APPLICATION OF A HYDRODYNAMIC WATER QUALITY MODEL IN SUNGAI JOHOR ESTUARY MAZNAH BINTI ISMAIL A thesis submitted in fulfillment of the requirements for the award of the degree of Master of Engineering (Hydraulics and Hydrology) Faculty of Civil Engineering Universiti Teknologi Malaysia JULY 2009 iii ALHAMDULILLAH All Praise To Allah, Creator Of This Universe Thanks For The Precious Iman & Islam You Blessed On Me Thanks For All The Strength And Knowledge You Granted On Me And Also Peace Be Upon The Holy Prophet Muhammad All This Hardship I Dedicate To Some Special People In My Life My Caring & Loving Parents, Ismail Ali & Jamilah Ibrahim My Siblings Robiah, Mazlan, Mohd. Yazid and Radzuran Endless Appreciation On All Sacrifices You Did For Me My Caring Lecturer & Supervisor, Dr. Noor Baharim Ever Loving and Caring Friends I love all of you dearly Thanks iv ACKNOWLEDGEMENTS First and foremost I would like to express my thanks to Almighty ALLAH on the successful completion of this research work and thesis. I would like to thank my supervisor Dr. Noor Baharim bin Hashim for his sincere advice and guidance provided throughout my studies. His trust, patience, knowledge and friendly personality has always been an inspiration for me and will deeply influence my career and future life. The technical support and help of Paul M. Craig of the Dynamic Solutions, LLC and Professor James L. Martin of Mississippi State University for their guidance in numerical model is deeply appreciated. Special thanks and appreciation is extended to Noor Hasbullah Hashim, Anie Raflikha Abdul Malek, Mohd Zaharifudin Muhamad Ali, Juwita Asfar, Norazlina Bateni, and Nuryazmeen Farhan Haron and other undergraduate students for their invaluable assistance on data gathering and field data collection during the intensive survey. Appreciation is extended to the staff of the following agencies; Department of Environmental (DOE) Malaysia for the marine and river water quality data of Sungai Johor, Department of Irrigation and Drainage (DID) for the hydrology data, Malaysian Meteorological Service (MMS) for the meteorological data, Department of Chemistry, Faculty of Science, UTM for the laboratory data analysis, and Department of Hydraulics and Hydrology, Faculty of Civil Engineering, UTM for the hydrological field data collection. Fund for this study was provided through a grant from the Ministry of Science, Technology and Innovation (MOSTI) Malaysia under VOT 79003 and supported by Research Management Center (RMC) UTM. A very special gratitude is reserved for my family; my parents Ismail Ali and Jamilah Ibrahim for their kindness and support especially motivate me during completion of my thesis. My appreciation also goes to my siblings Robiah, Mazlan, Mohd Yazid and Radzuran for their continuous warm encouragement and support given. Special thank to my friends Siti Nurhazwani Abdul Kahar and Marina Md Arshad for their understanding and support. v ABSTRACT Sungai Johor estuary is a vital water body in the south of Johor and greatly affects the water quality in the Johor Straits. In the development of the hydrodynamic and water quality models for Sungai Johor estuary, the Environmental Fluid Dynamics Code (EFDC) model was selected. In this application, the EFDC hydrodynamic model was configured to simulate time varying surface elevation, velocity, salinity, and water temperature. The EFDC water quality model was configured to simulate dissolved oxygen (DO), dissolved organic carbon (DOC), chemical oxygen demand (COD), ammoniacal nitrogen (NH3-N), nitrate nitrogen (NO3-N), phosphate (PO4), and Chlorophyll a. The hydrodynamic and water quality model calibration was performed utilizing a set of site specific data acquired in January 2008. The simulated water temperature, salinity and DO showed good and fairly good agreement with observations. The calculated correlation coefficients between computed and observed temperature and salinity were lower compared with the water level. Sensitivity analysis was performed on hydrodynamic and water quality models input parameters to quantify their impact on modeling results such as water surface elevation, salinity and dissolved oxygen concentration. It is anticipated and recommended that the development of this model be continued to synthesize additional field data into the modeling process. vi ABSTRAK Muara Sungai Johor merupakan salah satu sungai yang penting di selatan Johor dan sangat mempengaruhi kualiti air di Selat Johor. Dalam pembangunan model hidrodinamik dan kualiti air bagi sistem muara Sungai Johor, model Environmental Fluid Dynamic Code (EFDC) telah dipilih. Dalam aplikasi model hidrodinamik EFDC ini, simulasi ketinggian permukaan, halaju, dan kemasinan air dapat diukur. Model kualiti air EFDC pula dapat mengukur beberapa parameter seperti oksigen terlarut (DO), karbon organik terlarut (DOC), permintaan oksigen kimia (COD), nitrogen ammonia (NH3-N), nitrogen nitrat (NO3-N), fosfat (PO4), dan Chlorophyll a. Kalibrasi model hidrodinamik dan kualiti air dilakukan dengan menggunakan set data di tapak dalam bulan Januari 2008. Simulasi suhu air, kemasinan air dan oksigen terlarut menunjukkan hasil yang baik dengan hasil cerapan. Pengiraan korelasi di antara model dan cerapan suhu dan kemasinan adalah lebih rendah berbanding dengan paras air. Analisis kepekaan dijalankan terhadap parameter masukan model hidrodinamik dan kualiti air untuk mengukur kesan terhadap hasil permodelan seperti paras air permukaan, kemasinan dan konsentrasi oksigen terlarut. Adalah diharapkan agar pembangunan model ini akan diteruskan dengan mengumpulkan lebih banyak data lapangan dalam proses permodelan. vii TABLE OF CONTENTS CHAPTER 1 2 TITLE PAGE AUTHOR’S DECLARATION ii DEDICATION iii ACKNOWLEDGEMENTS iv ABSTRACT v ABSTRAK vi TABLE OF CONTENTS vii LIST OF TABLES xi LIST OF FIGURES xiii LIST OF ABBREVIATIONS xvi LIST OF SYMBOLS xviii LIST OF APPENDIXES xx INTRODUCTION 1 1.1 Introduction 1 1.2 Problem Statement 3 1.3 Objectives 6 1.4 Scope of Study 7 1.5 Significance of Research 7 LITERATURE REVIEW 9 2.1 Introduction 9 2.2 Overview of Water Quality Modeling in Malaysia 10 2.3 Estuarine Model 12 2.4 Review of Available Hydrodynamic Models 15 2.5 Review of Available Water Quality Models 19 viii 2.6 2.7 3 4 Environmental Fluid Dynamic Code (EFDC) 22 2.6.1 Summary of EFDC Theory 23 2.6.2 Modeling Assumption 26 EFDC Water Quality Model 27 2.7.1 Water Quality Model Formulation 28 RESEARCH METHODOLOGY 30 3.1 Introduction 30 3.2 Database 32 3.2.1 Geographical Information System (GIS) 33 3.3 Equipments 34 3.4 Model Set Up 36 3.4.1 Model Domain 37 3.4.2 Bathymetry 37 3.4.3 Model Boundary Conditions 39 3.4.4 Model Initial Conditions 39 3.4.5 Model Kinetics 41 3.4.6 Model Input Parameters 42 3.5 Model Calibration 43 3.6 Model Sensitivity Analysis 44 3.7 Statistical Comparison Techniques 45 DATA COLLECTION & ANALYSIS 4.1 Stream Data Assessment 48 48 4.2 Meteorological Data 49 4.3 Freshwater Flow 49 4.4 DOE Water Quality Monitoring Data 50 4.5 Intensive Survey 57 4.6 Discrete Water Chemistry Samples 65 4.7 Continuous Monitoring Data 67 4.8 Vertical Profiles 68 ix 5 RESULTS & DISCUSSIONS 5.0 Introduction 72 72 5.1 Hydrodynamic Model Calibration 73 5.1.1 Water Surface Elevation Calibration 74 5.1.2 Temperature Calibration 76 5.1.3 Salinity Calibration 79 Water Quality Model Calibration 81 5.2.1 Dissolved Oxygen 82 5.2.2 Ammonia Nitrogen 84 5.2.3 Nitrate Nitrogen 85 5.2.6 Total Phosphate 85 5.2.7 Chlorophyll a 86 Hydrodynamic Model Sensitivity Analysis 87 5.2 5.3 5.3.1 Sensitivity of Water Surface Elevation to Bottom Roughness 87 5.3.2 Sensitivity of Salinity to Bottom Roughness 89 5.3.3 Sensitivity of Salinity to Horizontal Eddy Viscosity 89 5.3.4 Sensitivity of Salinity to Upstream Boundary Condition 91 5.3.5 Sensitivity of Salinity to Downstream Salinity Boundary 5.4 91 Water Quality Model Sensitivity Analysis 92 5.4.1 Sensitivity of DO to COD Decay Rate 93 5.4.2 Sensitivity of DO to Nitrification Rate 95 5.4.3 Sensitivity of DO to SOD 96 5.4.4 Sensitivity of DO to Maximum Algal Growth Rate 99 5.4.5 Sensitivity of DO to Loads from Point Sources 5.4.6 Sensitivity of DO to reaeration rate 99 100 x 6 CONCLUSIONS & RECOMMENDATIONS 6.1 Conclusions 101 101 6.2 102 Recommendations REFERENCES 104 APPENDICES 114 xi LIST OF TABLES TABLE NO. TITLE PAGE 2.1 Available estuary model 14 2.2 Evaluation of capability for hydrodynamic models 18 2.3 Evaluation of capability for water quality models 21 3.1 Data Sources of Sungai Johor Estuary Model 32 3.2 Historical Water Quality and Quantity Data for Sungai Johor Estuary 33 3.3 Initial Conditions for Sungai Johor Estuary Model 40 3.4 EFDC kinetic coefficients in the present model application 41 3.5 Files required for hydrodynamic model simulation 42 4.1 Hydraulic Data for Sungai Johor Basin 49 4.2 Meteorological Data for Sungai Johor Basin 49 4.3 Averaged flow discharges for Sungai Johor Estuary Model 50 4.4 Water Quality Index (WQI) 52 4.5 DOE Water Quality Index Classification 53 4.6 Water Quality Parameters and Value Ranges of Sungai Johor 56 4.7 Summary of Intensive Surveys Data 58 4.8 Water Quality Parameters Data from Kota Tinggi to Tanjung Buai 60 4.9 Summary of Continuous Monitoring Stations of Sungai Johor 67 5.1 Error analysis for observed and simulated water surface Elevations 75 xii 5.2 Error analysis for observed and simulated temperatures 77 5.3 Error analysis for observed and simulated salinity 80 5.4 Error analysis for observed and simulated DO 82 5.5 Sensitivity analysis of water surface elevation with bottom roughness at Tanjung Surat 88 Sensitivity analysis of water surface elevation with bottom roughness at Teluk Sengat 88 Sensitivity analysis of water surface elevation with bottom roughness at Kota Tinggi Bridge 88 5.6 5.7 5.8 5.9 Sensitivity analysis of salinity with bottom roughness At Tanjung Surat Sensitivity analysis of salinity with horizontal eddy viscosity At Tanjung Surat 89 90 5.10 Sensitivity analysis of DO to COD decay rate at Tg Surat 94 5.11 Sensitivity analysis of DO to COD decay rate at Teluk Sengat 94 5.12 Sensitivity analysis of DO to nitrification rate at Tg Surat 5.13 Sensitivity analysis of DO to nitrification rate at Teluk Sengat 96 5.14 Sediment oxygen demand values 97 5.15 Sediment oxygen demand for Sungai Tebrau 97 5.16 Sensitivity analysis of DO to SOD at Tanjung Surat 98 95 xiii LIST OF FIGURES FIGURE NO. TITLE PAGE 1.1 Map of Sungai Johor study area 6 2.1 Primary models of the EFDC model 23 2.2 Structure of the EFDC hydrodynamic model 23 2.3 Structure of the EFDC water quality model 27 2.4 Schematic diagram for the EFDC water column water Quality model 29 3.1 Research Methodology Flow Chart 31 3.2 Garmin GPS 72 34 3.3 YSI Water Quality Monitoring System 35 3.4 Hondex Digital Depth Sounder 35 3.5 Solinst Lovelogger 36 3.6 Curvilinear-orthogornal horizontal model domain for the Sungai Johor 38 3.7 The model bathymetry 38 4.1 Stream flow at Rantau Panjang in year 2006 48 4.2 Location of DOE river and marine water quality stations 51 4.3 Range of WQI for selected rivers along Sungai Johor basin 54 4.4 Water Quality trends at DOE river monitoring stations 55 4.5 Trend of temperature from downstream boundary at Tanjung Pengelih towards upstream boundary at Rantau Panjang 56 4.6 Trend of DO from downstream boundary at Tanjung Pengelih towards upstream boundary at Rantau Panjang 57 xiv 4.7 Trend of salinity from downstream boundary at Tanjung Pengelih towards upstream boundary at Rantau Panjang 57 4.8 Location of intensive survey stations along Sungai Johor 59 4.9 Trend of salinity from Kota Tinggi towards downstream at Tanjung Buai 60 Trend of temperature from Kota Tinggi towards downstream at Tanjung Buai 61 Trend of DO from Kota Tinggi towards downstream at Tanjung Buai 61 4.12 Nitrogen and Phosphorus Loads at Rantau Panjang 63 4.13 Water quality concentration in Sungai Johor tributaries 64 4.14 Water quality concentration along Sungai Johor 66 4.15 Location of vertical profile stations 68 4.16 Vertical profiles of observed salinity, temperature and DO 69 5.1 Observed and simulated water surface elevation at Tanjung Surat 75 Observed and simulated water surface elevation at Teluk Sengat 75 Observed and simulated water surface elevation at Kota Tinggi Bridge 76 5.4 Observed and simulated temperature at Tanjung Surat 77 5.5 Observed and simulated temperature at Teluk Sengat 78 5.6 Temperature profile along Sungai Johor 78 5.7 Temperature profile along Johor Straits 79 5.8 Observed and simulated salinity at Tanjung Surat 80 5.9 Salinity profile along Sungai Johor 81 5.10 Salinity profile along Johor Straits 81 5.11 Observed and simulated DO at Tanjung Surat 83 4.10 4.11 5.2 5.3 xv 5.12 DO concentration profile along Sungai Johor 83 5.13 DO concentration profile along Johor Straits 84 5.14 Ammonia nitrogen concentration profile 84 5.15 Nitrate nitrogen concentration profile 85 5.16 Total Phosphate concentration profile 86 5.17 Chlorophyll a concentration profile 87 5.18 Sensitivity of salinity to bottom roughness at Tg Surat 89 5.19 Sensitivity of salinity to horizontal eddy viscosity at Station Tanjung Surat 90 5.20 Sensitivity of salinity to upstream boundary condition 91 5.21 Sensitivity of salinity to downstream salinity boundary 92 5.22 Sensitivity of DO to COD decay rate at Tanjung Surat 93 5.23 Sensitivity of DO to COD decay rate at Teluk Sengat 94 5.24 Sensitivity of DO to nitrification rate at Tanjung Surat 95 5.25 Sensitivity of DO to nitrification rate at Teluk Sengat 96 5.26 Sensitivity of DO to SOD at Tanjung Surat 98 5.27 Sensitivity of DO to SOD 98 5.28 Sensitivity of DO to maximum algal growth rate 99 5.29 Sensitivity of DO to loads from point sources 100 5.30 Sensitivity of DO to reaeration rate 100 xvi LIST OF ABBREVIATIONS AME Absolute mean error ASCE American Society of Civil Engineers BOD Biochemical Oxygen Demand CE-QUALICM Three-Dimensional Eutrophication Model CE-QUALW2 Two-Dimensional, Laterally Averaged Hydrodynamic and Water Quality Model CH3DWES Curvilinear Hydrodynamics in 3-Dimensions Waterways Experiment Station COD Chemical oxygen demand DID Department of Irrigation and Drainage DO Dissolved oxygen DOC Dissolved organic carbon DOE Department of Environment DYNHYD5 Link Node Tidal Hydrodynamic Model EFDC Environmental Fluid Dynamic Code EPA Environmental Protection Agency HABs Harmful algal blooms HEM-3D Three dimensional hydrodynamic eutrophication model INWQS Interim National Water Quality Standards for Malaysia ME Mean error N Nitrogen xvii NBOD Nitrogenous Biochemical Oxygen Demand NH+4 Ammonium ions NH3-N Ammoniacal Nitrogen NO-3 Nitrate ions NO3-N Nitrate Nitrogen P Phosphorus PAHs Polycyclic Aromatic Hydrocarbons PCBs Polychlorinated Biophenyls PO4 Inorganic Phosphorus PO4-3 Inorganic Phosphate ions POM Princeton Ocean Model QUAL-2E Enhanced Stream Water Quality Model RIVMOD-H River Hydrodynamic Model RMSE Root mean square error SOD Sediment oxygen demand SS Suspended Solids TMDLs Total Maximum Daily Loads TOC Total Organic Carbon USACOE United State Army Corps of Engineer’s UTM Universiti Teknologi Malaysia WASP5 Water Quality Simulation Program WQI Water Quality Index xviii LIST OF SYMBOLS u = velocity component in the x-direction v = velocity component in the y-direction w = velocity component in the z-direction x, y = curvilinear horizontal coordinates Kx = turbulent diffusivities in the x-direction Ky = turbulent diffusivities in the y-direction Kz = turbulent diffusivities in the z-direction SC = internal and external sources and sinks per unit volume κ = von Karman constant ∆1 = dimensionless thickness of the bottom layer zo = dimensionless roughness height b = buoyancy ρ = actual water density ρo = reference water density ρa = air density ρw = water density cs = wind stress coefficient cb = bottom drag coefficient Uw, Vw = component of the wind velocity at 10 meter above the water surface AH = horizontal turbulence mass diffusion coefficient Ab = vertical turbulence mass diffusion coefficient Rc = physical and biogeochemical sources and sinks QH = volume sources and sinks including rainfall, evaporation, infiltration, and lateral inflows and outflows having negligible momentum fluxes mx , my = scale factors of the horizontal coordinates w vertical velocity in the stretched vertical coordinate = xix z s* = physical vertical coordinate of the free surface z b* = physical vertical coordinate of the bottom bed H = total water column depth φ = free surface potential Fe = effective Coriolis acceleration Q = horizontal momentum diffusion terms Av = vertical turbulent viscosity ρatm = atmospheric pressure u* = shear velocity cb = bottom stress coefficient U = flow velocity at the bottom layer Aν = viscosity Kν = turbulent diffusivity Rq = turbulent intensity Richardson Number xx LIST OF APPENDICES APPENDIX. TITLE PAGE A.1 DO concentration profiles along Sungai Johor 114 A.2 Salinity profiles along Sungai Johor 115 A.3 Temperature profiles along Sungai Johor 116 B Methods of Analysis 117 C Temporal Profiles of Stream Flow 118 D Temporal Profiles of DO Concentrations and Nutrient Loads 119 CHAPTER 1 INTRODUCTION 1.1 Introduction An estuary is a semi-enclosed coastal body of water with one or more rivers or streams flowing into it, and with a free connection to the open sea (Pritchard, 1967). They are affected by both marine influences, such as tides, waves, and the influx of saline water; and riverine influences, such as flows of fresh water and sediment. As a result they may contain many biological niches within a small area, and so are associated with high biological diversity. Estuaries face a host of common challenges. As more people flock to the shore, we are upsetting the natural balance of estuaries and treating their health. We endanger our estuaries by polluting the water and building on the lands surrounding them. These activities can contribute to unsafe drinking water and beach, closing of shellfish bed, harmful algal blooms, declines in fisheries, loss of habitat, fish kills, and a host of other human health and natural resource problems. Although each of the estuaries in our country, Malaysia is unique, all of them face similar environmental problems and challenges, such as over enrichment of nutrients, contamination of pathogen, toxic chemicals, alteration of freshwater inflow, loss of habitat, declines in fish and wildlife, and introduction of invasive species. While no regional or national conclusions can be drawn about the overall health of estuaries in Malaysia, these problems tend to cause declines in water quality, living resources, and overall ecosystem health. 2 With regard to tidal estuaries and given specific input, such as stream flows, engineers and hydrologists use hydrodynamic models to predict outputs, such as water surface elevations and velocities. In addition, given hydrodynamics and contaminant loading rates, they make use of water quality models to predict contaminant concentrations. The hydrodynamic and water quality models utilization consist of a detailed set of equations that serve to represent complex physical processes. However, as the number of required equations to describe the processes in question increases, the computational time and model complexity also increases. As a result, numerical models have been developed to aid in the solution of complex process equations. Computer models for simulating estuary hydrodynamics and water quality have existed for more than 40 years (Chapra, 1997). Significant improvements have been made to the original computer models, therefore, improving the quality of model outputs. Today’s computer models allow users to simulate in one, two, and three dimensions. In addition, they enable users to model water bodies that are either in steady state or dynamic systems. Model solution techniques have also been improved and the two most commonly employed are finite differences or finite elements. As a result of these improvements, users are now applying computer models to larger and larger estuary systems, in order to estimate hydrodynamics and, more importantly, water quality. In order to advance the process of improving water quality assessment techniques within an estuarine system, a computer model will be necessary to estimate river and estuarine hydrodynamics and contaminant concentrations (Liu et al., 2008). However, since the model study area is tidally influenced, the model utilized will have to take into consideration the impacts of the flood and ebb tides that occur multiple times a day. In addition, the model should be fairly straightforward in terms of setup, and the computational time should not be excessive while using a current desktop computer. The model should be able to simulate a dynamic system, and it should employ a robust numerical solution technique, such as finite elements or finite differences. 