PERFORMANCE OF CONCRETE WITH UNCRUSHED PALM OIL SHELL AS COARSE AGGREGATE TAI KAH MON A project report submitted in partial fulfillment of the requirements for the award of the degree of Master of Engineering (Civil – Structure) Faculty of Civil Engineering Universiti Teknologi Malaysia JAN 2012 iii To My Beloved Family and Friends iv ACKNOWLEDGMENT In the process of preparing and completing this project, I was in contact either directly or indirectly with many people, researchers, academicians, and practitioners. They have contributed towards my understanding and thoughts. In particular, I wish to express my sincere appreciation to my project supervisor, Associate Professor Dr. Abdul Rahman Bin Mohd Sam, for his guidance, advices and motivation. Without his continued support and interest, this thesis would not have been the same as presented here. Besides, I also thanks to the Kilang Alaf, supplier who provide the palm oil shells for completing this project. Also, I have my parents to thank for its great success. Their unwavering support has kept my faith to finish this. Such a positive response from them proves that I’m worth to work hard of this. My sincere appreciation also extends to my siblings and my beloved family and friends who have always giving me their point of views. Without their continued support and interest, this thesis would not succeed in time. Finally, I hope that my findings in this research will expand the knowledge in this field and contribute to all of us in future. v ABSTRACT Malaysia is one of the largest producers of palm oil, contributing about 21 million tons of oil palm products in the export sector. During the process in extracting oil palm, million tons of palm oil shells (POS) as solid wastes were generated. The natural resources of coarse aggregate may be depleted in some day, and the POS as wastes can cause the pollution. In this study, uncrushed POS as aggregate replacement in concrete was studied to determine its performances. A total of 54 concrete cubes and prisms were cast and tested. The workability, apparent dry-density, compressive strength, flexural strength of POS concrete was determined. The findings show that the compressive strength and density of POS concrete was lower than the normal weight concrete. Only the full replacement of the POS concrete was considered as lightweight concrete as the density was lower than 2000 kg/m3. Besides, a total of 4 under-reinforced concrete beams were cast with the dimensions of 125 x 150 x 1600 mm, and tested to failure under four-point loading. The behaviour of the beams were studied through their load-deflection characteristic upon loading, cracking history, and mode of failure. From the result, the flexural behaviour of POS concrete beam was almost same with the normal weight concrete. The cracking pattern of the POS concrete beam was comparable with the control beam. However, the flexural strength of the POS concrete beam was lower compared with the control beam due to the weak bonding of the POS aggregates and cement paste. Overall results indicate that the POS concrete have a sufficient compressive strength that required by the ASTM C330 for lightweight structural concrete and can be used for lightweight partition in order to reduce the member selfweight. vi ABSTRAK Malaysia merupakan salah satu pengeluar minyak kelapa sawit yang terbesar, iaitu menyumbang kira-kira 21 juta tan minyak kelapa sawit dalam sektor eksport. Semasa pemprosesan minyak kelapa sawit, berjuta-juta tan tempurung kelapa sawit akan dihasilkan sebagai sisa pepejal. Sumber-sumber asli bagi agregat boleh habis pada suatu hari nanti dan tempurung kelapa sawit (POS) sebagai bahan buangan boleh menyebabkan pencemaran. Dalam kajian ini, “uncrushed POS” sebagai pengganti agregat dalam konkrit dikaji untuk menentukan prestasinya. Sebanyak 54 kiub dan prisma konkrit telah dibuat dan diuji. Kebolehkerjaan, ketumpatan kering, kekuatan mampatan, kekuatan lenturan konkrit POS telah ditentukan. Hasil kajian menunjukkan bahawa kekuatan mampatan dan ketumpatan konkrit POS adalah lebih rendah daripada konkrit biasa. Hanya penggantian penuh konkrit POS boleh dianggapkan sebagai konkrit ringan kerana ketumpatannya adalah lebih rendah daripada 2000 kg/m3. Di samping itu, sebanyak 4 rasuk konkrit bertetulang telah dibuat dengan dimensi 125 x 150 x 1600 mm, dan diuji di bawah ujian beban empat titik sehingga gagal. Kelakunan rasuk dikaji melalui ciri-ciri seperti beban-pesongan apabila dibebankan, corak keretakkan, dan bentuk kegagalan. Dari hasil kajian, kelakunan lenturan rasuk konkrit POS adalah hampir sama dengan konkrit kawalan. Corak keretakan rasuk konkrit POS adalah setanding dengan rasuk kawalan. Walaubagaimanapun, beban muktamad lenturan rasuk konkrit POS adalah lebih rendah berbanding dengan rasuk kawalan disebabkan ikatan yang lemah antara POS agregat dan simen. Hasil kajian keseluruhannya menunjukkan bahawa konkrit POS mempunyai kekuatan mampatan yang cukup seperti yang dikehendaki oleh ASTM C330 untuk konkrit ringan dan boleh digunakan sebagai “partition” untuk mengurangkan berat badan struktur. vii CONTENT CHAPTER CHAPTER I TITLE PAGE TITLE i DECLARATION ii DEDICATION iii ACKNOWLEDGEMENT iv ABSTRACT v ABSTRAK vi CONTENT vii LIST OF TABLES xii LIST OF FIGURES xiv INTRODUCTION 1.1 Background of Palm Oil Shell Concrete 1 1.2 Problem Statement 3 1.3 Objectives of Study 5 1.4 Scope of Study 5 viii CHAPTER II LITERATURE REVIEW 2.1 Historical Background of Lightweight Aggregate Concrete 6 2.2 Lightweight Concrete 7 2.3 Lightweight Aggregate 8 2.3.1 Natural Lightweight Aggregates 8 2.3.1.1 Volcanic Origin 8 2.3.1.2 Organic Origin 9 2.3.2 Synthetic Aggregate 10 Production of Lightweight Aggregates 10 2.4.1 Palm Oil Shells 11 2.5 Palm Oil Industry in Malaysia 12 2.6 The Palm Oil 13 2.7 Properties of Palm Oil Shells (POS) 15 2.8 Properties of Fresh Lightweight 2.4 Concrete Using Palm Oil Shells 2.9 2.10 Properties of Harden Lightweight Concrete Using Palm Oil Shells 21 2.9.1 Compressive Strength 21 2.9.2 Flexural strength 24 2.9.3 Creep 25 2.9.4 Drying Shrinkage 26 2.9.5 Sound Absorption 28 2.9.6 Thermal Conductivity 28 Comparisons of Palm Oil Shells with other Agricultural Wastes 2.11 19 30 Previous Studies on Palm Oil Shells Concrete 31 2.11.1 Study 1 31 2.11.2 Study 2 34 ix CHAPTER III 2.11.3 Study 3 39 2.11.4 Study 4 42 METHODOLOGY 3.1 Introduction 45 3.2 Experimental Program 46 3.3 Sieve Analysis 49 3.4 Design of Reinforced Concrete Beam 50 3.5 Laboratory Works 50 3.5.1 Materials of Concrete 50 3.5.2 Reinforcements 54 3.5.3 Formwork 56 3.5.4 Concrete Mixing 57 3.5.5 Placing Fresh Concrete 57 3.5.6 Curing 58 3.5.7 Installation of Demec Disc 59 Laboratory Test 59 3.6.1 Sieve Analysis 60 3.6 3.6.2 Compressive Test on POS Aggregates 60 3.6.3 Trial Mix 60 3.6.4 Slump Test 60 3.6.5 Apparent Air-Dry Density of Concrete Cube 61 3.6.6 Ultrasonic Pulse Velocity (UPV) Test 61 3.6.7 Cube Test 62 3.6.8 Flexural Strength Test on Prisms 62 3.6.9 Flexural Strength Test on x Concrete Beams CHAPTER IV 63 RESULTS AND ANALYSIS 4.1 Introduction 65 4.2 Sieve Analysis 66 4.3 Compressive Strength Test of POS Aggregates and Conventional Coarse Aggregates 69 4.4 Slump Test 71 4.5 Apparent Density of Concrete Cube 72 4.6 Ultrasonic Pulse Velocity Test (UPV Test) 77 4.7 Cube Test 78 4.8 Flexural Strength Test of Prisms 87 4.9 Flexural Strength Test on Beam 94 4.9.1 Load-Deflection of Concrete Beams CHAPTER V 94 4.9.2 Bonding Behaviour 97 4.9.3 Concrete Strain Distribution 101 4.9.4 Cracking Behaviour 102 4.9.5 Neutral Axis 104 4.9.6 Mode of Failure 107 CONCLUSION AND RECOMMENDATION 5.1 Conclusion 109 5.2 Recommendation 110 xi REFERENCES APPENDIX A APPENDIX B APPENDIX C xii LIST OF TABLES TABLE 2.1 TITLE Summary on the Performance of the Malaysian Oil Palm Industry in 2008 2.2 PAGE 12 Mechanical Properties of POS, Crushed Granite and River Sand 17 2.3 Chemical Composition of POS Aggregate 18 2.4 Compressive and Tensile Strengths of Lightweight Concrete Using Agricultural Waste as Aggregates 30 2.5 Test Beam Details 32 2.6 Curing Regimes 35 2.7 Time to Corrosion Initiation 36 2.8 Curing Conditions for Both POS Concrete and Controlled Concrete 2.9 40 Curing Conditions for both POS Concrete and Controlled Concrete 43 3.1 Mix proportion of concrete with water-cement ratio 0.52 47 3.2 Mix Proportion of Concrete with w/c 0.45 and 0.4 Respectively 48 3.3 Sample Specimen for Compression Test 48 3.4 Sample Specimen for Bending Test 49 3.5 Beam Specimen for Flexural Test 49 4.1 Sieve Analysis Result of Fine Aggregates 66 xiii 4.2 Sieve Analysis Result of Conventional Coarse Aggregates 67 4.3 Sieve Analysis Result of POS Aggregates 67 4.4 Peak Load Carried by POS and Conventional Coarse Aggregates 70 4.5 Workability of Fresh Concrete 71 4.6 Density of Samples with w/c 0.52 73 4.7 Density of Concrete Cube with w/c of 0.45 and 0.40 76 4.8 Density of Concrete Cube at Ages of 28 days 76 4.9 Results of UPV Test 77 4.10 Compressive Strength of Concrete Cube for Trial Mix and Design 4.11 81 Compressive Strength of CB0.5POS and CB1.0POS with w/c of 0.45 and 0.40 respectively 84 4.12 Flexural Strength of Concrete Prisms 89 4.13 Ultimate Loads, First Crack Load and Maximum Deflection at the Ultimate Load 95 4.14 Characteristic of Cracks 102 4.15 Cracks Spacing Pattern for All Beams 102 4.16 Mode of Failure for Concrete Beam Specimens 107 xiv LIST OF FIGURES FIGURE TITLE PAGE 2.1 Fresh Fruit Bunches 14 2.2 Cross Section of the Palm Oil Fruit 14 2.3 Types of the Palm Oil Fruits 15 2.4 Sieve Analysis for River and POS Aggregate 19 2.5 Development of Compressive Strength of POS Concrete 23 2.6 Crack paths (a) at earlier stages (b) at later stages 23 2.7 Development of the Flexural Strength with Age 25 2.8 Variation of Flexural Strength with Water-Cement Ratio 25 2.9 Experimental Moment-Deflection Curve for Singly Reinforced Beams 2.10 Experimental Moment-Deflection Curve for Doubly Reinforced Beams 2.11 36 Sorptivity of POS Concrete under Different Curing Conditions 2.13 33 Volume of Permeable Voids of POS Concrete Under Different Conditions 2.12 33 37 Water Permeability of POS Concrete under Different Curing Conditions 37 2.14 Profile in POS Concrete under Different Curing Conditions 38 2.15 Variation of RCPT Values for POS Concrete under Different Curing Conditions 38 xv 2.16 Variation of Ultrasonic Pulse Velocity with Curing Age of POS Concrete under Six Types of Curing Environment 2.17 40 Variation of Ultrasonic Pulse Velocity with Curing Age of Controlled Concrete under Six Types of Curing Environment 2.18 41 Relationship between the Compressive Strength and the Curing Age of the POS concrete under 6 types of Curing Conditions 2.19 41 Relationship between the Compressive Strength and the Curing Age of the Controlled Concrete under 6 types of Curing Conditions 2.20 Development of Compressive Strength of POS Concrete with Different Curing Conditions 2.21 42 44 Development of Compressive Strength of Controlled Concrete with Different Curing Conditions 44 3.1 Cement 52 3.2 Fly Ash 52 3.3 Uncrushed Palm Oil Shell 52 3.4 Air-Dry Sand 53 3.5 Pre-soaked of POS Aggregates in Water 53 3.6 Air-Dry POS Aggregates 54 3.7 Strain Gauge with N1 Glue 55 3.8 Bitumen Film on the Strain Gauge 55 3.9 25 mm Spacer 55 3.10 Reinforcement Cage 56 3.11 Reinforcement Bar in Formwork 56 3.12 Finishing Surface of Concrete Cubes 58 3.13 Curing of Concrete Beams 58 3.14 Demec Disc on Concrete Beam Surface 59 xvi 3.15 Slump Test 61 3.16 Compressive Strength Test of Concrete Cube 62 3.17 Flexural Test and Component Equipments 64 3.18 Arrangement of Components on Concrete Beam 64 4.1 Sieve Analysis for Fine Aggregate 68 4.2 Grading for POS and Conventional Coarse Aggregate 68 4.3 Sieve Analysis for Fine Aggregates, Coarse Aggregates and POS Aggregates 69 4.4 Failure Mode of POS Aggregates 70 4.5 Failure Mode of Conventional Coarse Aggregates 71 4.6 Workability of Fresh Concrete 72 4.7 Comparisons of Time Taken for Specimens 78 4.8 Development Compressive Strength of Concrete Cubes 84 4.9 Comparisons Compressive Strength with different w/c 85 4.10 Failure Mode of Control Cube at the age of 7 days (left) and age of 28 days (right) 4.11 Failure Mode of CB0.5POS at the age of 7 days (left) and age of 28 days (right) 4.12 85 86 Failure Mode of CB1.0POS at the age of 7 days (left) and age of 28 days (right) 86 4.13 Development of Flexural Strength of Concrete Prism 92 4.14 Failure Mode of Prism without POS aggregates (left) and Prism with POS aggregates (right) 92 4.15 Fibres on the Surface of POS Aggregates 92 4.16 Failure Mode of Controlled Prism at age of 7 days (left) and at age of 28 days (right) 4.17 Failure Mode of CP0.5POS at age of 7 days (left) and at age of 28 days (right) 4.18 4.19 93 93 Failure Mode of CP1.0POS at age of 7 days (left) and at age of 28 days (right) 94 Flexural Behaviour of All Concrete Beams 95 xvii 4.20 Graph Load versus Strain for Beam BC0.0POS 99 4.21 Graph Load versus Strain for Beam BC0.0POSFA 99 4.22 Graph Load versus Strain for Beam BC0.5POS 100 4.23 Graph Load versus Strain for Beam BC1.0POS 100 4.24 Load versus Concrete Strain 101 4.25 Cracking Patterns for All Beam Specimens 104 4.26 Location of Neutral Axis for Beam BC0.0POS 105 4.27 Location of Neutral Axis for Beam BC0.0POSFA 105 4.28 Location of Neutral Axis for Beam BC0.5POS 106 4.29 Location of Neutral Axis for Beam BC1.0POS 106 4.30 Failure Mode of Beam BC0.0POS 107 4.31 Failure Mode of Beam BC0.0POSFA 108 4.32 Failure Mode of Beam BC0.5POS 108 4.33 Failure Mode of Beam BC1.0POS 108 CHAPTER I INTRODUCTION 1.1 Background of Palm Oil Shell Concrete Concrete is composite materials that contain cement that acts as binders and other cementitious material, coarse aggregate such as the granite stone, fine aggregate such as the sand and some more may contain the chemical admixtures such as water reducing chemicals. However, palm oil shell concrete is different compared with the conventional concrete in terms of the constituents’ materials. Palm oil shell concrete is composite materials that contain cement as the binder, cementitious material, fine aggregate such as sand, but the coarse aggregate replaced by the palm oil shell. Hence, the palm oil shells acts as coarse aggregate in this type of concrete. Malaysia is well known for the palm oil industries and is one of the largest palm oil producers and exporter in the world [1]. In 2009, total productions of the 2 oil palms are about 29 million tons, whereas in the export sector, it contributes about 21 million tons of oil palm products [2]. Although the palm oil industries can give economical advantages to the country, but excessive waste products are generated and left to rot in large amounts and sometimes disposed through incineration which can cause pollution to the environment. Since the palm oil shell is a byproduct during the extraction process of oil palm fruitlets, hence, it can be categorized as organic materials that can be deteriorated with the time. However, these oil palm shells will not contaminate or leach to produce toxic substance once it bound inside the concrete [3]. The palm oil shells obtained can be crushed type or uncrushed type. The crushed palm oil shells have irregular shapes and different sizes of shells, different thickness of the shell and having low density compared with the conventional aggregate. Whereas for the uncrushed palm oil shell, the shapes are spherical and it can be smooth or rough depend on the extraction process. Besides, the properties of the palm oil shell are very different from the conventional aggregates. These shells have high porosity compared to conventional aggregates, hence it will have a low bulk density and having a high water absorption capacity [4]. The low bulk density of the palm oil shells can produce lightweight hardened concrete. These lightweight concretes are very useful in construction industry since the lightweight concrete can reduce the self weight of structural members. Thus, it can reduce the dead load of the structure and reduce the use of reinforcement steel. This results the overall cost reduction in construction industries [1]. 