Durability of concrete as affected by low air temperature at time of placing by Floyd D Swenson A THESIS Submitted to the Graduate Faculty in partial fulfillment of the requirements for the degree of Master Of Science in Civil Engineering Montana State University © Copyright by Floyd D Swenson (1952) Abstract: In this study, plain and air-entrained concrete specimens made with two Montana aggregates were subjected to storage temperatures varying from 45° F. to 5° F. immediately after casting for a period of 24 hours. The concrete specimens were subsequently given 27 days curing at 70° and 100 per cent humidity. At the total age of 28 days freezing and thawing cycles were started on the specimens. One freezing and thawing cycle consisted of 24 hours in a freezer with an air temperature of approximately 5° F. and 24 hours in a water bath at a temperature of 70° F. At the end of about 50 such freezing and thawing cycles, one-half of the specimens were tested to failure in compression, the other one-half continued, the freezing and thawing cycles. An attempt was made to estimate the detrimental effects of the initial storage temperatures and of the freezing and thawing cycles and to correlate these results with conclusions drawn from similar tests by other authors, Besults from this study show a decrease in compressive strength up to 30 per cent from that of normally cured concrete of the same age due to the initial storage temperature. The percentage of decrease was generally higher for the lower, values of storage temperature, Two appendixes are attached giving a brief outline of the con- siderations involved in making freezing and thawing tests, and of the mechanism of disintegration. DURABILITY" OF OOWGRBiTE AS, AFFECTED BY DOW AIR TEMPERATURE ;AT TIME OF PLACING * • by . ■ FLOYD D . : SWENSON ' . F $:•■■■■■ ' ' I: ' .. • A THESIS " . ; SuD m itied t o th e GspadtiAtei p a o u lty 1 4 '= / / ' p a r t i a l f u lf il lm e n t , of; t h e 1,req u irem en ts f o r th e d eg ree o f I'/", ; ■ M aster o f S c ie n c e i^ , C iv il-E n g in e e r in g . i" ; ' 1' W ": Montana S t a t e C o l l e g e ■ Kr, ’ . Approved? , I r r t, Headjf Major .Department. ____ - J |: ' 'I »:v Exajnining Gotanitteer ^ a n /'G ra d u a te d i v i s i o n Bozeman #. M ontana■ F eb ru ary s .1952 ' AU ' 3 to - \ ' I -2 TABLE OF CONTENTS Page U A cknowledgement A b s tr a c t 5 I n tr o d u c tio n 6 Purpose 6 In p o rta n ce 6 P re v io u s Work 7 L ab oratory Equipment IU C oncrete Mixer IU S p ecin en Molds IU Curing Room IU F r e e z e r C hest 15 S to r a g e Tank v A ir D eterm in ator 15 ' ' 15 M a te r ia ls 16 Procedure 18 M ixing and C a stin g 18 I n i t i a l F r e e z e r Procedure 19 Curing 19 T e s tin g o f C on p ression Specim ens 19 F r e e z in g and Thawing C y cles 20 Mix D ata 22 R e s u lt s 27 I n te r p r e t a t io n o f R e s u lt s 32 1033P8 - Page 39 C o n clu sio n s S u g g e s tio n s f o r F u rth er Studgr . . ■I, ■. ■ A ppendix A • - T-V , ■, . , . . 