Unit 1 Project Developing a Chemistry Newsletter Student Textbook pages 152–153 This performance task provides an excellent opportunity for students to learn about the safe use of household chemicals in everyday life, and to demonstrate their communication skills by presenting what they have learned in the form of a newsletter. Students will have a chance to experience first-hand the challenges faced by scientists as they try to communicate important chemical information to the public. Through this performance task, students will begin to recognize the importance of achieving excellence in scientific literacy. Many students will be tempted to carry out all of their research on the Internet. Encourage students to do research “in the field” by gleaning information from products found in their own homes and in hardware and grocery stores. Students have an opportunity to flex their creative muscles with this performance task. Suggest to artistic students that they create comic strips or visual organizers to add interest to the newsletter. Students who like to write may enjoy creating fictitious scenarios or news items to illustrate safe and unsafe use of household chemicals. While the scenarios and comic strips can be imaginary or fanciful, the safety and chemical information contained within them must be factual, and the purpose clear. Students may balk at the idea of interviewing a professional. Although experts are often more willing to help when contacted over the phone or by mail, students can send a questionnaire via e-mail. It is relatively easy to search for experts on the Web. You may want to go over students’ planned list of questions with them before they approach an expert. Assessment and Evaluation Performance Task Curriculum Expectations Assessment Tools/Techniques Achievement Chart Category Learning Skills Unit 1 Project: Developing a Chemistry Newsletter ■ ■ ■ ■ ■ [MCB V.03] describe how an understanding of matter and its properties can lead to the production of useful substances and new technologies [MCB 3.04] demonstrate an understanding of the need for the safe use of chemicals in everyday life (e.g. cleaners in the home, pesticides in the garden) ■ Studentdesigned rubric for self-assessment: Rubric for Unit 1 Project (see “Assessment and Evaluation” in the front matter of Teacher's Resource CD-ROM) ■ Making Connections Inquiry ■ ■ Teamwork Initiative Organization Unit 1 Review Answers Student Textbook pages 154 –157 Answers to Knowledge/Understanding Questions 1. (c) 2. (c) 3. (e) Unit 1 Matter and Chemical Bonding • MHR 157 4. (d) 5. (b) 6. (a) 7. (c) 8. (b) 9. (a) 10. (a) 11. (c) 12. (d) 13. False — this scale is precise, but not accurate. 14. True 15. False — matter is anything that has mass and occupies space. 16. False — the three standard states of matter that exist at room temperature are solid, 17. 18. 19. 20. 21. 22. 23. 24. 25. liquid, and gas. False — when iron rusts, elements becomes a compound. This is a chemical change. False — acid rain is a solution. False — when water melts, a physical change occurs. False — to change water from ice to liquid - energy must be added to the water. False — a gold ring is an alloy of gold, which is a homogenous mixture. False — water is an example of a compound. True True False — the number of particles, such as molecules, may be different, but the number of atoms of each element is the same. Answers to Short Answer Questions 26. Examples of everday reactions include iron rusting, food cooking, plants growing, and food digesting. 27. In a cylinder of pure nitrogen gas, you would find nitrogen–14 and nitrogen–15 — two different types of atoms. 28. (a) K, Na, H (b) Mg, Si, S (c) K, Cl, Ar 29. (a) B, N, F (b) Br, Cl, F (c) Cs, K, Na 30. (a) Ca, Mg, Be (b) Se, Br, Kr (c) Cs, K, Na 31. (a) ammonium nitrate (b) lead(IV) acetate (c) Disulfur dichloride (d) barium nitrite (e) tetraphosphorus decaoxide (f) manganese(III) oxide 32. (a) SrCl2 (b) PbSO3 (c) Cr(CH3COO)3 (d) H2S (e) IF7 158 MHR • Unit 1 Matter and Chemical Bonding 33. Classification allows better understanding of the reactions, simplifies the nature of each reaction, can generalize each reaction type for better understanding and explanation. 34. (a) Zn(s) + 2AgNO3(aq) → Zn(NO3)2(aq) + 2Ag(s) , single displacement (b) balanced, synthesis (c) 2KClO3(s) → 2KCl(s) + 3O2(g) , decomposition (d) balanced, double displacement (e) 2C2H6O6(l) + 7O2(g) → 4CO2(g) + 6H2O(g) , combustion 35. (a) Mg(s) + 2HCl(aq) → H2(g) + MgCl2(aq) , single displacement (b) 2HgO(s) → 2Hg(l) + O2(g) , decomposition (c) 4Al(s) + 3O2(g) → 2Al2O3(s) , synthesis/combustion (d) C6H12O6(s) + 6O2(g) → 6CO2(g) + 6H2O(g) , combustion (e) BaCl2(aq) + Na2SO4(aq) → BaSO4(s) + 2NaCl(aq) , double displacement Answers to Inquiry Questions 36. Students should state the properties they are testing for. It is trivial to test for many qualitative properties; physical state at room temperature and colour can be described just by looking at the sample. Students may come up with interesting ways to test for malleability, ductility, hardness, and brittleness. Quantitative properties that are fairly straightforward to test for are density, solubility, and electrical conductivity. Ensure that students provide a detailed procedure that addresses safety and includes controls where appropriate. 