3 A multifunction surface water modeling system, which includes hydrodynamic, sediment-contaminant and water quality models, was developed and applied for Sungai Johor estuary. The hydrodynamic model, based on the principles of conservation of volume, momentum and mass, predicts surface elevation, current velocity and salinity. The water quality model, based on the conservation of mass balance, predicts seven parameters, such as dissolved oxygen, COD, DOC, ammonia nitrogen, nitrate nitrogen, total phosphate and Chlorophyll a. The model equations were solved using finite difference scheme. Model parameters were estimated from existing and collected datasets during initial setup. A calibration time period was used to modify and refine the model parameters. 1.2 Problem Statement River and marine water quality monitoring in Malaysia has been conducted by Malaysian Department of Environment (DOE) since 1978, primarily to establish the status of water quality, detect water quality changes and identify pollution sources. In 2007, there were a total of 1063 water quality monitoring stations located within 143 river basins through out Malaysia. This involves routine monitoring at predetermined stations, in-situ and laboratory analysis, and data interpretation in terms of their physic-chemical and biological characteristics. River water quality appraisal is based on Water Quality Index (WQI) involving parameters such as Dissolved Oxyen (DO), Biochemical Oxygen Demand (BOD), Chemical Oxygen Demand (COD), Ammoniacal Nitrogen (NH3N), Suspended Solids (SS) and pH. The WQI serves as a basis for assessment of a water course in relation to pollution categorization and designated classes of beneficial uses in accordance with the Proposed Interim National Water Quality Standards for Malaysia (INWQS). The DOE maintains 39 monitoring stations for Sungai Johor river basin. DOE (2007) reported that there were a total of 51 marine water quality monitoring stations located at Johor estuary and coastal area. 4 Dr. Noor Baharim, lecturer in the Faculty of Civil Engineering, Universiti Teknologi Malaysia, Skudai said a significant increase of freshwater inflow into the estuarine areas during flash flood at Kota Tinggi has affected the aquatic life for up to three weeks. Many of the fish die or swim to other river resulting in dwindling catch for the local fishermen. He said the nutrient level of the water samples collected from the Straits of Johor showed there was a risk of algal bloom in the region. There is an increasing concern of oversupply of nutrients from multiple sources in Sungai Johor estuary. This has ecological effects on the shallow coastal and estuarine areas. These effects include decrease in dissolved oxygen, impacts on living resources and loss of aquatic habitat. Degraded water quality has adverse effects on critical habitats in Sungai Johor estuary such as seagrass, which is an essential food for dugong and many herbivorous fish (Land Clearing, Sand Mining Affect Rivers, 2007, April 16). Hence, there is the need for comprehensive and intensive baseline studies of the water quality in the Sungai Johor estuary in order to assess the impact of all existing and future developments on the ecology of the Sungai Johor estuarine and coastal waters. 1.2.1 Description of Study Area Johor is the second largest state in Peninsular Malaysia with an area of 18,941 km2. Sungai Johor is considered the main river in Johor. The river flows in a roughly north-south direction and empties into the Johor Straits. The water quality of Sungai Johor has been deteriorating with increasing levels of various pollutants. Besides, it persists to be silted and chocked by rubbish and wastes as a consequence of storage of enforcement by local-authorities. These contaminants eventually flow into Sungai Johor estuary, which are rich in habitats that provide spawning and feeding areas for fish and poultry. The Johor estuarine system, an interconnected series of estuarine systems, is a vital water body in the Southern Johor as the South Gateway to Peninsular Malaysia. The estuary provides convenient and inexpensive navigation and transportation support for the economic activities in the area. 5 The Sungai Johor river basin is located at the southeastern tip of Peninsular Malaysia as shown in Figure 1.1. Sungai Johor has a total length of about 122.7 km with catchment area of 2636 km2. The river originates from Gunung Belumut and Bukit Gemuruh in the north and flows to the southeastern part of Johor and finally into the Straits of Johor. The major tributaries of Sungai Johor are Sungai Sayong, Sungai Linggiu, Sungai Semanggar, Sungai Lebam, Sungai Seluyut and Sungai Tiram. A great amount of pollutants from various sources, such as the sewerage network of the Johor Bahru, Pasir Gudang, Ulu Tiram, and Kota Tinggi cities, the industrial wastewaters from many industries in the surroundings, and agricultural wastewater containing fertilizers and pesticides are discharged into the Sungai Johor. The catchment is irregular in shape. The maximum length and breadth are 80 km an 45 km respectively. About 60% of the catchment is undulating highland rising to a height of 366 m while the remainders are lowland and swamps. The highland in the north is mainly jungle. In the south, a major portion had been cleared and planted with oil palm and rubber. The highland areas have granite soil cover consisting of fine to coarse sand and clay. The alluvium consists of fine sand and clay. The catchment receives an average annual precipitation of 2470 mm while the mean annual discharge measured at Rantau Panjang (1130 km2) were 37.5 m3/s during the period 1963-1992. The temperature in the basin ranges from 21 ºC to 32 ºC. Due to the tidal influence, the Sungai Johor is an ideal study area for research on model implementation and the prediction of hydrodynamics and water quality in tidally influenced areas. 6 N Rantau Panjang W Sg.Johor E Kota Tinggi S Sg.Seluyut Sg.Berangan Sg.Temon Sg.Redan Johor Lama Sg.Tiram Sg.Papan Sg.Layang Sg.Chemangar Teluk Sengat Sg.Layau Sg.Tebrau Sg.Serai Tg.Serindet Sg.Lebam Tg.Surat Pasir Gudang Sg.Kim Kim Sg.Johor Sg.Buloh P.Ubin Sg.Belungkor P.Tekong Sg.Sebina Sg.Santi Tg.Pengelih Figure 1.1: Map of Sungai Johor study area. 1.3 Objective of the Study The primary purpose of the study is to apply EFDC hydrodynamic and water quality model to Sungai Johor estuarine system. The objectives of the study are listed as follows: i. To calibrate the model utilizing historical data and field data collection. ii. To do sensitivity analysis of input parameters of hydrodynamic and water quality model. 7 1.4 Scope of the Study The scope of this research concentrates on developing hydrodynamic and water quality modeling tools for Sungai Johor estuarine system. These tools have been used to minimize the cost of analysis. This study was limited to the following scope of work to meet the specific objectives:- i. To collect existing data and information relevant to the study area, Sungai Johor. The relevant data and information consist of bathymetry data, water level data, water quality data, fresh water inflow data, wind data, and temperature data. ii. To analyze the result from the hydrodynamics and water quality model that will give a reasonable and practical results to real condition in Sungai Johor estuarine system. iii. To develop hydrodynamic and water quality model that can be useful for the further development at Sungai Johor estuarine system. 1.5 Significance of Research Estuarine flow and DO distribution are three dimensional in nature. To simulate these completely, a three dimensional model with time dependent momentum and continuity equations, mass balance equations with details description of the biochemical kinetics, and sources and sinks of all dissolved constituents are necessary. It seems that the state of the art computer technology enables us to do three dimensional simulations, particularly of hydrodynamics (Blumberg and Mellor, 1987). The current sampling capacity, however, cannot provide us with the quantity and quality of field data that are indispensable for the calibration and verification of the model, particularly the water quality model. This hydrodynamic model was applied in the study to simulate the flow field and salinity distribution, and the corresponding water quality model was developed to simulate the distributions of DO and other related water quality parameters. 8 EFDC hydrodynamics and water quality modeling is applied in the Sungai Johor estuarine system. The recommendation is based on the following arguments: i. EFDC model comprises an advanced three dimensional surface water modelling system for hydrodynamic and reactive transport simulation of rivers, lakes, reservoirs, wetland systems, estuaries and the coastal ocean. ii. EFDC has sufficient hydrodynamic and water quality capability to model the fate and transport of dissolved oxygen and nutrients within tidal estuary. iii. EFDC was originally developed at Virginia Institute of Marine Science as part of a long term research program to develop operational models for resource management applications in Virginia’s estuarine and coastal waters (Hamrick, 1992). iv. EFDC is a public domain with current users including universities, governmental agencies and engineering consultants. v. EFDC can be used for long term simulation over many tidal cycles. 9 CHAPTER 2 LITERATURE REVIEW 2.1 Introduction Water quality problems in a tidal system generally result from a combination of physical and biochemical processes as human activities exert stress on the system. Therefore, water quality management in estuarine and coastal waters has received increased attention in recent years as human activities in these areas increase (Park, 1993). Dissolved oxygen (DO) deficiency, as an index of deteriorated water quality, has been widely observed in estuarine and coastal waters such as Chesapeake Bay (Officer et al., 1984) and Rappahannock Estuary in Virginia, United States of America (Park, 1993). Hypoxia (deficient dissolved oxygen) has been observed frequently in the deep basin of Rappahannock River in Virginia (Park, 1993). Biological productivity in most of the world’s oceans is controlled by the supply of nutrients to surface waters (Beman et al., 2005). They demonstrated that nitrogen deficient areas of the tropical and subtropical oceans are acutely vulnerable to nitrogen pollution. They used satellite imagery to demonstrate how agricultural runoff fuels large algal blooms in vulnerable areas of the ocean in the Gulf of California. According to Beman et al. (2005), artificially induced algal blooms could have major impacts on recreational and commercial fishing, a major industries in the gulf. Another concern is hypoxia, or oxygen depletion, caused by excessive algae growth. 10 As much as these manifold processes affect the DO distribution in the water column, it is difficult to assess the relative importance of each process. A numerical model based on physical and biogeochemical principles is useful both to aid in understanding the system and to provide consistent, rational predictions of dynamic responses of the system to changes in specified factors (Park, 2003). 2.2 Overview of Water Quality Modeling in Malaysia As stated by Ambrose et al. (1993), the water volume and water quality of constituent masses being studied in the estuarine system are tracked and accounted for over time and space using a series of mass balancing equations. The developed three dimensional hydrodynamic model has also been successfully applied to Singapore’s coastal waters (Zhang and Gin, 1998). These areas included the southern part of the state of Johor, the main island of Singapore and the southern island as well as Batam Island of Indonesia. The water quality modeling analysis of Sungai Lebam was studied by Koh and Lee (2001). It’s a tidal estuary that drains into Sungai Johor. They studied the impact of discharged wastes and residuals arising from the resort development which is located in Mukim Pantai Timur Kota Tinggi Johor on the water quality of the receiving water. Four parameters of concern in the analysis were Biochemical Oxygen Demand, Dissolved Oxygen, Suspended Solids and Fecal Coliforms (FC). They demonstrated the distribution of FC along the river stretch, downstream of project site, indicating that for some 10 km downstream of project site, the estuarine water was unsafe for swimming and other contact sports. The study on the behavior of salinity transport and water quality of Sungai Lebam, which is the largest main stream of Sungai Johor estuary were studied by Khairul Ihsan (2008) and Muhammad Hanif (2008). It is essential to determine the origin of the freshwater, where it will be heading and where it will end up. The data was collected at several selected points along Sungai Lebam, ranging from the most upstream of the river to the meet point of Sungai Johor. 11 Syamsidik and Koh (2003) studied the impact assessment modeling of coastal reclamation at Pulau Tekong, a Singaporean island. They studied a water system consisting of several rivers, namely Sungai Johor, Sungai Lebam, Sungai Santi and Selat Johor and 16 other tributaries such as Sungai Layau, Sungai Serai, Sungai Khatib Bonsu, Sungai Punggol, and Sungai Seletar. Two softwares were used to assess the possible impacts generated by these reclamation projects, namely Water Quality Analysis Simulation Program (WASP5) and AQUASEA. They concluded that the coastal reclamations at Pulau Tekong and Changi’s Bay will have the potential to generate several negative impacts to the tidal hydrodynamic regimes by significantly increasing tidal velocity around Pulau Tekong and suspended sediment concentrations in the water column. This may lead to diverse problems such as eutrophication, which will cause regular occurrence of algae blooms. Lee (2006) studied the river pollution in the Sungai Johor estuary system using EFDC hydrodynamic model. The results of velocity, salinity and sediment profiles had been simulated over a seven days. The study of the results revealed the great influences of the value of various pollution sources on the distribution of pollution loads in the Sungai Johor estuary (Hashim et al.,2008). Application of EFDC model has been used to simulate suspended sediment dispersion at Sungai Pulai estuary (Hashim et al., 2007). They described an effort to understand and predict the transport of sediment in Sungai Pulai estuary using EFDC hydrodynamic model. Oversupply of sediment from multiple sources will cause unstable conditions to rivers, lakes, and shallow coastal and estuaries areas. Development in industrial activities along the Sungai Tiram area had an adverse effect on its water quality. Besides that, rapid development in agricultural sector caused the pollution and effects to the aquatic life balance at Sungai Tiram. Application of EFDC Water Quality has successfully been developed for Sungai Tiram by Mohd Shafiq (2008) and Roslan (2008). Nurhidayah (2007) studied the status of Sungai Batu Pahat based on the quantitative and qualititative of water quality and biodiversity analysis. According to 12 DOE-WQI, Sungai Batu Pahat is classified as Class III at upstream and downstream but dropped to class IV at the middle stream. The EFDC hydrodynamic and sediment model was selected to perform the hydrodynamic and sediment modeling for Sungai Batu Pahat estuary area because of its comprehensive development (Muhamad, 2008; Mohamad Faazil, 2008). Said et al.(2009) explored the use of a water quality simulation model via InfoWorks River Simulation (RS) for the Maong River, which flows into the Kuching City, Sarawak. They focused on predicting the dissolved oxygen (DO) parameters in the river basin. The model adopted a hydrodynamic and transport flow simulation tools to capture the advection and diffusion processes for different flow conditions. From the results, it is clear that the model generally predicted and identified the main impacts of flooding on the river water quality. Ali et al. (2009) study predicted water quality parameters at Johor River basin utilizing Artificial Neural Network (ANN) modeling. The results showed that the proposed ANN prediction model had a great potential to simulate and predict the total dissolved solids, electrical conductivity, and turbidity with absolute mean error of 10% for the difference water bodies. 2.3 Estuarine Models Estuarine models are needed to assess the hydrodynamic and water quality conditions in the bay and estuarine environments. This section presents a brief survey of available hydrodynamic models that were considered for the rivers and estuaries water quality-modeling projects. A number of existing models were reported in a document entitled “Estuarine and Coastal Modeling” published by the American Society of Civil Engineers (Spaulding, 2000). Most currently available three-dimensional models were developed for application to large lakes, estuaries, and other coastal regions. Mendelsohn et al.(1999) studied the Lower Savannah River Estuary using a 3-D, coupled, prognostic, general curvilinear coordinate, boundary fitted, hydrodynamic and water quality model system (WQMAP). They 13 discussed on the factors affecting salinity intrusion in the estuary and model predictions of that intrusion. A three dimensional primitive equation ocean model was used to study the dynamics of the Gaspe Current and cyclonic circulation over the northwestern gulf of St. Lawrence (Sheng, 1999). Numerical models of estuarine and coastal processes begun to be used in planned engineering works when Lorentz (1926) simulated the closure of the Zuider Zee in Netherlands. Harlemann (1971) reviewed the early development of onedimensional, estuarine model to simulate mixing and salinity. O’Connor (1960) and Thomann (1962) pioneered the finite volume approach to modeling estuarine water quality. It is similar to the box modeling approach (Officer, 1978) developed for one dimensional applications. The use of one- dimensional models is limited to simulations of averaged cross sections based on the Chezy or Manning equation to specify losses and dispersion coefficient to quantify mixing (Martin et al., 1999). The models should be limited to well mixed estuary. A large number of two dimensional, horizontal plane, finite difference or finite elements models assume that the estuary is well mixed vertically, and resolve longitudinal and lateral gradients (Martin et al., 1999). In practice, the longitudinal and lateral mass dispersion coefficients are taken to be equivalent. There are a number of quasi two dimensional models available such as link node models. The link node models apply the one dimensional equations of motion in a two dimensional framework consisting of a series of computational nodes that are connected by channels. The earliest 3-D circulation models were developed in the 1960s for the applications of oceans and lakes (Smith, 1997). The first three-dimensional (3-D) models applicable to the modeling of tidal motions in estuaries and coastal seas were done in the early 1970s (Heaps, 1972; Leendertse et al., 1973; Sundermann, 1975). 