142 - C o n sid e r a tio n s I n v o lv e d i n t h e ,M king; o f f r e e z in g and ' Thawing T e s t s on C oncrete Appendix, B ■ ■ ■ n. . ■Mechanism o f •d is in t e g r a t i o n l i t e r a t u r e ■C ite d -and C o n su lted ' , = ; I I I 1 , -** : : I . h l' , , . . ■ . ' 24' 2i5 2t5 b?, ' \ : ; ACKNOWLEDGEMENT T h is o p p o rtm it-y i s ta k en b y th e au th or t o e g r e s s h i s g r a titu d e t o th e fo llo w in g |B r o fe s s o r R o b ert Ge De H art5 f o r h i s a d v ic e and s u g g e s tio n s on th e problem s en cou n tered ^ ■' ■ • ■■ : 1 *■ 1 ' ■ i D r0, E ldon R . B odge5 f o r h i s a d v ic e on th e com p letion o f th e w r it t e n t h e s i s 5, • ■■. Bruno D a n is e v s k is 5 f o r h i s a s s i s t a n c e in co n d u ctin g th e r o u tin e la b o r a to r y in v e s t i g a t i o n s 1 j The Bureau o f R ecla m a tio n a t Canyon F er ry Pam5 H elen a 9 Io n ta n a 9 f o r su p p ly in g th e a g g r e g a te s n eeded f o r p a r t o f t h i s stu d y 3 The E n g in eer in g Experim ent S ta tio n 9 f o r th e f i n a n c i a l a s s is t a n c e ■ t h a t made t h i s stu d y p o s s ib le * ’ ABSTRACT . Ba t h i s stu d y ^ p la in and, a ir -e n t r a in e d c o n c r e te specim ens made w ith two $$ontana a g g r e g a te s w ere s u b je c te d t o s to r a g e tem p eratu res vary­ in g from ItS0 Fe t o 5 ° F 0 im m ed iately a f t e r c a s t in g f o r a p e r io d o f 2it hour s o The c o n c r e te specim ens w ere su b seq u en tly g iv e n 27 d ays c u r in g a t .700 F i and 100 p e r c e n t hum idity= At. th e t o t a l a g e o f 28 d a y s9 f r e e z in g and thaw ing, c y c l e s w ere s t a r t e d on t h e specim ens= One f r e e z in g and thaw­ in g c y c le c o n s is t e d o f 2It hou rs i n a f r e e z e r w ith an a i r tem perature o f a p p ro x im a tely 5 ° F= and 2 it hou rs i n a w a ter b a th a t a tem perature o f 70° Po A t. th e end o f a b o u t .$0 su ch fr e e z in g ' and th aw ing c y c l e s , one-**half o f th e sp ecim en s w ere t e s t e d t o f a i l u r e i n co m p ressio n , th e o th e r o n e - h a lf co n tin u ed th e f r e e z in g and thaw ing c y c le s= An a ttem p t was made t o e s t im a t e th e d e tr im e n ta l e f f e c t s o f th e i n i t i a l s to r a g e tem p era tu res and o f t h e fr e e z in g : and thaw ing c y c l e s and t o c o r r e la t e t h e s e r e s u l t s w ith c o n c lu s io n s drawn from s im ila r t e s t s by o th e r au th ors= , J l o s u l t s from t h i s s t u d y . show a d e c r e a se i n com p ressive s t r e n g t h up t o 30 p e r c e n t from t h a t o f n o rm a lly ,cu re d c o n c r e te Of th e same, a g e due t o t h e . i n i t i a l s to r a g e tem perature= The p e rce n ta g e o f d e c r e a se was g e n e r a lly h ig h e r f o r th e lo w er v a lu e s o f s to r a g e tem perature= Two a p p en d ix es a r e a tta c h e d g iv in g a b r i e f o u t lin e o f th e c o n -s id e r a t io n s in v o lv e d i n making f r e e z in g and thaw ing t e s t s , and o f th e mechanism o f d is in t e g r a t io n = I . /' . P urpose -t' .. ■ .'OTRQDUonQH ./ ■ . ; _ Ther p u rp ose o f , t h i s t h e s i s -was to d eterm ine t h e , e f f e c t o f ,law' tempei-a-bure >on th e s tr e n g th and d u r a b ilit y o f concrete=, -The, c o n c r e te was ■ ■ ; e x p o s e d , t o ■te n p e r a tu r e s - v a r y in g from 1|5 ° F-« to. 5 ° F= im e .d ia .te ly a f t e r ■ ' * ' 1 , castin g= ,’ An a ttem p t was made to. ,provid e, t e s t ,c o n d itio n s w hich w ould a p - ' • . ■ ; - . . . p roxim ate t h o s e w h ich m ight, occu r ,du ring ,c o n c r e tin g • o p e r a tio n s in .the. , f ie ld ,, T h is study! en d eavors t o in d ic