3 In addition, palm oil shells do not need any chemical pretreatment compared with the artificially produced lightweight aggregate before it is used [5]. The palm oil shell concrete can easily attain the strength of more than 17 MPa which is a requirement of structural lightweight concrete as ASTM C330 [6]. Palm oil shells can be used to as the road base material especially in palm oil estate to reduce the cost in buying the granite stone to construct crusher run. Besides, palm oil shell concrete can be used for the construction of low cost houses. The oil palm shell used to make the hollow blocks for the walls and the oil palm shell concrete used to construct the footings, lintels and beams. These has been done in Universiti Malaysia Sabah (UMS) in 2003 and these structures are still performing well and has no structural problems [7]. 1.2 Problem Statement With the continual use of natural resources aggregate in the production of concrete which consume a lot of it, the resources will be depleted someday. The prices of the conventional aggregate begin to increase due to the limited resources and the process involved in crushing the aggregate. This will create an economy chain that will cause the prices of housing increases, and not only the housing, other products’ prices will also increase due to the indirect effects. In ensuring the availability of resources in future, steps must be taken to conserve the nonrenewable resources and energy. In other industries, especially the agro-based industries, abundant wastes are produced and treated improper way will cause the pollution to the environment [1]. The untreated waste can pollute the land, water and air via leaching, dusting and volatilization. Legislatives are needed to be determined in order to control and 4 minimized the pollutants released to other areas [6]. But if these wastes are investigated and studied, these wastes have a potential to be used as construction material. Recycling and utilization of agricultural waste and industrial by-products are very beneficial to our environment and industry. Increasing of the wastes products, resources preservation and material cost has result in the utilization of solid wastes. Material recovery from the agricultural wastes and industrial waste into reusable materials not only can protect the environment, but also can preserve the natural resources since the natural resources are limited [6]. Malaysia, the second largest oil palms producer and exporter in the world, produce more than 4 million tons of palm oil shells during the process of palm oil extraction annually [5]. These oil palm shells, as a waste product of the extraction process, being left at the mill to rot in a large amount and some of the wastes are being disposed through incineration. This will cause pollution to the environment indirectly [5]. As the natural resources are being depleted and the pollution cause by the palm oil shell are getting serious, this situation justify the investigation and studies need to be done on the suitability of palm oil shell as a replacement of conventional aggregate in concrete. Hence, this study is carried out to investigate the performance of concrete with uncrushed palm oil shell as aggregate. 5 1.3 Objectives of Study The purpose of this study is to investigate the performance of concrete with uncrushed palm oil shells (UCPOS) as aggregates. Objectives of this study are as follow. i.) To study the workability of the fresh UCPOS concrete ii.) To study the dry-density of UCPOS concrete iii.) To study the compressive strength and flexural strength of the UCPOS concrete with different percentage of UCPOS replacement. iv.) To study the flexural behavior of UCPOS concrete beam. 1.4 Scope of Study The scope of this research will cover the application of the uncrushed palm oil shells (UCPOS) as aggregates, where the conventional aggregates in normal weight concrete will be replaced by the palm oil shells by percentage. Tests will be carried out to determine the performance of palm oil shell concrete. Data to be collected include: i.) Workability of the fresh palm oil shell concrete ii.) Compressive strength and flexural strength of palm oil shell concrete with different percentage of UCPOS replacement iii.) Flexural strength of the palm oil shell concrete beam iv.) Load-deflection characteristics of the UCPOS concrete beam v.) Mode of structural failure of UCPOS concrete beam CHAPTER II LITERATURE REVIEW 2.1 Historical Background of Lightweight Aggregate Concrete Lightweight aggregate concrete is not a new material invention in concrete technology, and has been used since ancient times. Lightweight aggregate concrete was made by using natural aggregates of volcanic origin such as pumice, scoria, etc. Buildings made from these lightweight aggregate are Babylon in the 3rd millennium B.C.; Roman temple, Pantheon, which was erected in the years A.D. 14; and the great Roman amphitheatre, Colosseum, built between A.D. 70 and 82. Romans used natural lightweight aggregate and hollow clay vases for their “Opus Caementitium” to reduce the weight. This was also used in the construction of the Pyramids during the Mayan period in Mexico [8]. With the increase in the demand of lightweight aggregate concrete and the unavailability of the aggregates, technology for producing the lightweight aggregate has developed. In Germany, porous clay pieces were produced by quick evaporation of water, in 19th century. The industrial use of natural lightweight aggregates started in 1845 by Ferdinand Nebel who produced masonry blocks from pumice with burnt 7 limes as the binder [9]. In Iceland, the uses of pumice in local building start in 1928 [10]. 2.2 Lightweight Concrete Nodaway, lightweight concrete includes the aerated and no-fines concrete and defined as concrete with an air-dry density not exceeding 1850 kg/m3, compared to normal concrete which has a density of 2300 kg/m3. Lightweight concrete has many applications include in pre-stressed concrete and reinforced concrete [11]. Lightweight concrete can be produced by using lightweight aggregate, omitting the fine aggregates or aeration. Combinations of the above methods are also possible. The American institute defines the structural lightweight concrete as concrete having air-dry density of less than 1840 kg/m3 and a compressive strength of over 17.2 N/mm2 after 28 days. Whereas the British Code of Practice BS 8110 recommends minimum characteristic strength of 15.0 N/mm2 at 28 days [11]. Lightweight concrete is used in many applications such as structural applications and thermal insulation applications. The advantage of lightweight concrete is it can significantly reduce the total dead weights which mean a large proportion of the dead load on the structure. For the lightweight concrete used in insulation purpose, the lightweight concrete are usually under 400 kg/m3, while structural lightweight concrete are usually range from 1600 kg/m3 to 2000 kg/m3 [11]. 8 2.3 Lightweight Aggregate Lightweight aggregate can originate from man-made or natural resources. The major natural resources is the volcanic material whereas man-made or synthetic are produced by thermal process in factories binder [9]. 2.3.1 Natural Lightweight Aggregates Natural lightweights aggregate are mostly of volcanic origin, thus are only found in certain parts of the world. Pumice and scoria are the oldest known lightweight aggregate. These aggregates are light and strong to be used in natural state, but having different properties. 2.3.1.1 Volcanic Origin In volcanic origin, when the lava from a volcano cools down, it will produce a spongy well-sintered mass. When sudden cooling of molten magma mass, the material will freezes. If sudden cooling of the molten magma, crystallization not occur, and the material acquires a glassy structure, which similar to the process of glass production known as obsidian. This can be called as supercooled liquid which do not have crystalline phase. It is highly amorphous and glassy structure binder [9]. Lava is a boiling melt which may contain air and gases, and will formed spongy porous mass when cooled down. Lava can produce lightweight material that is porous and reactive. This material known as volcanic aggregates, or pumice or 9 scoria aggregates. The aggregates are produced by mechanical handling of lava by crushing, sieving and grinding binder [9]. Lightweight aggregate concrete made with pumice has low density, thus lead to relatively weight reduction of the structure and foundation, thereby reducing the dead load. This can be significant in high rise buildings. This also can be used as material for repairs the old buildings as it will not increase the total dead load of the building structure. 2.3.1.2 Organic Origin In organic aggregates, one of it is the palm oil shells. The use of agricultural waste as aggregates for building materials has several benefits and economical advantages. The palm oil industry is very important in many countries such as Malaysia, Indonesia, and Nigeria, which produces a large amount of waste which can be utilized in the production of building materials. These shells which produced in large quantities can be used in the production of lightweight aggregate concrete. Till now there is no commercial production of these lightweight aggregates, and normally used in locally. There are two major advantages by using this aggregates i.e. these aggregates have no commercial value, and as being locally, the transport cost is cheap [9]. 10 2.3.2 Synthetic Aggregate Synthetic aggregate are produced by thermal treatment of material having expansive properties. These materials can be divided in three groups: i.) Natural materials, such as perlite, vermiculite, clay, shale, and slate. ii.) Industrial products, such as glass. iii.) Industrial by-products, like fly ash, expanded slag cinder, bed ash, etc. The most common types of lightweight aggregates produced from expansive clays are known as Leca and Liapor. Those made from fly ash are known as Lytag. The bulk density of the aggregate varies greatly depending upon the raw materials and the process in their manufacturing binder [9]. 2.4 Production of Lightweight Aggregates Lightweight aggregate can occurred naturally or produced by thermal treatment. For the aggregate occurred naturally, the aggregate are ready to be use only after the mechanical treatment which include crushing and sieving. Some industrial by-products, waste materials, naturally occurring materials, etc., thermal treatments are applied in order to made them as aggregate [9]. The properties of lightweight aggregate concrete depend on the properties of the aggregate used, which in turn depend on the type of the material and the producing process to produce these aggregates. In lightweight aggregate concrete, there is a vast variation in the density of the aggregate, thus, there will be a vast variation in the strength of the lightweight aggregate concrete [9]. 11 2.4.1 Palm Oil Shells Palm oil shells are one of the naturally occurring raw materials and obtained as a byproduct when palm oil is extracted from the palm nuts. The palm oil tree, which the palm oil shell is extracted from, is a type of wet tropical tree, which found mostly around the equatorial zone [12]. The species of palm oil tree normally found in Malaysia are oleifera, dura, psifera, and tenera. The shells comprise about 10% to 50% of the total composition of oil palm fruitlets, except for the psifera species which has virtually no shell to the kernel [4]. Palm oil shells are agriculture wastes which are renewable and occurring abundance in some countries, and begin interested in alternative to the traditional building materials particularly for low cost construction [9]. The agricultural waste as aggregates can be used as an alternative to conventional construction material in producing the lightweight aggregate concrete. These agricultural wastes are produced in a large quantity from the palm oil mills and can be used as aggregates in producing lightweight concrete. These agricultural wastes also can be used in production of cementitious materials, its fibers can be used in particle boards or sheets and its shell can be used as aggregates [11]. The material properties and structural performance of lightweight concrete made from palm oil shell are found to be similar with the lightweight concrete made from common aggregates such as clinker, foamed slag, and expanded clay. The palm oil shells are hard and crushed as a result of the process of extracting the oil. Sieving is needed in order to remove the fine particles. After sieving, the shells are air-dried before used in concrete mixing [9]. 12 2.5 Palm Oil Industry in Malaysia Malaysia is one of the largest production palm oil, contributing about 29 million tons in the year of 2008. Table 2.1 shows the summary on the performance of the Malaysian Oil Palm Industry in the year of 2008. Table 2.1: Summary on the Performance of the Malaysian Oil Palm Industry in 2008 [2] Year 2008 PLANTING (hectares) Area 4,487,957 PRODUCTION (tones) Crude palm oil 17,734,439 Palm kernel 4,577,500 Crude palm kernel oil 2,131,399 Palm kernel cake 2,358,732 Oleochemical products 2,207,994 EXPORTS (tones) Palm oil 15,408,753 Palm kernel oil 1,047,380 Palm kernel cake 2,255,092 Oleochemical products 2,072,221 Biodiesel 182,108 Finished products 670,569 Others 113,951 TOTAL EXPORTS (tones) 21,750,074 13 2.6 The Palm Oil Elaeis guineensis Jacq. which is generally known as oil palm is an important species in the genus Elaeis which belongs to the Palmae family. The second species which is Elaeis oleifera (H.B.K) Cortes is found in the south and central of America, and generally known as American oil palm [13]. The palm oil is an erect monoecious plant that produces both separate female and male inflorescences. This palm trees are cross-pollinated and the weevil act as the pollinating agent. The harvesting can started after 24 to 30 months of planting and each palm can produce in the range of eight to fifth-teen fresh fruit bunches per year. Each fresh fruit bunches can contain about 1000 to 1300 fruitlets. Figure 2.1 shows the fresh fruit bunches of oil palm. Each fruitlets consists of a fibrous mesocarp layer and the endocarp which is the shell that contain the kernel [13]. The common cultivars are the Dura, Tenera and Pisifera which are classified by the thickness of the endocarp or shell and the mesocarp content. Dura palms have an endocarp thickness of 2-8mm and a medium mesocarp content which consist the 35%-55% of fruit weight. The tenera race has an endocarp thickness of 0.5-3mm thick and high mesocarp content of 60%-95%. The pisifera palms do not have endocarp and have about 95% of mesocarp [14]. Figure 2.2 shows the cross section of the palm oil fruit. Figure 2.3 shows the type of the palm oil fruits. The palm oil produces two types of oils. The fibrous mesocarp produces the palm oil whereas the palm kernel produces the lauric oil. In the conventional milling process, the fresh fruit bunches are sterilized, then the fruitlets are stripped off, then digested and pressed to extract the crude palm oil. The nuts separated from the fiber in the press cake and cracked to obtain the palm kernels. The palm kernel then 14 crushed in another plant to obtain the crude palm kernel oil and a byproduct, palm kernel cake which is used as animal feed. Palm oil has a balanced ratio of saturated and unsaturated fatty acids whereas the palm kernel oil has saturated fatty acids almost the same with the composition of coconut oil [13]. Figure 2.1: Figure 2.2: Fresh Fruit Bunches [13] Cross Section of the Palm Oil Fruit [13], [15]. 