CALIFORNIA S'I'A'l'E UNIVERSI'l'Y 1 NORTHRIDGE TEACHING UNIT: ENVIRONHENT2\J.. HEALTH II AND 1\.IR POLLUTION LEVEL:· JUNIOR HIGH SCHOOL A Graduate Project submitted in partial fulfillwe:;.t of the requirements for the degree of Master of Se:i.E~nce in Hec~l th Science by Henry James Rollins June 1974 The Graduate Project of.Hel1ry,,,:rarnes-Rollins is approved by: California State Uni~ersity, Northridge June 1974 I j I '" ,_,____ ,,,,,.,,,,,,,.• --·-·--- ,., .... , .............. ·--- ---- .. ----·-· " ...... ""''' .... _________ _j ii "The nineteen-seventies absolutely must be the years when fu~erica pays its debt to the past by reclaiming the purity of its air, its waters and our living environment. It is literally now or never." Richard M. Nixon, January 1, 1970 iii 'I'ABLE OF CONTEN'I'S Pag·.~ I.IS'I' OF' TABLES • vi. .LIST OF FIGURES vii Chap-ter I. CO!~CEP'I'S v OBJECTIVES AND RELNL'ED :t-1lir1'ERIAL • 1 II. PICTURES, INCSUDING CAPTIONS 3 III. IV. ... ' "' SUGGESTIONS FOR TEACHERS ON USING SLIDES BACKGROUND 28 30 MA'rERII~L 30 Introduction Natural Sources of Air Pollution Man-made Sources of 1\ir Pollution 34 Transportation Sources 34 Stationary S6urces 38 Radioactive lo;'astes 45 Biological Poisons 45 Lead 45 Air Pollution and Ih.unan Health 46 Particulate Matter 46 Gases . 51 Disease Associated with Air Pollution 55 Effect of Radioactivity on Human Life 57 Presticid.es 59 Lead 59 Air Pollution and the Environment . 60 Summary . 62 iv · Page Chapter v. VI. 6 REFERENCES 1: ·.;; PHOTO CREDITS 70 v I.IS'l' OF TABLES Table Page ..... 1 Composition of the Earth's Atmosphere. 2. Amounts of Air Pollution in the United States - 1966 o o • o • o • vi .. •. " 32 39 o LIS'r OF FIGURES Page Figure 1. Inversion Layer . . 35 2. Comparison of Emissions from Motor Vehicles and Emissions from Stationary Sources 37 3. Projected Fine Partiule Emissions from Coal-fired Utility Boilers ... 41 4. Carbon Monoxide: Number of Days Per Year Levels Equaled or Exceeded in L.A. Basin. . 42 Oxides of Nitrogen: Number of Days Per Year N0 2 and NO~ Equaled or Exceeded Various Levels ln the L.A. Basin . . 43 Ozone: Number of Days Per Year With Highest Concentration Equal To or Greater Than J.Jevels Shown in the L.A. Basin 44 7. Clearing Mechanisms of the Human Lungs for Particulates . . . . . . . 47 8. Deposition of Partie] es Re,tai.ned by the Human Body . . . . . . . 48 9. Sizes of Particles in Microns 50 Effects of Radioactivity on Man 58 5. 6. 10. vii CHAPTER CONCEPTS, OBJECTIVES lmD .L ~.ELATED HATERIALS The concept. which follows is t.he main idea that :students .should develop about ai:c pollution crnO. health after participating in the unit. The :mat.erial in the unit :designed to empba.size the major concept. Behavioral obj ectivcs serve as a guide for t.he evaluation of t.he student 1 s achievement of the :main concept. l:. . . ..:J' . - OJ]ectlves h •Be.avloral 1nu~cate and the cognit~ve +-' ~ne content to b.e covere d behavior sought in the student. Air pollution can be detrimental to man's health. CONCEP'I': .BEHAVIORAL OBJEC'riVES A. After vievving Uw slides, the st.udents \vill be able to dis·tingui.sh l::an-made versus na·tural forms of air pollu·ti.on. a) definition of a.ir pollution b) natural forms of air pollution c) B. _major sources of man-made pollution 1. transportation 2. stationary sources After viewing the slides, the student will be able to swnmarize the adverse physiological effects of air pollution to man. a) overview of pollution related respiratory diseases b) effects on human heart and circulatory system. __.... _..... " ......... g)_ --~ye irritation 1 2 c. D. i .. ···- - --------. ·-·- --·-. After viewing the slides, the student will be able to identify major air pollutants. a) sulfur compounds b) carbon compounds c) nitrogen compounds d) ozone e) lead f) radioactivity After viewing the slides, the student will be able to describe the dangers of air pollution to man's environment and its effec·t on his well-being. a.) effects on animals b) effects on plants c) effects on materials (economic effects) t-~------·· -~~ .__,_- ··--.. ~-~~"'-·--·· ---··---- ~------~--------~·-·--···--·~---~------------------·--~-----~---·--··-- ----------~--- ·- .... ~~-------~--------···-····-- ···-·' CHAPTER II PICTURES, INCLUDING CAPTIONS 1. This is Our Planet Earth from 98,000 Nautical Miles in Space with Clouds Clearly Visible in its Thin Envelope of Air. Of All the Materials Taken In By Your Body, Approximately 8 Percent is Food, 12 Percent is Water and 80 Percen~ is Air. You Can Live Without Food About 3 Months, Without jwater a Few Days, But You Could Only Survive a Few Minutes lWithout Air. 3 4 2. Webster's Dictionary Defines Air As "The Mixture of Invisible, Odorless, Tasteless Gases That Surrounds the arth." When Wa s the Last Time You Can Remember That the ir You Were Breathing Fulfilled That Definition? 3. Our Air is Composed of About 21 Percent Oxygen, 78 Percent Nitrogen and 1 Percent Other Gases. A Portion of that 1 Percent is Put There by Man. Some of the Gases Added to the Atmosphere Can Be Harmful to Both Plant and Animal ife. 5 4 . Natural Forms of Air Pollution Have Existed Since the Beginning of the Earth. Volcanoes Spew Forth Assorted Gases and Particles in the Air. 5. Forest Fires Are a Source of Carbon Dioxide, Carbon Monoxide and Particulates Like Smoke. 6 6 . Dust Storms Across the Desert Stir Up Many Particles and Put Them Into the Air. You May Have Seen "Dust Devils,' Small Whirlpools of Air, Draw Dust and Paper Upward. ,~ 7. If You Know Someone Who Has Hayfever, Ask Them About th Effect of Another One of Nature's Pollutants -Pollen. 7 ------------- 8. Nature Has Many Different Ways of Polluting the Air. Before Man Began to Form Great Cities, Build Large Industries and Drive the "Horseless" Carriage, Nature Was Able to Scatter Her Pollutants Over Large Areas and Dilute Them. 9. When Cabrillo Sailed Into What Was to Become LosAngeles, He Noticed the Invisible Ceiling that Nature Put Over Some Areas, the Smoke from the Indian's Fires Rose Straight Up But Leveled Off, Going No Higher. This Strange Occurrence Was Later to be Called By Scientists, An Inversion Layer. 8 10. The Adiabatic Line Shows How Temperatures Normally Decrease the Higher One Goes Above the Ground. This Allows for the Dispersal of Gases By the Winds Into the Air. When High Pressure Cells Move In Over An Area, Like Los Angeles, the Air Drops Toward the Ground. As It Drops, the Air Becomes Warm, Changing the Normal Pattern of Low Temperatures Above the Ground. The Lower This Subsidence Inversio Layer Is, the Smaller the Area for Pollutants to Mix Since They Will Not Pass. Through the Layer. - - - - - - - - - - ·.--- - - - - - - - - - . WARM AIR """.,. ;..· •: ~ t. ·~- ;;I • . ~ . 11. Another Type of Inversion Layer is Created At Night, the Ground Cools the Air Surrounding It, Leaving Warmer Air Above. This Inversion Layer Also Keeps Air Pollutants From Dispersing. 9 The World's Number One Polluter is Man- You and I. here Are Over 90 Million Automobiles in the United States. he Internal Combustion Engine Which Powers Most Cars nstitutes the Largest Source of Carbon Monoxide, Hydroarbons, and Nitrogen Oxides To Our Air. All of These Are otentially Harmful to Your Health. ,r Burning of Fossil Fuels Such As Coal and Oil is the gest Source of Sulfur Oxides and Particulate Matter in Atmosphere. 10 The Sun's Energy Changes Some Pollutants Into Dif eren orms. These Are Called Photochemical Pollutants. Nitroge ioxides and Ozones Are Good Examples of this Class of Irritating Gas. c Sometimes One is Able to Identify an Air Pollutant By Its Color. Usually, Nitrogen Dioxides Are llowish Brown, While Sulfur Dioxide, Ozone and Carbon oxide Are Colorless. Particulate Matter is Usually sponsible for the Color of Smoke. Perhaps a More Important Effect of Particulate Matter in the Atmosphere Is To Cut Down Visibility. 15. The Following Slides Include a Summary of the Major Pollutants With Which We Will Be Dealing. Carbon Monoxide and Hydrocarbons Are Two Groups of Carbon Compounds. We Usually Don't Think of Carbon Dioxide As An Air Pollutant Since It Is Present In Unpolluted Air. Their Primary Sourc _Is Automobiles. ! --------------------------------------------------~ 11 16. Nitrogen Dioxides and Ozone Are Photochemical Pollutan s. I r l 17. Sulfur Oxides Are Formed From the Burning of Fossil Fuels. 