a t e t h e s tr e n g th and. d u r a b ilit y ,which ! Can W -e x p e c te d c o n c r e te exp osed t o t h e s e tem peratures= ‘ Im portance ■;, ■ . , , ' . , . C oncrete i s n o rm a lly p la c e d during, .warm .or m oderate w eath er t o ", - ' 'v ■ . . p r e c lu d e th e p o s s i b i l i t y o f harm or damage t o th e c o n c r e te due t o th e . ^ . . . , ^ ^ . , . ' '. a c t io n i o f c o ld w eather= 1 “ , 4 '" f ' , t / k, ■ , ,EdwardBovSauer s t a t e s ; « 1 * * ( . ; AYheneVer i t i s . a n t ic ip a t e d t h a t th e a i r tem perature a t th e p o in t ,O fcpiaceiaent i s l i k e l y t o f a l l b elow -UO0 F= d u rin g th e Wi hour p e r io d a f t e r p la c in g c o n c r e te Or b elow 3 0 ° F= d u rin g th e ,Su cceed in g 6 days* it;id > o ep m m en d ed th a t'p r o te c tiv e " m e a s u r e s Oei taken ^ ' , To p ro v id e -Some a r b it r a r y stan d ard o f s tr e n g th s t o u se in c o ld w eath er c o n c r e tin g o p e r a tio n s j t h e American C oncrete I n s t i t u t e h a s sug­ gested^ t h a t a minimum s tr e n g th o f ^OO pounds p er square in c h b e a t t a in e d b e fo r e f r e e z in g t o p r e v e n t permanent damage=2 « ■ 1Bdvzard E= Bauer 0, P la in . C o n c rete* (3d„ e d .; Mew Io r k s McGraw-Hill Book Cbmpany9 I n c 09 1 9 h 9 \s 200-201= 2Ib id = • ' ' • : -7' fin is i n th e n o rth ern clim a te's j, w h ere. th e tem p eratu res a r e more or I e S s s e v e r e ,; th e p lacem en t o f c o n c r e te m ust be suspended d u rin g a la r g e p o r tio n .of th e y e a r or* a s an a l t e r n a t i v e , t h e f r e s h l y p la c e d co n cre te' m ust b e p r o t e c t e d from f r e e z in g * ' The v a r io u s p ro ced u res f o r th e:',b o ld -.' ; ,, , • . , _ w eath er p r o t e c t io n o f c o n c r e te a r e s’ (I); h e a tin g o f th e m ixing w ater* ( 2 ) h e a tin g ,of th e w a ter !and th e a g g r e g a te s* ( 3 ) p ro tb o tiv O :.co v erin g Of' ■ fr ,e s h COncrete j (U ): .h e a te d :e n c lo su r e f o f .th e ,s t r u c t u r e , and' ( 5 ) th e use, o f ad m ixtu res t o low er th e f r e e z in g p o in t o f th e w a t e r , ' Any o r .s e v e r a l . o f th e s e p r e c a u tio n a r y o p e r a t io n s 'may be u sed depending, on th e c lim a te and tem p era tu re, c o n d itio n s a f f e c t i n g a s p e c i f i c p r o j e c t .^ . . , . A •d e t a ile d ',d e s c r ip t io n Of th e above m entioned methods, w i l l n o t ■ ' I / ' i- I I ■ ^ , 1 ; > 1 be attem pted., However*, ev en w ith ' th e u se'.o f t h e s e p r o t e c t iv e m easures* S f, , ' ' ' cd h c r e te l a o c c a s io n a lly fr o z e n b e fo r e a minimum, s tr e n g th hs.s been a t - ' : ; ta in ed o , S o s t s p e c if i c a t io n s , s t a t e t h a t any c o n c r e te ,so’, fr o z e n must b'^'V •' , ' - - ' ' . ' ' , removed and rep la ced - r e g a r d le s s , o f t h e : c o n d itio n s ,under w hich i t w as,, " '.Ty ' ' % ^ f r o z e n . W hile, th e s e s p e c i f i c a t i o n s , d o u b tle s s have m e r it , t h e r e '.is ia ; p o s s i b i l i t y t h a t much c o n c r e t e .rem oved under t h e s e c o n d itio n s, m ig h t w e ll, have' r e t a in e d enough, s tr e n g th or has, th e , a b i l i t y ., t o s u b se q u e n tly .,gain, ■ s u f f i c i e n t s tr e n g th t o .m e e t a l l . th e s tr e n g th and d u r a b ilit y req u irem en ts ,for. some c o n c r e tin g w ork. Thus* i f a method o f a c c u r a te ly p r e d ic t in g th e u ltin ia te s tr e n g th o f p rem atu rely f r o z e n c o n c r e te c o u ld b e ;devi,sed> ■ • &ohn H.; Bateman * M aterials of Construction^ (Toronto i ;Pitman Publishing C o r p o r a t i o n s ; , 1 S » B . ;,. : ‘ ''''vV'1' ' ' ' ' ' v. 