14 Table 2.1: Available Estuary Model Model name Branch network flow model CE-QUAL-RIV1 Primary application Dimensions 1-D 1-D Reference Rivers, estuaries Streams, rivers, estuaries Estuaries 1-D Schaffranek, 1987 Environmental Lab, 1995 Genet et al., 1974 Dynamic estuary model (DEM) MIT Transient Water Quality Network Model DYNHYD EXPLORE-I Estuaries 1-D Harleman et al., 1977 Rivers, estuaries Rivers, estuaries 1-D 1-D Ambrose et al., 1988 Baca et al., 1973 DYNTOX Rivers, estuaries 1-D TABS-MD 2-D (horizontal) WIFM-SAL Rivers, estuaries, bays, marshes Rivers, estuaries, bays, marshes Estuaries Martin and McCutcheon, 1999 Thomas and McAnally, 1985 Martin and McCutcheon, 1999 Schmalz, 1995 CAFEX Estuaries 2-D (horizontal) HSCTM-2D Rivers, estuaries 2-D (horizontal) Wang and Conner, 1975 Hayter et al., 1997 FESWMS-2DH 2-D (horizontal) Froehlich, 1989 2-D (horizontal) Leendertse, 1970 FETRA Streams, rivers, estuaries Estuaries, bays, marshes Rivers, estuaries 2-D (horizontal) Onishi et al., 1979 H.S. Chen’s Model TRIM Rivers, estuaries, seas Estuaries, bays 2-D (horizontal) 2-D (horizontal) Chen, 1978 Cheng et al., 1993 CE-QUAL-W2 Lakes, reservoirs, estuaries Lakes, estuaries, bays Lakes, rivers, estuaries, bays Lakes, estuaries 2-D (vertical) 3-D Cole and Buchak, 1995 Blumberg, 1977 Sheng and Butler, 1982 Sheng et al., 1986 3-D Hamrick, 1996 RMA Models Rivers, lakes, estuaries, bays Rivers, estuaries, bays 3-D HOTDIM Estuaries, seas 3-D WASP5 CE-QUAL-ICM Rivers, estuaries, bays Rivers, estuaries, bays 3-D 3-D HYDRO-3D/ SED3D Rivers, estuaries 3-D Martin and McCutcheon, 1999 Waldrop and Tatom, 1976 Ambrose et al., 1988 Martin and McCutcheon, 1999 Martin and McCutcheon, 1999 RMA2-WES SIMSYS2D Blumberg’s Model CH3D/CH3D-WES EHSM3D EFDC 2-D (horizontal) 2-D (horizontal) 2-D (vertical) 3-D 15 Estuary models, although often times more complex, solve the same set of equations as any other hydrodynamic model for lakes, rivers, or oceans. The primary difference in estuarine models is the processes by which the governing equations are solved, the scope of the parameters, and the functional structure of the model such as 1-D, 2-D, or 3-D. Various estuary models, listed in Table 2.1, were considered for this study. 2.4 Review of Available Hydrodynamic Models Hydrodynamic models can potentially represent the features of water movement in rivers, streams, lakes, reservoirs, estuaries, near coastal waters, and wetland systems. Depending on the type of system and model capabilities, spatial dimensions of the simulation can include 1-D longitudinal, 2-D in the vertical, 2-D in the horizontal or fully 3-D formulations. Some 3-D models can effectively “collapsed” to simulate systems in 1-D or 2-D. Hydrodynamic models employ numerical solutions of the fundamental governing equations in order to predict water movement based on the bottom topography and shoreline geometry. Hydrodynamic models simulate the dynamic or time varying features of water transport which, include water quantity and velocity of flow. Hydrodynamic models employ numerical solutions of the fundamental equations in order to predict water movement based on the bottom topography, shoreline geometry and external boundary conditions. Hydrodynamic models are either internally or externally coupled to water quality models for dynamic simulation of receiving waters. Some hydrodynamic models such as DYNHYD5 and EFDC are distributed as stand alone models and can be externally coupled with water quality models such as WASP5 and CE-QUAL-ICM. DYNHYD5 model is distributed as part of the comprehensive WASP5 modeling system and is typically applied externally to provide hydrodynamic flow computations, which are then input as the WASP5 water quality model. Warwick and Heim (1995) provide comparison of the performance of DYNHYD and RIVMOD models. DYNHYD has been applied to Sungai Skudai Estuary and Sungai Langat Estuary as part of the eutrophication studies (Hashim et 16 al., 2004). Tetra Tech (1995) describes a full 3-D application of EUTRO5 in conjunction with the EFDC hydrodynamic model to assess the effectiveness of total nitrogen removal from a wastewater treatment plant. Estuaries are most frequently simulated using full 3-D hydrodynamic grids to account for the complex mixing and transport processes. Link Node Tidal Hydrodynamic Model (DYNHYD5) is a one-dimensional model that uses the relatively simple link node concept to represent a waterbody (Ambrose et al., 1987). The link node representation is best applied to branching systems such as tidal rivers. The model solves the one dimensional equations of continuity and momentum of a long wave in a shallow water system. The model is distributed as a companion model to WASP5 and is typically applied externally to provide hydrodynamic flow computations, which are then input to WASP5. Most application of DYNHYD5 will use a simulation time step on the order of 30 seconds to 5 minutes due to stability requirements. However, the hydrodynamic output file created by DYNHYD5 may be stored at any user specified interval for use by a water quality simulation program. (Tetra Tech, 1995) Environmental Fluid Dynamics Computer Code (EFDC) is a general purpose three dimensional hydrodynamic and salinity numerical model (Hamrick, 1992). The theoritical and computational basis for the model is documented in Hamrick (1992). The model may be applied to a wide range of boundary layer type environmental flows that can be regarded as vertically hydrostatic. The model code uses a finite difference scheme to solve the equations of motion and transport, simulating density and topographically induced circulation, as well as tidal and wind driven flows, and spatial and temporal distributions of salinity, temperature, and sediment concentration. EFDC has been integrated with a water quality model to develop a three dimensional hydrodynamic eutrophication model, HEM-3D (Park et al., 1995). The EFDC model was used to develop a three dimensional hydrodynamic and salinity numerical model of the Indian River Lagoon (Tetra Tech, 1994). The EFDC model was linked to WASP5 for application to the Norwalk Harbor estuary in Norwalk, Connecticut, for the purposes of developing a TMDL (Stoddard et al., 1995). EFDC is one of the most extensively used hydrodynamic models and has 17 been tested in more than 60 modeling studies (Ji et al., 2001). The EFDC model has been successfully applied to simulated hydrodynamics in rivers, reservoirs, lakes, wetlands, harbors, estuaries and coastal seas, and the majority of EFDC applications have been conducted in estuaries (Moustafa and Hamrick, 2000; Ji et al., 2001; Liu et al., 2008). Other hydrodynamic models are internally coupled, or connected, to the water quality and toxic simulation programs such as CE-QUAL-W2 and CE-QUAL-RIV1. CE-QUAL-W2 model has been applied to rivers, lakes, and estuaries (Martin, 1988; Scott, 2000). Table 2.2 describes the key features of both the stand-alone hydrodynamic models and the internally coupled models. A review of the table shows that capabilities vary widely in terms of dimension. Two dimensional, Laterally Averaged, Hydrodynamic and Water Quality Model (CE-QUAL-W2) is a two dimensional, laterally averaged hydrodynamic and water quality model (Cole and Buchak, 1994). CE-QUAL-W2 is best applied to stratified waterbodies like reservoirs and narrow estuaries where large variations in lateral velocities and constituents do not occur. The water quality and hydrodynamic routines are directly coupled; however, the water quality routines can be updated less frequently than the hydrodynamic time step, which can reduce the computation burden for complex systems. The starting point of the present hydrodynamic model is the three dimensional time dependent Navier Stokes equations for incompressible fluid with hydrostatic pressure distribution and Boussinesq approximation. Although three dimensional models have been successfully developed to describe circulations driven by wind, tide, and density gradients in estuaries, lakes, and marine waters (Sheng, 1987), it is not necessary to use three dimensional models at all times. For example, for certain simpler geometry and bathymetry, it is possible to use a two dimensional laterally averaged model and even a one dimensional laterally and vertically averaged model. For these simpler models, equations and numerical solutions become significantly simpler than those for a three dimensional model. 18 Table 2.2: Evaluation of Capability – Hydrodynamic Models Externally coupled models Internally coupled models CE- Hydrodynamic RIVMOD DYNHYD5 EFDC Models CE- CH3D- QUAL- QUALWES RIV1 W2 HSPF Water body type Rivers/ streams 1 1 1 1 1 1 1 Lakes/ 3 3 1 1 3 1 3 3 2 1 1 1-D 1 1 1 1 1 1 1 2-D - - 1 1 - 1 - 3-D - - 1 1 - - - reservoirs Dimension Input data Requirements 3 3 1 1 3 2 2 Calibration 1 1 1 1 1 1 1 Grid - - 1 3 - - - generation/ interface Output data Format options 1 1 1 3 1 1 1 Graphics 3 2 3 3 3 3 3 Hydrologic 1 3 1 1 1 1 2 3 3 1 1 3 2 2 1 1 1 1 1 1 1 structure simulation Expertise required for application Documentation Shoemaker et al. (1997). 1 High 2 Medium 3 Low - Not incorporated 19 2.5 Review of Available Water Quality Models Water quality models can simulate the chemical and biological processes that occur within a waterbody system, based on external and internal inputs and reactions. Eutrophication models include those, which simulate biological inputs, nutrients, and algal growth in rivers, streams, lakes, reservoirs, and estuaries. Other receiving water models specialize in the simulation of toxic constituents and their transformation and degradation in waterbodies. Water quality models can be grouped by how they address change over time. Some models employ a steady state formulation for simulation purposes. Typical steady state applications include use of design flow, or pre-selected critical conditions, for the assessment of steady state water quality impacts. Steady state formulations are the most commonly used and the easiest to implement. A steady state model such as QUAL-2E is appropriate to be used for a system that has steady state inputs. QUAL-2E has been applied for prediction of water quality in Sungai Langat system (Unit Perundingan Universiti Malaya, 2002), Sungai Tebrau and Sungai Segget systems (IPASA, 2002). For more detailed assessments of time varying conditions in receiving waters, water quality models can be linked with hydrodynamic models. The use of dynamic water quality models allows for a more detailed evaluation of time varying inputs, such as non point sources and the examination of the short and longer term receiving water response. Hydrodynamic and water quality models for Sungai Skudai Estuary system has been applied using WASP5 model (Chua, 2002; Hashim et al., 2004). Lung and Larson (1995) have used WASP5 model to evaluate phosphorus loading reduction scenarios for the Upper Mississippi River and Lake Pepin. WASP5 is a modeling system for assessing the fate and transport of conventional and toxic pollutants in surface water bodies (Ambrose, 1993). It is designed for linkage with the link node hydrodynamic model, DYNHYD5 and dynamic simulation purposes that may be driven by either constantly repetitive or variable tides. WASP5 was successfully linked with other hydrodynamic program 20 such as EFDC (Stoddard et al., 1995). WASP5 includes two submodels for water quality or eutrophication and toxics, referred to as EUTRO5 and TOXI5, respectively. Hashim et al. (2005) used the model to simulate the transport and fate of dissolved oxygen (DO), biochemical oxygen demand (BOD), and nutrient loads for the development of hydrodynamic and water quality models for Sungai Skudai Estuary and Sungai Langat Estuary. EFDC was integrated with a water quality model to develop a threedimensional hydrodynamic-eutrophication model, HEM-3D (Park et al., 1995). The water quality portion of the model simulates the spatial and temporal distributions of 21 water quality parameters including dissolved oxygen, suspended algae (3 groups), and various components of carbon, nitrogen, phosphorus and silica cycles, and fecal coliform bacteria. Salinity, water temperature, and total suspended solids are needed for computation of the twenty-one state variables within the hydrodynamic model. Kinetic processes are similar to those in the Chesapeake Bay three-dimensional water quality model, CE-QUAL-ICM (Cerco and Cole, 1994). The model was used to develop a three dimensional hydrodynamic and salinity numerical model of the Indian River Lagoon/Turkey Creek, with calibration and validation for St. Johns river water management district, Palatka, Florida (Tetra Tech, 1994). The principal differentiating factor for characterizing water quality models is how they address the process of advection, dispersion and reaction. Advection is the primary transport mechanism in a downstream and/or lateral direction. Dispersion transport represents mixing (lateral and longitudinal) caused by local velocity gradients. Reactions include the processes and transformation of constituents within a water body. Table 2.3 presents a summary of the key features of water quality models. 21 Table 2.3: Evaluation of Capability – Water Quality Models Dynamic Water Quality DYNTOX WASP5 Models Steady state CE- CE- QUAL- EPA QUAL- QUAL- 2E SCREENING ICM W2 Water body type Rivers/ streams 1 1 1 1 1 1 Lakes/ - 3 1 1 3 1 Estuaries - 1 1 2 2 1 Coastal - 2 1 3 - - Physical processes Advection 1 1 1 1 1 1 Dispersion - 1 1 1 1 1 Heat balance - - 1 1 - - Particle fate - 2 1 2 - 3 Eutrophication - 1 1 1 1 1 Chemical fate 3 1 3 3 3 1 Sediment- - 2 1 2 3 3 3 1 1 1 1 1 - - - - - - User interface 1 3 - - 3 - Documentation 2 1 2 2 1 1 reservoirs water External loading dynamic Internally calculated non point sources (NPS) loading Shoemaker et al. (1997). 1 High 2 Medium 3 Low - Not incorporated 22 2.6 Environmental Fluid Dynamic Code (EFDC) The Environmental Fluid Dynamics Code is a general purpose modeling package for simulating three-dimensional flow, transport, and biogeochemical processes in surface water systems including rivers, lakes, estuaries, reservoirs, wetlands, and coastal regions. The EFDC model was originally developed at the Virginia Institute of Marine Science for estuarine and coastal applications and is considered public domain software. In addition to hydrodynamic and salinity and temperature transport simulation capabilities, EFDC is capable of simulating cohesive and noncohesive sediment transport, near field and far field discharge dilution from multiple sources, eutrophication processes, the transport and fate of toxic contaminants in the water and sediment phases, and the transport and fate of various life stages of finfish and shellfish. Special enhancements to the hydrodynamic portion of the code, including vegetation resistance, drying and wetting, hydraulic structure representation, wave-current boundary layer interaction, and wave-induced currents, allow refined modeling of wetland marsh systems, controlled flow systems, and near shore wave induced currents and sediment transport. The EFDC model has been extensively tested and documented for more than 20 modeling studies. The model is presently being used by a number of organizations including universities, governmental agencies, and environmental consulting firms. The structure of the EFDC model as shown Figure 2.1 in includes four major modules: (1) a hydrodynamic model, (2) a water quality model, (3) a sediment transport model, and (4) a toxics model. The EFDC hydrodynamic model itself, which was used for this study, is composed of six transport modules including dynamics, dye, temperature, salinity, near field plume, and drifter as shown in Figure 2.2. 23 EFDC Model Hydrodynamics Water Quality Sediment Transport Toxics Figure 2.1: Primary modules of the EFDC model. Hydrodynamics Dynamics (E, u, w, mixing) Dye Temperature Salinity Near Field Plume Drifter Figure 2.2: Structure of the EFDC hydrodynamic model. 2.6.1 Summary of EFDC Model Theory The EFDC model's hydrodynamic component is based on the threedimensional hydrostatic equations formulated in curvilinear-orthogonal horizontal coordinates and a sigma or stretched vertical coordinate. The momentum equations are: ∂ t (m x my Hu)+ ∂ x (m y Huu)+ ∂ y (mx Hvu) + ∂ z (mx my wu)− fe mx my Hv A ⎛ = −my H∂ x ( p + patm + φ ) + my (∂ x z*b + z∂ x H )∂ z p + ∂ z ⎝ mx my v ∂z u⎞⎠ + Qx H (2.1) 24 ∂t (mx my Hv)+ ∂ x (my Huv) + ∂ y (mx Hvv ) + ∂z (mx mywv )+ f emx m y Hu = −mx H∂ y ( p + patm A ⎛ + φ ) + m x (∂ z + z∂ y H )∂ z p + ∂z ⎝ mx my v ∂z v⎞⎠ + Qy H (2.3) mx my fe = mx my f − u∂ y mx + v∂ x my (τ ,τ ) = A H xz yz v (2.2) * y b ∂ z (u,v) −1 (2.4) where u and v are the horizontal velocity components in the curvilinear horizontal coordinates x and y, respectively. The scale factors of the horizontal coordinates are mx and my. The vertical velocity in the stretched vertical coordinate z is w. The physical vertical coordinates of the free surface and bottom bed are zs*, and zb* respectively. The total water column depth is H, and φ is the free surface potential, which is equal to gzs*. The effective Coriolis acceleration fe incorporates the curvature acceleration terms according to (2.3). The Q terms in equations 2.1 and 2.2 represent optional horizontal momentum diffusion terms. The vertical turbulent viscosity Av relates to the shear stresses by the vertical shear of the horizontal velocity components by equation 2.4. The kinematics atmospheric pressure, referenced to water density ρatm; the excess hydrostatic pressure in the water column and is given by ∂ z p = −gHb = −gH(ρ − ρ o )ρ o−1 (2.5) where ρ and ρo are the actual and referenced water densities and b is the buoyancy. The three-dimensional continuity equation in the stretched vertical and curvilinear horizontal coordinate system is ∂t (mx my H) + ∂ x (my Hu)+ ∂ y (mx Hv) + ∂ z (mx my w) = QH (2.6) with QH representing volume sources and sinks including rainfall, evaporation, infiltration, and lateral inflows and outflows having negligible momentum fluxes. The generic three-dimensional transport and transformation 25 equation for a dissolved or suspended material represented by the concentration variable C is ∂t (m x my HC)+ ∂ x (my HuC)+ ∂y (mx HvC ) + ∂z (mx mywC ) ⎛m ⎛m ⎞ ⎛m m ⎞ ⎞ = ∂ x ⎜ y HAH ∂ x C⎟ + ∂ y ⎜ x HAH∂ y C⎟ + ∂ z ⎜ x y Ab∂ z C + mx my HRC ⎝ H ⎠ ⎝ mx ⎠ ⎝ my ⎠ (2.7) where AH and Ab are horizontal and vertical turbulent mass diffusion coefficients and Rc represents physical and biogeochemical sources and sinks. The horizontal mass diffusion terms in (2.7) are generally omitted in the numerical solution when the model is configured for three-dimensional simulation. Vertical boundary conditions for the solution of the momentum equations are based on the specification of the kinematic shear stresses (τ ,τ ) = (τ ,τ )= c xz yz bx by b u12 + v12 (u1 , v1 ) (2.8) Uw2 + Vw2 (Uw , Vw ) (2.9) and (τ ,τ ) = (τ ,τ ) = c xz yz sx sy s At the bottom, z=0, and on the free surface, z=1, with Uw and Vw being the components of the wind velocity at 10 meters above the water surface. The subscript 1 refers to the velocity and elevation at the mid-point of the bottom layer. The bottom drag coefficient is given by ⎛ ⎞ κ cb = ⎜ ⎟ ⎝ ln(∆ 1 / 2zo ) ⎠ 2 (2.10) where κ, is the von Karman constant, ∆1 is the dimensionless thickness of the bottom layer, and zo=zo*/H is the dimensionless roughness height. The wind stress coefficient is given by 26 cs = 0.001 ( ρa 0.8 + 0.065 Uw2 + Vw2 ρw ) (2.11) for the wind velocity components in meters per second, with ρa and ρw denoting air and water densities, respectively. A no flux vertical boundary condition is used for the transport equation (2.7) where C represents salinity. Turbulent viscosity and diffusion coefficients in the momentum and transport equations, respectively, are determined using a turbulence closure model (Galperin et al., 1988; Mellor and Yamada, 1982). The numerical solution procedures used in the EFDC model are documented by Hamrick (1992) and summarized by Hamrick and Wu (1997). 