37. Students should use Investigation 4-A as a model. They should note that the production of hydrogen gas indicates that a reaction has taken place. 38. In Trial #1 the mass of paper and powder should be reported to 2 decimal places. In Trial #2 the mass of filter paper should be reported to 2 decimal places. Also, the mass of calcium sulfate should be 8.61 g according to the data. In Trial #3 the mass of calcium sulfate should be reported to 2 decimal places. 39. Students’ procedures will probably include tests to compare the several different properties of metals and non-metals. For example, metals tend to be are ductile and malleable solids, while non-metals tend to be gases, liquids, or brittle or crystalline solids. Solid metals tend to conduct electricity, while non-metal solids do not. Students may also propose carrying out various reactions to test the reactivity of the unknown substances with reactants such as acids. Accept all reasoned and reasonable answers, and ensure students have included safety considerations in their procedures. 40. (a) Based on appearance, the compound could be either ionic or covalent. (b) Both salt-like crystals (NaCl) and sugar-like crystals fit the description of the compound. (c) Students’ procedures could include testing for the melting point of the unknown compound and for the conductivity of a solution of the unknown compound. 41. (a) The reaction is a single displacement reaction, in which metal X is displacing metal Z. (b) X is more reactive since it is displacing Z from its compound. (c) Possible combinations of substances that would behave like metal X and compound ZSO4 are: zinc metal and copper(II) sulfate, magnesium metal and zinc sulfate. Unit 1 Matter and Chemical Bonding • MHR 159 Answers to Communication Questions 21.5 g 58 cm3 19.3 kg/dm3 17.5 g 298 43. Group 1 – alkali metals – soft, gray metals, react with water to produce hydrogen gas Group 2 – alkaline earth metals – gray metals, some react with water Group 17 – halogens – tend to exist as diatomic molecules Group 18 – noble gases – very non-reactive 42. (a) (b) (c) (d) (e) 44. Atom or ion with mass number Number of protons Number of neutrons Number of electrons 14 3− N 7 7 10 16 2− S 16 16 18 He 2 2 2 7 + 3 4 2 20 20 18 4 Li 40 2+ Ca 45. (a) (d) Ar B (b) Na (c) Al (e) Al (f) B 46. (a) C (b) N (c) O (d) F (e) Cl (f) Br Pattern 1: Number of valence shell electrons increase across a period (row). Pattern 2: Number of valence shell electrons stays the same down a group (column). 47. Atomic radius increases going down the periodic table and decreases going across the periodic table. Ionization energy decreases going down the periodic table and increases going across the periodic table. Electron affinity decreases going down the periodic table and increases going across the periodic table. 48. 49. (a) (d) 50. (a) (b) (c) (d) (e) 160 Chemical Properties Physical Qualitative Properties Physical Quantitative Properties Reactivity with acids Colour Melting point Flammability Malleability Density Reactivity with air Hardness Electrical conductivity Toxicity Brittleness Boiling point Br Cr Br (b) H S H H As H C S (e) S H A + B → AB XY → X + Y compound or element + O2 → oxides M + RX → R + MX AB + CD → AD + CB MHR • Unit 1 Matter and Chemical Bonding (c) Cl Cl C Cl Cl 51. Because nitrogen, phosphorus, and arsenic are all in the same group, students will assume their hydrogen compounds have the same shape. Students know that ammonia is a polar molecule. The bonds in phosphine and arsine, however, have very small electronegativity values, so the molecules will be almost non-polar. Therefore, you would expect phosphine and arsine to have lower boiling points than ammonia, since the intermolecular forces due to dipole attractions would be significantly weaker. (Arsine has a boiling point of –55˚C, phosphine has a boiling point of –88˚C, and ammonia has a boiling point of –33˚C) 52. The molecule BF3 is trigonal planar (you will probably need to give students this information). Because the polar bonds balance each other, the molecule is non-polar. Answers to Making Connections Questions 53. Students will probably work with the idea that a defense lawyer tries to establish reasonable doubt when arguing a case. If expert witnesses for the prosecution provide scientific evidence that can be shown to have a significant degree of uncertainty, the evidence will be effectively worthless to the prosecution. The argument can work the other way, of course. If counterevidence is provided by the defense, the prosecution will try to find out whether the science behind it is inaccurate, is incomplete, or has a significant margin of error. 54. In ancient times, the known metals were the least reactive ones that occurred naturally (such as silver), or were easily extracted from their ores (such as iron). The most reactive metals were unknown since no extraction methods were known to decompose their compounds. Theories of matter at the time did not predict new metals so no one was looking for them. Unit 1 Matter and Chemical Bonding • MHR 161