'f , a s a v in g i n tim e . and' money would- r e S u it 5,; and more eco n o m ica l c o n c r e te ivqrk; Gould be o b tain ed o ’ 'Previows-W oyk • • ■ . . , . . , . .■ - . ■ ■ ' ' : v.-:: _ .X The ',work -th a t'b a s, been- -conducted .in ,'th e - p a s t can be, p la c e d In,- two, • , , - ./■ . , , 1 ■■ '■ ,c l a s s i f i c a t i o n s : ( I ) . la b o r a to r y o r e x p e r i m e n t a la n d (.2 ) c o n s tr u c tio n , ex p ed ie n c e # d o b s e r v a tio n ,; i -As, compared - t o ,o th er 'con crete, s t u d i e s , r e , ■I d tiv e ijr ' l i t t l e I m fo r m d tim r is a v a il a b l e on, th is-'" su b jectv ',Whet, d a t a ’i s : ■-',a v a ila b le vfr'om d i f f e r e h t " so u rces1, is ' no^,' in' ,',good agreements-' th e r e ^ b e ih g ;'.1 ■ '' t^ o ,.distdnot-- - b e l i e f s $ , ( i ) , t h a t ',con crete ,/w h ich ,,h asb een fr o z e n . Btejr'an V1 .• ''V ea-zf]^-i'iage/'duffe r s ' i i t t l e ,damage-^-dmd ( 2 ) th a t- f r e ^ ; e n c o n c r e te s u f f e r s ' a ,• l o s s ' i n - s t r e n g t h rin th e-ra n g e-,.o f t.O, to' .60,,,per 'cebti.'" A p r M c ip le :'rea so n v ; ' , I ■ ' . ' ,. \ ., for-' 'th ese; d iffe r e n c e s ',n f ,o p in io n s, is-, th'dt r e s u l t s from .two. v e r y / s i m ila r V■ t e s t s !Sometimes-, have-; v e r y l i t t l e , c o r r e la t io n “to-'each : o th e r ^vimd as,',a' p o n * .' • Sequenc'd#: the- t y p e s 1,o f t e s t s u sed /a re' no't s ta n d a r d iz e d ,;., T h is -i'a-aS.' I t - '. ■ , should,-bej,.: a t l e a s t u n t i l - s u f f i c i e n t ‘knowledge,.' h as been, b u ilt , up: t o pro* . v id e a ,s ta n d a r d iz e d ..te s t, an assurbrioe. o f s u c c e s s ., ; I n donstrtictibn,*:.no , attem pt., i s . made t o c o r itr o l c o n d itio n s ,,a s i n a" la b o r a tory.j, ,and: p p in id h s 1 ■ and r e s u l t s can be .e x p e c t e d ' to., d i f f e r . , The f o llo w in g , q u o ta tio n ,b y,A , :Me,; f Unzbergy .w ritten f Or th e ; Engin-. , ' ’ ' '^i ' I ' ' ' ] ' ' ‘ ’ ' ' . ■ e e r in g Mews^v August-'bj?..-1931» i i l u s t r a t e . s a, c o n s t r u c t io n 'e ^ e r ie n c e ,th a t ' . ' ' \ \ . i . . - . - " ' ' ' : i s unique and- h a s been; r e c e iv e d w ith v a r io u s d e g r e e s o f ( b e l i e f I t i s . : , ' ' ; ■ : ■ ■ p r e s e n te d 'h e r e in, i t s ,e n t i r e t y t o , provid e, a thorough knowledge o f .th e , iflethbd u s e d . , . G p n cretin g during, s e v e r e w in te r w e a th e r , i n t h e open a i r a w it h the; p u rp ose o f f Qroing th e c o n c r e te t o f r e e z e b e fo r e s e t t i n g b e g in s ,, h as . . been, c a r r ie d on i n R u s s ia Under s p e c i a l m ethods. d e v is e d by th e author# ' , /.w h o ,s ta t e s t h a t s in c e XSO^ he h a s u sed t h e s e m ethods i n th e U kraine • f o r JiJany la r g e c o n c r e te and r e in fo r c e d b u ild in g s , w hich have a l l prov- 1 ; ed s a t i s f a c t o r y o G oncrete p la c e d i n t h i s manner i s p r o te c te d t o keep , v.; . - i t i n a- fr o z e n c o n d itio n u n t i l sp rin g * «— E d ito r* ■ j , , . A t th e moment b e fo r e a c t u a l s e t t i n g o f c o n c r e te th e cement g r a i n s . ,are en v elo p ed i n a t h in m o lecu la r f i l m o f w ater; and th e g r e a te r the,',,. ■;;..