2.6.2 Modeling Assumption The main objective of applying the EFDC model was to set up hydrodynamic information throughout Sungai Johor estuary and its tributaries for the application of the water quality model. It was necessary to accurately understand the variability of flow throughout the stream network. Major assumptions taken contributed to the final approach taken includes: i. Wind effects on flow and transport were not a critical factor due to the one dimensional flow pattern. ii. The water-body was well mixed laterally and vertically, therefore a longitudinal one dimensional configuration is appropriate. iii. Thermal stratification was not likely due to the shallow and narrow characteristics of the estuary and river, thus temperature is not an important driving force for flow and transport. iv. The impact of groundwater interaction on flow and transport was minimal during low flow conditions, thus flow distribution can be obtained through directly balancing the upstream and downstream flow rates. 27 2.7 EFDC Water Quality Model Hydrodynamic Model Dynamics Organic Carbon Algae Phosphorus Water Quality Nitrogen Silica DO COD TAM FCB Sediment Diagenesis Predicted Flux Greens Diatoms Specified Flux Other Figure 2.3: Structure of the EFDC water quality model (Park et al., 1995). The EFDC subsequently has been internally integrated with a water column eutrophication model and sediment-diagenesis model (Park et al., 1995) to develop the Three Dimensional Hydrodynamic Eutrophication Model (HEM-3D). HEM-3D consists of a hydrodynamic and water quality model linked internally as shown in Figure 2.3. The computational scheme used in the internal eutrophication models employs a fractional step extension of the same advective and diffusive algorithms used for salinity and temperature, which guarantee positive constituent concentrations. A novel ordering of the reaction sequence in the reactive source and sink fractional step allows the linearized reactions to be solved implicitly, further guaranteeing positive concentrations. The eutrophication models accept an arbitrary number of point and nonpoint source loadings as well as atmospheric and ground water loadings. 28 The central issues in the water quality model are primary production of carbon by algae and concentration of dissolved oxygen. Primary production provides the energy required by the ecosystem to function. However, excessive primary production is detrimental since its decomposition in the water and sediments consume oxygen. Dissolved oxygen is necessary to support the life functions of higher organisms and is considered an indicator of the health of estuarine systems. In order to predict primary production and dissolved oxygen, a large suite of model state variables is necessary. The nitrate state variable in the model represents the sum of nitrate and nitrite nitrogen. The three variables (salinity, water temperature, and total suspended solids) needed for computation of the above 21 state variables are provided by the EFDC hydrodynamic model. The interaction among the state variables is illustrated in Figure 2.4. In this study, the water quality model consists of seven interlinked components including phytoplankton population (Chlorophyll a), dissolved oxygen (DO), ammonia nitrogen (NH3N), nitrate nitrogen (NO3N), phosphate (PO4), chemical oxygen demand (COD) and dissolved organic carbon (DOC). Another nutrient not included in this model is silica. Silica is a limiting nutrient for diatoms only and thus it is generally modeled only when diatoms are simulated as a separate phytoplankton group (Bowie et al., 1985). The present model uses the chlorophyll a concentration to quantify the whole phytoplankton population. 2.7.1 Water Quality Model Formulation This section presents the basic equations used in the EFDC's water quality model, and provides an overview of the methods used to obtain a numerical solution. The information in this section was obtained from a technical report written by Park et al. (1995). The water column eutrophication model in HEM-3D solves mass balance equations for the 21 state variables in the water column, simulating three algal groups, cycles of organic carbon, phosphorus, nitrogen, silica, dissolved oxygen 29 dynamics, and fecal coliform bacteria. The mass balance equation for state variables may be expressed as: ∂C ⎞ ∂C ∂ (uC ) ∂ (vC ) ∂ (wC ) ∂ ⎛ ∂C ⎞ ∂ ⎛ ∂C ⎞ ∂ ⎛ ⎟⎟ + ⎜ K z + + + = ⎜Kx ⎟ + S C (2.12) ⎟ + ⎜⎜ K y ∂z ⎠ ∂t ∂x ∂y ∂z ∂x ⎝ ∂x ⎠ ∂y ⎝ ∂y ⎠ ∂z ⎝ where C = concentration of a water quality state variable u, v & w = velocity components in the x-, y- and z-directions, respectively Kx, Ky & Kz = turbulent diffusivities in the x-, y- and z-directions, respectively SC = internal and external sources and sinks per unit volume. Figure 2.4: Schematic diagram for the EFDC water column water quality model (Park et al., 1995). 30 CHAPTER 3 RESEARCH METHODOLOGY 3.1 Introduction Numerical water quality models have been extensively used to study and manage water quality conditions in aquatic systems. Deterministic models for the water column conditions are based on mass balance equations for dissolved and particulate substances in water column, which consists of physical transport (advective and turbulent diffusive transport) processes and biogeochemical processes. Information on physical processes is usually obtained by applying the hydrodynamic models. Depending on the characteristics of a system, one may choose an appropriate hydrodynamic model. For a large coastal system where both horizontal and vertical gradient are significant, one needs to employ a three dimensional hydrodynamic model, for example the Environmental Fluid Dynamic Code, EFDC (Hamrick, 1992). Generally, there are two main purposes for the nature process to be simulated into a model. The first one is, to understand the relationship between the cause and the consequences in where they can be used to make an important decision about the maintenance of the river, while the second one is to analyze the input data mathematically to achieve a liable and trusted output. In order to fulfill a complete water quality model that can be used to assist in decision making for the whole management activity in the future, a hydrodynamic model and water quality model need to be developed. For this study, Environmental 31 Fluid Dynamic Code (EFDC) has been selected. A powerful three-dimensional hydrodynamic model is required to construct an estuarine and coastal hydrodynamic model because the model cannot be treated as a simple adjective system such as the many rivers due to the consequence of these complex transport processes. Figure 3.1 shows the methodology approach to this study. Data Collection & Analysis (primary and secondary data) Hydrodynamics and Water Quality Model development Hydrodynamic and water quality model calibration Hydrodynamics and water quality sensitivity analysis Hydrodynamics and water quality model application Figure 3.1: Research methodology flow chart 32 3.2 Database It is important to collect the necessary data for the hydrodynamic and water quality modeling. An intensive field observation surveys was conducted by the UTM research group during January- June 2008. Field data are required to specify the initial conditions, boundary conditions, and forcing function distributions in time and space for the calibration, verification and application of a three-dimensional hydrodynamic and water quality model of the study area. The data source of the study area is summarized in Table 3.1. Table 3.1: Data Sources of Sungai Johor Estuary Model Date Agency Project component Flow measurement Data category Freshwater inflows Tide stage 2008 UTM researchers Water surface elevation Currents Velocity and direction Water quality study Water quality parameters In situ WQ water DO, salinity, column profiles conductivity, temperature Continuous DO DO, salinity, monitoring conductivity, temperature Bacteriological Chlorophyll a sampling Historical water quality and quantity data collection was conducted in the Sungai Johor basin and its tributaries are summarized in Table 3.2. Data are also obtained from other resources such as government departments and private agencies. 33 Table 3.2: Historical water quality and quantity data for Sungai Johor estuary Survey date 1997-2006 Agency 1997-2006 River DOE 1997-2008 DID Monthy T, salinity, DO, pH Monthy T, DO, salinity, pH, SS, BOD, COD, NH3-N, NO3, Cond, - 1997-2004 MMS - 1998-2008 NAVY - 2004 DHI - 2004 DHI - 3.2.1 Marine DOE Water quality data Hydrological data - Daily DID stream flow measurement at Station Rantau Panjang Rainfall data, wind speed and direction, temperature Tide level at Sungai Belungkor Tide level at Tanjung Pengelih Current meter data at Tanjung Pengelih Geographical Information System (GIS) GIS is a computer-aided resource assessment and planning tool for the input, storage, retrieval, analysis and display of interpreted geographic data. Data sets, such as water quality parameters, land use patterns, topographic projections and others, are used, analyzed and interpreted according to a set of criteria in determining potential areas for coastal aquaculture development. Such evaluation process using both spatial and attribute information (empirical data sets) can be effectively generated using ArcView GIS. Farah Salwa (2008) applied ArcView GIS to analyze the water quality for Sungai Johor. 34 3.3 Equipments This research work has been done using the advanced technology instruments because the work that this research was involved in is complex in mechanism and needs an accuracy reading to make sure that the data obtained can be trusted and reliable. Data sampling at various locations along the Sungai Johor was conducted from January to June 2008. Garmin GPS-72 (Geographical Positioning System) as showed in Figure 3.2 was used to determine each coordinate of water quality stations. Figure 3.2: Garmin GPS 72 A commercially available multi parameter water quality probe, Yellow Springs Industries (YSI) water quality monitoring system model 6600 and 600-R are shown in Figure 3.3. It was configured with conductivity, dissolved oxygen, salinity, pH and temperature sensors to measure water quality conditions through water column. The probes were lowered into the water column and the reading taken after a steady value was obtained. The YSI meter is pre-calibrated as recommended by the instrument manual in the laboratory and rechecked in the field prior to each measurement. The internal data logger that came with the YSI sonde was not flexible enough to accommodate our sampling data, and therefore a separate, external data logger (EcoWatch) was used. EcoWatch is the PC software interface of YSI environmental monitoring system used to upload the collected data on the equipment. 35 Figure 3.3: YSI water quality monitoring system model While the rest of the water quality parameters such as ammonia nitrogen, nitrate, BOD, orthophosphate and suspended solids have been analyzed at the Chemistry Laboratory of Faculty of Science UTM from a water sample that was put into a 2 liter polyethylene bottle which was cleaned according to the Standard Method APHA 4500-P. The water sample was then being preserved by putting a few drops of nitrite acid (H-NH3) and stored at 4°C cold room as soon as the BOD analysis had carried out in order to minimize the biological activities in the water. Table B.1 summarized the water quality parameters and their corresponding methods of analysis in Appendix B. Hondex digital depth sounder as shown in Figure 3.4 was used with the portable digital depth sounder to measure the depth of water body. Figure 3.4: Hondex Digital Depth Sounder 36 Solinst levelogger as shown in Figure 3.5 was used to record the water surface elevation fluctuations and temperature in Sungai Johor estuary system. Time series data of water level were used to calibrate the water level. Figure 3.5: Solinst levelogger 3.4 Model Set Up The general procedure for the application of the EFDC model to study area follows a sequence of steps beginning with the model set-up or configuration. Model configuration involves the construction of a horizontal grid of the water body and interpolation of bathymetric data to the grid, construction of EFDC input files, and compilation of the source code with appropriate parameter specification of array dimensions. In this application, the EFDC model was configured to simulate time varying surface water elevation, velocity, salinity, water temperature and water quality parameters. 37 3.4.1 Model domain The model domain, as shown in Figure 3.6, defines the Sungai Johor estuarine system and major surrounding tributaries that provide fresh water inflow into the estuary. The curvilinear-orthogonal horizontal model grid for the Sungai Johor estuary system was comprised of approximately 6613 active quadrilateral water cells, with each cell divided into 10 layers to capture the vertical variations of simulated constituents. The grid systems were constructed by using GEFDC program. GEFDC is a preprocessor system, which can generate either Cartesian or curvilinear orthogonal grids using methods outlined by Mobley and Stewart (1980) and Ryskin and Leal (1983). There are 48 downstream (seaward) boundary cells located at Tanjung Pengelih. The upstream boundary cells include Sungai Seluyut, Sungai Berangan, Sungai Redan, Sungai Temon, Sungai Tiram, Sungai Layang, Sungai Layau, Sungai Papan, Sungai Lebam, Sungai Pelepah, Sungai Serai, and several unnamed tributaries. 3.4.2 Bathymetry The bathymetric data of Sungai Johor estuarine system and its surrounding areas were obtained from the Malaysian Navy navigational chart. Overall bathymetric features are illustrated in Figure 3.7. 38 Figure 3.6: The curvilinear orthogornal horizontal model domain of Sungai Johor estuary Figure 3.7: The model bathymetry incorporated data from bathymetric data. 39 3.4.3 Model Boundary Conditions The EFDC hydrodynamic model was configured to simulate four characteristics of the Sungai Johor estuarine model: salinity, velocity, temperature, and water surface elevation. As a condition to the numerical solution of the equation used to predict the four variables, values for salinity, velocity, temperature and water elevation must be specified at the model boundaries. Conditions at the Sungai Johor estuary seaward boundary was defined by water elevation, temperature, and salinity time series. Conditions at the upstream boundary was defined by averaged daily river flow and freshwater (zero salinity). In this study, the model is capable of reading separate input files for time series specifications of tidal height as well as salinity at the seaward boundary and freshwater discharges at upstream and tributaries locations. The downstream boundary point for the model is located at Tanjung Pengelih. This downstream seaward boundary was forced by a tidal elevation series as measured at Sungai Belungkor. The upstream boundary of Sungai Johor is located outside the tidal influence, allowing the use of a simple flow time series boundary condition at Kampung Rantau Panjang. A flow condition was defined by the Department of Irrigation and Drainage (DID) data. Information on wind speed and direction was obtained from the Senai Airport meteorological stations to define wind conditions within the model domain. The boundary conditions of surface water elevation, wind speed and direction, air temperature, atmospheric pressure, and solar radiation are used for calibration period. 3.4.4 Model Initial Conditions When the EFDC model is first activated, an initial flow field of tidal height and salinity values is required. It is important that the residual effects of any 40 inaccurate initial spatial distribution be eliminated for each state variable (tidal elevation, salinity, and temperature) prior to comparing model results to field data. It is advantageous to restart the model with a set of values from a prior run for it to be as realistic as possible. In this study, tidal heights were initialized to zero (level free surface) everywhere. Prescribed boundary conditions were used to drive the system until an equilibrium condition. The initial conditions of salinity and temperature were specified in salt.inp and temp.inp files, respectively. Constant values were prescribed throughout the domain for each variable. Initial conditions for EFDC water quality model include initial concentrations, as well as solid transport field for each solid in each segment/ grid. In this study, the initial concentrations of ammonia nitrogen, nitrate nitrogen and dissolved oxygen was based on the depth averaged conditions. Linear interpolations were made on the available water quality sampling stations to initialize the concentrations of water quality parameters throughout the water quality segments. Table 3.3 shows the water quality initial conditions for Sungai Johor estuary model. Table 3.3: Initial conditions for Sungai Johor water quality model Description Value Total phosphate 0.01 Ammonia nitrogen 0.01 Nitrate nitrogen 0.01 Chemical oxygen demand 10.00 Dissolved oxygen 6.00 41 3.4.5 Model Kinetics Model kinetics and parameters determine the decay of the pollutants and the oxygen uptake amount in the system. These kinetic rates and parameters are determined based on the measured data and standard water quality modeling assumptions. The parameters are shown in Table 3.4. Table 3.4: EFDC kinetic coefficients in the water quality model application Description Reaeration constant Temperature rate constant for reaeration Oxygen half-saturation constant for COD decay (mg/l O2) COD decay rate (per day) Reference temperature for COD decay (ºC) Temperature rate constant for COD decay Maximum algal growth rate (per day) Optimum temperature for algal growth (ºC) Effect of temperature on algal growth below optimum temperature (ºC-2) Effect of temperature on algal growth below optimum temperature (ºC-2) Algal basal metabolism rate at 20ºC (d-1) Half saturation constant for nitrogen uptake of algae (g N m-3) Half saturation constant for Phosphorus uptake of algae (g P m-3) Half saturation constant for Silica uptake of diatoms (g Si m-3) Algal predation rate at 20ºC (d-1) Algal settling rate (m d-1) Decay rate of organic carbon at 20ºC (d-1) Decay rate of organic phosphorus at 20ºC (d-1) Decay rate of organic nitrogen at 20ºC (d-1) Settling rate of particulate organic matter (m d-1) Maximum nitrification rate at 27ºC (g N m-3 d-1) Dissolution rate of particulate silica at 20ºC (d-1) Sediment oxygen demand (g O2 m-2 d-1) Benthic flux of ammonia (g N m-2 d-1) Benthic flux of nitrate (g N m-2 d-1) Benthic flux of phosphorus (g P m-2 d-1) Benthic flux of dissolved silica (g N m-2 d-1) Value 2.00 1.024 1.5 0.1 20 0.041 2.25 15.0 0.008 0.008 0.03 0.01 0.001 0.05 0.16 0.10 0.005 0.005 0.005 1.0 0.07 0.03 2.00 0.1 0.005 0.005 0.075 42 3.4.6 Model Input Parameters Application of the EFDC model to Sungai Johor estuarine system is managed through a series of input files listed in Table 3.5. A complete description of user designated input can be found in Hamrick (1996). Two files output by the GEFDC grid processor (dxdy.out and lxly.out) were renamed to dxdy.in and lxly.inp and used as input to the hydrodynamic portion. File dxdy.inp includes each cell, the I and J indices, the x and y horizontal dimensions, depth, and bottom elevations, and bottom roughness and vegetation class. The file lxly.inp specifies both the horizontal cell center coordinates but also the cell orientations (cartesian or curvilinear). Table 3.5: Files required for EFDC model simulation Filename Efdc.for Type Model Comments No changes required source Cell.inp Input Grid cell types Celllt.inp Input Grid cell types Dxdy.inp Input Cell dimensions, bottom roughness Lxly.inp Input Cell locations in UTM (m) Salt.inp Input Initial salinity concentration Temp.inp Input Initial temperature Dye.inp Input Initial dye concentration Aser.inp Input Atmospheric data: air temperature, solar radiation, atmospheric pressure, evaporation, rainfall, cloud cover Wser.inp Input Wind speed and direction Pser.inp Input Tidal height time series Qser.inp Input Time series data for freshwater discharge Tser.inp Input Temperature specification at boundaries. Sser.inp Input Salinity concentration specification at boundaries. Wq3dwc.inp Input Water quality concentration specification at boundaries. 