15 Figure 2.3: 2.7 Types of the Palm Oil Fruits [15] Properties of Palm Oil Shells (POS) Palm oil shells is a type of agricultural solid wastes and as being an organic material, it can be biodegradable and decay over a long period of time if the environment is full with moisture and sufficient air are present [16]. Presently, the uses of palm oil shell are limited to the fuel for burning and as finishes in mud houses. The shells can provide several advantages if it was found to be structurally adequate. Such advantages include the low density of the shells which can reduce the self weight of the material, good thermal insulation and good sound absorption [12]. Palm oil shells are dark grey to black in color. The shell has two faces that are outer face and inner face. The outer face are from which the fibers and palm oil has been extracted, and this face can be smooth or rough depend on the extraction process. The inner faces are from which the kernel are extracted, and this face is relatively smooth [12]. 16 The shells also have irregular shapes such as angular or polygonal, depending on the extraction process. Besides, the thickness of the shells is variable and can range from 0.15 to about 3mm, depend on the species and the time of year [12]. Sometimes, the oil coating can present on the surface of fresh palm oil shells, therefore, pretreatment to remove this oil coating are necessary. The pretreatment can be done via various ways, including natural weathering, boiling in water, and washing with detergent [4]. The mechanical properties of palm oil shell, crushed granite and sand are shown in Table 2.2. From the Table 2.2, it shows that the shell has higher water absorption with a capacity of 23.3%. This high water absorption may due to the high porosity in the shell. This shows that the shell need more water compared to the conventional aggregate to attain the same consistency [12]. Since the shell has higher water absorption, the shells need to be pre-soaked in potable water for 24 hour to achieve saturated surface dry (SSD) condition before mixing. This is to prevent the absorption from occurring during the mixing [7]. From Table 2.2, the aggregate impact value (AIV) and the aggregate abrasion value of POS aggregates are having more lower value compared to the conventional crushed stone aggregate, which indicate that the POS aggregate have good absorbance to shock. The abrasion value of the shell determine from the Los Angeles abrasion test was 4.80% [7]. This value was lower than the 24.0% obtained for the granite which is normal weight aggregate. The abrasion value of aggregate shows the wear resistance of aggregate. The lower value shows that the aggregate has higher wear resistance, hence, it shows that the POS aggregate have good resistance to wear compared to conventional aggregate. This property of the shell has been exploited by forefathers as floor finishes in mud house. Evidence shows that the floor is still existence to date, despite the structure has severely deteriorated for many years. Most of the house are not inhabited and not maintained, but the floor is still relatively in good condition [12]. 17 As shown in Table 2.2, the specific gravity of the shell was found to be 1.17. The specific gravity are depends on the specific gravity of the minerals of which the aggregate is composed and the voids. The shell has a bulk unit weight of 500-600 kg/m3, thus, this place the POS within the range of the bulk density of lightweight aggregate. The bulk density of the lightweight aggregate can vary from 300 to 1100 kg/m3 [17]. Hence, the palm oil shell can be classified as lightweight aggregate [12]. Figure 2.4 shows the results of sieve analysis for the river sand and POS aggregate. Before the POS being used as aggregate, they were sieved and only aggregates passing through the 12.5mm sieve and retained on the 4.75mm sieve was used in mixing [7], [4]. In addition, the chemical properties of the oil palm shells also determined and presented in Table 2.3. Table 2.2: Mechanical Properties of POS, Crushed Granite and River Sand [18]. Properties Palm oil (POS) shell Crushed granite River sand Specific gravity 1.17 2.61 2.60 Flakiness index (%) 65.17 24.94 - 12.36 33.38 - 590 1470 - 6.24 6.33 2.56 4.80 24 - 7.86 17.29 - Elongation index (%) Bulk unit weight (kg/m3) Fineness modulus Los Angeles abrasion value (%) Aggregate impact value (%) 18 Table 2.2: Loss on ignition 24-h water absorption (%) Table 2.3: Elements (continues) 100 - - 23.30 0.76 0.95 Chemical Composition of POS Aggregate [7] Results (%) Ash 1.53 Nitrogen (as N) 0.41 Sulphur (as S) 0.000783 Calcium (as CaO) 0.0765 Magnesium (as MgO) 0.0352 Sodium (as Na2O) 0.00156 Potassium (as K2O) 0.00042 Aluminium (as Al2 O3) 0.130 Iron (as Fe2O3) 0.0333 Silica (as SiO2) 0.0146 Chloride (as Cl-) 0.00072 Loss on Ignition 98.5 19 Figure 2.4: 2.8 Sieve Analysis for River and POS Aggregate [7]. Properties of Fresh Lightweight Concrete Using Palm Oil Shells As the result of crushing during extracting the oil from the palm nut, the hard palm oil shells are received as crushed pieces. A lot of fine particles were produced, hence, the sieving process are needed to remove the large amount of fine particles. After the sieving process, the shells then air-dried before use in concrete mixing [11]. Since the palm oil shells are lighter than the cement matrix, it tends to segregate in the wet concrete mixes. Trial mixes are normally necessary to achieve a good mix design [11]. The workability of freshly mixed concrete depend on the mix proportions, the materials and environmental conditions. The aggregate normally occupy about 70% of the total volume of the concrete. The total specific areas of the aggregate are minimized by proper selection of the size, proportion of the fine and coarse 20 aggregate, and the shape of aggregates. The surface texture and the shape of aggregates affect the void content and the water requirement of the concrete mixing. The fineness modulus of aggregate is a numerical index of the fineness which indicates the mean size of that aggregate. The fineness modulus of aggregate is a prime indication in obtaining the required strength and workability which can give the most economic mix design [6]. The workability of fresh concrete and bonds between the mortar phase and the aggregate are influenced by the physical characteristic of the aggregate such as the roughness, texture and shapes. The surface texture of the aggregate can be smooth or rough; whereas the surface can be glassy, smooth, granular, rough, crystalline, and porous [19]. The roughness and the porosity of the surface of the aggregate affect the development of the bond. The porous surface of the aggregate can improve the development of bond by the suction of the paste into its pores [6]. A study was done by a group of researchers on the workability of fresh concrete with palm oil shells as aggregates. The results showed that the POS concrete has better workability than that of the normal concrete. In the same watercement ratio, the smooth surface of the palm oil shells may has led to a better workability, slump and compaction factor when compared with the normal concrete [6]. This similar trends also being reported that the presence of palm kernel shell as aggregate can lead to better workability for a same water-cement ratio [20]. The addition of fly ash in POS concrete did not show any significant difference in workability [6]. However as the percentage of the POS replacement increase, the slump of the concrete will decrease [1]. This may due to the higher shells content combined with the irregular and angular shapes of the shells lead to poor workability. Lower workability might also due to the friction of the angular shapes between the shells and lower fines content [21]. Besides, the porosity of the shells can influence the 21 workability. The higher the porosity of the shells, the absorption capacity will be higher, which consequently reduces the workability. The lower compacting values of the shells indicate that less work is done on the shell concrete by gravity. This may due to the lower density of the shell aggregate when compared with granite aggregate [12]. 2.9 Properties of Harden Lightweight Concrete Using Palm Oil Shells 2.9.1 Compressive Strength The proportion of the palm oil shells and the water cement ratio normally affect the workability and the compressive strength of the lightweight concrete with palm oil shells as aggregate. The 28 day cube compressive strength of the lightweight concrete are found to be vary in the range of 5.0 to 19.5 N/mm2 [11]. The compressive strength of concrete with POS was found continue to increase with age. This shows that the POS do not undergo any degradation after mixed with the concrete matrix. Besides, study was done by other researchers that the compressive strength of the POS concrete at 28 day was higher than the minimum required strength of 17 MPa as stipulated by ACI 318 (1995) for structural purposes [1]. Even though the compressive strength of the POS concrete continues to develop with age, but still remained below that of the normal concrete. The development of the compressive strength of POS concrete was about 49-55% lower compared with the normal concrete [6]. Although the POS aggregate is a type of organic material, but study was done by other researchers showing that the 22 biological decay was not evident as the concrete cubes gained strength even after 6 months [4]. Figure 2.5 shows the development of compressive strength of POS concrete. At the early ages, the compression failure pattern of POS concrete was governed by the POS aggregate. The failure was due to the breakdown of the bond between the POS aggregate and the cement paste. This shows that the strength of the bond was not strong because of the organic effect and smoothness of the POS surface [6]. This situation maybe can be overcome if the POS aggregate were treated with lime solution before mixing [22]. However, at the later ages, the failure pattern was more governed by the strength of the POS aggregate-paste bond than the POS aggregate itself. Figure 2.6 shows the crack paths of the POS concrete at the early ages and later ages. In most cases, the lower the density, the strength will be lower [23]. The POS concrete were lighter than the normal concrete, thus, the strength of POS concrete were lower than the normal concrete. Besides, the porosity also affects the compressive strength of POS concrete. POS concrete were found to have higher porosity compared with normal concrete. Furthermore, the physical properties of the POS aggregate such as the strength, the thickness, stiffness and density, are lower than the crushed stone aggregate which govern the compressive strength of the concrete [6]. The development of the compressive strength was also affected by the shapes of the POS aggregate [24]. Generally, the compressive strength is controlled by both the strength of aggregate and the strength of paste, but depends on which of them failed first. When the free water-cement ratio were the same, the lightweight aggregate requires higher water content for absorption compared with the normal weight concrete. For a given workability, the compressive strength increase with cement content as well as the type of aggregate used. Thus, the development of the compressive strength of POS 23 concrete was lower than normal concrete [6]. Hence, the concrete strength depends on the stiffness, strength and density of coarse aggregates [18]. Figure 2.5: Development of Compressive Strength of POS Concrete [20]. Figure 2.6: Crack paths (a) at earlier stages (b) at later stages [4]. 24 2.9.2 Flexural strength Reinforced concrete beam made from palm oil shells are found to be exhibited satisfactory in structural behavior. With a lightweight concrete mix of 1:1.5:0.5/0.5 cement, sand, palm oil shells and water-to-cement ratio, a 28 day cube compressive strength are found about 17.5 N/mm2 [11]. Study done by other researchers has shown that the 28 day flexural strength of OPS concrete was about 14% to 17% of the compressive strength whereas for normal concrete, the flexural strength is about 13% to 15%. This shows that the behavior of the OPS concrete is similar with the normal concrete [18]. However, the flexural strength of concrete with OPS is weak in resisting bending stress compared with the normal concrete [1]. These flexural strength values obtained still fall within the normal range of the conventional concretes, in which the flexural strength is about 10 to 23% of its compressive strength [25]. The flexural strength of concrete depends on physical strength of coarse aggregate to some extent, just like compressive strength [18]. Besides, the flexural strength is influenced by the diffused moisture distribution in the test samples significantly [26]. As the density decrease, the flexural strength also decrease [12]. Figure 2.7 shows the development of the flexural strength with age. The trends are very similar with the compressive and tensile splitting strengths. Figure 2.8 shows the development of flexural strength for 7 and 28 days curing. 25 Figure 2.7: Figure 2.8: Development of the Flexural Strength with Age [27]. Variation of Flexural Strength with Water-Cement Ratio [12]. 2.9.3 Creep A load equivalent to a stress of 6.0 N/mm2 are applied on three 150 mm diameter cylinders made from lightweight concrete with palm oil shell as aggregates 26 in order to perform the creep test according to ASTM. The strain obtained by deducting the initial reading from the final reading immediately after loading. The readings were taken after six hours, then daily for one week, weekly for one month and monthly for nine months. Strain readings of the control sample were taken at the same time schedule. The total strains then divided by the average stress giving the total strain per unit stress. This total strain per unit stress then plotted. The results show that the creep curve for the lightweight concrete with palm oil shells shows a large creep compared with the ordinary concrete. The creep rate for lightweight concrete using palm oil shells did not show a constant value after 3 months, and this property will be concerned when used as structural lightweight concrete [11]. 