12 18. Particulate Matter, For Example Carbon Particles In Smoke, Comes In Different Sizes. The Smaller the Particles the Longer They Will Remain in the Air and the Further They ill Be Dispersed. Tiny Particles Are Taken Deep Into 'the Lungs Where the Body Is Less Able to Remove Them. These Small Particles May Carry Additional Poisons Into the Body. 19. Lastly, There Are Two Major Air Pollutants Which We Haven't Mentioned. Both Are Potentially Dangerous To Human Life. The First Is Radiation Which Is Produced By Atomic Fission Such As In An Atomic Bomb Explosion. 13 20. The Other Is Pesticides, Chemicals Designed To Protect Our Food Supply But Possibly . Damaging Human and Animal Life in the P 21. The Potential Danger of Air Pollution to Human Life Can Best Be Seen in Past Disasters Involving Air Pollution. In 1930, the Highly Industrialized Meuse Valley of Belgium Was Covered by a Temperature Inversion Which Led To a High Concentration of Atmospheric Pollutants. Irritation of the Lungs and Throat Were Experienced by Residents of the Area. The Elderly and Persons With Respiratory and Heart Diseases Were Most Affected. Six Thousand People Became Ill and Sixty Died During a Four - Day Period. The Year 1948 Saw a Fog Cover Donora, Pennsylvania. Many of the Citizens Experienced Respiratory Irritation and Other Assorted Illnesses. The Death Rate Rose That Year. London Was Covered for Four Da ys By a Fog in 1952. Statistics Revealed Later That Over Three Thousand Deaths Occurred During a Seven Day Period . London Suffered Another Major Attack of Air Pollution in 1962. 14 22. New York Suffered Similar Problems in 1953 and 1962. Here Again, the Peo ple Hardest Hit Were Those With Respiratory Diseases and Elderly Persons. 23. Air Pollution Can Be Responsible For Many of the Minor Irritations Suffered by Persons Living in Polluted Air. Perha ps You Have Experienced Some of These Same Symptoms Without Apparent Cause. 15 24. This is the Lung From What Might Be Called Mr. Typical Nonsmoker, City Dweller. The Dark Spots in the Lung Are From Air Pollution Breathed In During the Person's Lifetime Contrast This With the Lu ng on the Following Slide From a Person Who Died of Lung Cancer. 25. Lung Cancer Rates Have Risen During the Past Thirty Years. Although the Rate is Much Higher for Smokers Than Nonsmokers, People That Live in the City Are More Likely to Get This Disease Than Their Country Friends. The Whitish Area Is Cancer. This Lung Also Shows Darkening From Emphysema. I I 26. This is a Close-up View of Cancer That Developed in the Bronchial Tube That Leads Into the Lungs. The White, Cone-shaped Tissue Is the Cancer. Usually a Cancer Like This Goes Unnoticed Until It Is So Big That It Begins to ause Pain. By This Time, It Would Have Spread To Other arts of the Body. Approximately One Out of Every Twenty Persons Identified As Having The Disease Is Cured. NORMAL LUNG 27. Normally Tiny Air Sacs in the Lung, Called Alveoli eceive Air From the Respiratory System's Airways. It Is rom These Air Sacs That Oxygen Passes Into the Blood In xchange For Carbon Dioxide. These Alveoli Are the Main oints of Entry for Air Pollutants Into the Body. 17 r 28. Notice the Very Small Air Sacs and Coloring of This Normal Lung. ', 29. In Emphysema, the Air Sacs Break Down. Notice the Large Appearing Holes Which Were At One Time Like the Tiny Air Sacs in the Lung Just Viewed. 18 30. Large Air Sacs Cannot Exchange Gases Properly. The Lung Loses Its Elasticity and the Person With Emphysema Finds It Very Difficult to Breathe. 31. Other Respiratory Disease Associated With Air Pollution Are Chronic Bronchitis and Bronchial Asthma Which Causes Extra Effort in Breathing. All of These Conditions Become More Severe in High Pollution Areas. 19 32. Radiation Destroys Living Cells. Broken Carriers of Heredity May Pass On Harmful Information to Other Cells Whe Dividing. Excessive Radiation Exposure Could Corne From Fallout of an Atomic Bomb. Atomic Wastes From Nuclear Powe Plants Are Also a Potential Hazard. Research for Better Controls is Now Being Conducted. 33. Pesticides, Which Are Used to Kill Insect Pests and eeds, Find Their Way Back to Man Either Directly Through the Air or Through His Food. Studies Have Shown That Pesti cides Are Spread by High Winds Above the Surface of the Earth. Man~s Food Supply May Become Contaminated by These Poisons. Thousands of Small Organisms at the Beginning of This Food Chain May Take in Small Amounts of a Poison. As These Organisms Are Eaten By Larger Creatures, the Poisons May Become More Concentrated. Man, at the End of the Food Chain, Could Get ..a Harmful Dose. \' I 20 34. Air Pollutants Corrode, Tarnish, Crack, Weaken and Discolor Many Materials in Our Environment. Ozone Attacks ubber and Causes It To Crack. It Also Damages Cloth and Discolors_nva.. - -1 - 35. Plants and Animals Are Involved in- an Intricate "Carbo i11 p ioxide-oxygen" cycle in Which Plants Use Carbon Dioxide and ~ roduce Oxygen. Animals Use Oxygen and Produce Carbon Dioxide. As We Destroy More Plants By Cutting Them Down ~nd Poisoning Them, We Are Po.t entially Destroying This Cycle. ~ s Yet, There Is No Noticeable Change in the Amount of Oxyge' On Earth. I 21 36. Ozone in the Air Prevents Certain Sensitive Pine Trees From Making Food By Use of the Sun's Energy. Pines Above Los Angeles Are Dying Out by the Acre Because of Ozone in the Air. I I 37. The Southern California Area Used To Be An Important Producer of Spinach Until Air Pollutants Rose To Levels Which Destroy the Plant. I i 22 38. Sulfur Dioxide in the Presence of Moist Air Turns Into Sulfuric Acid. This Is What Happens When a Plant Is Subjected To Sulfuric Acid in the Air. It Also Attacks Stone Statues and Other Materials in our Environment. --- I 39. As More Plants Are Destroyed and As More Fossil Fuels Are Combusted, the Carbon Dioxide Level Will Rise Since It Cannot Be Recycled Back Into Oxygen. As More and More Carbon Dioxide Remains in the Atmosphere, It Prevents Heat Waves From Leaving the Earth. This Is Called the Greenhouse Effect. If Not Counterbalanced, the Temperature of the Earth Would Rise, Causing the Ice Caps to Melt and Mass Flooding. I 23 40. Particles in the Atmosphere Reflect Sunlight Away From he Earth. Thus, Less Sunlight Will Reach the Earth. This Fould Cause a Lowering of the Earth's Temperature, Returning Us To An Ice Age. I L 41. The Rather Bleak Picture of Air Pollution Is Beginning o Become Brighter. Man Is Rallying With Extensive Research n All Areas of Pollution Prevention. Newer and Better ontrol Methods Are Being Devised. 24 42. The Automobile Is Slowly Being Cleansed of its Dangerous Pollutants. Devices Such As Catalytic Convertors Are Being Inve s tigated To Help Make Our Air Less Polluted. 43. Faster and Larger Mass Transportation Systems Being Built Will Help Lessen the Burden of Air Pollution. 25 II 44. As the Energy Crises Become More Severe, We May Reach a Crossroads of Decision-making. Should We Lower Our Pollutant Control Standards To Conserve Energy Or Will We Find Other Methods To Save Energy Which Will Not Dirty the Air? ·' I I I, 45. Science Continues Its Attempts To Keep the Air Clean. Here, An Activated Carbon Filter is Used to Pull Pollutants Out of the Air. -------~ 26 46. Better Methods of Cleaning the Air Are Being Discovered Every Day. Newer Forms of Clean Energy Sources Are Being Sought. Here a Spray Tower Is Used To Clean the Gas Passing Through It. ·' 47. Perhaps in the Near Future, Pollution Control and the Clean Air It Brings Will Once Again Allow Us To Breathe Air Which Is Not Hazardous To Our Health. This Cooling Tower Is Another Example of How Industry is Attempting to Control Pollution. The Cooling Tower Will Prevent What Has Been Called Thermal Pollution. 