though. You will probably see similar problems again. If this kind of material seems completely hopeless to you, you may wish to transfer to Chem 1001, then return to try 1201 another semester. Don't give up too easily; we will help you. Due: Thursday, January 28 at the beginning of class. 100 points. Show your work neatly. We will not grade papers that just show an answer, nor can we assign partial credit if we don't see the work. ________________________________________________________________________ Question #1. (BLB Text 1.12) In 1807 Humphry Davy passed an electric current through molten potassium hydroxide and isolated a bright, shiny, reactive substance. He claimed the discovery of a new element, which he named potassium. In those days, before the advent of modern instruments, what was the basis on which one could claim that a substance was an element? Be skeptical and critical like a good scientist. Your answer must fit in this box! Question #2. (related to BLB Text 1.24-c) The density of a piece of ebony wood is 1.20 g/cm3. What is the volume of 4.23 pounds of ebony wood? Express your answer in cubic meters. __________________ Put your answer here Chem 1201 Sec. 4 Exam #1 Page 1 PRINT NEATLY Alias Name_________________ Real Name (Optional) ___________________ Question #3. (BLB Text 1.30-c) Mercury is a liquid metal that freezes at 234.28 K. What is its freezing point in oF? __________________ Put your answer here Question #4. Someone tells you there are 107 seconds in one year. Compute the percent error in this assessment. __________________ Put your answer here Question #5. (BLB #1.38) Carry out the following operations and express the answers with the appropriate numbers of significant digits. (a) 320.55 - (6104.5/2.3) = __________________________ (b) [(285.3 105)-(1.200 103)] 2.8954 = __________________________ (c) (0.0045 x 20,000.0) + (2813 x 12) = __________________________ (d) 863 x [1255 - (3.45 x 108)] = __________________________ Chem 1201 Sec. 4 Exam #1 Page 2 PRINT NEATLY Alias Name_________________ Real Name (Optional) ___________________ Question #6. This problem deals with how errors or uncertainties propagate from one measurement to the next. A certain quantity used in the measurement of polymers is usually given the Greek symbol, . The mass of the polymer molecules is proportional to the square of this property--i.e., m . Suppose that you measure = 1.015 0.020 where the indicates the uncertainty of the measurement. (This is best obtained by repeating the measurements). Based on the uncertainty in , what is the percentage uncertainty in the measurement of m? __________________ Put your answer here Question #7. (BLB Text 1.48) The maximum allowable concentration of carbon monoxide in urban air is 10 mg/m3 over an 8-hour period. At this level, what mass of carbon monoxide in grams is present in a room measuring 8 12 20 feet? (Hint: the 8 hour time span has nothing to do with the answer). Show your work! __________________ Put your answer here Chem 1201 Sec. 4 Exam #1 Page 3 PRINT NEATLY Alias Name_________________ Real Name (Optional) ___________________ Question #8. (BLB Text 1.63-c) A brass sphere has a radius of 2.37 cm. If the density of brass is 8.47 g/mL what is the mass of the sphere? (The volume of a sphere of radius R is given by V = 4R3/3). __________________ Put your answer here Question #9. (BLB Text 1.64) An 8.47 g sample of solid is placed in a 25.00-mL flask. The remaining volume in the flask is filled with benzene in which the solid is insoluble. The solid and benzene together weigh 24.54 g. The density of the benzene is 0.879 g/mL. What is the density of the solid? 25.00 mL ; Total mass: 24.54 g Solid: 8.47 g __________________ Put your answer here Chem 1201 Sec. 4 Exam #1 Page 4 PRINT NEATLY Alias Name_________________ Real Name (Optional) ___________________ Question #10. Is ink an element, compound or mixture? Defend your answer briefly in the box provided. Your answer must fit in this box! Chem 1201 Sec. 4 Exam #1 Page 5