43 The cell.inp is the important file for grid generation and EFDC application. It includes geometry or domain boundary and a designator file. This is accomplished by assigning a cell type (water or dry land) within the specified grid matrix. The files salt.inp and temp.inp were used to initialize the model domain with a pre-determined salinity and temperature, respectively. Salinity and temperature were input to each layer of the cells. Time series data for freshwater discharge were input to EFDC via file qser.inp. The file ser.inp specifies the tidal height time series at the open seaward boundary. Meteorological data including atmospheric pressure, air temperature, solar radiation, rainfall and evaporation are important to the model and are input via the file aser.inp. Wind speed and direction are input to the file wser.inp. Salinity and temperature specification at the Tanjung Pengelih and upstream boundary at Kampung Rantau Panjang are also required. These variables were input via files sser.inp and tser.inp, respectively. 3.5 Model Calibration Model calibration appears in various forms, dependent on data availability, characteristics of water body, and most of all, the perceptions and opinions of modelers. It often happens that calibrated model results are compared with observed data to demonstrate agreements, with little explanation of which coefficients were adjusted (and the nature of the adjustment) in arriving at the calibrated model. Hsu et al. (1999) calibrated their vertical (lateral averaged) 2D model in three steps; preliminary calibration, fine tune calibration of friction coefficient and calibration of mixing processes. They recommended using the distribution of the tidal range as a function of distance from the river mouth to calibrate the friction coefficient. It is an accepted requirement that a numerical model of estuarine hydrodynamics be calibrated and verified before being put into any practical usage. 44 3.6 Model Sensitivity Analysis Sensitivity analysis is used to determine how sensitive a model is to changes in the value of the parameters of the model and to changes in the structure of the model. In this study, we focused on parameter sensitivity. Parameter sensitivity is usually performed as a series of tests in which the modeler sets different parameter values to see how a change in the parameter causes a change in the dynamic behavior of the stocks. By showing how the model behavior responds to changes in parameter values, sensitivity analysis is a useful tool in model building as well as in model evaluation. Sensitivity analysis helps to build confidence in the model by studying the uncertainties that are often associated with parameters in models. Many parameters in system dynamics models represent quantities that are very difficult, or even impossible to measure to a great deal of accuracy in the real world. In addition, some parameter values change in the real world. Therefore, when building a system dynamics model, the modeler is usually at least somewhat uncertain about the parameter values he chooses and therefore, must use estimation. Sensitivity analysis allows him to determine what level of accuracy is necessary for a parameter in order to make the model sufficiently useful and valid. If the tests reveal that the model is insensitive, then it may be possible to use an estimation rather than a value with greater precision. Sensitivity analysis can also indicate which parameter values are reasonable to be used in the model. If the model behaves as expected from real world observations, it gives some indication that the parameter values reflect, at least in part, the “real world.” Sensitivity tests help the modeler to understand dynamics of a system. Experimenting with a wide range of values can offer insights into behavior of a system in extreme situations. Discovering that the system behavior greatly changes for a change in a parameter value can identify a leverage point in the model, a parameter whose specific value can significantly influence the behavioral mode of the system. 45 3.7 Statistical Comparison Techniques Basic comparative statistics and their associated tests (Ambrose, 1987) were compiled into a recent book about hydrodynamic modeling (Martin and McCutcheon, 1999) and were used to validate the EFDC model. The simplest statistical test was the mean error (ME) defined as the difference of the means ME = ∑ x−c (3.1) N where x is the observed values, c is the model-predicted or calculated values and N is the number of data pairs compared. Where data are missing the error is not computed and therefore not included in the calculation. The mean error is as it sounds, a comparison of how the simulated averages of a parameter (e.g., salinity) compares with the measured average over the period chosen for comparison. The units of the mean error were the same as those for the observations. A mean error of zero is ideal. Positive mean error indicates that on average, model predictions are less than observations. A negative mean error indicates model predictions exceed observations, on average. The absolute mean error is also used. It is determined to be similar to the mean error except that the absolute value of the difference between calculated and observed values is taken. The absolute mean error is defined as: AME = ∑ x−c N (3.2) where x is the observed values, c is the model-predicted or calculated values and N is again the number of data pairs. It represents the average difference in the two signals as compared to the differences in the average. The closer AME is to zero, the better the model accuracy is. 46 Mean error or absolute mean error is a measure of model accuracy, bias, or systematic error. If ME > 0, the model had systematically oversimulated and if ME < 0, the model had systematically undersimulated the response of the natural system. Neither mean error nor absolute mean error measured imprecision or scatter in residuals (observed-simulated). Overall, the ME was useful for guiding calibration and judging validation testing, but other statistics were necessary to determine the precision and correlation. Precision of a simulation was determined from the standard error of estimation or root mean square error, ∑ (S N RMSE = i =1 i − Oi ) 2 N (3.3) where N is the total number of measurements in space or time. It is statistically well behaved and is a direct measure of the model error. RMSE had the same units and dimensions as the observations and simulations. A root mean square error of zero is ideal. The root mean square error is an indicator of the deviation between predictions and observations. The root mean square is an alternative to (and usually larger than) the absolute mean error. The dimensionless coefficient of variation or % root mean square error is % RMSE = RMSE × 100 O (3.4) where O was the average of observation Oi Correlation between model and observed data completed using the regression analysis was more useful in evaluating the calibration or validation of a model. The regression equation is Oi = α 1 + β1 S i + ∈ (3.5) 47 where α 1 and β1 were dimensionless regression coefficients representing the true yintercept and slope of a plot of observed versus simulated values, and ∈ was the error in simulation S i . The coefficient of determination R ( or for correlation coefficient R2) is R2 = n ⎛ n ⎞ ⎛ n ⎞ ⎜ n ∑ (S i × Oi )⎟ − ⎜ ∑ Oi × ∑ S i ⎟ i =1 ⎝ i =1 ⎠ ⎝ i =1 ⎠ ⎛⎛ n 2 ⎞ ⎛ n ⎞ ⎜⎜ ⎜ n∑ S i ⎟⎟ − ⎜ ∑ S i ⎟ ⎝ ⎝ i =1 ⎠ ⎝ i =1 ⎠ 2 ⎞ ⎟× ⎟ ⎠ 2 n ⎛⎛ n ⎞ ⎜ ⎜ n O 2 ⎞⎟ − ⎛⎜ O ⎞⎟ ⎟ ∑ ∑ i i ⎜ ⎝ i =1 ⎠ ⎝ i =1 ⎠ ⎟⎠ ⎝ (3.6) and provided an indication of the degree correlation between the observed (Oi) and predicted (Si) data for a given number of observations, n. The dimensionless correlation coefficient, R2 approached one when a high degree of correlation occurred, and approached zero when data were not correlated. Whether the simulation was accurate was determined by testing the significance of the intercept α 1 and the slope β1 . If the slope was not significantly different from one and the intercept was less than or equal to some tolerance centered about zero, the statistics indicated accuracy. Salinity was chosen as the observed and simulated values to test the accuracy, precision, and correlation of the model to field data. The ME was used to determine model accuracy where the more accurate the model, the closer to zero the ME approached. The RMSE was used as an indicator of model precision with values close to zero are more precise. Finally, the R2 statistic was used as a measure of the variability in the observed data that was explained by the model. 48 CHAPTER 4 DATA COLLECTION AND ANALYSIS 4.1 Stream Data Assessment As indicated in Table 4.1, stream stage and discharge measurements on the Sungai Johor at Rantau Panjang are available from a Department of Irrigation and Drainage (DID) gauge station that was maintained from 1965 to 2008. This flow measurement station provided the upstream freshwater inflow data for the model. The Rantau Panjang gage is located approximately 80 kilometers upstream at Tanjung Pengelih. A representative hydrograph for calendar year 2006 is presented in Figure 4.1. The temporal profiles of stream flow at Station Rantau Panjang from year 1996 to 2006 are shown in Appendix C. Station Sungai Johor at Rantau Panjang 350 300 Flow (m3/s) 250 200 150 100 50 0 Jan06 Feb06 Mar06 Apr- May06 06 Jun- Jul-06 Aug- Sep06 06 06 Oct06 Nov- Dec06 06 Jan07 Tim e (m onth, year) Figure 4.1: Stream Flow Data of Sungai Johor at Rantau Panjang (2006). 49 Table 4.1: Hydraulic Data for Sungai Johor basin Location DID station Available data Duration Frequency Rantau 1737451 Stage, 1965-2007 Daily Panjang 4.2 Discharge Meteorological Data Meteorological data are available from climatological station 48679 Senai Airport. As indicated in Table 4.2, hourly meteorological data includes rainfall duration, temperature, solar radiation, and cloud cover is required as input file in order to run EFDC model. Table 4.2: Meteorological Data for Sg Johor basin Location 4.3 Available data Duration Frequency Air temperature 1974-2004 ~Monthly Rainfall 1974-2004 ~Monthly Wind speed and direction 1990-2001 ~Monthly Senai Airport Rainfall duration and amount January 2008 Hourly (48679) Dry and wet bulb temperature January 2008 Hourly Solar radiation January 2008 Hourly Mean sea level pressure (MSL) January 2008 Hourly Total cloud cover January 2008 Hourly Freshwater Flow The Sungai Johor hydrodynamic model includes major point sources discharges from tributaries. The average flow discharge for Sungai Johor hydrodynamic model input files is presented in Table 4.3. 50 Table 4.3: Averaged flow discharges for Sungai Johor estuary model Flow ID Cell I,J Description Flow discharge (m3/s) Flow01 157, 329 Rantau Panjang Time variables Flow02 185, 221 Sungai Seluyut 0.104 Flow03 157, 215 Sungai Berangan 0.012 Flow04 162, 174 Sungai Temon 0.012 Flow05 150, 171 Sungai Redan 0.012 Flow06 141, 159 Sungai Tiram 1.500 Flow07 160, 150 Sungai Layang 0.012 Flow08 176, 141 Sungai Serai 0.012 Flow09 210, 122 Sungai Layau Kiri 0.023 Flow10 247, 148 Sungai Papan 1.240 Flow11 272, 140 Sungai Lebam 1.610 Flow12 211, 90 Sungai Belungkor 1.500 Flow13 255, 75 Sungai Santi 1.240 Flow14 268, 66 Sungai Sebina 0.509 Flow15 160, 71 Sungai Kim Kim 1.500 Flow16 128, 74 Sungai Buloh 0.012 Flow17 45, 118 Sungai Tebrau 1.500 Flow18 174, 525 Sungai Pelepah 2.500 Flow19 169,567 Sungai Sisek 0.509 Flow20 168,671 Sungai Lebak 1.500 Flow21 148,686 Sungai Semangar 0.509 4.4 DOE Water Quality Monitoring Data According to DOE (2007), a total of 51 marine water quality monitoring stations were set up throughout the Johor State and 29 river water quality monitoring stations were set up in the Johor river basin. Under the Malaysia Singapore Joint Committee on the Environment (MSJCE) monitoring program, 20 stations were also 51 monitored in 2007. Locations of DOE river and marine water quality monitoring stations are shown in Figure 4.2. Water quality data from 1997 to 2006 is available from DOE. 3JH13 # S N 3JH15 # S Sg.Johor # S 3JH16 # S 3JH19 W Rantau Panjang 3JH20 S Kota Tinggi 3JH18 # S Sg.Seluyut 3JH08 # S 3JH07 # S U % DOE River WQS DOE Marine WQS Sg.Temon Sg.Redan Johor Lama Sg.Tiram 3JH06 # S # S 3JH22 # S Sg.Berangan 3JH09 # S E # S Sg.Papan Sg.Layang Teluk Sengat # S 3JH03 Sg.Chemangar # S3JH25 # S Sg.Layau 3JH05 # S # S 3JH28 3JH30 Sg.Serai Tg.Serindet Sg.Tebrau U SJ4A % 1437951 U % 1340973 % U U % SJ4 % U 1438913 Pasir Gudang Sg.Kim Kim Tg.Surat U % Sg.Johor Sg.Belungkor 1440963 Sg.Buloh 1428939 U % U % 1439965 U % 1440916 Sg.Lebam U % SJ2 SJ1% U P.Ubin 1441966 U % P.Tekong 3JH33 # S Sg.Sebina 1443969 Sg.Santi U % Tg.Pengelih 1441967 % U U % 1441968 Figure 4.2: Locations of DOE river and marine water quality stations Water quality index (WQI) as shown in Table 4.4 is the most important criteria in order to determine the water quality in particular waterbodies and limit to freshwater or river. The use of an appropriate WQI would be more beneficial for administrative and management purposes and for meaningful communication with the public. DO, BOD, COD, AN, SS and pH are common parameters that are used by DOE in determining WQI. River classification for each parameter can be measured by using Table 4.5. The percentage of the entire parameters will be evaluated from that the classes will be determined. 52 Table 4.4: Water Quality Index (DOE, 1986) WQI range Pollution Degree <31.0 Severely polluted 31.0-51.9 Slightly polluted 51.9-76.5 Moderate 76.5-92.7 Clean >92.7 Very clean To compare the water quality status of the rivers and their changes over the past three years, the maximum, minimum and average values of the annual mean WQI for each river in 2004, 2005 and 2006 are plotted in Figure 4.3. Based on WQI, Sungai Serai, Sungai Berangan and Sungai Tiram are categorized as moderate river or Class III and most of the rivers are categorized as clean river or Class II. Figure 4.4 displays the water quality trend at each monitoring station along upper Sungai Johor mainstream over the past ten years from 1997 to 2006. The rivers’ water quality generally deteriorated towards the estuaries, indicating multiple inputs of pollutants along the river systems (Lim and Leong, 1988). As shown in Figure 4.4, stations 3JH19 and 3JH20 are categorized as clean or Class II except in June 1997 and the year 2000, which have been categorized as polluted river and moderate river, respectively. Station 3JH20 is located near Kota Tinggi bridge and station 3JH19 is approximately 7 kilometers upward from station 3JH20. Stations 3JH13 and 3JH15 are categorized as clean river or Class II. Station 3JH13 is located near Kampung Rantau Panjang, Kota Tinggi and station 3JH15 is located approximately 5 kilometers downward of station 3JH13. 53 Table 4.5: The DOE Water Quality Index Classification (DOE, 1986) Class Parameter Unit I II III IV V mg/l <0.1 0.1-0.3 0.3-0.9 0.9-2.7 >2.7 BOD mg/l <1 1-3 3-6 6-12 >12 COD mg/l <10 10-25 25-30 50-100 >100 DO mg/l >7 5-7 3-5 1-3 <1 pH - >7 6-7 5-6 <5 >5 mg/l <25 25-50 50-150 150-300 >300 76.5-92.7 51.9-76.5 31.0-51.9 <31.0 Ammoniacal Nitrogen Suspended solids Water quality Index >92.7 WQI (mg/l) WQI (mg/l) 60 Sa nt i Pa pa n Se lu yu t Pe le pa h La ya u Le ba m Te m on Se ra i Ti ra m Se m an ge Be r ra ng an La ya ng Sa nt i Pa pa n Se lu yu t Pe le pa h La ya u Le ba m Te m on Se ra i Ti ra m Se m an ge Be r ra ng an La ya ng WQI (mg/l) 60 Sa nt i Pa pa n Se lu yu t Pe le pa h La ya u Le ba m Te m on Se ra i Ti ra m Se m an ge Be r ra ng an La ya ng 54 100 2004 80 clean moderate 40 20 polluted 0 River 100 2005 80 clean moderate 40 20 polluted 0 River 100 2006 80 clean 60 moderate 40 20 polluted 0 River Figure 4.3: Range of WQI for selected rivers along Sungai Johor 55 3JH20 3JH19 100 Water QuaIity Index 90 clean 80 70 moderate 60 50 40 30 polluted 20 10 0 1997 1998 1999 2000 2001 2002 2003 tim e (years) 3JH15 2004 2005 2006 2007 3JH13 100 Water QuaIity Index 90 clean 80 70 moderate 60 50 40 30 polluted 20 10 0 1997 1998 1999 2000 2001 2002 2003 2004 tim e (years) 2005 2006 2007 Figure 4.4: Water quality trends at DOE river monitoring stations Water quality is the most important criterion in site selection. Marine and river water quality data of Sungai Johor basin were used to investigate the relationship between the longitudinal distribution of salinity, temperature and DO. The range of values of longitudinal distribution of salinity, temperature and DO parameters from Tanjung Pengelih to Kampung Rantau Panjang are summarized in Tables 4.6. Eight of the marine and river water quality stations were analyzed to investigate the temperature, dissolved oxygen and salinity concentration trend along Sungai Johor mainstream from downstream boundary at Tanjung Pengelih to 56 upstream boundary at Kampung Rantau Panjang. Trend of temperature, DO and salinity are shown in Figure 4.5-4.7, respectively. The longitudinal profiles of DO concentration, salinity and temperature for year 2003 to year 2005 are shown in Appendix A. Table 4.6: The Ranges of Value of Water Quality Parameters in Sungai Johor (DOE, 2006) Station No. 1441967 1440963 1440916 1340973 3JH20 3JH19 3JH15 3JH13 Distance from Tanjung Pengelih (km) 0 12 19 22 62 68 78 84 Temperature (°C) min max average 27.53 28.34 27.94 28.48 28.72 28.60 29.54 31.57 30.56 29.25 29.98 29.62 26.86 28.72 27.67 26.07 28.07 27.17 25.84 28.10 27.22 26.17 28.01 27.17 DO (mg/l) max average 6.71 6.59 6.71 6.57 6.62 6.48 6.32 6.21 6.40 5.59 6.67 6.36 6.85 6.54 6.75 6.57 min 6.47 6.42 6.33 6.09 4.87 5.94 6.07 6.22 min min 29.68 31.62 24.66 30.40 0.02 0.02 0.02 0.02 max Salinity (ppt) max average 32.82 31.25 33.33 32.48 29.68 27.17 31.02 30.71 0.03 0.03 0.03 0.02 0.03 0.03 0.04 0.03 average 1440916 32 temperature (°C) 31 1340973 30 1440963 3JH20 29 3JH19 3JH15 3JH13 28 27 1441967 26 25 0 DOWNSTREAM (Tg Pengelih) 10 20 30 40 50 60 distance from Tanjung Pengelih (km ) 70 80 90 UPSTREAM (Rantau Panjang) Figure 4.5: Trend of temperature from downstream boundary at Tanjung Pengelih towards upstream boundary at Rantau Panjang, Kota Tinggi (DOE, 2006). 57 min max average 1440916 8 7 1340973 DO (mg/l) 6 3JH20 1440963 5 3JH19 3JH15 3JH13 4 3 1441967 2 1 0 DOWNSTREAM (Tg Pengelih) 10 20 30 40 50 60 70 distance from Tanjung Pengelih (km ) 80 90 UPSTREAM Rantau Panjang) Figure 4.6: Trend of dissolved oxygen (DO) from downstream boundary at Tanjung Pengelih towards upstream boundary at Rantau Panjang, Kota Tinggi (DOE, 2006). min max average 1440916 40 35 1340973 salinity (ppt) 30 25 3JH20 1440963 3JH19 20 3JH15 3JH13 15 10 1441967 5 0 0 DOWNSTREAM (Tg Pengelih) 10 20 30 40 50 60 distance from Tanjung Pengelih (km ) 70 80 90 UPSTREAM (Rantau Panjang) Figure 4.7: Trend of salinity from downstream boundary at Tanjung Pengelih towards upstream boundary at Rantau Panjang, Kota Tinggi (DOE, 2006). 