27 48. Together, We Should Be Able to Live in a Land Where the Air More Closely Resembles Webster's Dictionary Definition of "Invisible, Odorless, and Tasteless Gases," Where Man Has Wo~ked to Clean Up His Envir~nment, Where the United States Has Again Become -America, the Beautiful CHAPTER III SUGGESTIONS FOR TEACHERS AND USING SLIDES ; :' There is probably no one best way to teach with :slides. The presen·tat.ion may vary according ·t:o the purposes ~f the instructor and the situation under which the slides are used. To achieve maximum value from the slide present.a- ' tion, the following suggestions are being presented. A. Prepare ~~£ (1) Note organization of content. (2) Consult study guide for background information. (3) Decide methods to call attention to key words during class~ {4) List several key questions for which the slides present information. B. Help the class develop a readiness for viewing the slides-.--{1) Devise preliminary questions, perhaps a pre-post tes·t. (2) Give a brief overview of the content. {3) Relate slide presentation to students and the current field of study. (4} List major points. (5) Indicate a follow-up discussion. C. Encourage appropriate student participation durin~ showing. (1) Have students make up questions. (2) List major points. 28 29 De (3) Prepare study guide sheets. {4) •ra:ke notes. (5) Answer specific questions. Follow-up the showing with the appropriate activities. {1) Should be geared to clarifying unclear points. (2) Evaluate the extent to vllhich the original purposes were achieved. (3) Help the student solidify the learning opportunity through oral discussion and application. (a) Have students take post test. (b) Have students ask each other questions. (c) Have students write down main points. (d) Assign additional research. (e) Read an appropriate section in the textbook and compare the presentations. (5) Reshow all slides or specific portions. (6) Have students evaluate slide presentation and indicate how they would improve it and suggest how it might be used for future classes. ~~·· <-·~·· l l I CHAPTER IV BACKGROUND INFORMATION FOR 'I'EACHER 1 INTRODUCTION AIR: "'rhe mixture of invisible odorless, tasteless gases that surrounds the earth." (46;19) Will the children of urbanized America know that the 'air arounC. them can be anything other than a smelling, irritating and damaging cesspool for man's gaseous and particulate wastes? Man takes in approximately three pounds of food, seven and one-half pounds of· vmter and thirty pounds of air I 'during a single day. The body's-total intake may be calcu~ ilated for a single day as being approximately eight percent :food, twelve percent water and eighty percent air. Man can ! !live without water a few days, and without food about three months, but he cannot continue to survive without air more :than a few minutes. ; i ~ir, He must have a continuous supply of whether it is clean or not, to survive. ,I Air is a prime concern to man for his survival on :earth, a component of our environment more valuable than I (food or water. It has been sugg·ested that the air of many ;cities could not meet the quality standards, feeble as they ' ~are, for food additives. <27 } Apathy must not be allowed to bring about more air !pollution disasters (Belgium - 1930, Donora, Pennsylvania '... --···~·· -···~···~- ~~ ·-···"'- ···--·--· 30 31 1948, London - 1952) before concerned citizens of America and the \¥orld t.ake steps to preserve their health and wellbeing. This teaching.unit on air pollution was designed to inform and motivate junior high school students, who have known no other condition than polluted skies above: about the dangers of their exposure. Solutions to the air pollu·- tion problem may involve personal sacrifice and social readjustment. When these students are at the crossroads of this decision, they need the facts and the concern to seek solutions beneficial to their health and others sharing their community. A discussion of pure and unpure (polluted) air must begin with a definition on which to build and expand. Air pollution has been described as the presence of "foreign" substances in the air. It leaves one to define and deter- mine what is foreign to the air. pollution in terms of, 11 Turk has discussed air the addition of unwanted airborne matter which changes the composition of the earth's atmosphere, possibly bringing harm to life and altering : . materials." ( 45) In order to develop a practical definition of air pollution as it concerns man's contribution and his ability· to control his wastes, pollution will be confined to the .changing of the cornposi tion of the earth's atmosphere by man. Natural air pollution is a result of non-human events, 32 such as dust, volcanoes, pollen dispersal or fores·t fires ignited by lightning. TABLE 1 COMPOSITION OF THE ATMOSPHERE GAS CONCENT.RATION (PPM) Nitrogen Oxygen Argon Carbon dioxide Neon Helium Methane Krypton Nitrous oxide Hydrogen Xenon Nitrogen dioxide Ozone 780,900. 209,400. 9,300. 315. 18. 5.2 1.0 to 1.2 1.0 0.5 0.5 0.08 0.02 0.01 to 0.04 The table above lists the concentrations of gases in the earth's normal dry atmosphere at sea level. <44 > Most air pollution appears to be a result of man's conversion of energy to enrich his life. The first air pollution could possibly be traced back to the initial use of fire by early man. As man started to develop and expand his technology and urbanization slowly began to take hold, air pollution problems on a larger scale appeared. The short life span of early man, his wide dispersal on our planet and insignificant industrialization left little possibility for the accumulation of dangerous pollutants and their harmful effects on the population of the world. 33 , In modern times, by-products of man's energy con-;· . ---.~--~ verson coupled with an increase in world population and their concentration .in urban areas combined to form an "air pollution 11 problem that could threaten the existence of mankind. Modern industrialized man has reached a time 6f decision in which he must control the wastes produced by his technology to minimize the health risks to himself and society. NATURAL SOURCES OF AIR POLLUTION Natural air pollution has existed since the beginning(of·time. The earth has supplied the atmosphere with smok~ and its associated gases from forest fires and volca- noes. Volcanic eruptions and wind storms on deserts are sources of airborne particulate matter. Hayfever sufferers will/attest to the effect of flower pollens upon sensitive human nasal tissues. The movement of the earth's atmo- ·sphere, its winds, has been able to scatter these pollutants over large areas and dilute them. The sun provides the energy necessary for the pro'duction of oxidants in photochemical smog. Ozone is a good' example of a photochemical pollutant. Temperatures in the atmosphere drop as there is an increase in height above the surface of the earth. is known as the environmental lapse rate. This This aids in the dispersal of gaseous pollutants in the air, as the warmer gases rise above the more dense lower layers. However, in 34 '--- <- _,.. ' .. -· ------ -~--"~"-·-,-- •• -~- --~ -~ ------- ---------~~ -~------- r;.Ira1 areas, a rever-sal of the temperature gradient takes place .by the rapid radiational cooling of the ground at ni~ht and the cooling of the air near the surface of the This creates an "inversion layer" d"L1ring the day·- · earth. time and is characterized by an increase in temperature \<Ji·th height (See Pigure 1). This tends to reduce vert:ical dilu- tion of pollu·tcm:t gases in the atmosphere. 'rhe lower the inversion ·laysr, the more intense the air pollution problem. In Los Angeles, a "subsidence" inversion layer _is formed. Air from high pressure cells moves to low pressure cells: causing the air t:o warm as it lowers and contracts. This ;creates an inversion layer that is usually higher in the atmosphere than the radiation inversion layer previously desc.ribed. MAN Ml\DE SOURCES OF AIR POLLUTION Transportation. There are over 90 million automo- biles in the United States. It is noted on the following page that a large portion of each pollutant listed with the exception of particulate matter and sulfur oxides is contri~uted by transporation sources. ' The automobile with its internal combustion engine has several points where pollutants may be emitted into the air. Gasoline is a highly volatile liquid which is lost from the gas tank and from the carburetor by evaporation. Large amounts of carbon monoxide, hydrocarbons and nitrogen oxides are released from the tailpipe, while small amounts 35 \ \ \ \ \ 2.0 MAXIMUM RA'l,E \ Height. (Km) ADIABATIC LAPSE \ 1. 