2.9.4 Drying Shrinkage Generally, all the cement products undergo volume changes which are small in values with response to the changes in moisture conditions. Although the volume changes are small, but the effects are considerably important [28]. When a fresh concrete dried, it undergoes shrinkage which is termed as initial drying shrinkage. After that, the concrete will subsequently experienced the alternative wetting and drying showing the alternative expansion and contraction which termed as reversible moisture movement [28]. The reversible moisture expansion in lightweight concrete with response to the change in moisture condition is found that more often than but not as great as the initial drying shrinkage [28]. Recent study [29] shows that not only the cement undergo the shrinkage, but a few natural aggregate have shown marked shrinkage that contribute the total shrinkage of the concrete [28]. 27 An only cement paste without any constituents has a high drying shrinkage, but for the concrete with its dense and hard aggregate, the drying shrinkage is relatively small. This is because the movements are constraints by the rigidity of the aggregates. For lightweight aggregate concrete, the drying shrinkage are high due to the use of weaker and less rigidity of the aggregates, causing less restrained are imposed on the cement paste. The drying shrinkage of the lightweight aggregate concrete are about twice that of the observed in heavy concrete [28]. The shrinkage of lightweight concrete is about 50% greater than the normal weight concrete [30]. Besides, concrete with the aggregate having open textured and irregular surface can produce shrinkage of about 1000 microstrain [26]. Tensile stress can be set up in the concrete as the result of drying shrinkage, especially it is restrained. If the shrinkage stress exceeds the tensile strength of the concrete, crack will occurred [28]. Study was conducted by researchers to study the drying shrinkage of the POS concrete. It was found that the POS concrete experienced more shrinkage of about 14% higher than the normal weight concrete. Shrinkage can be due to the loss of free water in concrete mixture, the settlement of solids, drying of concrete and chemical reaction of the cement paste [18]. This drying shrinkage is a long lasting process when the concrete exposed to dry condition, same as the hydration process. There are some factors which govern the drying shrinkage of the lightweight concrete such as the water-cement ratio, curing temperature, moisture content, admixture, aggregate characteristic (with the stiffness, content and volume/surface ratio), relative humidity, and the rate and duration of drying [31], [32]. 28 2.9.5 Sound Absorption Sound absorption was measured through the noise reduction coefficient. The sound absorption coefficient was measured at frequencies of 250, 500, 1000 and 2000 Hz which used in U.S.A moderately some time [33]. A study was conducted by researchers’ shows that the normal weight concrete have a noise reduction coefficient of about 0.02 [34]. For the concrete with shell as aggregates, the noise reduction coefficient is about 0.34 for water-cement ratio of 0.5. This shows that the shell concrete which is lightweight concrete has better sound absorption capacity than the normal weight concrete [12]. If the water-cement ratio increases, the noise reduction coefficient increased. This may due to the increasing in the water-cement ratio that will cause the porosity of the concrete increase as well. This enable the shell concrete as a porous material act as a good sound absorbent. When sound energy pass through the shell concrete, part of the energy is used up in exciting the air that held in the discrete pores within the structure. Hence, as the porosity increase, more pores will present and this would probably increase the absorption capacity. The sound absorption capacity of shell concrete can be used as sound proofing in some purposes [12]. 2.9.6 Thermal Conductivity A study was conducted to obtain the thermal conductivity of shell concrete which have a value of 0.45 Wm-1oC-1, whereas for the shell aggregate, the thermal conductivity is 0.19 Wm-1oC-1. These values shows that both the concrete shell and shell aggregate have low thermal conductivity. Hence, the material can be 29 considered as a poor conductor of heat. The thermal conductivity value obtained for the shell concrete were higher when compared with the shell aggregate due to the shell concrete have other constituents such as the fine aggregates, cement or hydration product. These imply that these constituents conduct heat more than the shell aggregate [12]. Thermal conductivity of normal weight concrete in saturated state lie between 1.38 and 3.68 Wm-1oC-1 as found by Mitchell [34]. Besides, suggestion from Loudon and Stacey states that the thermal conductivity of normal weight concrete that tested at a moisture content of not more than 5% are in the range between 0.707 and 2.267 Wm-1oC-1. This implies that if the determination was done at moisture content of 5% or less than that, lower value of thermal conductivity will be obtained, since the conductivity of water are higher than the air [12]. Furthermore, it has been stated that for the lightweight concrete, if the moisture content increase by 10%, the thermal conductivity will be increased by one-half [17]. For the lightweight concrete, the thermal conductivity was in the range between 0.05 and 0.69 Wm-1oC-1as reported by Neville [17]. The low thermal conductivity of the shell concrete can be due to its high porosity. The thermal conductivity through the poor conductor is mainly bring about by the heat waves which produced by the lattice vibration due to the thermal motion of the molecules. Thus, the high porosity of the shell concrete may reduced the propagation of the waves [12]. Some of the pores contain air molecules which have low thermal conductivity [17], and consequently reduced the heat transfer rate through the pores [12]. 30 2.10 Comparisons of Palm Oil Shells with other Agricultural Wastes The strength properties of concrete with palm oil shells as aggregate were compared with other lightweight concrete with other agricultural wastes as aggregates. Four types of agricultural wastes were studied including palm oil shells, palm oil clinkers, rice husks and coconut shells. The palm oil clinkers are the byproducts of the palm oil mills energy generating burners. Both the palm oil clinkers and the coconut shells needed to be crushed and broken into size not larger than 20 mm before use in concrete mixing. Before using these agricultural wastes, these aggregates wastes need to be air-dried. The concrete mixed with a ratio of 1:1:2 of cement, sand and agricultural wastes with water-cement-ratio of 0.55. After the test, the bulk density, compressive strength and the tensile strength of the lightweight concrete with agricultural wastes as aggregates were summarized in Table 2.4. From the test results, the lightweight concrete using the palm oil clinkers and palm oil shells were found to have a higher compressive strength and tensile strengths values [11]. Table 2.4 : Compressive and Tensile Strengths of Lightweight Concrete Using Agricultural Waste as Aggregates [11] Agricultural Wastes Bulk density of wastes Lightweight Concrete Strength (N/mm2) (kg/m3) Compressive Tensile 7 days 28 days 28 days 830 20.7 29.8 1.37 Oil palm shell 620 12.6 17.4 1.12 Coconut shell 445 8.9 11.6 1.15 Rice husk 136 3.4 6.3 0.82 Oil palm clinker 31 2.11 Previous Studies on Palm Oil Shells Concrete Many studies have been carried out on the use of palm oil shells as aggregate in concrete. Several studies are discussed in the following section. 2.11.1 Study 1 A group of researchers has been conducted a studies on the flexural behavior of the reinforced lightweight concrete beams made with palm oil shells [5]. In this study, a total of 6 under reinforced concrete beams with varying reinforcement ratios were fabricated and tested. Three of the beams were singly reinforced and the other three were doubly reinforced. All the coarse aggregates in beams were fully replaced by POS as coarse aggregates. From the experimental investigation, the flexural behavior of the POS concrete was observed that almost comparable with the other types of lightweight concrete. This observation and results encouraging the POS used as aggregate in the production of structural lightweight concrete especially for the low cost house. Table 2.5 shows the test beam details used in this study. Figure 2.9 shows the experimental moment-deflection curve for singly reinforced beams. Figure 2.10 shows the moment-deflection curve for doubly reinforced beams. All the observations and conclusions are as follows: i.) All of the POS concrete beams have a typical structural behavior in flexure. Before crushing of the compression concrete in the pure bending zone, the yielding of reinforcement occurred, since the beams are under-reinforced. ii.) The deflections of the POS concrete calculated from the BS 8110 under service loads can be used to provide reasonable prediction. For the deflections under the service design load of the singly reinforced beams, the deflections were within the allowable limit provided by BS 8110. For the 32 doubly reinforced beams, the deflections under the design of service loads have exceed the limit, suggesting the beams can be increased in the depth. iii.) POS concrete beams in this investigation showing a good quality in ductility behavior. All beams showed a considerable amount of deflection and this can give enough warning to the imminence of failure. iv.) The crack widths at service load ranged from 0.22 mm to 0.27 mm. These crack widths are within the maximum allowable value as required in BS 8110 for durability requirements. Table 2.5: Beam no. Beam type Tension reinforcement no. and size Test Beam Details [5] Nominal/ compression reinforcement no. and size Beam size, Area of B tensile steel, = ,% x D (mm) As (mm2) 150 x 230 157 0.52 150 x 231 226 0.75 150 x 231 339 1.13 S1 Singly 2Y10 S2 Singly 2Y12 S3 Singly 3Y12 D1 Doubly 3Y16 2Y10 150 x 233 603 2.01 D2 Doubly 3Y20 2Y16+1Y12 150 x 235 943 3.14 D3 Doubly 3Y20+2Y12 2Y20+1Y10 150 x 242 1169 3.90 2R8 33 Figure 2.9: Experimental Moment-Deflection Curve for Singly Reinforced Beams [5] Figure 2.10: Experimental Moment-Deflection Curve for Doubly Reinforced Beams [5] 34 2.11.2 Study 2 A group of researchers also investigate the durability of the lightweight POS concrete under different curing conditions [35]. The durability properties investigated include the volume of permeable voids (VPVs), water permeability, chloride diffusion coefficient, sorptivity and time to corrosion initiation from the 90 day salt ponding test, and Rapid Chloride Penetrability Test (RCPT). Through this investigation, the results obtained provide valuable information on the durability of the lightweight concrete made from POS. The hydration process for POS concrete is enhanced at the early stages due to the process of internal curing from the water absorbed by the lightweight aggregate. But a proper curing is needed at the later ages to achieve a better durability. The durability properties of the POS concrete are found to be comparable well with the other lightweight concretes. Table 2.6 shows the curing regimes of the specimens. Table 2.7 shows the durability properties of the concrete in terms of the time to corrosion initiation. Figure 2.11, Figure 2.12, Figure 2.13, Figure 2.14 and Figure 2.15 show the results of the durability of the concrete under different curing regimes. The following results show the durability properties of POS concrete: i.) The VPV of POS concrete at age 28 days was found in the range of 20.121.2%. ii.) At age 28 days, the sorptivity of the POS concrete was about 0.06-0.14 mm/min0.5. This relatively low sorptivity was due to the high quality of the cement paste which was produced with a low water-cement ratio of 0.38 and well compacted POS concrete. iii.) At the age of 28 days, the permeability coefficient was ranged from 6.4 x 10-12 to 57.5 x 10-12. iv.) The chloride diffusion was ranged from 5.86 x 10-8 to 12.02 x 10-8 cm2/s. v.) The time to corrosion can be enhanced when the cover was adequate and the proper curing is adopted. 35 vi.) At 28 days, the RCPT values were ranged from 3581 to 4549 Coulombs, showing that the chloride permeability was in moderate to high. Besides, the decrease in the charge with the increase of the age of concrete shows that the pore structure of the POS concrete improved due to the continual process of hydration of cement products. vii.) Proper curing is required for POS concrete to achieve a good durability especially at the later ages. Therefore, for the POS concrete, minimum duration of moist curing should be carried out for at least 7 days. Table 2.6: Curing designation Curing Regimes [35] Temperature & Type of curing Curing method relative humidity Curing duration Covered with CS1 Site-1 plastic sheet for Temp = 28 ±5oc Until the age three additional RH = 68 – 91% of testing days Covered with wet burlap for six CS2 Site-2 additional days & water spray three times a time CL CC Laboratory Unprotected (no Temp = 25±3oc (air-dry) curing) RH = 74 - 88% Laboratory (full water) Temp = 23±2oc Kept in water tank RH = 100% 36 Table 2.7: Time to Corrosion Initiation[35] Time, years Curing Concrete cover regimes 25 mm 50 mm 75 mm 100 mm CS1 0.2 0.7 2.4 4.2 CS2 0.3 1.9 4.4 7.6 CL 0.2 0.7 2.2 3.9 CC 0.3 1.6 3.9 7.0 Figure 2.11: Volume of Permeable Voids of POS Concrete Under Different Conditions[35] 37 Figure 2.12: Sorptivity of POS Concrete under Different Curing Conditions [35] Figure 2.13: Water Permeability of POS Concrete under Different Curing Conditions [35] 38 Figure 2.14: Chloride Profile in POS Concrete under Different Curing Conditions [35] Figure 2.15: Variation of RCPT Values for POS Concrete under Different Curing Conditions [35] 39 2.11.3 Study 3 A group of researchers conducted a study on the effect of curing conditions on the properties of POS concrete [36]. In this study, effect 6 types of curing conditions on the pulse velocity and compressive strength of POS concrete were studied. Table 2.8 showed the curing conditions of both type of concretes. Figure 2.16 and Figure 2.17 shows the variation of the pulse velocity of both type concretes. Figure 2.18 and Figure 2.19 showed the development of compressive strength of both types of concrete. The results obtained from the investigation were shown below: i.) The pulse velocity of the POS concrete was about 25% lower than the crushed stone concrete. ii.) The compressive strength of POS concrete was about 52% lower than the crushed stone concrete. iii.) The compressive strength of the POS concrete satisfies the minimum required strength as structural lightweight concrete. iv.) The method and curing period have significant effects on engineering properties for both types of concrete. The strength development of the POS concrete was delay at the early stages due to the early drying and the present of organic POS aggregate. v.) The strength of the concrete is dependent to some extent of the aggregate strength. vi.) The increment rate of strength is higher in the crushed stone compared to POS concrete. 