4.5 Intensive Survey Several intensive surveys were conducted by UTM research group during January- April 2008. The location of the intensive survey stations is shown in Figure 4.8. In this study, a large number of physical, chemical and biological parameters were collected from selected sampling sites along Sungai Johor estuarine system as 58 summarized in Table 4.7. Dissolved oxygen (DO), salinity, water temperature and specific conductance were taken at the sampling sites in January to April 2008. Measurements were taken vertically every one meter and about 1 foot below the water surface and 1 foot above the bottom. The maximum depth that could be measured at the site was 20 meters. Other water column analyses were biochemical oxygen demand, nitrite plus nitrate nitrogen, ammonia nitrogen, total phosphorus and total suspended solid. The samples were collected near mid channel by composting equal-sample volumes of water collected vertically from the surface to near the bottom. Table 4.7: Summary of intensive field surveys data (2008) Survey date N Location January 2008 7 Sungai Tiram February 2008 7 Sungai Tiram February 2008 12 Sungai Lebam February 2008 24 Sungai Johor mainstream March 2008 20 Sungai Johor mainstream March 2008 17 From Tg Pengelih to Tg Buai April 2008 17 Sungai Johor mainstream 59 N Rantau Panjang Sg.Johor W # S # S # S # S # S # S S # S # S Sg.Seluyut # S T $ # S Sg.Berangan U % # S V & # S 'W # S Sg.Redan V & 7 V & 6 # S 5 Johor Lama Sg.Papan V & 1 V & 4 V & 3 V & 2 Sg.Layang Sg.Chemangar # S Teluk Sengat # S Sg.Tebrau Sg.Serai Sg.Layau # S # S U % # S # S 'W 'W Pasir Gudang 'W Sg.Buloh 'W 'W Tg Pengelih Sg Johor Sg Lebam Sg Tiram Johor Strait Sg.Temon Sg.Tiram V & E Kota Tinggi U % # S U % % UU % U % U % U %% U Tg.Serindet Sg.Lebam U % T $ $% T U T Tg.Surat $ U % T $ Sg.Kim Kim T Sg.Johor$ T Sg.Belungkor $ T $ $ T T $ 'W 'W T $ T $ P.Tekong $ T P.Ubin T $ T $ Sg.Santi T $ T $ Tg.Pengelih T $ Sg.Sebina Figure 4.8: Locations of intensive survey stations along Sungai Johor. Water quality data from the Sungai Johor were used to investigate the relationship between the longitudinal distribution of salinity, temperature and DO. Figure 4.8 shows the location of longitudinal sampling stations along Sungai Johor estuary. The range of values of longitudinal distribution of salinity, temperature and DO parameters are shown in Tables 4.7 and Figures 4.9- 4.11. 60 Table 4.8: Data of in situ water quality parameters from Tg Pengelih to Kota Tinggi Station ID Distance from P01 (km) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 19 23 25 29 31 35 41 43 47 49 51 54 56 58 60 64 66 68 69 Salinity (ppt) P01 P02 P03 P04 P05 P06 P07 P08 P09 P10 P11 P12 P13 P14 P15 P16 P17 J20 J19 J18 J17 J16 J15 J14 J13 J12 J11 J10 J09 J08 J07 J06 J05 J04 J03 J02 J01 X (m) Y (m) 676636 676905 677226 677506 677651 677431 676998 676654 675852 674913 673898 673112 672253 671267 671401 671605 672180 672045 670877 670513 670278 670229 669970 667963 664151 661732 660657 659026 660300 660025 658805 657511 657709 656933 656711 655237 653974 151434 152409 153063 154082 155266 156293 157177 157778 158491 159031 159507 160100 160913 161780 162666 163268 164121 164565 164725 167102 168822 169761 171454 174875 179470 181209 182401 183439 186519 187410 187825 189121 189990 189953 190964 190927 191435 min 28.04 28.40 28.08 27.85 28.00 27.78 27.87 27.98 27.89 27.96 27.98 27.99 27.84 27.86 27.81 27.82 27.85 27.74 27.52 27.63 27.47 27.62 27.71 28.19 28.01 28.02 28.10 27.80 27.51 27.10 26.61 26.44 26.39 26.34 26.36 26.45 26.53 Temperature (°C) max average 28.30 28.14 28.72 28.55 28.33 28.17 28.03 27.91 28.60 28.23 28.40 28.10 28.64 28.15 28.15 28.05 27.95 27.92 27.96 27.96 27.99 27.99 28.70 28.24 27.98 27.90 28.46 28.06 28.33 28.04 28.33 28.02 28.45 28.09 27.85 27.79 27.76 27.68 27.85 27.73 27.82 27.60 27.87 27.71 27.99 27.89 28.25 28.21 28.32 28.16 28.46 28.31 28.43 28.29 28.17 28.01 28.32 27.90 27.19 27.14 27.01 26.76 27.04 26.70 26.54 26.45 26.46 26.38 26.36 26.36 26.45 26.45 26.54 26.54 min 22.25 21.71 27.35 27.09 25.77 25.41 26.13 25.36 25.54 25.18 24.64 23.62 23.71 21.32 21.45 21.12 20.61 27.42 26.52 26.15 25.79 26.11 26.85 24.39 21.39 19.82 20.14 15.44 10.84 5.66 1.73 1.04 0.67 0.15 0.07 0.08 0.17 Salinity (ppt) max 23.11 28.13 28.02 28.03 27.13 27.41 26.85 26.13 25.98 25.20 24.80 24.29 24.92 24.11 23.80 23.68 23.46 27.94 27.55 27.48 27.43 28.37 28.67 27.96 26.64 23.90 22.94 19.02 19.01 6.53 6.47 5.67 2.57 1.03 0.08 0.08 0.23 30 28 26 24 22 20 18 16 14 12 10 8 6 4 2 0 average 22.81 24.26 27.76 27.63 26.63 26.60 26.49 25.80 25.76 25.19 24.71 23.93 24.33 23.02 22.99 22.80 22.24 27.64 27.17 26.68 26.46 26.93 28.03 19.25 24.17 22.39 21.41 17.43 14.91 6.19 4.07 3.15 1.56 0.47 0.07 0.08 0.20 MIN 0 Tg Pengelih 10 20 30 40 50 Distance from Tanjung Pengelih (km) 60 MAX DO (mg/l) max 8.79 7.18 6.60 6.66 6.16 6.10 5.86 5.79 5.71 5.53 5.57 5.41 5.44 5.68 5.49 5.39 5.45 3.93 4.25 4.30 4.33 4.36 4.60 4.84 5.26 5.26 5.45 5.28 5.38 6.28 7.01 8.85 7.96 6.44 3.41 3.61 3.60 min 7.19 6.70 6.33 6.12 5.99 5.84 5.67 5.59 5.51 5.37 5.31 5.32 5.01 4.83 4.84 4.80 4.73 3.80 3.97 4.09 4.23 4.01 4.03 2.12 4.79 4.60 4.69 4.70 4.27 5.90 4.31 4.18 5.01 3.51 3.36 3.49 3.53 MEAN 70 80 Kota Tinggi Figure 4.9: Trend of salinity from Tanjung Pengelih (downstream) to Kota Tinggi (upstream) average 7.86 6.96 6.44 6.32 6.07 5.96 5.75 5.67 5.60 5.45 5.40 5.35 5.17 5.18 5.13 5.05 5.03 3.88 4.09 4.21 4.27 4.22 4.27 3.76 5.02 4.85 5.04 4.94 4.83 6.11 5.54 6.04 6.44 4.58 3.38 3.54 3.56 61 30 MIN MAX MEAN Temperature (°C) 29 28 27 26 25 0 10 20 30 40 50 60 Distance from Tanjung Pengelih (km) Tg Pengelih 70 80 Kota Tinggi Figure 4.10: Trend of temperature from Tanjung Pengelih (downstream) to Kota Tinggi (upstream) 10 MIN MAX MEAN Dissolved oxygen (mg/l) 9 8 7 6 5 4 3 2 Lower Sungai Johor 1 Upper Sungai Johor 0 0 10 Tg Pengelih 20 30 40 50 Distance from Tanjung Pengelih (km) 60 70 80 Kota Tinggi Figure 4.11: Trend of dissolved oxygen from Tanjung Pengelih (downstream) to Kota Tinggi (upstream) As shown in Figure 4.11, dissolved oxygen (DO) at upper and lower Sungai Johor estuary can be described as low DO a consequence of high nutrient enrichment as shown in Figure 4.12 and Figure 4.13 and becomes one of the most prominent stressor of estuarine and coastal aquatic biota. This condition of low DO is known as hypoxia. 62 Dissolved oxygen (DO) deficiency, as an index of deteriorated water quality, has been widely observed in estuarine and coastal waters. Hypoxia (deficient dissolved oxygen) has been observed frequently in the bottom water of the lower portion of the Rappahannock River tidal, a western shore tributary of Chesapeake Bay (Park et al., 1996). Several studies have been conducted to understand the controlling processes for hypoxia in Malaysian estuaries system such as Sungai Langat estuary and Sungai Skudai estuary (Hashim et al., 2005). Oxygen depletion was linked to nutrient loading such as eutrophication through the accumulation, deposition and decomposition of phytoplankton biomass (Smith et al., 1992). As stated by Vollenweider et al. (1992), the basic cause of nutrient problem in estuaries and near shore coastal waters is the enrichment of freshwater with nitrogen and phosphorus on their way to the sea and by direct input within the tidal systems. Coastal water receive pollutants either through direct discharges from coastal activities or indirectly through rivers which may be polluted from inland activities. Figure 4.12 shows the nitrogen (N) and phosphorus (P) loads from upper boundary of Sungai Johor estuary at Kampung Rantau Panjang. The most common effect of increased N and P supplies to aquatic ecosystems is an increase in the abundance of algae and aquatic plants. As stated by Smith (2003), these nutrient inputs have had profound negative effects upon the quality of surface waters worldwide. The maximum value of N load at Rantau Panjang in April 2006 is 3292 kg/day and minimum value of N load in August 2006 is 270 kg/day. The maximum value of P load in April 2006 is 32 kg/day and minimum value of P load in February 2006 is 10 kg/day. According to DHI Water and Environment (2004), Chlorophyll a measurements show relative high values with 15-20 µg/l for Malaysian rivers and 2540 µg/l in Singapore rivers, which could be due to the growth of phytoplankton in the upstream freshwater system. The nutrient levels in the same rivers are also high. 63 The maximum, minimum and average values of nitrate nitrogen, ammonia nitrogen and phosphorus concentrations of Sungai Johor tributaries are shown in Figure 4.13. Nitrate nitrogen concentration is high according to Interim Water Quality Standards (INWQS) at Sungai Serai and Sungai Berangan with average values of 3.94 mg/l and 4.85 mg/l, respectively. Ammonia nitrogen concentration is high in value at Sungai Serai, Sungai Tiram and Sungai Berangan with average values of 6.14 mg/l, 2.08 mg/l, and 3.30 mg/l, respectively. Phosphate concentration is high in value at Sungai Serai and Sungai Berangan with average values of 0.52 mg/l and 0.45 mg/l, respectively. The temporal profiles of DO concentrations, nitrogen and phosphorus loads of Sungai Johor tributaries from year 1996 to 2007 are shown in Appendix D. 2006 3500 350 3000 300 2500 250 2000 200 1500 150 1000 100 500 50 0 Jan (b) 0 Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2006 40 P load (kg/day) 400 Flow (m3/s) N load (kg/day) 4000 400 35 350 30 300 25 250 20 200 15 150 10 100 5 50 0 Jan Flow (m3/s) (a) 0 Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Figure 4.12: Nitrogen and Phosphorus Loads at Kampung Rantau Panjang Se ra i Ti r Se am m an ge Be r ra ng an Te m on La ya u Le ba m La ya ng NH3-N (mg/l) River (c) River Sa nt i Pa pa n Se lu yu t Pe R an le pa ta u h Pa nj an g Se ra i Ti r Se am m an ge Be r ra ng an Te m on La ya u Le ba m La ya ng NO3 (mg/l) (a) (b) Sa nt i Pa pa n Se lu yu t Pe R le an p ta ah u Pa nj an g River Sa nt i Pa pa n Se lu yu Pe t R an le pa ta u h Pa nj an g La ya ng Se ra i Ti ra m Se m an Be ger ra ng an Te m on La ya u Le ba m PO4 (mg/l) 64 MIN MIN MIN (a) Nitrate nitrogen (b) Ammonia nitrogen (c) Phosphate MAX MAX MEAN 14 12 10 8 6 4 2 0 MAX MEAN 16 14 12 10 8 6 4 2 0 2.00 MEAN 1.50 1.00 0.50 0.00 Figure 4.13: Water Quality Concentration in Sungai Johor tributaries. 65 4.6 Discrete Water Chemistry Samples The sampling program consists of water sample collection at each of the sampling locations along Sungai Johor estuary system. Laboratory data analysis has been conducted by the Faculty of Science, UTM Skudai. Figure 4.14 shows the water quality concentration trend along Sungai Johor estuary system from downstream boundary at Tanjung Pengelih to upstream boundary at Kota Tinggi. Figure 4.14(a) shows the profile of BOD concentration along Sungai Johor estuary system. The maximum value of BOD concentration is 1.1 mg/l and minimum value of BOD concentration is 0.9 mg/l. The maximum value of ammonia nitrogen concentration is 0.21 mg/l and minimum value is 0.07 mg/l. The maximum value of nitrate nitrogen concentration is 1.3 mg/l and minimum value is 0.1 mg/l. The maximum value of phosphate concentration is 0.47 mg/l and minimum value is 0.18 mg/l. (a) 2.0 WQ01 WQ02 WQ03 WQ04 WQ05 WQ06 WQ07 WQ08 1.8 1.6 BOD5 (mg/l) 1.4 1.2 1.0 0.8 0.6 0.4 0.2 0.0 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 Tanjung Pengelih distance (km ) Kota Tinggi 66 (b) 1.0 WQ01 WQ02 WQ03 WQ04 WQ05 WQ06 WQ07 WQ08 0.9 0.8 NH4-N (mg/l) 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 distance (km ) Tanjung Pengelih (c) 2.0 WQ01 WQ02 WQ03 WQ04 WQ05 WQ06 Kota Tinggi WQ07 WQ08 1.8 NO3-N (mg/l) 1.6 1.4 1.2 1.0 0.8 0.6 0.4 0.2 0.0 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 distance (km ) Tanjung Pengelih (d) 1.0 WQ01 WQ02 WQ03 WQ04 WQ05 WQ06 Kota Tinggi WQ07 WQ08 0.9 0.8 PO4 (mg/l) 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 Tanjung Pengelih distance (km ) Kota Tinggi Figure 4.14: Water quality concentration along Sungai Johor estuary system a) BOD b) NH3-N c) NO3-N and d) PO4 concentrations 67 4.7 Continuous Monitoring Data For the purpose of model calibration, an intensive field-monitoring to quantify the hydrodynamic conditions within the Sungai Johor Estuary was conducted on December 2007 to February 2008. Under this monitoring effort, a total of five continuous monitoring stations measured water surface elevation, salinity, DO and temperature. The continuous monitoring stations consists of permanently mounted instruments which recorded a 10-minute intervals of data. The instruments were placed near the bottom, approximately 3 feet above the river bed. The stations are located at Teluk Sengat, Johor Lama, Tanjung Serindet, Tanjung Buai and Tanjung Surat as shown in Figure 4.15 and summarized in Table 4.9. Table 4.9: Summary of Continuous Monitoring Stations of Sungai Johor Location Install date Removal date Duration Johor Lama 13/12/2007 06/01/2008 25 days Tanjung Buai 09/02/2008 08/02/2008 29 days Tanjung Serindet 13/02/2008 06/02/2008 25 days Tanjung Surat 13/12/2007 27/12/2007 15 days 13/01/2008 12/02/2008 31 days 13/12/2007 05/01/2008 24 days 13/01/2008 12/02/2008 31 days Teluk Sengat 68 Sg.Johor Rantau Panjang Vertical profile stations Continuous monitoring stations Kota Tinggi Sg.Seluyut N W Sg.Berangan E S Sg.Redan Sg.Temon # S V16 Johor Lama Sg.Tiram Sg.Papan V15 # S Sg.Layang Teluk Sengat V14 Sg.Chemangar Sg.Layau # S Sg.Serai V11 # S Sg.Tebrau # S V12 # S V13 Tg.Serindet Sg.Lebam V10#S Sg.Kim Kim Pasir Gudang Sg.Buloh V5 # S Sg.Johor Tg.Surat Sg.Belungkor V4#S # S V9 # S V8 # S V7 P.Ubin # SV6 V3 # S P.Tekong Sg.Sebina V2#S Sg.Santi Tg.Pengelih V1 #S Figure 4.15: Locations of vertical profile and continuous monitoring stations along Sungai Johor 4.8 Vertical Profiles Vertical profiles of salinity, temperature and dissolved oxygen were taken at each sampling stations as shown in Figure 4.15. Data were grouped with a one meter vertical resolution. Cruises typically started from Station Tanjung Pengelih and proceeded north towards Kota Tinggi or east to Pasir Gudang. The vertical salinity distribution characterized the degree of stratification and controled the vertical mixing process. A direct relationship between the occurrence of stratification and the depletion of oxygen below the pycnocline was found 69 throughtout the literature for many estuaries (Reynolds Fleming, 2003). Stratification separated the water column into vertical sections where the bottom layer was effectively cut off from reaeration due to the lack of mixing processes. This separation allowed benthic respiration to deplete DO in the lower layers. Increased benthic respiration and hence DO depletion were directly attributed to eutrophication. Hypoxia was defined as the reduction of DO concentration to less than 4 mg/l for a period lasting 24 hours or more (Thursby et al., 1999). The term severe hypoxia represented DO values less than 2 mg/l. Figure 4.16 which shows the measured vertical profiles of salinity, temperature and dissolved oxygen at Tanjung Pengelih, Tanjung Buai, Teluk Sengat, Pasir Gudang Port and Tanjung Belungkor stations. The profiles were measured on the same day as the longitudinal survey illustrated in Figure 4.8. The salinity increases with depth, while oxygen decreases with depth. The temperature does not changes with depth. The plots below indicate that the circulation pattern in a stratified estuarine system sustains the depleted oxygen condition, making estuaries fundamentally different in their oxygen budgets from freshwater rivers. Station: WQ01-Tg Pengelih 20 Salinity (ppt) and tem perature (°C) 22 24 26 28 30 32 0 2 4 Depth (m) (a) 6 8 10 temperature salinity DO 12 14 0 1 2 3 4 5 Dissolved oxygen (m g/l) 6 7 8 70 (b) Station: Tg Buai Salinity (ppt) and tem perature (°C) 20 22 24 26 28 30 32 0 1 2 Depth (m) 3 4 5 6 7 temperature salinity DO 8 9 0 2 Station: WQ07- Teluk Sengat 20 3 4 5 Dissolved oxygen (m g/l) 6 7 8 Salinity (ppt) and tem perature (°C) 22 24 26 28 30 32 0 1 2 Depth (m) (c) 1 3 4 5 temperature salinity DO 6 7 0 1 2 3 4 5 Dissolved oxygen (m g/l) 6 7 8 71 (d) Station: WQ05- Pasir Gudang Port 20 22 Salinity (ppt) and tem perature (°C) 24 26 28 30 32 0 2 Depth (m) 4 6 8 10 temperature salinity DO 12 14 0 2 Station: Belungkor 3 4 5 Dissolved oxygen (m g/l) 6 22 24 26 8 Date: 25 April 2008 Salinity (ppt) and tem perature (°C) 20 7 28 30 32 0 temperature salinity 2 DO 4 Depth (m) (e) 1 6 8 10 12 14 0 1 2 3 4 5 Dissolved oxygen (m g/l) 6 7 8 Figure 4.16: Vertical profiles of observed salinity, temperature and DO at Tanjung Pengelih, Tanjung Buai, Teluk Sengat, Pasir Gudang Port and Tanjung Belungkor stations 72 CHAPTER 5 RESULTS AND DISCUSSIONS 5.0 Introduction Calibration resulted in a consistent set of model coefficients that reproduced the observed data for all state variables considered. All model coefficients should be consistent between the calibration period and the verification period. The method used in determining the values for the model coefficients is essentially one of trial and error. The criteria for selecting an appropriate calibration and verification data set are adequate temporal and spatial coverage, and available data for all variables considered in the computation. An intensive survey conducted in January 14-30, 2008 was used as calibration data set. This calibration data set was selected because of the availability of a comprehensive set of data and adequate description of boundary conditions during the study period. Hsu et al. (1999) stated that it is an accepted requirement that a numerical model of estuarine hydrodynamics be calibrated and verified before being put into any practical usage. However, there is no widely accepted procedure for carrying out these tasks. Model calibration appears in various forms, dependent on data availability, characteristics of water body, and most of all, the perceptions and opinions of modelers. It often happens that calibrated model results were compared with observed data to demonstrate agreements, with little explanation of which coefficients were adjusted in arriving at the calibrated model. 73 Wang et al. (1990) reported that a model was initially calibrated to surface elevations and currents of astronomical tides, followed by calibration of exchange processes and turbulence closures. They further emphasized the quantitative measure of model performance in comparison with prototype data but they did not propose any procedure for carrying out model calibration and verification. Hsu et al. (1999) calibrated their vertical (lateral averaged) 2D model in three steps; preliminary calibration, fine tune calibration of friction coefficient and calibration of mixing processes. They recommended using the distribution of the tidal range as a function of distance from the river mouth to calibrate the friction coefficient. Hsu et al. (1999) gave a rational approach to calibrate and verify a hydrodynamic model of partially stratified estuaries. They applied their vertical (laterally averaged) 2D model to the tidal Tanshui River system, which is the largest tidal river in Taiwan. The friction coefficient was calibrated and verified with model simulation of barotropic flow, and the turbulent diffusion and dispersion coefficients were calibrated through comparison of salinity distribution. 5.1 Hydrodynamic Model Calibration The calibration methodology for the Sungai Johor EFDC model included graphical time series comparisons (qualitative) and statistical calculations (quantitative). The statistical calculations include a variety of statistical calculations. The calibration methodology is also parameter specific starting with the following: i. Water Surface Elevation ii. Temperature iii. Salinity Each one of these parameters has its importance in the determination of success for the model calibration and verification. The order in which the hydrodynamic model is calibrated is performed to address issues such as bathymetry, friction, tidal volume, cross-sectional area, and heat budget before salinity is 74 calibrated. Salinity is the predominant signal in the model to ensure that mass is being moved horizontally and vertically with the appropriate timing and direction. 