5 1.0 0.5 Surface NIGHTTIME SURFACE INVERSION ~I I I \ \ \ \ \ / ~- Daily Maximum Temperature Figure 1 Inversion Layer (36) 36 ••-A• •• -- • <> ~-~- -·-·- 00 o•A - --· ·-••• 0 ~---- ""•"--·•• -- of these pollutants are "blown 11 by the pistons into the .crankcase. On older cars the crankcas.e was . vented to the i ;outside air. The automobile industry has attempted to control j ~ach pollutant at its source. The gasoline .tank is sealed :and any evaporated vapors are passed over :·to remove them. ~ngine. activ~ted charcoal "Blown-by" gases are recycled through the Catalytic converters attached to the tailpipe and ! i :using platinum are being proposed for test in California. Fuel additives such as tetra-ethyl lead have been an additional source of pollut.ion. Lead must be removed ifrom gasoline to insure proper operation of catalytic ~ converters. In Los Angeles, the hydr6carbons and nitrogen dioxides necessary for the production of photochemical smog :has been contributed almost entirely by motor vehicle ! ! • • ( 42) em1ssJ.ons. Figure 2 on the following page presents a comparison ! of emissions from motor vehicles and stationary sources in i \Los Angeles County since 1940. i ~ned This graph should be exam- carefully because it does not represent individual i ~ollutants and ane might get the impression that all pollut- iI :ants have decreased in Los Angele8 which is not the case. While hydrocarbons and carbon monoxide have decreased, i nitrogen oxides have been increased by the control procedures U:sed. 37 ,.. ., ., 20 / / 1 . .//. 15 / .," 2. /_ ~ ~ v f - k/- ---- 1950 1940 1. 2. / / .Oc \ 3. ,......... .... .,.."' ~ , ~ \ \ \ '' ........._ 4. -- 1960 10 ., I / ... ., --...... ' " / Total Errlissions in l,OOO's Tons/Day .... ... -- --- r------ 1970 5 1980 1990 Motor Vehicle Emissions with no Control Program Motor Vehicle Emissions with Present Control Program 3. Stationary Source Emissions with No Control Program 4. Stationary Source Emissions with Present Control Program ·Figure 2 Comparison of Emissions From Motor Vehicles and Emissions From Stationary Sources (42) 38 Early control systems used to reduce hydrocarbons mental agencies were not too concerned until scientists began to examine the effects of nitrogen dioxides. The early systems actually increased nitrogen dioxides in the atmosphere by 175 tons/day in Los Angeles. ( 42 ) It was only tN.i th 1971 automobiles that automobile manufacturers had to ~nclude controls for nitrogen dioxides. Stationary Sources. The burning of fossil fuels (coal and oil) from stationary locations accounts for a large source of sulfur oxides dispersed into the atmosphere. These include electrical generators, space heating systems as well as industrial operations and incinerators. In 1966, the United States used approximately 1.250 billion kilowatt hours of electricity. More than 9S percent of this energy was produced by burning coal and oil. {4) When these fuels are burned, the sulfur is oxidized to sulfur oxides, which form a serious type of pollution, primarily on the east coast,of the United States. The rapid increase in the use of electricity {from :300,000 megawatts in 1969 to an anticipated 600,000 mega! ' watts in 1980) and a slowdown in the building of other power sources (i.e.,- nuclear power plants), may add to the problem of sulfur oxides in the future. Processes using limestone in conjunction with I boilers or stack gas scrubbers have been developed to remove . ~--. -· -" -. --~ ··-· ··-· - , .. ---~ ·-· -·----· . ·-·- .... --- -.. ... ----·-·- '""" ....... -----·- ......--- . -· ·-· TABLE 2 1 . ··--···~------·- .. . . .• ._,., ·- _ _,, ••• -~ --..-+M-';•'"'~i AMOUNTS OF AIR POLLUTION IN THE UNI'I'ED STATES - 1966 (4} (listed as millions of tons per year) Carbon monoxide Hydrocarbons 64.5 17.6 7.6 0.4 1.2 91.3 1.9 0.7 6.7 22.9 9.2 41.4 10.7 3.5 0.2 7.2 7.6 29.2 Solid Waste Disposal 7.6 1.5 0.5 0.1 1.0 10.7 Miscellaneous 9.7 6.0 0.5 0.6 2.9 14.7 94.4 29.3 15.5 31.2 21.9 192.3 7.2 2.2 1.2 (*'.!t) 6.7 17.3 101.6 31.5 16.7 31.2 28.6 209.6 Source Transportation Fuel Combustion, Stationary Sources Industrial Processes Total Forest Fires Total Nitrogen oxides Sulfur oxides* Particulates Total * for the year 1967 ** negligible --····- __________ ,_ ___ _______ , w \.0 40 · 'Gt la~g~ pot·ti;~ ;£- -~~pell~d ~:~i£~~---;~i~cii~~-~-·-· F;~~~-t·l~;;··of sulfuric acid as a by-:-product, is also a possible solution. The emission of sulfur oxides will be under fairly good control by 1980 or 1985 but ·the total sulfur emissions will have risen over those at the present time. (g) Electrostatic precipitators have been used to lower the emissions of particulate matter into the atmosphere. Particles of less than one micron are not as effectively removed from effluent gases as larger particles. These particles are carried high into the atmosphere, remain suspended for a long period of time, but upon reaching the ground and inhaled, penetrate deep into the lungs. Formation of nitrogen oxides from stationary sources and from automobiles is highly dependent on flame temperature and oxygen concentration. Research in this area is far behind developments to control sulfur oxides. Control efforts are being developed around minimizing the formation of nitrogen dioxides and techniques for removal of the gas after it has been formed. The major sources of industrial polluters of the air are paper mills, iron and steel mills, oil refineries, smelters, and organic and inorganic chemical manufacturers. The source charts on the preceding pages show that industries provide approximately 23 percent of the country's sulfur oxide pollutants, 84 percent of the particulate matter and over 10 percent of the carbon monoxide and hydrocarbons. 41 Number of Fine Particles Per Year in Sextillions 60 1.2 5 3 // Without Control .,.. , ,., With 0.8 0.6 Convential .Electrostatic Precipitators 2 1.0 0.4 1 0.2 1970 '75 '80 1 85 '90 '95 2000 Year Figure 3 Projected Fine Particle Emissions From CoalFired Utility Boilers. (9) Weight of Fine Particles Per Year in Millions of Tons 42 350 l · STP.~TE STANDARD ppm Ave . I 12 hr. ) 300 250 Ul !>i lti Q 200 ;4-1 ·o 'H 'Q) '.Q ;§ z 150 School and Health Warning (40 ppm for 5 min.} ..., 1957 1965 1970 Year Figure 4 Carbon Monoxide: Nurr~er of Days Per Year Various Levels Equaled or Exceeded in the Los Angeles Basin (42) 43 0.25 ppm/1 hour 140 120 100 (/J :>i (!j 0 80 '4-1 l 0 H Q) ~:::1 z 20 1.5 ppm/Instantaneous Maximum ~ NO X 10 0 1960 1965 1970 Year Figure 5 Oxides of Nitrogen: Number of Days per Year N0 and NO Equaled or Exceeded Various Levels in the2 x Los Angeles Basin (42) 44 350 0.10 ppm (1 hr./Ave.) 300 250 11) :>-; l'tl Cl 200 '4-i 0.15 ppm (Inst. Max.) ;o l~ !Q) :s ,.Q 150 0.25 ppm Max.) '---~(Inst. 'Z 100 0.35 ppm (Inst. Max.) 50 I 1956 I 1960 1965 1970 Years Figure 6 Ozone: Number of Days per Years with Highest Concentration to or Greater Than Levels Shown in the Los Angeles Basin (42) 45 Radioactive Wastes. Man has increased his use of radioactive materials since the discovery of atomic fission in 1939. The a·tmosphere may be contaminai:ed by radioactive pollutants in several ways.. The least important of these would be from research projects, whe:r:e an accident might cause the pollution of the atmosphere. Nuclear povJer plants r under proper controls, give off small amount.s of radiat.ion. The Atomic Energy Commission describes the nuclear industry as one of the most carefully controlled of all industries in the United States. The potential for a major disaster exis·ts in case of an accidental discharge of radioactive materials. Another source of radiation pollution is from nuclear weapons. Radioactive pollutants, once in the atmo- sphere, may be widely dispersed. Biological Poisons. Another source of air pollution to be discussed is pesticides, insecticides, and herbicides biological poisons. These are used primarily in agricul- tural- endeavors and defoliation during warfare. Evidence continues to mount showing the spread of these poisons into the atmosphere and their transportation throughout the world by air currents. (lS) Lead. There are many sources of lead contamination in the environment. A primary source in air pollut.ion has been in the emission of automobile smoke, natural emissions of silicate dusts, volcanic halogen aerosols, and forest fire smoke. ( 2 l) 46 ' "• '~' •- '•' ··~~''• ',,._,_ ~--~-.,> ' -•-- ~~ ••~•• •· .