40 Table 2.8: Curing Conditions for Both POS Concrete and Controlled Concrete [36]. No. 1 2 3 4 5 6 Duration of curing with place (day) Curing Curing description symbol Mold Water Plastic Room Full water FW 1 364 0 0 PW-1 1 6 0 358 PW-2 1 27 0 337 FP-1 1 6 364 0 PP-1 1 6 358 0 PP-2 1 27 337 0 Partial water-1 Partial water-2 Full plastic Partial plastic Partial plastic 2 Figure 2.16: Variation of Ultrasonic Pulse Velocity with Curing Age of POS Concrete under Six Types of Curing Environment [36]. 41 Figure 2.17: Variation of Ultrasonic Pulse Velocity with Curing Age of Controlled Concrete under Six Types of Curing Environment [36] Figure 2.18: Relationship between the Compressive Strength and the Curing Age of the POS concrete under 6 types of Curing Conditions [36] 42 Figure 2.19: Relationship between the Compressive Strength and the Curing Age of the Controlled Concrete under 6 types of Curing Conditions [36] 2.11.4 Study 4 A group of researchers also conducted study on long term strength of concrete with palm oil shell as coarse aggregate [37]. In this study, long term investigation up to 365 days on compressive strength of POS concrete in different environmental conditions was conducted. Besides that, a comparative study also being carried out by using controlled concrete with crushed stone as coarse concrete. From this study, the compressive strength of POS concrete range from 20 to 24 N/mm2 for 28 days in different types of curing includes the field and laboratory. Table 2.9 showed the curing condition for both type of concrete. Figure 2.20 and Figure 2.21 showed the development of compressive strength of POS concrete and controlled concrete in different curing conditions. The observations are shown as follows: i.) The compressive strength of the POS concrete was in the range of 20.1 to 24 N/mm2 depend on the type of curing. 43 ii.) The long term behavior of POS concrete was very similar to the controlled concrete in generally. Hence, there was no retrogression of compressive strength due to any of the curing conditions. iii.) Hence, the use of POS concrete as structural lightweight concrete is recommended. Table 2.9: Curing Conditions for both POS Concrete and Controlled Concrete [37] Duration of curing with place (day) Number Curing symbol Mold Water Kept in room temperature 1 W-1 1 6 358 2 W-2 1 27 337 3 W-3 1 364 - 4 P-1 1 6 5 P-2 1 27 6 P-3 1 - 358 (with plastic wrapper) 337 (with plastic wrapper) 364 (with plastic wrapper) 44 Figure 2.20: Development of Compressive Strength of POS Concrete with Different Curing Conditions [37] Figure 2.21: Development of Compressive Strength of Controlled Concrete with Different Curing Conditions [37] 45 CHAPTER III METHODOLOGY 3.1 Introduction This research program is designed to study the performance of concrete with uncrushed palm oil shell as coarse aggregate. In this study, a total of 54 concrete cubes and 54 concrete prisms were cast and tested. Besides, a total of 4 underreinforced concrete beams were fabricated and tested. A controlled beam and concrete cubes and prisms without any palm oil shell replacement were used for the comparison purposes. In this study, for the palm oil shell concrete cube, the observations will be more on the workability, the ultrasonic pulse velocity, air-dry density, the compressive strength, and the mode of failure. For the palm oil shell concrete prism, the test includes the bending test. For the palm oil shell concrete beams, the observation will be more on the deflection, strain, type of failures, the crack behavior, and the ultimate load carrying capacity. Comparisons will lead to the effect of the palm oil shell as coarse aggregate on the performance of the concrete. 46 3.2 Experimental Program In this study, a total of 54 concrete cubes of dimensions 150 x 150 x 150 mm, 54 concrete prisms of dimensions 100 x 100 x 500 mm, and a total of 4 concrete beams with the dimensions of 150 x 125 x 1600 mm were cast and tested. The concrete was design having a compressive strength of 30 MPa at the age of 28 days with water-cement ratio of 0.52. The concrete mix was designed based to the DOE method. Table 3.1 shows the mix proportion of the concrete with w/c of 0.52. Besides, additional concrete cubes with 50% and full replacement of coarse aggregate with POS were cast with water-cement ratio of 0.45 and 0.40, respectively, and tested at the age of 7 days and 28 days. Table 3.2 shows the mix proportions of cube specimens with w/c of 0.45 and 0.40, respectively. For concrete cubes, a total of 6 sets of concrete cubes were cast and tested. Each set of the cubes have different replacement percentage of coarse aggregate with the POS. The replacement percentages were 50% and full replacement of coarse aggregates with the POS. The replacement was done by using volume method. Besides, additional samples with 10% of the cement content by weight were replaced by fly ash and mixed with the POS were cast. Each sample set have a quantity of 9 units. These cubes were tested at the age of 3, 7 and 28 days. Tests include the ultrasonic pulse velocity test, dry-density, and the compressive strength test. Table 3.3 shows the details of the cubes. Same procedures for the concrete prisms were done. Table 3.4 shows the details of the prisms. For concrete beams, a total of 4 under-reinforced concrete beams with the dimensions of 125 x 150 x 1600 mm were fabricated and tested. One of the beams was control beam; the other one was control beam but replaced with 10% of fly ash. The other two beams were cast by replacing the coarse aggregate with POS with different percentage. The percentage replacement were 50% and full replacement of coarse aggregate. The replacement of coarse aggregate was done by volume in 47 percentage. Each beam was fabricated with high tensile strength of 10 mm diameter reinforcement bar. Each concrete beams were tested to failure at the age of 28 days by using four-point load test to determine its flexural strength and behaviour. The control beam was designed according to the British Standard, BS 8110:1997-Structural use of concrete: code of practice for design and construction [38]. The other POS concrete beams were design by referring the control beam as to make comparison between the samples and the control beam. Table 3.5 shows the details of the concrete beams. Table 3.1: Mix Proportion of Concrete with Water-Cement Ratio 0.52 Quantity ( kg/m3) Description Concrete without fly ash Free water content 210 Cement content 405 Fine aggregate content 700 Coarse aggregate content 1090 Concrete with fly ash Free water content 210 Cement content 364 Fly ash content 40 Fine aggregate content 700 Coarse aggregate content 1090 48 Mix Proportion of Concrete with w/c 0.45 and 0.4 respectively Table 3.2: Quantity ( kg/m3) Description CB0.5POS with w/c 0.45 Free water content 182 Cement content 405 Fine aggregate content 700 Coarse aggregate content 1090 CB1.0POS with w/c 0.40 Free water content 162 Cement content 405 Fine aggregate content 700 Coarse aggregate content 1090 Table 3.3: Sample Identification Sample Specimen for Compression Test Quantity POS (%) Fly Ash (%) CB 0.0 POS 9 0 0 CB 0.5 POS 9 50 0 CB 1.0 POS 9 100 0 CB 0.0 POSFA 9 0 10 CB 0.5 POSFA 9 50 10 CB 1.0 POSFA 9 100 10 Cubes (150x150x150 mm) Notation: CB – Cube, POS – Palm Oil Shell, FA – Fly Ash, Numerical digit – Percentage Replacement of POS 49 Table 3.4: Sample Identification Sample Specimen for Bending Test Quantity POS (%) Fly Ash (%) PS 0.0 POS 9 0 0 PS 0.5 POS 9 50 0 PS 1.0 POS 9 100 0 PS 0.0 POSFA 9 0 10 PS 0.5 POSFA 9 50 10 PS 1.0 POSFA 9 100 10 Prisms (100x100x500 mm) Notation: PS – Prism, POS – Palm Oil Shell, FA – Fly Ash, Numerical digit – Percentage Replacement of POS Table 3.5: Beam Identification Beam Specimen for Flexural Test Steel reinforcement POS replacement (%) Fly ash (%) BC0.0POS 2-T10 0 0 BC0.0POSFA 2-T10 0 10 BC0.5POS 2-T10 50 0 BC1.0POS 2-T10 100 0 Notation: BC – Beam Concrete, POS – Palm Oil Shell, FA – Fly Ash, Numerical digit – Percentage Replacement of POS 3.3 Sieve Analysis Sieve analysis was conducted to determine the aggregates used for the mixture to meet the specification. Sieve test was done on the fine aggregate, coarse aggregate and POS aggregate. In this study, the fine aggregate was sieved to determine its grading stated in British Standard, BS 882: 1992 – Specification for Aggregates from Natural Sources for Concrete [39]. 50 3.4 Design of Reinforced Concrete Beam The control reinforced concrete beam was designed in accordance to the British Standard, BS8110: Part 1: 1997 – Structural Use of Concrete: Code of Practice for Design and Construction [38]. The other 3 beams were design similar to the control beam for comparisons purpose. Due to some limitations on the availability of the reinforced material, the size of the beams with dimensions of 125 x 150 x 1600 mm was chosen. 3.5 Laboratory Works All laboratory works were carried out in Structures and Materials Laboratory, Faculty of Civil Engineering, Universiti Teknologi Malaysia. The works included the preparation of raw materials, concrete cubes and prisms, beams, and testing of all the samples. 3.5.1 Materials of Concrete Raw materials such as ordinary Portland cement, fly ash, coarse aggregate, uncrushed palm oil shell (POS) and fine aggregate were required in the preparation for the concrete mix. The concrete mix was designed to achieve a compressive strength of Grade 30 according to the Design of Normal Concrete Mixes, Department of Environment (DOE) Method [40]. The type of the cement used was Ordinary Portland Cement (OPC) with Holcim brand as shown in Figure 3.1. The fly ash is shown in Figure 3.2. The coarse 51 aggregate used was uncrushed palm oil shell as shown in Figure 3.3. The river sand was used in this study. Sieve analysis was conducted according to the British Standard, BS 882: 1992 – Specification for Aggregates from Natural Sources for Concrete [39] to determine the percentage of fine aggregates that passes through 600 μm size. Besides, the maximum size of coarse aggregate used in this study was 20 mm. Finally, both of these aggregates were dried through air dry method. Figure 3.4 shows the air-dry sand. For the uncrushed POS aggregates, special treatments were carried out during the preparation. Usually, there will be oil coating on the surface of POS. Hence, POS aggregates were washed to clear the oil coating on the shell. Before the mixing process, the POS was pre-soaked in portable water for 24 hours as shown in Figure 3.5. After that, the shells were taken out and let it for air dry to achieve a saturated surface dry condition as shown in Figure 3.6. Then, these saturated surface dry POS were used in concrete mixing. Trial mix was conducted before the actual mixing process to ensure that the concrete will achieve the required compressive strength. In trial mix, a total of 3 cubes were cast to determine the compressive strength at the age of 7 days. By calculating the volume of 9 unit cubes, approximately 0.031 m3 of concrete mixture was required in casting. Extra 10% of concrete volume was added for proper placing and testing. Besides, 9 concrete prisms were cast and used 0.045 m3 of concrete mixture. Additional 10% of concrete volume required for proper placing. For the concrete beam, approximately 0.03 m3 of concrete mixture was required in casting. Extra 25% of concrete was added for proper placing and testing. Extra cubes were prepared with the beams to determine the compressive strength of concrete at the day the beams is tested. 52 Figure 3.1: Cement Figure 3.2: Fly Ash Figure 3.3: Uncrushed Palm Oil Shell 53 Figure 3.4: Figure 3.5: Air-Dry Sand Pre-soaked of POS Aggregates in Water 54 Figure 3.6: Air-Dry POS Aggregates 3.5.2 Reinforcements In this study, reinforcement steel bar of 10 mm diameter and shear link of 6 mm diameter were used in fabricating the beams. The length of the steel bars and the shear links were cut into the required length. The cutting process was done by using the electrical cutter whereas the bent process was done by using electrical bender machine. The reinforcement bars and the shear links were tied together by using wire. Strain gauge was use and fixed at the centre of the reinforcement bar. Grinder was used to roughen the steel bars surface where the strain gauge is located for proper bonding. In preventing the short circuit due to the water from concrete mixing, the strain gauge was covered with water proofing gel namely N1 glue and left for 24 hours which shown in Figure 3.7. Lastly, the strain gauge was covered with bitumen film to protect it from aggregate dropping impact during the concrete pouring as shown in Figure 3.8. The in-placed strain gauge was tested by using ammeter to ensure it will gives reading within 120 -125 ampere. 55 After all the preparation works have been done, the reinforcements were tied with the 25 mm spacers into the formwork as shown in Figure 3.9. The whole reinforcement cage is shown in Figure 3.10. The reinforcement cage in formwork is shown in Figure 3.11. After that, concrete was poured and cast into the formwork. Figure 3.7: Figure 3.8: Strain Gauge with N1 Glue Bitumen Film on the Strain Gauge Figure 3.9: 25 mm Spacer 56 Figure 3.10: Reinforcement Cage 3.5.3 Formwork The standard steel mould for cubes has been provided; the only preparation is a layer of oil applies on the surface of the formwork one day before casting the cube. For the beams, the type of formwork used was made of plywood. Oil coating were applied on the formwork surface for easier in demoulding the concrete from formwork after 7 days. Figure 3.11 show the reinforcement cage in the formwork. Figure 3.11: Reinforcement Bar in Formwork 57 3.5.4 Concrete Mixing Before the concrete mixing, the quantities of each constituent were prepared by using the weighing scale. All of the specimens were cast by using mechanical pan mixer. The steps in concrete mixing are as follows: i.) The coarse aggregates were poured into the pan mixer followed by the fine aggregates. ii.) The cement was poured into the pan mixer. iii.) Let the mixture of fine aggregates, coarse aggregate and cement thoroughly mixed to obtained uniform mixture for about 5 minutes. iv.) Water was added slowly to the mixture. v.) Lastly, the mixture was mixed about 10 minutes in order to obtain uniform mixture. After the mixing process, some of the amount of fresh concrete was used for workability testing. The others were placed into the formworks and used for the making of the samples. 3.5.5 Placing Fresh Concrete After conducting the workability test, the fresh concrete was place into the formwork. The distance of the placement must be as low as possible to avoid the segregation. For concrete cubes and prisms, the vibration of concrete was done by using the vibrating table. For the concrete beams, the vibration was done by using vibrating poker. The surface of the concrete was levelled to produce a smooth surface as shown in Figure 3.12. 