5.1.1 Water Surface Elevation Calibration The water surface calibration was performed by modifying the downstream elevation boundary until the model closely fits the data at Tanjung Surat. Then, the bottom roughness was modified to reach an appropriate phase shift of the elevation signal at each of the stations. The model was executed using the boundary conditions for the calibration period of 30 days (January 1-30, 2008). During the calibration process, bottom roughness was determined to be the most influential modeling parameter for hydrodynamic modeling (Hashim, 2001; Liu et al., 2008). Bottom roughness values were adjusted until the predicted results reasonably matched the observed data. After several adjustments, a bottom roughness of 2 cm was selected for the use in this study. The model results were compared against observed data in the study period (January 14-30, 2008). The temporal profiles of observed and predicted tide level are compared in for the calibration period. As shown in Figures 5.1 and 5.2, the predicted tide levels reasonably matched the observed data at two sampling stations: Station Teluk Sengat and Tanjung Surat. These figures indicate that the model reasonably simulated the tide range and phase at a number of locations throughout Sungai Johor estuary. A study by Mohd Zaharifudin (2008) showed that after several adjustments, a bottom roughness of 4 cm was selected for use in upper Sungai Johor near Kota Tinggi Bridge. The modeled results were compared against DID data in his study period (July 1-31, 2006). The simulated water level showed a good and fairly good agreement with observations, indicated by the low values of root mean square as shown in Figures 5.1, 5.2, and 5.3 respectively and summarized in Table 5.1. 75 Table 5.1: Error analysis for observed and simulated water surface elevations Station Average error Average absolute Root Mean Square difference error difference difference Tanjung Surat 0.141 0.249 0.321 Teluk Sengat 0.136 0.231 0.281 Kota Tinggi 0.002 0.421 0.500 DS-INTL DS-INTL Water Quality Modeling for Sg Johor - Min value Calibration Results: Tanjung Surat (January 2008) 3.50 3.25 3.00 Water Surface Elevation (m) 2.75 2.50 2.25 2.00 1.75 1.50 1.25 1.00 Legend 0.75 tgsurat_WSE-Model tgsurat_WSE-Data 0.50 0.25 0.00 13 15 17 19 21 23 25 27 29 31 Time (days) DS-INTL DS-INTL Figure 5.1: Observed and simulated water surface elevations at Station Tanjung Surat DS-INTL DS-INTL Water Quality Modeling for Sg Johor - Min value Calibration Results: Teluk Sengat (January 2008) 3.50 3.25 3.00 Water Surface Elevation (m) 2.75 2.50 2.25 2.00 1.75 1.50 1.25 1.00 0.75 Legend 0.50 tlksengat_WSE-Model tlksengat_WSE-Data 0.25 0.00 13 15 17 19 21 23 25 27 29 31 Time (days) DS-INTL DS-INTL Figure 5.2: Observed and simulated water surface elevations at Station Teluk Sengat 76 Figure 5.3: Observed and simulated water surface elevations at Kota Tinggi (Mohd Zaharifudin, 2008). 5.1.2 Temperature Calibration Temperature was the hydrodynamic parameter with the least calibration. The temperature data were used at Tanjung Pengelih for the downstream boundary. The summary statistics, time series plots of the draft calibration for temperature at Station Tanjung Surat and Teluk Sengat are shown in Table 5.2 and Figures 5.4-5.5, respectively. The simulated water temperature showed good and fairly good agreement with observations, indicated by the low values of root mean square as shown in Figures 5.4 and 5.5 and summarized in Table 5.2. 77 Table 5.2: Error analysis for observed and simulated water temperature Station Average error Average absolute error RMS Tanjung Surat 0.595 0.941 1.126 Teluk Sengat -0.158 0.428 0.524 Figures 5.6 and 5.7 present the longitudinal comparisons of the simulated water temperature and the measured data. The pattern of water temperature along Sungai Johor can be seen in Figure 5.6 from Tanjung Pengelih to Johor Lama. The pattern of water temperature along Johor Straits can be seen in Figure 5.7 from Tanjung Kopok to Sungai Tebrau estuary. The simulated water temperature is compared with DOE marine water quality data at Station SJ1, SJ2, SJ4 and SJ4A. NTL DS- Temperature Calibration for Sg Johor Station: Tanjung Surat 35 34 33 Legend Measured Simulated Temperature (°C) 32 31 30 29 28 27 26 25 14 15 16 17 18 19 20 21 22 Time (days) NTL DS- Figure 5.4: Observed and Simulated Temperatures at Station Tanjung Surat 78 Figure 5.5: Observed and Simulated Temperatures at Station Teluk Sengat measured simulated 35 WQ01 PF03 BLKR WQ02 WQ03 WQ06 WQ08 WQ07 Temperature,°C 30 25 20 15 10 0 2 4 Tanjung Pengelih 6 8 10 12 14 16 18 20 22 distance, km Figure 5.6: Temperature profile along Sungai Johor 24 26 28 Johor Lama 79 MIN SJ1 MAX MEAN model 34 SJ2 Temperature (°C) 33 SJ4A 32 31 30 29 28 27 0 2 4 6 Kg Tg Kopok 8 10 12 14 16 18 20 distance from Tg Kopok 22 24 26 28 Sg Tebrau Estuary Figure 5.7: Temperature profile along Johor Straits 5.1.3 Salinity Calibration In most estuaries with a significant freshwater discharge, salinity may serve as an ideal natural tracer for mixing processes calibration. Salinity distribution in an estuary is affected by the tidal current, freshwater discharge, density circulation, as well as turbulent mixing processes. Therefore the salinity distribution reflects the combined results of all processes, and in turn it controls density circulation and modifies mixing processes. Salinity is the key parameter of concern because it can dictate how well the model is transporting mass in the system. Hsu et al. (1999) calibrated the coefficient in the turbulence model by matching the observed and computed salinity distributions. The summary statistic and time series plot of the preliminary calibration for salinity are shown in Figure 5.8 and Table 5.3. 80 DS-INTL DS-IN Salinity Calibration for Station Tanjung Surat Calibration Results: Time Series Summary 30 28 Legend Simulated Measured Salinity (ppt) 26 24 22 20 14 16 18 20 22 24 26 28 30 Time (days) Figure 5.8: Observed and Simulated Salinity at Station Tanjung Surat To provide a quantitative assessment of the EFDC predictive capability, each time series comparison underwent a simple statistical treatment to determine a mean difference, mean absolute difference, and root mean square difference as shown in Table 5.3. Based on the error analysis as shown in Table 5.3, the model is underpredicted in response to the natural system at Station Tanjung Surat. This might be due to the errors in the bathymetry data or the errors associated to the prescribed boundary conditions as stated by Liu et al., (2008). In Figure 5.9, the model reproduced seasonal trends of measured salinity for the Sungai Johor estuarine system. Figure 5.10 present the longitudinal comparison of the simulated salinity against the DOE marine water quality monitoring data at SJ1, SJ2, SJ4 and SJ4A stations. Table 5.3: Error analysis for observed and simulated salinity Station Tanjung Surat Average error -0.495 Average absolute error 1.026 RMS 1.206 81 measured 35 WQ01 PF03 30 WQ02 simulated WQ06 BLKR WQ03 WQ07 WQ08 Salinity, ppt 25 20 WQ09 15 10 5 0 -5 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 distance, km Figure 5.9: Salinity profile along Sungai Johor MIN SJ1 MAX MEAN model 30 Salinity (ppt) 28 SJ2 26 24 SJ4A 22 20 18 0 Kg Tg Kopok 2 4 6 8 10 12 14 16 18 distance from Tg Kopok 20 22 24 26 28 Sg Tebrau Estuary Figure 5.10: Salinity profile along Johor Straits 5.2 Water Quality Model Calibration The measured values from the collected survey data were used for calibrating the EFDC water quality model. The data consists of dissolved oxygen, BOD, ammonia, other nutrients, and chlorophyll-a concentrations. Specifically, for the EFDC model calibration, dissolved oxygen concentration at Station Tanjung Surat was used. 82 5.2.1 Dissolved Oxygen Predicted and measured DO concentration was compared at Station Tanjung Surat as presented in Figure 5.11. To provide a quantitative assessment of the EFDC predictive capability, time series comparison underwent a simple statistical treatment to determine a mean difference, mean absolute difference, and root mean square difference as shown in Table 5.4. DO calibration result as presented in Table 5.4 shows that the response of the natural system of the DO concentration at Station Tanjung Surat was overpredicted. Table 5.4: Error analysis for observed and simulated dissolved oxygen Station Tanjung Surat Average error Average absolute error 0.795 0.826 RMS 0.949 Dissolved oxygen longitudinal profile along Sungai Johor as shown in Figure 5.12 shows that DO concentration increased at upper Sungai Johor estuary and decreased at lower Sungai Johor estuary. A component analysis for DO indicated that, on average, the major source of DO was reaeration, algal production, while sinks included sediment oxygen demand (SOD) and respiration. Figure 5.13 present the longitudinal comparison of the simulated dissolved oxygen concentration to the DOE marine water quality monitoring data at SJ1, SJ2, SJ4 and SJ4A stations. 83 INTL DS-IN DO calibration profile for Sungai Johor Station: Tanjung Surat 8 7 Legend Dissolved Oxygen (mg/l) 6 measured data 5 4 3 2 1 14 15 16 17 18 19 20 21 22 Time (days) DS-IN INTL Figure 5.11: Observed and Simulated DO at Station Tanjung Surat measured simulated 10 9 8 DO, mg/l 7 6 WQ01 PF03 WQ02 BLKR 5 WQ09 WQ03 WQ06 WQ07 4 WQ08 3 2 1 0 2 Tg Pengelih 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 distance, km Figure 5.12: DO concentration profile along Sungai Johor 40 42 44 46 Kota Tinggi 84 MIN Dissolved oxygen (mg/l) SJ1 10 9 8 7 6 5 4 3 2 1 0 MAX MEAN model SJ2 0 2 4 6 8 SJ4A 10 12 14 16 18 20 24 26 28 Sg Tebrau Estuary distance from Tg Kopok Kg Tg Kopok 22 Figure 5.13: Dissolved oxygen concentration profile along Johor Straits 5.2.2 Ammonia Nitrogen Model prediction and simulation for ammonia nitrogen concentration were compared as shown in Figure 5.14. The predicted ammonia nitrogen was compared to the measured values from the sampling data in January 2008. The longitudinal profile of simulated and observed ammonia nitrogen are shown in Figure 5.14. The predicted ammonia nitrogen is in the range of observed data. NH4-N longitudinal profile along Sungai Johor 1.0 measured 0.9 simulated 0.8 NH4-N, mg/ 0.7 0.6 0.5 0.4 0.3 0.2 WQ01 WQ02 0.1 WQ03 WQ06 WQ07 WQ08 WQ09 WQ10 0.0 0 2 4 6 Tanjung Pengelih 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 distance, km Kota Tinggi Figure 5.14: Ammonia nitrogen concentration profile along Sungai Johor 85 5.2.3 Nitrate Nitrogen Model prediction and simulation for nitrate nitrogen concentration were compared as shown in Figure 5.15. The longitudinal profile of simulated and observed nitrate nitrogen are shown in Figure 5.15. The predicted nitrate nitrogen is in the range of observed data. NO3-N longitudinal profile along Sungai Johor NO3-N, mg/ measured 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0.6 0.4 0.2 0.0 simulated WQ10 WQ06 WQ07 WQ02 WQ03 WQ08 WQ09 WQ01 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 Tanjung Pengelih distance, km Kota Tinggi Figure 5.15: Nitrate nitrogen concentration profile along Sungai Johor 5.2.6 Total Phosphate Model predictions and simulations for total phosphorus concentration were compared as shown in Figure 5.16. The longitudinal profile of simulated and observed phosphate are shown in Figure 5.14. The predicted phosphate is in the range of observed data. 86 PO4 longitudinal profile along Sungai Johor measured simulated 1.0 PO4, mg/l 0.8 0.6 0.4 WQ08 WQ01 WQ02 0.2 WQ03 WQ06 WQ07 WQ10 WQ09 0.0 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46 48 50 distance, km Figure 5.16: Total Phosphate concentration profile along Sungai Johor 5.2.7 Chlorophyll a According to DHI Water and Environment (2004), Chlorophyll a measurements show relatively high values (15-20 µg/l for Malaysian rivers and 2540 µg/l for Singapore rivers) which could be due to the growth of phytoplankton in the upstream freshwater system. The nutrient levels in the same rivers are also high. Mixing with marine-based Chlorophyll a from eutropied waters is also a possible factor for the high readings. Model simulation for Chlorophyll a concentration along Sungai Johor is shown in Figure 5.17. As shown in Figure 5.17, Chlorophyll a concentration along Sungai Johor is affected by the change of maximum algal growth rate. 87 baseline algal gro wth rate=1 algal gro wth rate=3 10 9 8 Chl a (ug/l) 7 6 5 4 3 2 1 0 0 5 Tg P engelih 10 15 20 25 30 35 40 distance, km 45 Ko ta Tinggi Figure 5.17: Chlorophyll a concentration profile along Sungai Johor 5.3 Hydrodynamic Model Sensitivity Analysis Through model calibration, the sensitivity of each parameters can be identified in EFDC model. Obviously, bathymetry is one of the most critical pieces of information for the model and a significant amount of time and effort were placed on capturing the bathymetry in the model with limited smoothing and averaging. As for the other model inputs and calibration parameters, the Sungai Johor upstream flow, downstream/ocean salinity boundary, and bottom roughness rank as the most sensitive parameters for the EFDC model. The horizontal eddy viscosity was also run for comparisons. These parameters were changed in the EFDC model while holding the bathymetry constant. 5.3.1 Sensitivity of Water Surface Elevation to Bottom Roughness The EFDC model uses bottom roughness to account for the energy loss due to the friction exerted from the sides and bottom of the channel and any other forms of energy loss, such as meandering channels. Based on the sensitivity analysis, the bottom roughness was constant throughout most of the model domain. Bottom 88 roughness is very sensitive to water surface elevation at upper Sungai Johor and insensitive to lower Sungai Johor as presented in Tables 5.5, 5.6, and 5.7, respectively. Table 5.5: Sensitivity analysis of bottom roughness with water surface elevation at Station Tanjung Surat Scenarios At Station Tanjung Surat Average error difference Average absolute error difference Root Mean Square, RMS difference Z= 0.01 Z= 0.02 Z= 0.03 Z= 0.04 0.143 0.141 0.145 0.143 0.252 0.249 0.252 0.251 0.327 0.321 0.324 0.323 Table 5.6: Sensitivity analysis of bottom roughness with water surface elevation at Station Teluk Sengat Scenarios At Station Teluk Sengat Average error difference Z= 0.01 Z= 0.02 Z= 0.03 Z= 0.04 0.135 0.136 0.136 0.136 Average absolute Root Mean Square, error difference RMS difference 0.236 0.231 0.234 0.235 0.288 0.281 0.286 0.287 Table 5.7: Sensitivity analysis of bottom roughness with water surface elevation at Station Kota Tinggi (Mohd. Zaharifudin, 2008) Scenarios At Station Kota Tinggi Average error difference Average absolute error difference Root Mean Square, RMS difference Z= 0.02 Z= 0.03 Z= 0.04 Z= 0.05 Z= 0.06 Z= 0.07 2.374 0.932 0.002 0.008 0.015 0.021 2.387 1.129 0.421 0.440 0.458 0.474 2.498 1.408 0.500 0.523 0.543 0.561 89 5.3.2 Sensitivity of Salinity to Bottom Roughness Based on the error analysis at Tanjung Surat as shown in Table 5.8 and Figure 5.18, mean error values are less than zero. It shows that the model is underpredicted in response to the natural system. Table 5.8: Error analysis for salinity sensitivity analysis with bottom roughness at Station Tanjung Surat Station Average error Average absolute error RMS Z= 0.01 -0.355 0.987 1.203 Z= 0.02 -0.314 0.947 1.158 Z= 0.03 -0.410 0.964 1.191 Z= 0.04 -0.450 1.002 1.243 DS-INTL DS-INTL Salinity sensitivity analysis with bottom roughness Station: Tanjung Surat 26 25 24 Salinity (ppt) 23 22 21 Legend 20 z= 0.02 z=0.01 z=0.03 z=0.04 19 18 14.00 14.80 15.60 16.40 17.20 18.00 18.80 19.60 20.40 21.20 22.00 Time (days) DS-INTL DS-INTL Figure 5.18: Sensitivity of salinity to bottom roughness at Station Tanjung Surat 5.3.3 Sensitivity of Salinity to Horizontal Eddy Viscosity The EFDC model was sensitive to the horizontal eddy viscosity. The calibration run was made with the horizontal eddy viscosity at 25 m2/s. This 90 parameter was varied from 0.005 m2/s to 75 m2/s. The profile of various values of horizontal eddy viscosity at Station Tanjung Surat are shown in Tables 5.9 and Figure 5.19. DS-INTL DS-INTL Salinity Calibration for Sg Johor - horizontal eddy visc=25, decrease water temp Calibration Results: Time Series Summary 25 24 Salinity (ppt) 23 22 Legend sal1_eddy0.005 sal1_eddy50 sal1_eddy75 sal1_eddy0.01 sal1_eddy0.05 21 20 14 15 16 17 18 19 20 21 22 Time (days) DS-INTL DS-INTL Figure 5.19: Sensitivity of salinity to horizontal eddy viscosity at Station Tanjung Surat Table 5.9: Error analysis for salinity sensitivity analysis with horizontal eddy viscosity at Station Tanjung Surat Scenarios Horizontal eddy viscosity 0.005 0.01 25.00 50.00 75.00 RMS error Average absolute error Average error 1.145 1.534 0.428 1.451 1.491 0.797 1.090 0.329 1.160 1.205 0.509 0.734 0.291 -0.441 -0.488 91 5.3.4 Sensitivity of Salinity to Upstream Boundary Condition As shown in Figure 5.20, the salinity concentrations are sensitive to the upstream boundary condition at Rantau Panjang. The model was run for the worse case scenario during the flood event at Kota Tinggi in January 2007. The freshwater inflows from upstream boundary at Rantau Panjang has significantly changed the salinity concentrations at upper Sungai Johor estuarine system. no rmal flo w heavy flow 30 salinity, ppt 25 20 15 10 5 0 0 Tg Pengelih 5 10 15 20 25 30 35 distance, km 40 45 Kota Tinggi Figure 5.20: Sensitivity of salinity to upstream boundary conditions 5.3.5 Sensitivity of Salinity to Downstream Salinity Boundary The downstream salinity boundary was increased by 1 ppt and 2 ppt when the salinity boundary changed by 10% and 20% from the baseline run. As shown in Figure 5.21, the salinity concentration is sensitive to dowstream salinity boundary. 92 10% 20% 28 26 24 salinity, ppt 22 20 18 16 14 12 10 8 6 4 2 0 0 5 10 15 Tg Pengelih 20 25 distance, km 30 35 40 45 Kota Tinggi Figure 5.21: Sensitivity of salinity to downstream salinity boundary 5.4 Water Quality Model Sensitivity Analysis Since a mathematical model is a simplified representation of the real world, its prediction is often subject to considerable uncertainty from a variety of sources. These sources include over simplification of modeling assumptions and formulations, noise-distorted data, and model parameter values. It is important to gain a better understanding of a model’s reliability by analyzing the uncertainties associated with a model. Sensitivity analysis is a prime method in measuring a model’s uncertainty and reliability. In this study, the sensitivity of the DO concentration to various parameters was evaluated. The analysis was performed by assessing the impacts of the following factors on DO: i) COD decay rates ii) Nitrification rates iii) Sediment oxygen demand (SOD) iv) Maximum algal growth rate v) Loads from point sources vi) Reaeration rate 93 Sensitivity tests were run on a baseline model simulation in January 2008. The sensitivity of the dissolved oxygen to the parameters changes were estimated by comparing it with the baseline model scenario. The sensitivity analysis results are based upon the varying parameters are shown in tables and figures below. The following sections discuss the results of the tested parameters. 