• .--~-~·•·• '·~·• ·•-•~·•· ~···'c' ••• "~~- ·-·--• -<••••~~•-• .. -u• •· • ' - •• -~· •••«•~•' •• ~,·•-·-- '' Contamination of our food supply.takes place by fallout on crops and pastures, uptake by animals and plants from effluents used in irrigation materials, and dust fallout. from mining operations. AIR POLLUTION AND HU!~N HEALTH Particulate Matter. Man's respira·tory system continuously exchanges oxygen and carbon dioxide with the surrounding environment. Atmospheric pollutants are drawn· :into the lungs along with life-giving oxygen. The lungs are the prime point of entry of potentially dangerous gases a!ld particles into the human body. The lungs, in turn, stand as man's natural defense against foreign particles entering his body. Any irritation can cause ill effects, not only in the respiratory tract but throughout the body. The protective mechanisms are s~~arized in ,Figure 7 on the following page. If particles are not rrunoved in one of the five ways listed in Figure 7, then they may ultimately take their .Place in various body tissues, as seen in Figure 8. The size of the particles involved is very important in their distribution in the lungs. Large particles quickly ·settle to earth, while small particles are drawn into the respiratory system. The upper portion of the respiratory tract filters out the large particles while the smaller ones penetrate deep into the lungs. 47 1. .2. 4. Out with expired air. Penetrates tracheobronch ..;: ial area, out with mucus in sputum. Caugh.t in nose_, . out with mucus. Taken up by phagocytes in al veo 1 us , 1---~~t----'"' destroyed, generally out via mucus 5. Swallowed, passes through gastrointestinal tract, excreted. "The body's defenses against invasion by foreign particles are considerable, but can be overwhelmed by excessive amounts of particulate pollution, or by breath' ing particles in combination wi 'ch gases or by particles !that are infectious, irritating or toxic." Figure 7 Clearing Mechanisms (8) 1. J_,ung ·tissue. If soluble, i t may be dissolved in lung fluid and chemically bound with tissue. If insoluble, i t may penetrate tissue and remain there. 2. / / Blood stream. Particle reaches blood via nasal clearing; or by passing into pulmonary capillaries with inhal oxygen; or by penetrating lung tissue, passes into lymph and from lymph to blood; or is taken up by phagocyte in alveoli and absorbed into blood; or be swallowed with mucus, passes through digestive system, is absorbe into blood and may reach other parts of the body in the blood flow. 4. Lymph nodes. Particle passes from llli!g tissue ~o lymph, :i.s st.ored J.n lymph nodes. 'J.'he gastrointest.inal system. After reaching the system the particle remains in one of the organs of the system instead of passing into the blood stream. l'..,igure 8 Deposition of Particles Retained by the Human Body (8) 49 The particles may be toxic or 1 they may carry other chemicals (.i.e. - benzepyrene, a known carcinogen) with them. A third possibility is t.hat they might act as a catalyst for chemical reactions which are harmful to the body. Particles larger .than 3 microns in diameter are filtered 6ut in the upper respiratory tract. below 3 microns may penetrate to the alveoli. Particles As the particle size decreases to 1 micron, the percentage of particles deposited in the alveoli increases, but the retention decreases as the size is reduced from 1 micron to .75 microns. Particulate matter below .25 microns is still being investigated. Air pollution control groups face the dilemma of t.rying to set standards for pollutant levels. Where a single gas is the cause of a known disease, it is a relatively simple matter to determine the threshold concentration for the gas, then add a margin of safety. Unfortunately, the synergistic effects of the pollutant gases in the atrnosphere compound the problem. Added to this are the varied exposure of the population involved, different heredity in terms of susceptibility, the effect of weather and other environmental factors. Man's respiratory system needs the air passages open and freely flowing to function properly. Air pollutants .such as sulfur dioxide, nitrogen dioxide, and ozone may ··~······" -·· ---·--·-·~- ·-·-··----. ' \ i ' (1 micron equals 1/1,000 of a millimeter, or 1/25,000 of an inch) l VIRUSES I I I BACTERI.A !FOG DROPLETS 0 I I RAINDROPS I I DUST '· l I FLY ASH I I I AEROSOLS - '"' l SMOKE, FUiviE 1--- t ; I MISTS --- 1,000. 100. 10. 1.0 0.1 0.01 I 0.001. Figure 9 The Sizes of Particulates in Microns (1) V1 . ··-·-· ---·-·---- ....-------' o· 51 cause spasms of the muscles of t~hB bronchial airways .. Circulation of the air and removal of the mucus are . . d ( 8) 1mpa1re . ' The exposure to particles of lead, cadmium or asbestos becomes more dangerous. Sulfur and Its Compounds. Fossil fuels (coal and fuel oil) when burned produce sulfur dioxide, a colorless gas. It is a harshly irritating gas which can paralyze ciliary action \vi thin the lungs and stimulate mucus production as well as causing bronchiospasm and edema. <35 ) Airway constriction is closely associated with the development of . cons . t r1.c . t'1 ve ven t1' l a tory d'1sease. (l 2· ) c h ron1.c Th'1s d'J.seCl.se is associated with several irritant pollutants. Sulfur dioxide is converted in the body fluids to sodium acid sulfite, which in turn, brings about further chemical changes in the chromosomes. Mutations have been produced in bacteria by sulfur dioxide. <40 ) Sulfur dioxide can be further oxidized to form sulfur trioxide which in a humid atmosphere produces a sulfuric acid mist. This acidic mist can cause the leaves of plant.s t.o yellow and die and can etch marble, iron and steel. This gas was one of the first atmospheric pollutants foi: which air quality standards were set. Average yearly concentrations above 0.04 ppm adversely affect health. This concentration has been surpassed in Chicago, Philadelphia, S ·t. L ou1s, . . · ( 4 4) . Was h 1ngton, an d o th.er maJOr c1· t1es. . """• ---- --~"··-'"···------ ~-------- -----~-----------~~-~---·--------------------- .. ···---- i -----~---··--·- ---····-- -~- ~- ---~-- ----~·-·-···---~-~ 52 · Carbon Comp9.unC!_~. Carbon black found . in chimney smoke and automobile tire rubber is a known carcinogen. Carbon monoxide :i.s ·the result of incomplete com.. b llS'!'.:l0!1. No other polllrtant is found at such relatively high concen·trations in t:h0. urban environment. Carbon monoxide interacts with hemoglobin in the human bl.ood .:md int:erferes v.rith oxygen transpor-t. (J?) It does this by combining with the hemoglobin and increasing the o.ffir.dt.y of the remaining hemoglobin for oxy·:;;en. 'This causes the tissue oxygen tension to drop lm..rer ·Lhan expected for the unloading of oxygen from the blood. (?8'1 ~ A study by Horvath ( 24 ) found that subjects exposed to 111 ppm (the concentrations determined while driving in urban ·t.raffic) raised the carbon monoxide level in the blood to 6.6 percent and impaired the vigilance of the subjects. The effect of ca.rbon monoxide exposure i.s ad1i tive since hemog-lobin is able to expell t.he carbon monoxide molecule only very slowly. It has been shcl.vn tbat t.be unborn fetus ~:0r.c::i ti v-e ext:remel:\:' brought: > ' ~:DOUt.: m,:.~y be to insufficient oxygen which could be • DY carnon monox1o.e exposure. · 2) I • " ( Carbon dioxide is not usually considered a pollutant since it is present in unpolluted air. It, like sulfur dioxode, in the presence of high humidity can produce an acid (carbonic acid) which is dam.aging to metals. Carbon dioxide prevents the radiation of long wave heat loss which could cause a rise in the temperature of 53 the earth. ( 29 ) -. • '-••·-·~ •-·-·~•·•«-•~·· ·•• -•·----•- ·" "•r.