58 Figure 3.12: Finishing Surface of Concrete Cubes 3.5.6 Curing After placing the fresh concrete, plastic film was put on it to reduce the evaporation of water from the concrete. After 24 hours, the concrete cubes were demould and cured in the water tank. For the concrete beams, the curing was done by putting wet gunny covering on it as shown in Figure 3.13. Figure 3.13: Curing of Concrete Beams 59 3.5.7 Installation of Demec Disc After the proper curing, the process of patching mortar to the pores on the concrete surface was done to get a smooth surface. White paint was applied on the surface to enable the cracks can be detected easily during the flexural test. Demec disc were installed on the surface of beam by bonding it with epoxy as shown in Figure 3.14. Demec disc with spacing of 150 mm were used to determine the concrete strain during the test. Demec Disc Figure 3.14: Demec Disc on Concrete Beam Surface 3.6 Laboratory Test A series of test were conduct on the performance of concrete with palm oil shell as coarse aggregate. Tests conducted include sieve analysis, compressive test on POS aggregates, trial mix, slump test, UPV test, determination of apparent drydensity, cube test, and flexural test. 60 3.6.1 Sieve Analysis Sieve analysis was conducted on the POS aggregates, the river sand and the coarse aggregates. Coarse aggregate with 20 mm size was used in this study. 3.6.2 Compression Test on POS Aggregates Compressive strength test was done on the POS aggregates and the gravel aggregates to determine the peak load that the aggregates can carry. This test was done but not according to any standard. 3.6.3 Trial Mix Trial mix was conducted to determine the required compressive strength of the concrete will be achieved at the age of 28 days. The mixing was done by hand since it has only a small quantity, i.e. for 3 cubes. 3.6.4 Slump Test Slump test was conducted on the fresh concrete to determine its workability. The fresh concrete was placed into the slump cone with 300 mm height and compacted in three layers. Each layer was compacted with 25 strokes by using steel rod. After that, the frustum was lifted up and the displacement of the original top surface was measured as the slump and shown in Figure 3.15. 61 Slump Figure 3.15: Slump Test 3.6.5 Apparent Air-Dry Density of Concrete Cube The air-dry density of concrete cube was conducted at the age of 3, 7 and 28 days. In this test, the weights of the samples were determined and divided by its volume to get the density. 3.6.6 Ultrasonic Pulse Velocity (UPV) Test UPV test was conducted on the concrete cube to determine the time taken for the pulse to pass through the concrete. Before the test, the calibration was carried out by using a reference bar having a known pulse transmit time value. The surface of the transmitter was applied with grease to enhance the surface contact with the concrete. The transmitter was placed at the centre cube position and the receiver at the opposite side of the cube. The time taken for the ultrasonic pulse to travel from 62 the transmitter through the length of the cube to the receiver was recorded. From these values, the global average value of pulse velocity of the cubes was determined. 3.6.7 Cube Test Compressive strength test was conducted on the concrete cubes at the age of 3, 7 and 28 days. The cubes must be free from the cracks, chipped surface and other defects that can give inaccurate results. All specimens were tested at the loading rate of 6.8 kN/sec by using compressive machine. Figure 3.16 shows the compressive strength test on concrete cubes. Figure 3.16: Compressive Strength Test of Concrete Cube 3.6.8 Flexural Strength Test on Prisms Flexural strength test was done on the concrete prisms according to British Standard, BS 1881-118:1983-Method for the Determination of Flexural Strength [41]. The flexural strength test was done on specimens at the age of 3, 7 and 28 days. 63 The test was done by using four point load test. The load causing the break of prism was recorded and converted to flexural strength by using formula: = × × 22 Where, f is the breaking load in N d1 and d2 are the lateral dimensions of the cross-section in mm l is the distance between the supporting rollers in mm 3.6.9 Flexural Strength Test on Concrete Beams Flexural strength test was conducted on the beams at the age of 28 days. Magnus frame was used during the flexural strength test. Figure 3.17 shows the Magnus frame. During this test, hydraulic jack component was loaded at the mid span of the beam. Steel spreader was put at the end of the jack to produce two point loads with equal distance from the mid span of the beam. Besides, an electronic component load cell was placed at the end of the jack to measure the applied load on the beam. Linear Variable Differential Transducers (LVDT) was used in measuring the deflection of the beam when the load was applied. A total of three LVDT were used in this test and placed at the bottom part mid span of the beam. After that, all the components including the strain gauge, load cell and transducers were connected to data logger to obtain the experimental data. Figure 3.18 shows the set up of the flexural test. 64 After preparation, the load was applied to the beam with certain increment until failure. Demec disc was used to record the data of strain distribution of concrete through measuring the displacement between the demec disc. Figure 3.17: Flexural Test and Component Equipments Figure 3.18: Arrangement of Components on Concrete Beam 65 CHAPTER IV RESULTS AND ANALYSIS 4.1 Introduction All the data obtained from the experiment were analysed in this chapter. The data obtained include the cube strength test, UPV test, bending prism test and fourpoint flexural test of beams. In this analysis, the reinforced concrete beams with the palm oil shell as coarse aggregate replacement were compared with the conventional reinforced concrete beam. In order to make the results more clearly, all the data were tabulated and presented in tables and graphs. The data from the workability of fresh concrete, compressive test and UPV test of the cubes, bending test of the prisms, compressive test on the conventional aggregate and palm oil shells were compared in certain age of the concrete. Lastly, the four beams were compared in terms of the ultimate strength, deflection, strain of concrete and the reinforcement bar, the pattern of the cracking, the bonding characteristic between the concrete and steel bar, the changes of the neutral axis and the mode of failure. 66 4.2 Sieve Analysis Table 4.1 shows the result of sieve analysis for fine aggregate which were used in the concrete mixture. From the analysis of the result, the fine aggregate was categorized in the medium class. This was because the percentage of the fine aggregates passing through the 600 μm sieve was 40.36%. Based on the British Standard, BS 882: 1992 – Specification for Aggregates from Natural Sources for Concrete [39], this value was located within the range of the medium grading limit. Table 4.2 shows the sieve analysis result of conventional coarse aggregate whereas Table 4.3 shows the sieve results of POS aggregates. Figure 4.1 show the graph of sieve analysis for fine aggregates. From the graph, the percentage passing of fine aggregate is within the upper limit and lower limit which were categorized as medium class. Figure 4.2 shows the grading of POS and conventional coarse aggregate. Figure 4.3 shows the sieve results of fine aggregates, conventional coarse aggregates and POS aggregates. Table 4.1: Sieve Analysis Result of Fine Aggregates Medium Size Sieve Retained Passing Percentage (mm) Weight (g) Weight (g) Passing (%) 5.0 0.2 499.8 99.96 - 2.36 26.3 473.5 94.7 65-100 1.18 121.5 352 70.4 45-100 0.60 150.2 201.8 40.36 25-80 0.30 113.2 88.6 17.72 5-48 0.15 68.9 19.7 3.94 - pan 19.7 - - - Total 500 - - - Grading Limit (%) 67 Table 4.2: Sieve Analysis Result of Conventional Coarse Aggregates Size Sieve Retained Weight Passing Weight Percentage Passing (mm) (g) (g) (%) 28.0 0 2000.0 100 19.0 355.0 1645.0 82.25 13.2 790.0 855.0 42.75 9.5 330.0 525.0 26.25 4.0 430.0 95.0 4.75 2.8 20.0 75.0 3.75 pan 75.0 - - Total 2000 - - Table 4.3: Sieve Analysis Result of POS Aggregates Size Sieve Retained Weight Passing Weight Percentage Passing (mm) (g) (g) (%) 28.0 0 2000.0 100 19.0 55.0 1945.0 97.25 13.2 1080.0 865.0 43.25 9.5 805.0 60.0 3.0 4.0 60.0 0 0 2.8 0 0 0 pan 0 - - Total 2000 - - 68 120 Percentage Passing (%) 100 80 60 sample lower limit 40 upper limit 20 0 0.0 1.0 2.0 3.0 4.0 5.0 6.0 Sieve Size (mm) Figure 4.1: Sieve Analysis for Fine Aggregate 120 Percentage Passing (%) 100 80 POS Aggregates 60 Conventional Coarse Aggregates M(LL) 40 M(UL) 20 0 1 Figure 4.2: 10 Sieve Size (mm) 100 Grading for POS and Conventional Coarse Aggregate 69 120 Percentage Passing (%) 100 80 POS Aggregates 60 Conventional Coarse Aggregates 40 Fine Aggregates 20 0 0.1 1 10 100 Sieve Size (mm) Figure 4.3: Sieve Analysis for Fine Aggregates, Coarse Aggregates and POS Aggregates 4.3 Compressive Strength Test of POS Aggregates and Conventional Coarse Aggregates Compressive strength test was done on the POS aggregates and conventional coarse aggregates. The data obtained were tabulated in Table 4.4. From the results, it can be seen that the POS aggregates have a lower load carrying capacity compared with the conventional coarse aggregates. This may due to the higher porosity inside the POS compared with the conventional coarse aggregates. Figure 4.4 and 4.5 shows the failure mode of the POS aggregates and conventional coarse aggregates, respectively. 70 Table 4.4: Peak Load Carried by POS and Conventional Coarse Aggregates Peak Load (kN) No. Uncrushed POS Aggregates Conventional Coarse Aggregates 1 0.9 2.9 2 1.6 3.2 3 2.2 3.3 4 1.5 3.0 5 1.4 2.8 6 1.2 3.5 7 1.1 3.1 8 0.7 3.8 9 2.0 3.4 10 1.3 2.9 Average 1.4 3.2 Figure 4.4: Failure Mode of POS Aggregates 71 Figure 4.5: 4.4 Failure Mode of Conventional Coarse Aggregates Slump Test Slump tests were conducted on the fresh concrete to determine the workability of concrete. The slump of the concrete was determined by measuring the displacement of the top surface concrete from the original surface. As the percentage replacement of the POS increases, the workability of the concrete increase. This was due to the shape and the surface texture of the POS. The round and smooth surface of the POS decrease the friction between the aggregates and hence increase the aggregate movement compared to conventional aggregate which have rough and irregular shape. The results were tabulated in Table 4.5 and shown in Figure 4.6. Table 4.5: Samples Workability of Fresh Concrete Slump (mm) CB0.0POS 30 CB0.0POSFA 30 CB0.5POS 75 CB0.5POSFA 70 CB1.0POS 115 CB1.0POSFA 110 72 140 120 Slump (mm) 100 80 60 40 20 0 CB0.0POS CB0.0POSFA CB0.5POS CB0.5POSFA CB1.0POS CB1.0POSFA Sample Figure 4.6: 4.5 Workability of Fresh Concrete Apparent Density of Concrete Cube From the determination of density of concrete cube, the density of POS concrete cube have a lower density compared to the normal weight concrete due to the lightweight of the POS aggregates. The densities of all the concrete cubes with w/c of 0.52 were tabulated in Table 4.6. The density of concrete cube of CB0.5POS and CB1.0POS with w/c of 0.45 and 0.40, respectively are shown in Table 4.7. The weight savings of the POS concrete was compared with the normal weight concrete at the age of 28 days as shown in Table 4.8. The benefit of reducing weight can reduce the dead load of structure. Besides, it can reduce the influence of the catastrophic earthquake force and inertia force that influenced the structure since these forces were proportional to the weight of structure [4]. 73 Table 4.6: Sample Ages (days) 3 CB0.0POS 7 28 3 CB0.0POSFA 7 28 Density of Samples with w/c 0.52 No’s Weight (kg) Density (kg/m3) 1 8.155 2416.3 2 8.23 2438.5 3 8.15 2414.8 1 8.085 2395.4 2 8.075 2392.6 3 8.150 2414.7 1 8.240 2441.5 2 8.235 2440.0 3 8.195 2442.2 1 8.242 2442.1 2 8.263 2448.3 3 8.163 2418.7 1 8.214 2433.8 2 8.287 2455.4 3 8.333 2469.0 1 8.265 2448.9 2 8.292 2456.9 3 8.253 2445.3 Average density (kg/m3) 2423 2400 2441 2436 2452 2450 74 Table 4.6: Sample Ages (days) 3 CB0.5POS 7 28 3 CB0.5POSFA 7 28 (Continues) Weight Density (kg) (kg/m3) 1 7.370 2183.7 2 7.470 2213.3 3 7.479 2216.0 1 7.433 2202.4 2 7.195 2131.9 3 7.297 2162.1 1 7.448 2206.7 2 7.449 2207.1 3 7.490 2219.3 1 7.450 2207.4 2 7.289 2159.7 3 7.423 2199.4 1 7.483 2217.0 2 7.382 2187.1 3 7.431 2201.8 1 7.363 2181.5 2 7.404 2193.6 3 7.421 2198.8 No’s Average density (kg/m3) 2204 2165 2211 2189 2202 2191 75 Table 4.6: Sample Ages (days) 3 CB1.0POS 7 28 3 CB1.0POSFA 7 28 (Continues) Weight Density (kg) (kg/m3) 1 6.342 1879.1 2 6.194 1835.3 3 6.253 1852.7 1 6.180 1831.1 2 6.260 1854.8 3 6.290 1863.7 1 6.549 1940.3 2 6.458 1933.3 3 6.435 1926.5 1 6.066 1797.3 2 6.152 1822.8 3 6.107 1809.5 1 6.110 1810.4 2 6.070 1798.5 3 6.170 1828.1 1 6.474 1918.2 2 6.527 1933.9 3 6.555 1919.2 No’s Average density (kg/m3) 1856 1850 1933 1810 1812 1924 76 Density of Concrete Cube with w/c of 0.45 and 0.40 Table 4.7: Sample Ages (days) No’s Weight (kg) 7.495 2220.7 2 7.524 2229.3 CB0.5POS 3 7.495 2220.7 w/c:0.45 1 7.537 2233.2 2 7.387 2188.7 3 7.547 2236.1 1 6.220 1842.8 2 6.183 1832.0 CB1.0POS 3 6.198 1836.4 w/c:0.40 1 6.165 1826.7 2 6.265 1856.3 3 6.185 1832.6 28 7 28 Table 4.8: density (kg/m3) 1 7 Average Density (kg/m3) 2223 2219 1837 1838 Density of Concrete Cube at Ages of 28 days Samples Density (kg/m3) Weight Savings (%) CB 0.0POS 2441 - CB0.0POSFA 2450 - CB0.5POS 2211 9.26 CB0.5POSFA 2191 10.06 CB1.0POS 1933 20.65 CB1.0POSFA 1924 21.04 77 4.6 Ultrasonic Pulse Velocity Test (UPV Test) This test was conducted to determine the indirect compressive strength of the concrete cube. This test was conducted according to British Standard, BS 1881: Part 203: 1983 – Recommendations for Measurement of Velocity of Ultrasonic Pulses in Concrete [42]. The UPV Test results were summarized in Table 4.9. In order to make the comparisons more clearly, the data were plotted in graph as shown in Figure 4.7. Table 4.9: Results of UPV Test Average velocity (km/s) Ages ( Days) Sample 3 7 28 CB0.0POS 4.27 4.37 4.63 CB0.0POSFA 4.19 4.49 4.66 CB0.5POS 3.99 4.19 4.31 CB0.5POSFA 3.94 4.10 4.20 CB1.0POS 3.23 3.30 3.71 CB1.0POSFA 2.99 3.24 3.51 78 60 50 Time (μs) 40 CB0.0POS CB0.0POSFA 30 CB0.5POS 20 CB0.5POSFA CB1.0POS 10 CB1.0POSFA 0 3 7 28 Ages (Days) Figure 4.7: 4.7 Comparisons of Time Taken for Specimens Cube Test To ensure the mix design meets the requirement in terms of the compressive strength and the workability, trial mixes were conducted. The trial mix of concrete with grade 30 and water cement ratio of 0.52 were carried out. The result showed that the trial mix meets the design requirement in terms of the compressive strength and the workability. The results of the cube test for the trial mix and design were summarised in Table 4.10. In order to make the comparisons more clearly and the trend development of the compressive strength of concrete, graph in Figure 4.8 was plotted. The strength development of the POS concrete was same as the control cube, i.e. the compressive strength continues developed with ages as shown in Figure 4.8. 