5.4.1 Sensitivity to COD Decay Rate The basic COD decay rate for the baseline run was 0.10 l/day. The variations of the parameter were 0.04 and 0.40 1/day at Station Tanjung Surat and Teluk Sengat. As shown in Figures 5.22 and 5.23, with the same magnitude of variation in parameter values, the DO concentrations are sensitive to the COD decay rate. Table 5.10 and 5.11 show the error analysis of DO concentration to COD decay rate. DS-INTL DS-INTL DO sensitivity analysis with COD decay rate Station: Tanjung Surat 8 Legend 7 Dissolved Oxygen (mg/l) 6 KCD=0.1 KCD=0.4 KCD=0.04 KCD=0.06 KCD=0.08 5 4 3 2 1 14 15 16 17 18 19 20 21 22 Time (days) DS-INTL DS-INTL Figure 5.22: Sensitivity of DO to COD decay rate at Station Tanjung Surat 94 Table 5.10: Error analysis of DO sensitivity analysis to COD decay rate at Station Tanjung Surat Scenarios RMS error Average absolute error Average error KCD = 0.10 0.571 0.406 0.380 KCD = 0.40 0.769 0.552 0.258 KCD=0.04 0.528 0.449 -0.373 KCD=0.06 0.365 0.283 -0.079 KCD= 0.08 0.374 0.265 0.134 DS-INTL DS-INTL DO sensitivity analysis with COD decay rate Station: Teluk Sengat 8 7 Dissolved Oxygen (mg/l) 6 5 4 Legend KCD=0.1 KCD=0.4 KCD=0.04 KCD=0.06 KCD=0.08 3 2 1 14 15 16 17 18 19 20 21 22 Time (days) DS-INTL DS-INTL Figure 5.23: Sensitivity of DO to COD decay rate at Station Teluk Sengat Table 5.11: Error analysis of DO sensitivity analysis to COD decay rate at Station Teluk Sengat Scenarios RMS error Average absolute error Average error KCD= 0.04 0.580 0.556 -0.556 KCD= 0.06 0.234 0.211 -0.211 KCD= 0.08 0.267 0.239 -0.237 KCD = 0.10 0.000 0.000 0.000 KCD = 0.40 0.645 0.533 0.075 95 5.4.2 Sensitivity of DO to Nitrification Rate The basic nitrification rate for the baseline run was 0.07 1/day. The sensitivity of the instream DO concentrations to the nitrification rate was analyzed by changing the value of the parameter with 0.01 and 0.10 1/day. The resulting sensitivity for Station Tanjung Surat and Teluk Sengat is shown in Figures 5.24 and 5.25, respectively. DO regime in Sungai Johor estuary is not sensitive to this parameter variation. Table 5.12 and 5.13 show the error analysis of DO concentration to nitrification rate. DS-INTL DS-INTL DO sensitivity analysis with Kn Station: Tanjung Surat 8 Legend 7 Kn=0.07 Kn= 0.1 Kn=0.01 Dissolved Oxygen (mg/l) 6 5 4 3 2 1 0 14 15 16 17 18 19 20 21 22 Time (days) DS-INTL DS-INTL Figure 5.24: Sensitivity of DO to nitrification rate at Station Tanjung Surat Table 5.12: Error analysis of DO sensitivity analysis to nitrification rate at Station Tanjung Surat Scenarios RMS error Average absolute error Average error Kn = 0.07 0.296 0.224 0.202 Kn = 0.10 0.487 0.388 -0.022 Kn = 0.01 0.268 0.197 0.160 96 DS-INTL DS-INTL DO sensitivity analysis with nitrification rate, Kn Station: Teluk Sengat 8 Legend Kn=0.07 Kn=0.1 Kn=0.01 7 Dissolved Oxygen (mg/l) 6 5 4 3 2 1 0 14 15 16 17 18 19 20 21 22 Time (days) DS-INTL DS-INTL Figure 5.25: Sensitivity of DO to nitrification rate at Station Teluk Sengat Table 5.13: Error analysis of DO sensitivity analysis to nitrification rate at Station Teluk Sengat Scenarios RMS error Average absolute error Average error Kn = 0.07 0.000 0.000 0.000 Kn = 0.10 0.204 0.170 -0.057 Kn = 0.01 0.267 0.237 -0.233 5.4.3 Sensitivity of DO to Sediment Oxygen Demand Benthic sediment is recognized as a potentially large oxygen sink in water bodies (Bowman and Delfino, 1980). Past research has indicated that the sediment oxygen demand can account for a major portion of the overall oxygen uptake for some surface waters. The SOD rate is an important parameter in water quality modelling especially for the modelling of dissolved oxygen in surface waters. The predictions from these models were used by some government agencies such as the United States 97 Environmental Protection Agency (USEPA) for determining the specifications for wastewater discharge permits from municipal and industrial effluent discharges (Brown and Barnwell, 1987). Some of the earliest work on the magnitude of the SOD was done by Baity (1938) and Fair et al. (1941). A variety of other in situ measurements have been made for numerous water bodies in recent years. Table 5.14 summaried the range of SOD values. For Malaysian river application, an example of the SOD values for Sungai Tebrau is presented in Table 5.15. Table 5.14: Some sediment oxygen demand values Bottom type and location Sphaerotilus – (10 g dry wt/m2) Municipal sewage sludge-outfall vicinity Municipal sewage sludge- “aged”, downstream of outfall Estuarine mud Sandy bottom Mineral soils Source: Thomann (1972) SOD (g O2/m2.day)@20ºC Range Approximate average 7 2-10.0 4 1-2 1.5 1-2 0.2-1.0 0.05-0.1 1.5 0.5 0.07 Table 5.15 :Sediment Oxygen Demand for Sungai Tebrau (IPASA, 2002) Location SOD (g/m2/day) Senai 1 0.144 Senai 2 1.987 Kg Maju Jaya 0.720 Pasar Borong Pandan 2.074 SOD is the total oxygen consumption incurred by the biochemical processes in the sediment layer. Generally, SOD is positively correlated to nutrient and organic loadings for a specific water body (Di Toro et al., 1990; Chapra, 1997; DNREC, 2001). The basic SOD value for the baseline run was 2.00 g/m2/day. The variations of the parameter were 1.00 and 5.00 g/m2/day at Station Tanjung Surat as presented 98 in Figure 5.26 and Table 5.16. Figure 5.27 shows that the DO concentration is moderately sensitive to changes in SOD along the Sungai Johor. Table 5.16: Sensitivity of DO to SOD Scenarios SOD= 1.00 SOD= 2.00 SOD= 3.00 SOD= 4.00 SOD= 5.00 RMS error 0.456 0.237 0.270 0.503 0.770 DS-INTL Average absolute error 0.401 0.191 0.204 0.458 0.732 Average error -0.382 -0.100 0.732 0.180 0.458 DS-INTL DO sensitivity analysis with SOD Station: Tanjung Surat 8 Legend SOD=1 SOD=2 SOD=5 SOD=3 SOD=4 7 Dissolved Oxygen (mg/l) 6 5 4 3 2 1 14 15 16 17 18 19 20 21 22 Time (days) DS-INTL DS-INTL Figure 5.26: Sensitivity of DO to SOD at Station Tanjung Surat baseline SOD=1 SOD=3 10 9 8 DO (mg/l) 7 6 5 4 3 2 1 0 0 Tg P engelih 5 10 15 20 25 30 35 distance, km Figure 5.27: Sensitivity of DO to SOD 40 45 Kota Tinggi 99 5.4.4 Sensitivity of DO to Maximum Algal Growth Rate The basic maximum algal growth rate value for the baseline run was 2.00 day-1. The variations of the parameter were 1.00 and 3.00 g/m2/day. As shown in Figure 5.28, DO concentration is sensitive to the changes in algal growth rate. baseline algal gro wth rate=1 algal gro wth rate=3 10 9 8 DO (mg/l) 7 6 5 4 3 2 1 0 0 5 Tg P engelih 10 15 20 25 30 distance, km 35 40 45 Ko ta Tinggi Figure 5.28: Sensitivity of DO to maximum algal growth rate 5.4.5 Sensitivity of DO to Loads from Point Sources. The sensitivity of DO concentration to the pollutant loads from the point sources was analyzed by changing the load of NH3-N, NO3-N, PO4, COD and DOC from the dischargers. The resulting sensitivity is shown in Figure 5.29. As shown in Figure 5.29, DO concentration is sensitive to changing loads from point sources. 100 10 baseline maximum lo ad minimum lo ad 9 8 DO (mg/l) 7 6 5 4 3 2 1 0 0 5 10 15 20 25 30 35 40 distance, km Tg P engelih 45 Ko ta Tinggi Figure 5.29: Sensitivity of DO to loads from point sources. 5.4.6 Sensitivity of DO to Reaeration Rate. The effect of reaeration rate on DO distribution was analyzed by changing the value of the reaeration rate with factors of 1.00 and 3.00. Figure 5.30 plots the relative sensitivity of DO to the reaeration rate constant by distance from downstream boundary at Tanjung Pengelih. It is observed that the DO concentration is moderately sensitive to the reaeration rate coefficient. baseline reaeratio n=1 reaeratio n=3 11 10 9 DO (mg/l) 8 7 6 5 4 3 2 1 0 0 Tg P engelih 5 10 15 20 25 30 35 40 distance, km Figure 5.30: Sensitivity of DO to reaeration rate 45 Ko ta Tinggi 101 CHAPTER 6 CONCLUSIONS AND RECOMMENDATIONS 6.1 Conclusions A numerical model has been applied to study the hydrodynamic and water quality characteristics of estuary. The hydrodynamic model is based on the principles of conservation of volume, momentum and mass, and the water quality on the conservation of mass. The model was successfully applied to Sungai Johor estuarine system. Sensitivity analysis method was used in this study to identify the sensitivity of EFDC hydrodynamic and water quality parameters of the Sungai Johor model. This identification enabled modellers to put more emphasis on sensitive model parameters during model calibration. With the available data and time constraints, reasonable results were obtained for hydrodynamic and water quality model calibration. Therefore, EFDC model proved to be quite effective in the hydrodynamic and water quality simulation of water surface elevation, water temperature, salinity, DO and nutrients concentration of Sungai Johor estuarine system. Model calibration was conducted to compare the observed and simulated results using graphical comparisons, absolute mean errors, and RMSEs. 102 6.2 Recommendations During the present study, the following limitations have been noted. These need to be further investigated and be included in future model calibration and applications to improve the model predictive capability. i) In the future research, the impacts of wind data and finer grids on the velocity simulation will be explored. ii) As almost all other investigators have noticed, it was the turbulence closure model that limited the predictive capability of the hydrodynamic model and thus its capability to other systems. More understanding and better numerical representation of the turbulent mixing processes are essential to improve the model capability. iii) Coupling of the water quality model with a sediment transport model and a sediment diagenesis model is important in predicting the nutrient movement, particularly for phosphate and sediment nutrient exchanges. The mechanisms that appear to be of significant include the absorption of phosphate to sediment particles and subsequent settling, transportation of sediment in response to high freshwater flow and the release of sediment phosphate. iv) The demise of freshwater phytoplankton in the presence of salt is thought to be a possible mechanism that limits the characteristic of high chrolophyll a concentration to the tidal freshwater portion of the river, as has been frequently observed in many estuarine environments including the Sungai Johor river system. v) The current calibration of the water quality model has a shortcoming in the prediction of nutrients. It was not because of the model but because of the quality and quantity of the field data used for the current calibration. The present model needs to be calibrated with more detailed field data to perform the sensitivity analysis pertaining to nutrient limitation. vi) Future works is to link the output of wave model such as SWAN nearshore modeling with EFDC hydrodynamic model to improve river 103 and coastal hydrodynamic with wave parameter effect at Sungai Johor estuarine system. vii) This modeling study should involve watershed hydrology modeling. A large number of modeling parameters have been defined based upon previous similar studies, the best available data, standard modeling assumptions, and comparison with with relevance literature. It is anticipated and recommended that the development of this model be continued to synthesis additional field data into the modeling process as that data become available. 104 REFERENCES Ali, N., Elshafie, A., Karim, O.A. and Jaafar, O. (2009). Prediction of Johor River Water Quality Parameters Using Artificial Neural Network. 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Issue 1. pp 71-92 114 APPENDIX A.1: DO concentration profiles along Sungai Johor 2005 min max average 10 1440916 9 DO (mg/l) 8 1440963 3JH15 7 3JH20 6 5 1441967 3JH13 3JH19 1340973 4 3 2 1 0 Tanjung Pengelih 10 20 30 40 50 60 70 80 90 Rantau Panjang distance from Tanjung Pengelih (km ) 2004 min max average 10 9 1440963 1340973 DO (mg/l) 8 3JH20 3JH15 7 6 5 1441967 3JH19 1440916 3JH13 4 3 2 1 0 Tanjung Pengelih 10 20 30 40 50 60 70 80 90 Rantau Panjang distance from Tanjung Pengelih (km ) 2003 min max average 10 9 3JH15 DO (mg/l) 8 7 6 1440963 1440916 3JH20 1441967 1340973 5 3JH13 3JH19 4 3 2 1 0 Tanjung Pengelih 10 20 30 40 50 60 distance from Tanjung Pengelih (km ) 70 80 90 Rantau Panjang 115 APPENDIX A.2: Salinity profiles along Sungai Johor 2005 min max average 40 35 1440963 1340973 Salinity (pptl) 30 25 1441967 20 1440916 15 10 5 3JH20 3JH19 3JH15 3JH13 0 0 Tanjung Pengelih 10 20 30 40 50 60 70 80 90 Rantau Panjang distance from Tanjung Pengelih (km ) 2004 min max average 40 35 Salinity (pptl) 30 25 1440963 1340973 1441967 20 15 10 5 1440916 3JH20 3JH19 3JH15 3JH13 0 0 Tanjung Pengelih 10 20 30 40 50 60 70 80 90 Rantau Panjang distance from Tanjung Pengelih (km ) 2003 min max average 40 35 Salinity (pptl) 30 25 1440963 1340973 20 15 1441967 1440916 10 5 3JH20 3JH19 3JH15 3JH13 0 0 Tanjung Pengelih 10 20 30 40 50 60 distance from Tanjung Pengelih (km ) 70 80 90 Rantau Panjang 116 APPENDIX A.3: Temperature profiles along Sungai Johor 2005 32 Temperature (°C) 30 min max average 1440916 1441967 3JH20 1340973 3JH15 28 1440963 26 3JH13 3JH19 24 22 20 0 Tanjung Pengelih 10 20 30 40 50 60 70 80 90 Rantau Panjang distance from Tanjung Pengelih (km ) 2004 min max average 1440916 32 1441967 Temperature (°C) 30 3JH20 3JH15 28 1440963 1340973 26 3JH13 3JH19 24 22 20 0 Tanjung Pengelih 10 20 30 40 50 60 80 90 Rantau Panjang distance from Tanjung Pengelih (km ) 2003 min max average 1440916 32 1441967 3JH20 30 Temperature (°C) 70 28 1440963 3JH15 1340973 26 3JH13 3JH19 24 22 20 0 Tanjung Pengelih 10 20 30 40 50 60 distance from Tanjung Pengelih (km ) 70 80 90 Rantau Panjang 117 APPENDIX B Methods of Analysis The APHA Standard Methods for the examination of water and wastewater (1992) have been adopted. Five of the water quality parameters namely DO, salinity, conductivity, turbidity and pH were measured in situ. All other parameters were analyzed in the laboratory at the Department of Chemistry, Faculty of Science, UTM Skudai. The water quality parameters are summarized in Table B.1 Table B.1: Range of Parameters and Methods of Analysis Parameters Methods of analysis pH YSI 600R / YSI 6600 Conductivity YSI 600R / YSI 6600 Salinity YSI 600R / YSI 6600 Turbidity YSI 6600 DO YSI 600R / YSI 6600 BOD Incubation at 20°C for 5 days TSS APHA Method 2540-D COD HACH DR4000 Method 8000 Ammonia nitrogen HACH DR4000 Method 8038 Total Phosphorus HACH DR4000 Method 8190 Nitrate HACH DR4000 Method 8171 118 APPENDIX C Temporal Profiles of Stream Flow Stream Flow at Station Rantau Panjang (1997-2006) 350 300 Flow (m3/s) 250 200 150 100 50 0 Jan-97 Jan-98 Jan-99 Jan-00 Jan-01 Jan-02 Jan-03 Jan-04 Jan-05 Jan-06 Jan-07 Tim e (m onth,year) Figure C.1: Stream flow at Station Rantau Panjang (1997-2006) Flow at Station Rantau Panjang (1997-2006) Mean Sta.dev 100 Flow (m 3/s) 80 60 40 20 0 JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV Tim e (m onth) Figure C.2: Stream flow analysis at Station Rantau Panjang DEC 119 APPENDIX D Temporal Profiles of DO Concentrations and Nutrient Loads Station 3JH13: Sg Johor at Rantau Panjang Class I Dissolved oxygen (mg/l) 8 7 Class II 6 5 4 Class III 3 Min:2.9 Max: 7.4 Mean: 6.2 2 1 Class IV Class V 0 Jan-97 Jan-98 Jan-99 Jan-00 Jan-01 Jan-02 Jan-03 Jan-04 Jan-05 Jan-06 Jan-07 Jan-08 Tim e (year) Station 3JH13: Sg Johor at Rantau Panjang 14000 N loads (kg/day) 12000 Min:19 Max: 13 133 Mean: 1 610 10000 8000 6000 4000 2000 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Jan05 Jan06 Jan07 Jan08 Tim e (year) Min:1 Max: 1 901 Mean: 134 Station 3JH13: Sg Johor at Rantau Panjang 2000 P loads (kg/day) 1800 1600 1400 1200 1000 800 600 400 200 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Jan05 Jan06 Jan07 Jan08 Tim e (year) Figure D.1: DO concentrations and nutrient loads at Station 3JH13 (1997-2007) 120 Station 3JH03: Sungai Layang Class I Dissolved oxygen (mg/l) 8 7 Class II 6 5 Class III 4 3 Min:4.1 Max:8.8 Mean:6.7 2 1 Class IV Class V 0 Jan-97 Jan-98 Jan-99 Jan-00 Jan-01 Jan-02 Jan-03 Jan-04 Jan-05 Jan-06 Jan-07 Jan-08 Tim e (year) Min: 0.3 Max: 729.9 Mean: 75.4 Station 3JH03: Sungai Layang 800 N loads (kg/day) 700 600 500 400 300 200 100 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Jan05 Jan06 Jan07 Jan08 Tim e (year) Min: 0.1 Max: 190.1 Mean: 12.8 Station 3JH03: Sungai Layang 200 P loads (kg/day) 180 160 140 120 100 80 60 40 20 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Jan05 Jan06 Jan07 Jan08 Tim e (year) Figure D.2: DO concentrations and nutrient loads at Station 3JH03 (1997-2007) 121 Min: 0.3 Max: 8.1 Mean: 3.6 Station 3JH05: Sungai Serai Dissolved oxygen (mg/l) 8 7 Class I Class II 6 5 4 Class III 3 2 Class IV 1 Class V 0 Jan-97 Jan-98 Jan-99 Jan-00 Jan-01 Jan-02 Jan-03 Jan-04 Jan-05 Jan-06 Jan-07 Jan-08 Tim e (year) 4000 N loads (kg/day) 3500 Min: 2 Max: 3 478 Mean: 749 Station 3JH05: Sungai Serai 3000 2500 2000 1500 1000 500 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Jan05 Jan06 Jan07 Jan08 Jan05 Jan06 Jan07 Jan08 Tim e (year) 500 P loads (kg/day) 450 400 Min: 0 Max: 461 Mean: 76 Station 3JH05: Sungai Serai 350 300 250 200 150 100 50 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Tim e (year) Figure D.3: DO concentrations and nutrient loads at Station 3JH05 (1997-2007) 122 Min: 1.3 Max: 6.0 Mean: 3.7 Dissolved oxygen (mg/l) 8 7 Station 3JH06: Sungai Tiram Class I Class II 6 5 Class III 4 3 2 Class IV 1 Class V 0 Jan-97 Jan-98 Jan-99 Jan-00 Jan-01 Jan-02 Jan-03 Jan-04 Jan-05 Jan-06 Jan-07 Jan-08 Tim e (year) Min: 55 Max: 4 793 Mean: 887 Station 3JH06: Sungai Tiram 6000 N loads (kg/day) 5000 4000 3000 2000 1000 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Jan05 Jan06 Jan07 Jan08 Tim e (year) Min: 0 Max: 190 Mean: 24 Station 3JH06: Sungai Tiram 200 P loads (kg/day) 180 160 140 120 100 80 60 40 20 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Jan05 Jan06 Jan07 Jan08 Tim e (year) Figure D.4: DO concentrations and nutrient loads at Station 3JH06 (1997-2007) 123 Min:0.01 Max: 7.8 Mean: 4.8 Dissolved oxygen (mg/l) 8 7 Station 3JH18: Sungai Berangan Class I Class II 6 5 4 Class III 3 2 Class IV 1 Class V 0 Jan-97 Jan-98 Jan-99 Jan-00 Jan-01 Jan-02 Jan-03 Jan-04 Jan-05 Jan-06 Jan-07 Jan-08 Tim e (year) Min:1 Max: 5 713 Mean: 459 Station 3JH18: Sungai Berangan 6000 N loads (kg/day) 5000 4000 3000 2000 1000 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Jan05 Jan06 Jan07 Jan08 Tim e (year) Min:0 Max: 479 Mean: 39 Station 3JH18: Sungai Berangan 600 P loads (kg/day) 500 400 300 200 100 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Jan05 Jan06 Jan07 Jan08 Tim e (year) Figure D.5: DO concentrations and nutrient loads at Station 3JH18 (1997-2007) 124 8 Dissolved oxygen (mg/l) Station 3JH22: Sungai Tem on Min:1.3 Max: 9.0 Mean: 5.9 9 Class I 7 Class II 6 5 Class III 4 3 Class IV 2 1 Class V 0 Jan-97 Jan-98 Jan-99 Jan-00 Jan-01 Jan-02 Jan-03 Jan-04 Jan-05 Jan-06 Jan-07 Jan-08 Tim e (year) Min:1 Max: 2 860 Mean: 245 3500 N loads (kg/day) 3000 Station 3JH22: Sungai Tem on 2500 2000 1500 1000 500 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Jan05 Jan06 Jan07 Jan08 Jan05 Jan06 Jan07 Jan08 Tim e (year) 250 Min:0 Max: 229 Mean: 18 Station 3JH22: Sungai Tem on P loads (kg/day) 200 150 100 50 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Tim e (year) Figure D.6: DO concentrations and nutrient loads at Station 3JH22 (1997-2007) 125 Station 3JH25: Sungai Layau Class I Dissolved oxygen (mg/l) 8 7 Class II 6 5 4 Class III 3 Min:3.0 Max: 7.8 Mean: 6.7 2 1 Class IV Class V 0 Jan-97 Jan-98 Jan-99 Jan-00 Jan-01 Jan-02 Jan-03 Jan-04 Jan-05 Jan-06 Jan-07 Jan-08 Tim e (year) Min:3 Max: 4 645 Mean: 345 Station 3JH25: Sungai Layau 5000 N loads (kg/day) 4500 4000 3500 3000 2500 2000 1500 1000 500 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Jan05 Jan06 Jan07 Jan08 Tim e (year) Min:0 Max: 409 Mean: 16 Station 3JH25: Sungai Layau 450 400 P loads (kg/day) 350 300 250 200 150 100 50 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Jan05 Jan06 Jan07 Jan08 Tim e (year) Figure D.7: DO concentrations and nutrient loads at Station 3JH25 (1997-2007) 126 Dissolved oxygen (mg/l) Station 3JH30: Sungai Lebam Min: 1.9 Max: 6.9 Mean: 3.7 8 7 Class I Class II 6 5 4 Class III 3 2 Class IV 1 Class V 0 Jan-97 Jan-98 Jan-99 Jan-00 Jan-01 Jan-02 Jan-03 Jan-04 Jan-05 Jan-06 Jan-07 Jan-08 Tim e (year) Min:1 Max: 6 965 Mean: 265 Station 3JH30: Sungai Lebam 8000 N loads (kg/day) 7000 6000 5000 4000 3000 2000 1000 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Jan05 Jan06 Jan07 Jan08 Tim e (year) Min:0 Max: 190 Mean: 12 Station 3JH30: Sungai Lebam 200 P loads (kg/day) 180 160 140 120 100 80 60 40 20 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Jan05 Jan06 Jan07 Jan08 Tim e (year) Figure D.8: DO concentrations and nutrient loads at Station 3JH30 (1997-2007) 127 Dissolved oxygen (mg/l) 8 7 Min:2.1 Max: 6.2 Mean: 4.7 Station 3JH33: Sungai Santi Class I Class II 6 5 4 Class III 3 2 Class IV 1 Class V 0 Jan-97 Jan-98 Jan-99 Jan-00 Jan-01 Jan-02 Jan-03 Jan-04 Jan-05 Jan-06 Jan-07 Jan-08 Tim e (year) Min:1 Max: 1 878 Mean: 159 Station 3JH33: Sungai Santi 2000 N loads (kg/day) 1800 1600 1400 1200 1000 800 600 400 200 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Jan05 Jan06 Jan07 Jan08 Tim e (year) Min:0 Max: 1 355 Mean: 34 Station 3JH33: Sungai Santi 1600 P loads (kg/day) 1400 1200 1000 800 600 400 200 0 Jan97 Jan98 Jan99 Jan00 Jan01 Jan02 Jan03 Jan04 Jan05 Jan06 Jan07 Jan08 Tim e (year) Figure D.9: DO concentrations and nutrient loads at Station 3JH33 (1997-2007)