~• •-o..u ~---~--·~ • = "------~·~•···~· •• -·~---•-·~•·-------~ •-'·•~-·--·~·-~~-·~-~ ... ~.~-~---· . .-, This is known as the "greenhouse" effect. ' The nu1nber of variables involved with the overall atmo...:. spheric heat b~lance is high so that it is difficult to evaluate the effect of any given increase of carbon dioxide in the atmosphere. Compounds that contain carbon and hydrogen (hydrocarbons) form another group of dangerous pollutants. They are produced in part by industrial processes but they are primarily a product of automobile exhaust. 'l'hese com- pounds are introduced into the atmosphere by the incomplete combustion of carbon-containing fuels. Evaporation of liquids containing these compounds such as from the handling 6f gasoline or the spra~ing of paint contributes to this type of pollution. Carcinoma of the lungs like that in humans has been observed in animals exposed to the inhalation of 3,4 benzepyrene in combination with sulfur dioxide. <27 ) Lung cancer is being carefully investigated, partly due to its association with smoking. The two major metropolitan areas ,of Los Angeles and San Francisco had higher mortality rates i :for cancer of the lung than mixed rural and urban counties. These differences were greater even for nonsmokers which 'confirms reports that urban residence carries a risk of : pulmonary cancer. (11) An association between air pollution and stomach cancer has also been observed in Nashville and Buffalo. ( 2 0, 47 ) l ~-- - -----· 54. .,,1 .... -~-·- ----·····< ------ ~ Gasoline engine exhaust tar is carcinogenic in mice. The activity of exhaust tars is due to a large extent to the presence of some condensed aromatic hydrocarbons. <49 ) When animals have been infected with influenze virus and exposed to artificial smog (ionized gasoline) lung cancer has been produced. ( 2 5 ) Oxides of Nitrogen. There are two important oxides of nitrogen in terms of air pollution. These two, nitric oxide and nitrogen dioxide, are produced by any combustion that takes place in the air. Nitric oxide occurs when high temperatures are reached, or when combustion takes place at high pressures, as in automobile cylinders. Automobiles appear to be the largest single source in urban areas. In the presence of sunlight, nitric oxide is changed to nitrogen dioxide by oxygen. is colored. This form is more toxic and It, therefore, can cut down visibility. Nitrogen dioxide is associated 'i.vith a lowered 'resistance to respiratory infection. (l 5 ) Pneumonia and influenza viruses were used to show the increased susceptibility of animals when exposed to nitrogen dioxide. (l 4 ) Ozone. Nitrogen dioxide and ozone are said to have similar affects; both gases can cause increased airway 'resistance and interfere with the clearing mechanism of bronchial tubes. <35 ) Ozone is associated with the loss of elasticity of the lungs due to edema. (l?) Air purifiers have been marketed along with the :claim that ·ozon·e is an effective germicide. The United 55 -~' .. " . ·- ' .. '- -~-·-· ··- . ··~ . ·--·-- -~----- ! States Department of Health, Education ·and Welfare has ,reported that .in .concentrations low enough ~co cause· no irritation of the human raspiratory tract, ,ozone fails -to protect against airborne bacterial in£ectionr( 3 ) Ozone is produced 1n the atmosphere on sunny days. , i ~n high concentrations it is extremely toxic. ' It is classi-' fied in a broad group of chemicals known as oxidants. The most common effect of oxidants on humans is eye irrit.ation. These gases are usually produced in the atmosphere by the reaction of hydrocarbons and other organic gases with oxides of nitrogen in sunlight. They generally have certain toxic and irritating effects on humans. They can cause drumage to vegetation and they cause cracks in natural rubber. Ozone, like nitrogen dioxide, is associated with an increase in respiratory infections. It has been found to impair the ability of phagocytes to trap streptococcal • (12) bacteria. Perhaps a primary reason many people do not associate air pollution with respiratory diseases is that it does not appear on a death certificate as a cause of death. The chronic respiratory diseases that it aggravates over a long period of time are given as the cause of death. Diseases Associated With Air Pollution. Emphysema is the fastest growing cause of death in the United States. This disease is characterized by the breakdown of the alveoli (air sacs) within the lungs. irritation of the bronchial tubes. It is caused by the 56 Over a long period of time, the irritation produces a thickening of the lining of the bronchial ~ub~s with cellular changes that produce partial obstruction to the intake and outflow of air. The resulting destruction of the alveoli severely restricts·the transfer of oxygen and carbon dioxide within the lungs. 'I'he Victim of emphysema has an increasingly difficult time breathing. He may eventually become a cripple, unable to do the simplest tasks required to live. Emphysema is closely associated with smoking and the tars in cigarette smoke. Death rates from emphysema are twice as high in the city as in the country. (l 3 ) This sugges·ts importance of air pollution as a potential causative agent in emphysema. The criteria for the determination of chronic bronchitis is not standardized in the United States. In Great Britain, it is defined as chronic productive cough. (l 3 ) Studies in the United States and England established a relationship between air pollution and chronic bronchitis. ( 33 ) It has been stated that if air pollution could be :eliminated, the incidence of diseases of the respiratory tract, notably chronic bronchitis, would be reduced. (lg) Once the normal defense mechanisms of the lung have been .impaired, any level of air pollution is a serious potential danger. Bronchial asthma is a condition which is aggravated by air pollution. Asthmatic attacks may be triggered by many things and it is difficult to determine the exact 57 . role of· air pollution. 'I'he lesson learned in Donora illuminated the fact that air pollution aggravated asth-. ·matic attacks and contributed to the death of persons suffering from asthma. Effects of Radioactivity on Human Life. •of radioactivity depend upon two major factors: The effects a) the intensity and types of rays and, b) the chemistry of the .radioisotopes. The energy of radioactivity causes chemical changes within the body, usually ¥7ithin the cells of the organism. Large doses result in death. If an organism is exposed to lov1 levels. of radiation, mutations may result. mutations are usually harmful These (See Figure 10). Radiation may affect many parts of the human body . . It may damage the blood by destroying white blood cells and by damaging bone marrow, the spleen, and the lymph nodes. Lung tumors, skin cancer, bone damage, sterility, and :cataracts are some specific effects of radiation. <45 ) Exposure to low dosages of radiation and its result: ing delayed damage to human life is harder to determine that acute effects. It is known th~t radioisotopes accumu- , late in food chains. Stronti.urn-90 has been widely studied. It is similar to calcium chemically and is concentrated in the bones of humans and other mammals ... i ·····-- ........ -·-~ ......................... ~---·-· ......................- .................................._,_. ______ ................... ___............. - .... - ... ...... ..... ........ .. ...........! 58 ,.--- .--·-........ ..c: .p !=: 0 s .-1 !=: ·r-1 50 ..c= ~ :>i .-1 Ul"d ;=j (!j 0 ~ ·r-1 ;=j ~-n ·:ll !=: Cf.lH :>i -tJ .-I'd :s: ....... ;::j·r-1 {/) (J) ·r-1 roQ) ~-n .!>1: .-1 .-1 ~ s:.: Q) Cf.lH .-1 ..-1.; ~ 0 ·r-1 ;=j roQ) .-1 .-1 ·r-1 ~ :>-t .-1 Ul"d ::l Q) 0 ~ ·r-1 ;=j "d Q) .-1 .-1 ·r-1 ~-n Q) !=: Cf.lH roQ) r-1 .