79 Since the compressive strength of the concrete cube CB0.5POS and CB1.0POS with w/c of 0.52 didn’t meet the structural compressive strength requirement i.e. 25 MPa, hence, additional concrete cubes CB0.5POS and CB1.0POS with w/c of 0.45 and 0.40, respectively, were cast and tested. The compressive strength of CB0.5POS and CB1.0POS were tabulated in Table 4.11. Comparisons were made between the w/c of 0.52 and 0.45 together with 0.40 as shown in Figure 4.9. The compressive strength of cube CB1.0POS was 18.1 MPa which achieved the minimum compressive strength of structural lightweight concrete which is 17 MPa according to ASTM C330 [43]. From the compressive strength test, it was found that the compressive strength of concrete cube with POS replacement was lower than the control concrete cube. As the percentage replacement of the POS increased, the compressive strength of the concrete cube was decreased. This probably was due to the shape of the POS aggregates. The circular shape of the POS causing weak interlocking bonding between the aggregate and the cement paste. The failure mode of the concrete cube was different at the age of testing. At the early age of testing, the cube was fail in the cracking through the cement paste, but at the later age of testing, the cubes fail mostly in coarse aggregate. This was because the early strength of the concrete cube was governed by the strength of the cement paste, but at the later age, the concrete strength was governed by the aggregate strength. However, for the POS concrete cube, the failure mode at the age of 28 days was observed break through the surface of the POS aggregates rather than break through the POS aggregates. The failure modes of the samples are shown in Figure 4.10, Figure 4.11 and Figure 4.12. For control cube with 10% fly ash replacement, the strength at the early age was lower than the control cube, but at the later age, the compressive strength was almost the same with the control cube. This was because fly ash react with the 80 calcium hydroxide, Ca(OH)2 together with moisture content at the later age. At the early age, the hydration of the cement produced little Ca(OH)2, but at the later age, complete hydration of cement produce enough Ca(OH)2 for the fly ash to react with the presence of moisture content. Fly ash reacts with Ca(OH)2 and with the presence of moisture to produce more C-S-H gel and hence increase the compressive strength of the cube. But for the cube with POS with 10% fly ash replacement, the strength was lower than the cube with only POS replacement. The same results found by other researchers. This may be due to the fact that fly ash prevented proper contact between the POS surface and the cement matrix causing the lower bonding and hence, reduce the compressive strength [3]. 81 Table 4.10: Compressive Strength of Concrete Cube for Trial Mix and Design Fly Ash Sample Replacement Compressive Days (%) Strength (MPa) Average Compressive Strength (MPa) Ratio of 7/28 d strength 30.9 Trial Mix 0 7 33.4 32.4 33.0 24.6 3 23.7 23.9 23.4 34.4 CB0.0POS 0 7 32.2 32.3 0.71 30.3 45.8 28 47.2 45.6 43.9 17.2 3 18.8 18.4 19.3 29.1 CB0.0POSFA 7 28.3 29.6 31.3 45.1 28 48.0 41.6 44.9 0.66 82 Table 4.10: Fly Ash Sample Replacement Days (%) (Continue) Compressive Average Ratio of Strength Compressive 7/28 d (MPa) Strength (MPa) strength 13.7 3 12.1 13.2 13.6 16.9 CB0.5POS 0 7 14.4 16.0 0.69 16.6 22.3 28 23.8 23.1 23.0 10.9 3 9.7 10.5 11.0 14.6 CB0.5POSFA 10 7 14.6 14.6 14.7 18.0 28 20.1 17.7 18.6 0.78 83 Table 4.10: Fly Ash Sample Replacement Days (%) (Continue) Compressive Average Ratio of Strength Compressive 7/28 d (MPa) Strength (MPa) strength 9.1 3 8.8 8.9 8.9 11.6 CB1.0POS 0 7 11.0 11.4 0.81 11.6 15.4 28 12.9 14.0 13.8 5.6 3 6.0 5.8 6.0 9.8 CB1.0POSFA 10 7 9.2 9.6 10.0 11.7 28 13.0 13.2 12.6 0.76 84 50.0 Compressive Strength (MPa) 45.0 CB0.0POS 40.0 CB0.0POSFA 35.0 30.0 CB0.5POS 25.0 CB0.5POSFA 20.0 15.0 CB1.0POS 10.0 CB1.0POSFA 5.0 0.0 0 7 14 21 28 35 Ages (Days) Figure 4.8: Table 4.11: Development Compressive Strength of Concrete Cubes Compressive Strength of CB0.5POS and CB1.0POS with w/c of 0.45 and 0.40 respectively. Sample w/c Ages Compressive (days) Strength (MPa) Average Ratio of Compressive 7/28 d Strength (MPa) strength 21.1 7 19.4 20.9 22.2 CB0.5POS 0.45 0.73 29.9 28 28.0 28.7 28.3 15.2 7 15.1 15.1 15.2 CB1.0POS 0.40 0.84 17.2 28 19.1 17.9 18.1 85 Compressive Strength (MPa) Figure 4.9: Comparisons Compressive Strength with different w/c 35 30 25 20 CB0.5POS-w/c 0.52 15 CB0.5POS-w/c 0.45 10 CB1.0POS-w/c 0.52 5 CB1.0POS-w/c 0.4 0 7 28 Ages (Days) 7 days 28 days Figure 4.10: Failure Mode of Control Cube at the age of 7 days (left) and age of 28 days (right) 86 7 days 28 days Figure 4.11: Failure Mode of CB0.5POS at the age of 7 days (left) and age of 28 days (right) 7 days 28 days Figure 4.12: Failure Mode of CB1.0POS at the age of 7 days (left) and age of 28 days (right) 87 4.8 Flexural Strength Test of Prisms Flexural strength test or modulus of rupture test was done on concrete prisms and the data are tabulated in Table 4.12. The comparison of the flexural strength is shown in Figure 4.13. Flexural strength is the ability of the beam or slab to resist the failure in bending. From the test, all the prisms showed typical flexural strength development as shown in Figure 4.13. But as the replacement of the POS increase, the flexural strength of the prism was decreased. This showed that the POS prisms have low flexural strength in resisting the failure in bending stress compared to control concrete. Same trend of results also obtained by other researchers [1]. The flexural strength of CP0.0POSFA which has fly ash replacement was lower at the early age when compared with the CP0.0POS. The rate of development of flexural strength of CP0.0POSFA begins to increase with time as shown in Figure 4.13. This happens because during the early stage, the cement reacts with water to produce C-S-H gel and Ca(OH)2, but the quantity of Ca(OH)2 was low at the early stage. At later ages, the quantity of Ca(OH)2 becomes higher and the fly ash react with the Ca(OH)2 with moisture to produce more silica gel, hence the flexural strength increase with time. For control prisms, the flexural strength was about 16% of the compressive strength. On the other hand, for the control prisms with fly ash, the flexural strength was about 14.7% of the compressive strength. For the prism CP0.5POS and CP0.5POSFA, the flexural strength is about 17.7% and 22% of the compressive strength, respectively. For the prisms CP1.0POS and CP1.0POSFA, the flexural strength was about 19% and 21%, respectively, of compressive strength. These values are within the normal range of flexural strength of conventional concrete which is 10 to 23% of its compressive strength [44]. 88 The flexural strength of POS concrete prisms was low compared with the control prisms due to the circular shape of the POS aggregates. The angular coarse aggregate used in the control concrete prisms provide a good bonding with the cement paste. The failure mode of control prisms was different with the POS concrete prisms at the first crack. At the first crack load, the control prisms broke into two parts whereas for the POS concrete prisms, they didn’t broke into two parts but still bond together as shown in Figure 4.14. The reason the broken part of the prisms still bond together was due to the fibres on the POS surface as shown in Figure 4.15. The failure modes of the concrete prisms were different at certain age of testing as shown in Figure 4.16, Figure 4.17 and Figure 4.18. At the early stage, the prisms break through the cement paste, but at the later age, the prisms break into the cement paste and the coarse aggregates. However, for POS concrete prisms, the failure was through on the surface of the POS aggregates rather than break through the POS aggregates. This may due to the circular shape of the POS aggregate and weak bonding between the surface of the POS aggregates and the cement paste. 89 Table 4.12: Samples Ages (days) 3 CP0.0POS 7 28 3 CP0.0POSFA 7 28 Flexural Strength of Concrete Prisms No’s Flexural Strength Average Flexural Strength (MPa) (MPa) 1 4.1 2 4.3 3 4.1 1 5.5 2 6.1 3 6.0 1 7.8 2 7.1 3 7.2 1 3.0 2 4.0 3 3.1 1 4.2 2 4.3 3 3.8 1 6.6 2 6.5 3 6.6 4.1 5.9 7.4 3.3 4.1 6.5 90 (Continues) Table 4.12: Flexural Samples Ages (days) No’s Strength (MPa) 3 CP0.5POS 7 28 3 CP0.5POSFA 7 28 1 2.0 2 1.7 3 1.8 1 2.4 2 3.0 3 2.7 1 4.0 2 4.2 3 4.0 1 1.6 2 1.8 3 1.4 1 2.6 2 2.7 3 2.3 1 4.5 2 3.7 3 4.1 Average Flexural Strength (MPa) 1.8 2.7 4.1 1.6 2.6 4.1 91 Table 4.12: (Continues) Flexural Samples Ages (days) No’s Strength (MPa) 3 CP1.0POS 7 28 3 CP1.0POSFA 7 28 1 1.8 2 2.0 3 1.4 1 1.6 2 2.2 3 2.5 1 2.7 2 2.6 3 2.8 1 1.5 2 1.7 3 1.8 1 2.1 2 2.0 3 2.1 1 2.8 2 2.7 3 2.7 Average Flexural Strength (MPa) 1.7 2.1 2.7 1.6 2.0 2.7 92 8 FlexuralStrength(MPa) 7 6 CP0.0POS 5 CP0.0POSFA 4 CP0.5POS 3 CP0.5POSFA 2 CP1.0POS CP1.0POSFA 1 0 0 7 14 Ages(Days) 21 28 35 Figure 4.13: Development of Flexural Strength of Concrete Prism Control POS Figure 4.14: Failure Mode of Prism without POS aggregates (left) and Prism with POS aggregates (right) Figure 4.15: Fibres on the Surface of POS Aggregates 93 7 days 28 days Figure 4.16: Failure Mode of Controlled Prism at age of 7 days (left) and at age of 28 days (right) 7 days 28 days Figure 4.17: Failure Mode of CP0.5POS at age of 7 days (left) and at age of 28 days (right) 94 7 days 28 days Figure 4.18: Failure Mode of CP1.0POS at age of 7 days (left) and at age of 28 days (right) 4.9 Flexural Strength Test on Beam During the flexural strength test on beams, the results obtained were ultimate load, deflection, steel and concrete strain distribution, the cracking pattern, change of neutral axis and mode of failure. Control beam was used to compare with other concrete beams. 4.9.1 Load-Deflection of Concrete Beams From the load deflection results, the data obtained were the ultimate load and the deflection of the beam at the ultimate load as shown in Table 4.13. Figure 4.19 shows the load-deflection or flexural behaviour of all the concrete beams tested. From the analysis, all the concrete beams show a typical structural behaviour in flexure. 95 Ultimate Loads, First Crack Load and Maximum Deflection at the Table 4.13: Ultimate Load. First crack load Ultimate load Maximum deflection (kN) (kN) (mm) BC0.0POS 8.5 39.5 11.35 BC0.0POSFA 8.0 39.8 16.92 BC0.5POS 8.0 33.5 11.09 BC1.0POSFA 6.0 34.5 11.12 Beam 45 40 35 Load (kN) 30 BC0.0POS 25 BC0.0POSFA 20 BC0.5POS 15 BC1.0POS 10 5 0 0 5 10 15 Deflection (mm) 20 25 Figure 4.19: Flexural Behaviour of All Concrete Beams For control beam BC0.0POS, the first crack was found in the middle of the span where the location of maximum bending occurred. The first crack load was 8.5 kN and the displacement of the mid span was 1.22 mm. The concrete tension strain and the bar strain at the first crack load was 599.5 x 10-6 and 415 x 10-6, respectively. Before the first crack occurred, the slope of load-deflection was steep and linear. But after the flexural crack was formed, the change in slope of the load-deflection curve occurred and remains linear until the major crack. After the major cracks 96 occurred, the reinforcement bar begins to yield. As the load increased, more vertical cracks were observed along the beam. The major cracks were observed when the loads achieved 36.9 kN. The beam failed when the load achieved 39.5 kN and failed in flexural-tension mode. The displacement of the beam at the ultimate load was 11.35 mm. For control beam with fly ash, BC0.0POSFA, the first crack load was found in the middle of the span at the load of 8.0 kN. The displacement of the beam at the first crack load was 1.26 mm and the concrete tension strain and bar strain was 708.5 x 10-6 and 426 x 10-6, respectively. Before the first crack load, the slope of the load-deflection was steep and linear until the first crack occurred. After the first crack occurred, the slope of the load-deflection has changed but remains linear until the major cracks occurred. The major cracks occurred at load of 36.0 kN. The ultimate load of this beam was 39.8 kN and the displacement of the beam at ultimate load was 16.92 mm. After the ultimate load occurred, the reinforcement bar begins to yield. The ultimate load of the beam BC0.0POSFA was almost similar with the control beam, BC0.0POS. This may be due to the class F fly ash with low reactivity. For POS concrete beam, BC0.5POS, the first crack was found in the middle part of the beam where the constant bending moment occurred. The first crack load was found to be 8.0 kN. The displacement of the concrete beam at the first crack load was 1.41 mm and the concrete tension strain and reinforcement bar strain was 305.2 x 10-6 and 430 x 10-6, respectively. As the loading increase, there were more cracks occurred until the major cracks occurred. The slope of the load-deflection before the first crack was steep and linear, but after the first crack, change occurred on the slope of the load-deflection and still remains linear until the major cracks occurred. The major cracks occurred at load of 32.0 kN. The ultimate load of the beam was 33.5 kN and the displacement of the beam was 11.42 mm. After that, the yielding of the bar begins and the beam failed in crushing of concrete cover. The ultimate load of this beam was lower than the control concrete beam due to the lower compressive strength of the concrete. The compressive strength of the 97 concrete cube before the beam was tested at age of 28 days was 28.7 MPa compared to 42 MPa of control concrete cube. For concrete beam with full POS replacement, BC1.0POS, the first crack was found at the mid span of the beam where the constant bending moment occurred. The first crack load was found at about 6.0 kN. The first crack load of this beam was low compared with the other 3 beams due to the weak bonding of the surface of POS aggregates and cement paste. Besides, flexural strength test on prisms also indicate that the full replacement POS have a lower flexural strength compared with other prisms which were not fully replaced by POS coarse aggregates. The deflection at the first crack load was 0.98 mm and the concrete tension strain and the bar strain was 272.5 x 10-6 and 263 x 10-6, respectively. Before the first crack occurred, the slope of the load-deflection was steep and linear, but after the first crack occurred, change in the slope was occurred but still remain linear until the occurrence of major crack. The major crack occurred at the load of about 32.1 kN. The ultimate load of the beam was 34.5 kN and the displacement at the ultimate load was 11.12 mm. The ultimate load of BC1.0POS was almost the same as CB0.5POS. This may be due to the fibre effect on the surface of the POS aggregates. The ultimate load for BC1.0POS was lower than the control beam due to the low compressive strength of the concrete. At the day of beam testing, the compressive strength of the concrete cube was only 18.1 MPa. But according to ASTM C330, the minimum compressive strength required for lightweight structural applications was 17.0 MPa [43]. Hence, the BC1.0POS can be used in lightweight structural applications. 