I. Molar Conversions What is a mole? A counting ___________________________ ______________________________ number 1 mole = ______________________________ Mole/Particle Conversions (Particles/mol) ________________________ ________________________ Particles = _________________________________________________________________, etc Example 1: How many molecules are in 2.50 moles of C12H22O11? Example 2: If you have 2.23 x 1018 atoms of sodium, how many moles is that? II. Molar Mass Avogadro discovered the relationship between _____________________________ and ____________________________ This was used to find the relationship for particles in a __________ Representative Particles and moles Substance Chemical Formula Representative Particle Carbon Nitrogen Gas Calcium Ion Magnesium Flouride Mass of 1 mole of an element or compound ____________(on the PT) tells the... _______________________ (amu) ________________________ (g/mol) Representative particle in 1 mole Molar Mass Examples: Carbon Water Aluminum Sodium Chloride III. Molar Conversions Mass in Grams Moles Number of Particles Example 1: How many moles of carbon are in 26 g of carbon Example 2: Find the mass of 2.1 1024 molecules of NaHCO3. Example 3: How many moles are in 22.5 grams of potassium? GASES & MOLES • • • • • • Many of the chemicals we deal with are ____________ They are difficult to weigh. Need to know how many __________ of ______ we have. Two things effect the volume of a gas ______________ and ______________ Compare at the same temp. and pressure. STANDARD TEMPERATURE AND PRESSURE ___ºC and ____ atm pressure abbreviated _______ At STP ___ mole of gas occupies ___________ Liters Called the _________ volume Avogadro’s Hypothesis - at the _______ temperature and pressure _________ volumes of gas have the __________ number of particles. Molar Volume Avogadro's Theory: _______ _________ containing equal numbers of molecules occupy __________ volumes under similar conditions. Standard Temperature and Pressure: 0OC and 1 atm. *Molar Volume at STP = ________________ L Example 1: What is the mass of 3.36 L of ozone gas, O3, at STP? Example 2: How many molecules of hydrogen gas, H2, occupy 0.500 L at STP? Mole Bridge (for ONE Substance) To convert from one box to another, multiply by the conversion next to the arrow going in the direction you want. ___________ of ________ or molecules of 6.02 x10 23 atoms / molecules x 1 mole x (Use the Molar Mass from the PT) 6.02 x 10 23 1 mole atoms / molecules x 1 mole grams moles of x 1 mole 22.4 L x 22.4 L 1 mole liters of gas at STP x grams 1 mole Formula Calculations Percent Composition _______________________________________________________________________________ _______________________________________________________________________ % mass of element = Ex 1 : Find the % composition of Sulfur and copper in the compound Cu2S. Gas Properties Kinetic Molecular Theory. Particles in an ideal gas… have no _________________ have elastic collisions are in constant, random, straight-line ________________ don’t ______________ or ______________ each other average kinetic energy is _____________ proportional to the absolute __________________ To change pressure you can: The gas laws focus on these relationships. Characteristics of Gases Gases _______________ to fill any container o random motion, no attraction Gases are ___________ (like liquids) o no attraction Gases have very low _________________ Gases can be ____________________ o Gases undergo ______________ & __________________ o o _____ ____________= lots of empty space Describing Gases Gases can be described by their: no volume = lots of empty space random motion Temperature - Temperature: Every time temperature is used in a gas law equation it must be stated in . The conversion: Pressure: K= Pressure of a gas is the _______________ of its particles exerted over a unit ___________ (number of ________________ against a container’s walls) Pressure = Pressure may have different units: torr, millimeters of mercury (mm Hg), atmospheres (atm), Pascals (Pa), or kilopascals (kPa). torr = mm Hg = atm = Pa = kPa = ________ psi Standard Temperature and Pressure (STP) STP is defined as °C ( K) and **The volume of 1 mole of gas at STP is atm. (_________kPa) L Practice: Convert the following pressures: A) .830 atm = kPa B) 1.75 atm= psi The Gas Laws Boyle’s Law: Robert Boyle investigated the relationship between the ______________ and ____________ on a gas, holding the temperature constant. He found that pressure and volume are related. This is done while having a constant ________________ and ________________. As pressure volume Boyle’s Law: Ex: A gas occupies 100. mL at 150. kPa. Find its volume at 200. kPa. Charles’s Law: Jacques Charles investigated the relationship of __________________ & ____________ in a gas. He found that the volume of a gas and the Kelvin temperature of a gas are related. As __________________ increases, Temperature _________________ Charles’s Law: Remember: Temperature MUST be stated in KELVIN. Ex 2: A gas occupies 473 cm3 at 36°C. Find its volume at 94°C. Ex 3: The volume of a sample of gas is 43.5 L at STP. What will the volume of the gas be if the temperature is increased to 35.4°C? Gay-Lussac’s Law Since temperature and volume are related, it would make sense that temperature and pressure are related. The equation for this will resemble Charle’s law. Equation: The pressure and absolute temperature (K) of a gas are ___________________ related • at constant mass & volume Ex: A gas’ pressure is 765 torr at 23°C. At what temperature will the pressure be 560. torr? Combined Gas Law And in case that wasn’t enough, there is also the combined gas law which takes the ideas of the scientists and melds them into one law which states: Example : A gas occupies 7.84 cm3 at 71.8 kPa & 25°C. Find its volume at STP. Ideal Gas Law & Gas Stoichiometry Avagadro’s Law: o o o The volume of a gas ____________ or _____________, as its number of ___________ is being increased or decreased. The volume of an enclosed gas is ________________ proportional to its number of ___________. Equal volumes of gases contain equal numbers of _____________. at constant ________________ & _________________ true for __________ gas _______ = number of moles Avagadro’s Principle: Merge the Combined Gas Law with Avogadro’s Principle: Universal Gas Constant: R = _______________________________ R = _______________________________ Example 1: Calculate the pressure in atmospheres of 0.412 mol of Heat 16°C & occupying 3.25 L. Example 2: Find the volume of 85 g of O2 at 25°C and 104.5 kPa.