-1 ·r-1 ~ ~ 0 ~ 600R 425R 300R 200R 25R R stands for roentgen. It is a measure of the intensity of gamma rays in terms of the energy absorbed by the body. The dose from natural radioactivity for a human is 5 R during the first 30 years of life. Figure 10 Effects of Radioactivity on Man. (45) 59 M.ilk is . an import.::mt source . of calcium for young offspring of mammals which .puts them at the end of a food chain which concentrates t.he Strontium-90. Pesticides. There is need for much research in the· area of long-term exposure to persistent pesticides and the storage of these chemicals in the tissues and body fluids. Some pesticides have been shown to produce cancer and birth defects in experimental mammals. Charles Wurster has stunmarized the danger of pesticides, especially DDT. "The chlori-nated hydrocarbon insecticides are now among the world's most widely distributed synthetic chemicals. They are dispersed throughout the environment in currents of air and water. The movement through an ecosystem is explained by their solubility characteristics and chemical stability, while their broad toxicity indicates a potential for biological effects on many kinds of organisms.· The chlorinated hydrocarbons are seriously degrading biotic cornmunities in many parts of the world." (48:556) Lead. Outward signs of lead poisoning range from .listlessness, abdominal pain and vomiting to mental retardation~ Lead interacts with the red blood cells and the regulation of potassium and water exchanges through the ' (22) :cell membranes. The effects are also seen in changes in the osmotic resistance and erythrocytes' survival time in circulation. Inhalation of lead oxides can interfere with pulmonary phagocytes. ( 6 ) 60 AIR POLLUTION AND THE ENVIRONMENT .Han's alteration of the atmosphere is bringing about direct and indirect changes in his environment. One of the easily observable effects of air pollution is the reduction of visibility. Studies have shown that as the level of oxidants in the air goes up, visibility decreases. acid mists reduce visibility by scattering light. Sulfuric The appearance of rainbows is decreasing due to this type of light scattering. . l Decreasing of the atmosphere's transparency whether by industry, automobiles or.dusts from poor agricultural practices has the same effect, that of lowering the amount of light energy reaching the earth. From 1940 to 1960, the average temperature of the earth dropped. {lO) Particulates in the atmosphere encourage the formation of low clouds. At present, on the average, 31 percent of the earth's surface is covered by low clouds. Increasing .this to 36 percent would decrease the tempera·ture of the earth about 4 degrees Centigrade. This would be near the :temperature drop needed to return the earth to an ice ' ! ~age. (29) Increasing the carbon dioxide content of the atrno,sphere would produce a "greenhouse" effect, in which the temperature of the earth would increase. From the 1880's to the 1940's the average temperature of the earth rose 0.7 of a degree Fahrenheit. The carbon dioxide content of 61 'the air rose about 11 percent during the same period of time. ( 10 ) The v1arming which occurred may be due to the carbon dioxide increase. Pollutants in the air corrode, tarnish, weaken,. and. discolor a wide variety of materials. Steel corrodes about three times faster in urban an.d industrial areas than in rural areas. There are many examples of the corrosive effect o.f sulfuric acid on stone and cement buildings. Cleopatra's Needle in New York is a good example of the destructiveness of air pollution, for it has been exposed to sulfuric acid mists produced by the burning of high sulfur containing fuels. Three thousand years of weathering in Egypt did less to deteriorate it than has approximately 90 years in New York City. Ozone damages clothing materials and increases the breakdown of natural rubber. Ozone has been shown to •depress respiration and photosynthesis. (S) Large areas of pines in the mountains above Los Angeles have been damaged by Ozone. (l 6 ) Spinach was at one time a major crop in 'Southern California but can no longer be grown. If the list of plants that are being damaged and killed by pollution continues to increase, a vital part of .the oxygen cycle may be removed. There is evidence that sulfur dioxide,(?) as well as fluoride( 34 ) are damaging to plants. Synergistic effects of pollutants also have been identified. () 4 ) For example, 62 - . --. ·- ···-···-···"-"" ······----- .. -- .... ---~·J·-. heavy metals in automobile exhausts have been shown to pollute soils and enter plan·t tissue. ( 26 ). ( 38 )Radiat.ion and radioisotopes-continue to be a threat to vegetation and animals~ ( 33) Virtually every urban area in the nation now experiences damage to veget.at.ion fr~m polluted air. (l.3) SUM.IvlARY Ideally, scientific studies would.be able to establish threshold values for each type of pollutant below 'which there "\'lOuld be no danger to the health of living organisms, including man. To shmv- the complexity of the problem scientists are confronted with, they are dealing with not only the primary pollutants directly given off by any given source, .• but also, secondary pollutants. An example of secondary pollutants would be those produced by the action of the sun upon the primary pollutants. effects of each pollutant need In addition, synergistic to be determined in order to est.ablish usable pollution standards. Governmental agencies are dealing not only with ichemicals ~1hich in high concentrations could kill but with I. !a segment of the population which would be affected by low ; concentrations of pollutants. 1 Persons suffering with chronic lung diseases are more susceptible to polluted air than is the general public. of risk versus benefit. This leads back to the question Who is the government willing to exclude from large cities in determining tolerable levels .. ··-· --~~-- --~-- ---.-- .... . ---· -- ···---· ·----~------ ----~ -- -----.---·-·-- .. _.- ·---~-------- -----~-----·· --------·-·- -~--- ---~----. ---------~ -------~-~--------~--- --·--·· I -----·-----------·--~ 63 of air pollution? Varied health patterns, different heredity, and exposure of the population to different com:( . binations of pollutants compound the p:roblem. Scientists have not been able to identify one pollutant as a cause of genetic damage because of i:he complex interactions of pollutants. It has been suggested perhaps man will be able to adapt to rising levels of air pollution. Unfortunately, i t appears that man does not have enough time for natural selection to solve the problem. Would man be willing to accept the loss of those individuals too weak to survive? At present, adverse health effects are reflected in air quality standards only where a specific concentration of a single pollutant can be demonstrated to cause a harmful effect on health. A margin of safety is then added. Man-made air pollutants consist. not only of those 'listed in the source chart but also radioactive gases and particles from nuclear power plants and the possibility of the contamination of the atmosphere by nuclear weapons. (Z 3 ) Radiation has been associated with the breakage of chromo:somes and mutations. Pesticides, not ordinarily thought of as air pollutants, are being carried around the world in the atmo-:J : sphere. (lS) Evidence is growing that particles of biologi- cal poisons (insecticides, herbicides) are commonly found in the atmosphere and carried throughout the world by air ; currents. ( 39) It has been shown that the photosynthetic 64 processes-of some phytoplankton_found in the drastically reduced by only small amounts of DDT in the water. ( 4 8) It may be concluded that the primary source of the earth's oxygen supply is now being affected, although there has been no detectable chang~s in the percentage by volume of the atmospheric oxygen since 1910. (JO) i . "---------------- ---- ------------------------------------------ ----------- ------------------------------------- __ I ,__,) CHAPTER V REFERENCES 1. Air Pollution Primer~ ---·-·n.e-spirat?.ll:-y·-~6Is(;ase National Tuberculosis and Association, New York! 1969, p. 32. 2. Ai_~~}d}.~~~Lh""SL ·:ri ter ia. fg£_f~rbor~-~C?!.~o~iC'~. 3. Air Qualitv Criteria for Photochemical Oxidants. ---unTFeci"'-~fEatE~s--nepar·tment of HeaJ:~E11·;· Education and Welfare, National Air Pollution Control Association, Washington, D.C., March 1970, pp. 6-18. 4. United S·tates Department. of Health, Education and Welfare, National Air Pollution Control Association, Washington, D.C., March 1970, pp. 8-9. Amounts of Air Pollution by Kind and Source Produced -----rn--·E}::eunii:ecC State-s-:--uni'tedSta·tes Depar'cment of iieaitii-;-Educat:lon and Welfare, Washington, D.C., 1970, p. 9. 