4.9.2 Bonding Behaviour The concrete strain for control beam in tension part and the reinforcement strain were plotted and shown in Figure 4.20. Figure 4.21, Figure 4.22 and Figure 4.23 show the concrete strain and bar strain for beam BC0.0POSFA, BC0.5POS and 98 BC1.0POS, respectively. All the graphs show a typical strain increase as the load increase. For beam BC0.0POS, the steel strain increased as the load increased until it yielded at the load of about 36.9 kN. The steel strain is about 3083 με before it yielded. The beam still can carry certain amount of load after the steel yielded before it failed at 39.5 kN. The steel strain at failure was about 15763 με. At the same time, the concrete strain at the bottom part of the beam also increased as the load increased. From the graph, the value of concrete strain was lower compared with the steel strain. The differences may due to the method of strain measurement. The concrete strains were measured using demec disc while the steel strains were measured using electrical strain gauge which provide higher accuracy compared with the demec disc. For beam BC0.0POSFA, the steel strain was increased before it yielded at load of about 36.0 kN. Before it yielded, the recorded steel strain was about 3497 με. The beam still can carry some load before it failed at 39.8 kN. At the point of failure, the steel strain was about 12402 με. At the same time, the concrete strain increased as the load increased. Since the difference of the concrete strain and the steel strain was lower, this showed that the bonding between the steel and the concrete was good. For beam BC0.5POS, the steel strain before it yielded was 2960 με at load level of about 32 kN. This beam still can carry certain amount of load before it failed at 33.5 kN with steel strain of about 8944 με. While for beam BC1.0POS, the steel strain before it yielded was 2976 με at the load of about 32.1 kN. This beam still can carry extra load before it failed at load of about 34.5 kN with the recorded steel strain of 23143 με. The bonding between the concrete and the steel was good for both beams, BC0.5POS and BC1.0POS, since the difference between the concrete strain and steel strain was small. 99 45 40 35 Load (kN) 30 25 Concrete Strain 20 Bar Strain 15 10 5 0 0 2000 4000 6000 8000 10000 12000 14000 Strain (X 10-6 ) Figure 4.20: Graph Load versus Strain for Beam BC0.0POS 40 35 Load (kN) 30 25 20 Concrete Strain 15 Bar Strain 10 5 0 0 2000 4000 6000 8000 10000 12000 14000 16000 Strain (X 10-6 ) Figure 4.21: Graph Load versus Strain for Beam BC0.0POSFA 100 35 30 Load (kN) 25 20 Concrete Strain 15 Bar Strain 10 5 0 0 2000 4000 6000 8000 Strain (X 10-6 ) Figure 4.22: Graph Load versus Strain for Beam BC0.5POS 40 35 Load (kN) 30 25 20 Concrete Strain 15 Bar Strain 10 5 0 0 2000 4000 6000 8000 10000 12000 14000 Strain (X 10-6 ) Figure 4.23: Graph Load versus Strain for Beam BC1.0POS 101 4.9.3 Concrete Strain Distribution Figure 4.24 shows the strain distribution for concrete in compression with the load for all the beams. From the graph, the strain of concrete increased as the load increased. The strain for beam BC0.0POS was 861.1 με whereas for beam BC0.5POS and BC1.0POS, the concrete strain was 981 με and 1384.3 με, respectively. For beam BC0.0POSFA, the concrete strain cannot be obtained before the failure due to the error in measurement method. The concrete was designed to fail in 3500 με theoretically. However, all the specimens were failed before the design value due to the difficulty in obtaining the data since all data were recorded using the demec gauge manually. 35 30 Load (kN) 25 20 BC0.0POS BC0.0POSFA 15 BC0.5POS 10 BC1.0POS 5 0 0 500 1000 1500 Concrete Strain (X 10-6 ) Figure 4.24: Load versus Concrete Strain 102 4.9.4 Cracking Behaviour Cracks happened at the bottom part of the beam due to the beam weak in tension which occurred at the bottom part of the beam. The crack patterns played important role in reinforced concrete structure. The characteristic of cracks on the beam were recorded and shown in Table 4.14 and Table 4.15. Besides, the cracking patterns of all the beams are shown in Figure 4.25. Table 4.14: Characteristic of Cracks Maximum Crack Average Crack Depth (mm) Depth (mm) BC0.0POS 120 102.5 10 BC0.0POSFA 125 101.8 11 BC0.5POS 110 78.0 15 BC1.0POS 150 71.5 23 Beam Table 4.15: Total No of Cracks Cracks Spacing Pattern for All Beams NOS of Cracks per Spacing Range (mm) Average Crack Beam 0-320 321-640 641-960 961-1280 1281-1600 Spacing ( mm) BC0.0POS 0 4 5 4 1 96.0 BC0.0POSFA 1 5 2 3 1 104.5 BC0.5POS 1 6 4 3 1 76.8 BC1.0POS 1 7 5 9 2 49.8 103 For control concrete beam, the first crack started when the load applied was about 8.5 kN. But for the beam BC0.0POSFA, BC0.5POS and BC01.0POS, the first crack load was about 8.0 kN, 8.0 kN and 6.0 kN, respectively. The first crack load for beam BC0.0POSFA, BC0.5POS and BC01.0POS was lower compared with the control beam probably due to the weak bonding between the aggregates and the cement paste. Same results were obtained through the flexural strength test of prisms which indicated that the control prisms having higher flexural strength compared with the other prisms specimens. All of the vertical cracks were formed at the bottom of the beam. When the applied load increased, the vertical cracks were gradually formed towards the upper part of the beam. Major cracks were formed after certain load applied. The vertical cracks widened progressively and propagated upwards. For control beam, the major cracks formed at the load of about 36.9 kN. For beam BC0.0POSFA, BC0.5POS and BC01.0POS, the major cracks were formed at load about 36.0 kN, 32.0 kN and 32.1 kN, respectively. The maximum crack depth was on beam BC1.0POS due the weak bonding of the aggregates compared with the control beam. For beam BC0.5POS, the maximum crack depth was about 110 mm due to the beam failed in concrete crushing at the upper part of the beam. For controlled beam and BC0.0POSFA, the maximum crack depth was almost the same. All beams have a combination of minor cracks and major cracks along the beam. Besides, no cracks were found near the support location of all the beams and this indicated that the beams were failed in bending-flexural mode. Beam BC1.0POS has more vertical cracks compared with the control beam and beam BC0.0POSFA. This may be due to the weak bonding between the aggregates and the cement paste. Besides, there were no cracks along the reinforcement bar at the 104 bottom part of beam and this indicated that the bonding between the reinforcement bar and the concrete was good. BC1.0POS BC0.5POS BC0.0POSFA BC0.0POS Figure 4.25: Cracking Patterns for All Beam Specimens 4.9.5 Neutral Axis The location of the neutral axis was shifted upward to the compression zone of the beam as the load applied increased. Figure 4.26, 4.27, 4.28 and 4.29 shows the location of the neutral axis as the load increased for beam BC0.0POS, BC0.0POSFA, BC0.5POS and BC1.0POS, respectively. From the graph, all the beam show a similar trend which the location of neutral axis shifted upward as the load applied increased. 105 160 140 Beam Depth (mm) 120 100 4 kN 80 12 kN 60 20 kN 25 kN 40 20 0 -1000 0 1000 3000 2000 4000 Concrete Strain (x 10-6 ) Figure 4.26: Location of Neutral Axis for Beam BC0.0POS 160 140 Beam Depth (mm) 120 100 80 4 kN 60 12 kN 20 kN 40 20 0 -1000 -500 0 500 1000 1500 2000 2500 Concrete Strain (x 10-6 ) Figure 4.27: Location of Neutral Axis for Beam BC0.0POSFA 106 140 120 Beam Depth (mm) 100 80 6 kN 60 20 kN 25 kN 40 20 0 -1000 -500 0 500 1000 1500 2000 Concrete Strain (x 10-6 ) Figure 4.28: Location of Neutral Axis for Beam BC0.5POS 160 140 Beam Depth (mm) 120 100 4 kN 80 12 kN 60 20 kN 25 kN 40 20 0 -1500 -1000 -500 0 500 1000 1500 2000 2500 3000 Concrete Strain (x 10-6 ) Figure 4.29: Location of Neutral Axis for Beam BC1.0POS 107 4.9.6 Mode of Failure Table 4.16 shows the type of failure for each beam specimen while Figure 4.30, 4.31, 4.32, 4.33 show the failure mode of beam specimens. Results from the experiment show that all beams were failed in the flexural-tension mode. Before all the beams failed in concrete compression, the reinforcement yielded as can be expected for the under-reinforced concrete beam. Table 4.16: Beam BC0.0POS BC0.0POSFA BC0.5POS BC1.0POS Mode of Failure for Concrete Beam Specimens Failure Mode Description Flexural- Reinforcement yielded before concrete failed in Tension compression Flexural- Reinforcement yielded before concrete failed in Tension compression Flexural- Reinforcement yielded before concrete failed in Tension compression Flexural- Reinforcement yielded before concrete failed in Tension compression Figure 4.30: Failure Mode of Beam BC0.0POS 108 Figure 4.31: Failure Mode of Beam BC0.0POSFA Figure 4.32: Failure Mode of Beam BC0.5POS Figure 4.33: Failure Mode of Beam BC1.0POS 109 CHAPTER V CONCLUSION AND RECOMMENDATION 5.1 Conclusion After these series of laboratory tests, concrete with uncrushed pal oil shell as coarse aggregates will have lower compressive strength and flexural strength compared with the conventional concrete. The concrete beams with uncrushed palm oil shell as aggregates exhibit same flexural behaviour as the conventional concrete beam. However, the load carrying capacity was lower compared with the conventional concrete beams. More extensive cracks were found for the POS concrete beams compared with the conventional concrete beam. The number of cracks provides sufficient warnings for the beam before failure occurred. Based on the overall results, analysis and comparisons in terms of the workability, compressive strength, flexural strength and flexural behaviour of the concrete beams, the conclusions that can be drawn are as follows: i.) As the replacement of the POS increased, it increased the workability of the fresh concrete due the spherical shape of the POS. 110 ii.) The compressive strength and flexural strength of concrete cube and prisms was decrease as the replacement of the POS increase. iii.) The density requirement for lightweight concrete is below 2000 kg/m3 [26], which mean that only the full replacement of the POS concrete considered as lightweight concrete. iv.) The minimum compressive strength for lightweight structural concrete is 17 MPa [43]. Hence, the full replacement of POS as aggregate can be used in structural lightweight concrete which has compressive strength of 18.1 MPa. v.) The flexural behaviour of the concrete beams with POS replacement act similar with the control concrete beams. An overall conclusion can be stated that the concrete with uncrushed palm oil shell as coarse aggregates can be used to reduce the member selfweight, which can reduce the cost for bigger dimension for beam and column required, the quantity of the reinforcement bar required and the bearing capacity of the foundations. Besides, it can save the gravel aggregates usage and hence decrease the depletion rate of the gravel aggregates. 5.2 Recommendation There are several recommendations for further experimental works regarding the usage of uncrushed POS as coarse aggregates in concrete in order to expand the knowledge and findings in this area. i.) Additional of organic palm oil shell fibre in the concrete to determine the effect on flexural strength. ii.) To study the creep and shrinkage of the uncrushed palm oil shell concrete. iii.) To study the sound and heat insulation of uncrushed POS concrete. 111 iv.) To study the durability of POS concrete by using blended cement. 112 REFERENCES [1] Teo, D. C. L., L.Y.F., The use of oil palm shell (OPS) as partial or full replacement for aggregate in concretes. [2] [3] [cited 2009; Available from: http:/econ.mpob.gov.my. Basri, H.B., M.M.A., Zain M.F.M., Concrete using waste oil palm shells as aggregates. Cement and concrete research, 1999. 29: p. 619-622. 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Upper Saddle River: Prentice Hall. 1995. 116 APPENDIX A DESIGN OF REINFORCED CONCRETE BEAM Design of Under Reinforced Concrete Beam according to the British Standard, BS 8110: Part 1: 1997 – Structural Use of Concrete: Code of Practice for Design and Construction Information: Length of beam, L = 1600 mm Width of beam, b = 125 mm Depth of beam, h = 150 mm Nominal cover, c = 25 mm Concrete strength, fcu = 25 N/mm2 Reinforcement strength, fyv = 460 N/mm2 Diameter of reinforcement, Øbar = 10 mm Shear link, Ølink = 6 mm 117 Design: Effective depth, = h – c – 0.5(Øbar) = 150 – 25 – 0.5(10) – 6 = 114 mm Fcc = Fst 0.405 fcu bx = 0.95 fyAs x = 0.95 fyAs / 0.405 fcub = 0.95 (460) (157) / 0.405 (25) (125) = 54.21 mm = 54.21 / 114 = 0.48 < 0.5 = d – 0.45 x = 114 – 0.45(54.21) = 89.61 mm = 0.95 fyAsz = 0.95(460) (157) (89.61) = 6.15 kNm = M/bd2 fcu = 6.15 x 106 / (125) (114) 2 (25) = 0.15 < 0.156 d x/d Therefore, under reinforced beam, Level arm, Ultimate moment, z M K Therefore, compression reinforcement is not required. 118 av/d = 550/114 = 4.8 2 < av/d < 6 Hence, beam fail in bending and shear Maximum shear force, P/2 Maximum shear force, V = 6.15 / 0.55 = 11.18 kN = 11.18 kN Maximum shear stress at support, 119 v 100 As/bd (400/d)0.25 = V/bvd = 11.18 x 103 / (125 x 114) = 0.78 N/mm2 < 0.8(fcu0.5) = 4.38N/mm2 = 100(157)/(125 x 114) = 1.10 < 3 (ok) = (400/114)0.25 = 1.37 >1 (ok) =0.79(100As/bd)1/3(400/d)1/4(fcu/25)1/3/1.25 Concrete shear stress, vc =0.79(1.10)1/3(1.37) (25/25)1/3 / 1.25 = 0.89 N/mm2 0.5 vc = 0.5(0.89) = 0.45 N/mm2 Vc + 0.4 = 0.89 + 0.4 = 1.29 N/mm2 Hence, 0.5 vc < v < vc + 0.4 = 0.45 < 1.07 < 1.29 Provide minimum shear links for the whole length of beam Asv / Sv = 0.4bv / 0.95 fyv = (0.4 x 125) / (0.95 x 250) = 0.21 N/mm2 Asv / Sv = 0.21 Sv = 56.6 / 0.21 = 270 mm > (0.75d = 85.5 mm) Use shear link R6 (Asv = 56.6 mm2) Use Sv = 80 mm Hence, provide R6 – 80 120 Deflection: M/bd2 Fs f.u.t.t = 6.15 x 106 / (125)(1142) = 3.79 N/mm2 = (2/3)(fy)(Areq/Aprov)(1/βb) = (2/3)(460)(1)(1) = 306.67 = 0.55 + {(477 – fs) / [120(0.9 + M/bd2)]} = 0.85 < 2 (L/d)basic = 20 (L/d)allowed = 20 x 0.85 = 17 (L/d)actual = 1600/114 = 14 Cracking: Allowed clear distance between bars = S1 y S2 H 155 mm = 125 – (2 x 25) – 10 – (2 x 6) = 53 mm < 155 mm = 25 + 10 + 10/2 = 40 mm = (402 + 402)0.5 – 10/2 = 51.6 mm < 77.5 mm (ok) = 150 mm < 750 mm (ok) (ok) 121 Detailing: 122 APPENDIX B CONCRETE MIX DESIGN Stage 1: Characteristic Strength : 30 N/mm2 at 28 days (Proportion Defective = 2.5%) Standard Deviation : 8 N/mm2 Margin : (k = 1.96), 1.96 x 8 = 16 Target Mean Strength : 30 + 16 = 46 N/mm2 Cement Type : OPC Coarse Aggregate Type : Crushed Fine Aggregate Type : Crushed Free Water Cement Ratio : 0.52 Slump : 30 – 60 mm Maximum Aggregate Size : 20 mm Free Water Content : 210 kg/m3 Stage 2: 123 Stage 3: Cement content : 210 / 0.52 = 403.8 kg/m3 Maximum Cement Content : 550 kg/m3 Relatively Density of Aggregate : 2.70 (assumed) Concrete Density : 2400 kg/m3 Total Aggregate Content : 2400 – 405 – 210 = 1785 kg/m3 Grading of the Aggregate : Percentage passing 600 μm size = 40% Proportion of Fine Aggregate : 39 % Fine Aggregate Content : 1785 x 0.39 = 696.5 kg/m3 Coarse Aggregate Content : 1786 – 695 = 1091 kg/m3 Hence, use 405 kg/m3 Stage 4: Stage 5: Quantities Cement (kg) Water (kg or Fine Coarese L) Aggregate Aggragate (kg) (kg) 1 m3 405 210 700 1090 0.011 m3 4.5 2.3 7.7 12.0 0.011 m3 = Total up specimens of 3 cubes and 10% wastage 124 APPENDIX C DETERMINATION OF WEIGHT POS REQUIRED Bulk density of POS = 606.7 kg/m3 For 50% replacement of POS: Weight required for coarse aggregate in concrete mixing is 15.26 kg for 3 cubes with 35% wastage, since 50% of it will be replaced by POS, the weight of coarse aggregate required is 7.63 kg. 1m3 : 2700 kg/m3 Assume volume occupied by coarse aggregate is X, Hence, X : 7.63 kg X = 7.63 / 2700 = 2.83 x 10-3 m3 POS required = = (2.83 x 10-3 m3) x 606.7 kg/m3 1.71 kg