5. Barnes, D. L. "Effects of Chronic Exposure to Ozone on and Respiration of Pines, 11 Environmc;rrt:al Pollution. Vol. 3, No. 2, April 1~f72-;-f)p-~·- 13 3-ITs-.--· Photosynt~hesis 6. Bingham, E., "Aleveolar Macrophages: Reduced Number in Rats After Prolonged Inhalation of Lead in Sesquinoxide." §ci!§:'EC~· Vol. 62, No. 3859, 1968. pp. 1297-1299. 7. Brant, C. S. and W. Heck. »Effects of Air Pollution on Veget.ation." Air Pollution. 2nd Edition, Vol. 1, Ed. by A. c:-s6ern;-Academ.ic Press, New York, 1968. 8. Brod.ine, Virginia. "Point of Dangerr 11 Environment. Vol. 14, No. 4, May 1972, pp. 2-15. 9. Brodine, Virginia. "Running in Place," Environment. Vol. 14, No. 1, January 1972, pp. 1-12. 11 10 • Bryson, R. R. All Other Factors Being Constant • Theories o£ Global Change," Man's Impac·t on Environment. Ed. by T. R. Detwyler, McGraw-Hill, San Fran-cisco, 1971, pp. 167-174. 65 66 11. Buell, P., J. Dunn and L. Breslow. "Cancer of the Lung and Los Angeles Type Air Poliution, Prospective Study,n Cancer. Vol. 20, No. 12,1967, pp. 2139-2147-.- - - 12. Coffin, D. L., "Influence of Ozone on Pulmonary Cells," Archives· of Environmental Health" ·Vol. 16, No.3·~:; 1968, p. 633. 13. Effects of Air Pollution. Uni·ted States Depar-tment: of Health, .Education and Welfare, National Control Center for Air Pollution, Washington, D.C., 1967, pp. 1-18. 14. Ehrlick, R. "Effects of Nitrogen Dioxide on Res is·tance to Respiratory Infection," Bacteriological Review. Vol. 3 o, No. 2, Sept. 19 6 6,-pp .6o4=-614. ------·--·-- 15. Ehrlick, R., and M. C. Henry. "Chronic Toxicity of Nitrogen Dioxide," Archives of Environme~tal Health. Vol. 17, No.-6"';"nec-:-T968·, pp:--·ecJ6=-a65. 16. Evans, L. S. and P. Miller, "Ozone Damage to Ponderosa Pines: Histochemical Apprisal:" American ,Journal ,9f Bota~2X,· Vol. 59. No. 16, 1972, pp:-297~.3~ 17. Frank, R., ~ 0. Flesch and J. D. Brair. "Effects of Ozone in Elastic Behavior of Excised Lungs of Dog·s," Environmental Research. Vol. 16, 1968, p. 633. 18. Frost, J. "Earth, Air, Water," Envi.roP...tllent. No. 9, 1969, pp. 14-33. ---- 19. Greg, I. aThe Effects of Air Pollution as Seen in General Pract.ice," Human_ Environment and Respirat:ory System, Proceedings. London, England, October 20, 1970, pp. 25-32. '20. Vol. 11, Hagston, R. M., H~ A. Sprague and E. Landau. "The Nashville Air Pollution Study: VII, Mortality frcm Cancer in Relation to Air Pollution," Archives of Environmental Health. Vol. 15, No. 8, August 1967, pp 3 7--2-4 8. :--2 21. Hankin, L. "Lead Poisoning- A Disease of Our Time," Journal oj: Milk and Food Technology. Vol. 35, No. 2, February 1972, pp. 86-97. 22. Hoffman, D., E. Theisz and E. C. Wynder. "Studies on the Carcinogens of Gas Exhaust," Journal of Air Pollution Control Association. Vol. 15, No. 4, April 1965, pp. 162-165. 57 ' 23. Holland, J. "Radioactive Pollution of the Atmosphere," Biological Implications of the Nuclear Age. United States Atomic Energy -Commission, Division of Technological Information, Washington, D.C., 1969, pp. 125-132. 24. Horvath, S. M., J. E. Dahms, and J. F. Hanlon. "Carbon Monoxide and Human Vigilance," Archives of Environmental Heal·th. Vol$ 23, No. 11, November 1971, pp. 343-347. 25. Ka>ciz, P. and J. Falk, "Atmospheric Factors in Pathology of Lung C{:lncer,:r Advances in Cancer Resear~h. Vol. 7, 1963, p.-sb4: 26. Langerwerff, J., and A. S. Specht, "Contamination of Roadside Soil and Vegetation with Cadmium, Nickel, Lead, and Zinc," Environinenta1 Science and Te~hnology. Vol. 4, No. i~1970, pp. 583-586. 27. Lederberg, J., "Air Pollution: Ingredients are Suspect for Mutation," vJashington Post. October 18, 1969. 28. Lindquist, V. "Carbon Monoxide: Its Relationship to Air Pollution and Cigarette Smoke," Public Health. London, England, Vol. 86, No. 1, 1972, pp. 20-26. 29. Ha.cDonald, G. J. F. "The Modification of Planet Earth by Man," Te<?.£I~lc~lY.__~e~~iew. October/November 1969, pp. 27-35. 30. Machta, L. and E. Hugh. "Air in 1967 to 1970," Science. Vol. 168, No. 3039~ 1970, pp. 15821584. 31. Martin, A. "Pollution: Its Effects on Health," Industrial Processing and Health. Vol. 9, 1970, pp:-1"7-18. ' 32. Mensen, H.A., and H. E. Heggestad, "Ozone and Sulfur Dioxide Synergism: Injury to Tobacco Plants," Science. Vol. 153, No. 3734, 1966, pp. 424-425. 33. Menzel, R. "Airborne Radionuclides and Plants," Aqriculture a.:1d the Quality of Our Environment. ecr:--byN~-Brac1y, American Association for the Advancement of Science Publication 85, Washington, D.C. , 19 6 7 , pp. 5 7·-7 5 . 68 · 34. McCune, D.C. and R. H. Daines. "Fluoride Criteria for Vegetation Reflect the Diversity of the Plant Kingdom," Environmental Science and 'l'echr~_oJ.ogy. Vol. 3, No. 8, August 1969~ pp. 720-732. 35. McKee, W.D. "Environmental Problems and the Allergist," Annals of Allergy. Vol. 29, No. 10, October 1971, pp. 510-524. 36. Pack, D. "Meteorology of Air Pollution," Man's Impact on Environment. ed. by T. R. Detwyler, McGraw-Hill, San Francisco, 1971, pp. 98--112. 37. Pernay, F., J. Dumardin, R. Deroanne and J. M. Petit. "Muscular Exercise During Intoxication by Carbon Monoxide," Journal of Applied Physio~_ogy. Vol. 31, No. 4, October 1971, pp. 573-575. : 38. 39. ' 40. Purves, D. and E. J. MacKenzie. "Trace Elements Con·t.:..unination of Parklands in Urban Areas," Journal of Soil Science. Vol. 20, No. 2, 1969. Rissbrough, R. W., R. J. Huggett, J. Griffen, and D. Goldberg. "Pesticides: TransAtlantic Movement in the N.E. Trades," Science. Vol. 159r No. 3820, 1971, pp. 1233-1236. Shapiro, R. "Reactions of Uracil and Cytocyine Derivatives with Sodium Bisulfite Diamination," Journal_ of the American Chemical Society, Vol. 9 8, No.2, J·anuary 28, 1970, pp. 422-427. 41. Smith, e.G., c. A. Nan and C.H. Lawrener, "Separation and Identification of Polycyclic Hydrocarbons in Rubber Dus·t," American Industrial Hyg·iene Association. Vol. 29, No. 3, 1968, 242-247. 42. "Smog, Is It Getting Better?" APCD Digest. ed. by W. Falkner, Air Pollution Control District, County of Los Angeles, Vol. 11, No. 5, May 1972, pp. 1-4. 43. Sterling, T.D., "Incidence of Lung Cancer in the United States Since 1955 in Relation to·the Etiology of the Disease," American Journal of Public Health. Vol. 62, No. 2, February 1972, pp. 152-158. - 44. Tebbins, B.D. "Gaseous Pollution in the Air," Air Pollution. 2nd Ed. Vol. 1, ed. by A. C. Stern, Academ1c Press, New York, 1968, pp. 23-46. 69 45. Turk, A., J. Turk arid J. Wittes. Ecolcgv, Pollution, Environment. W. B. Saunders Company, Phifadelphia, Pa., 1972, pp. 41-108. 46. Webster's 7th. Ne'l.v C_o11egiate Dictionary, G and C Merrian Co., Springfield, Mass., 1961, p. 9. 47. Winkelstein, W. and S. Kantor. nstomach Cancer, Positive Association with Suspended Particles in l",ix:· Pollution," Archives of Environmental Healt.h, VoL 18, No. 4, April 1969,.pp·:-s44.::::·.547. 48. Wurster, C. F., nchlorinated Hydrocarbon Insecticides and the vvorld Ecosystem," Man's Impact on Environment. ed. by T. R. Detwyler, McGraw Hill Co., San Francisco, 1971, pp. 555-564. 49. Ziethius, R. L. "Interrelationship of Biochemical Response to the Absorption of Inorganic Lead," Archives of Environmental Health. Val. 22, No.lO, October 1971, pp. 299-311. CHl1.PTER VI PHOTO CREDITS Ward's Educational Filmstrips Environmental Pollution: Our World "Na·t.ure of tl-le-Crisis"---1-5, 21 "Atmospheric Pollu"cion'·' -· 5, 23, 34 "Pollution Control" 2, 13, 20, 42, 45, 461 4 7 Movie Ne~rsreels ~0 ·- NASA 1 }-1 i !BFA Environmental Decisions ·'An Inqu~ry 1.n to Air" EMC Corporation Our Environment "Our Spaceship EarthCan It Survive?" 3 1 7 1 8 f 18 1 3 9 f 4, 6, 11, 14, 161 171 31, 32, 36, 37, 38 91 "What is Air?" :Hinsdale Sanitarium Lun_2. Slides 40 35 - 24, 25, 26, 28, 30 Eye Gate Co. Pollution "Don 1 t Just Stand Therer- 43, 44 Do Something." Fodor, J. & L. Glass, Cigarette Smoking and Health - A Teacher's Guide, HRA, IIi'C:"'; 19 71, p. -g/f, 9 5. - 27, 29 Aero Service Corporation 1 1 - 22 Leighton, P. "Geographical Aspects of Air Pollution", Man's Impact on Environment, McGraw-Hill, 1971, p. 115 - l.O 70