^proportions o f w a ter ,in' th e m is , t h e low er w i l l be th e s t r e n g t h o f / ' C oncrete* ,I f c o ld w a ter i s u s e d , 'th e ,volume w i l l be le h s tbati-';,,;v'_ -w ith , h e a te d w a ter b u t th e s t r e n g t h w i l l be g r e a te r * Xf th e concrete;'';.. , V / f r e e z e s w h ile s e t t i n g , i t w i l l become a r i g i d n o n e la s t ic mass o o n s is t 'ing o f san d, cem ent and i c e p a r t i c l e s , and su ch a mass w i l l f a i l a f t e r thawing* B ut by a llo w in g th e c o n c r e te t o f r e e z e b e fo r e s e t t i n g i t , , ■ . . w i l l b e in norm al c o n d itio n a f t e r th aw in g,, s o t h a t s e t t i n g Can th en • ■ b e g in and p ro ceed t o com p letion * , >! As th e c o n c r e tin g must be done' r a p id ly , th e forms must n o t be < deep and th e r e in f o r c in g b a rs must be s o arran ged t h a t th e c o n c r e te . w i l l f lo w f r e e l y and f i l l t h e form e q u ic k ly w ith o u t v o id s* Xt i s a b s o lu t e ly n e c e s s a r y f o r th e c o n c r e te t o f r e e z e b e fo r e s e t t i n g b e g in s * Xhe cement i s C o ld , th e a g g r e g a te must be c o ld and dry and t h e w a ter m ust have a tem perature o f IjQ t o 5>0 d eg , if . The l e s s w ater th e r e i d , ■ : th e b e t t e r th e co n crete* The' c o n c r e te i s . m ixed i n a - s h e lt e r e d lo c a ­ t i o n and i s p la c e d q u ic k ly i n t h in l a y e r s , ea ch la y e r b ein g thorough­ l y b u t r a p id ly tamped so t h a t th e r e w i l l be no s e p a r a tio n , or f r o s t p la n e ,'b e tw e e n the, l a y e r s , th e fundam ental req u irem en t b e in g 1co n tin u ­ ous p la c in g and com plete f r e e z in g o f th e e n t i r e mass* As soon a s th e p la c in g ' is , com pleted th e form i s covered w ith b o a r d s * ,, C on crete s la b s a r e covered w ith ' sand or str a w , over w hich . w ater i s poured and a llo w e d ’t o f r e e z e , t o p r e v e n t a ry thaw ing and con seq u en t s e t t i n g a c t io n i n th e co n c r e te * When i t i s n e c e s s a r y t o . s to p work b e fo r e c o m p le tio n , b e f o r e s t a r t i n g a g a in ,, warm w a ter i s to b e poured o v er th e fr o z e n s u r f a c e , w hich i s th en scrap ed and roughen­ ed b e fo r e th e new c o n c r e te i s placed*. The m ost d i f f i c u l t and most; im p ortan t o p era tio n i s th e w e ttin g o f c o n c r e te in th e s p r in g w h ile th aw in g, a s th e v ery d ry n o rth ern w inds i n th e BkrSine d u rin g w in te r can. ev a p o ra te m o istu re even from th e f r o z e n co n cre te* Thus i t w i l l '1be s o d ry t h a t i t can n ot s e t and , i t i s , n e c e s s a r y to ; a p p ly w a te r , b u t th e w a te r -m ust be a p p lie d v e r y ca re­ f u l l y i n o rd er n o t t o wash o u t . th e cem ent*. . , W inter -c o n c r e tin g by ,,methods t h a t employ .th e. h e a tin g , o f ,m a t e r ia ls : .arid.1- k eep in g -trie '.concrete-: warm ,go .,that ;4t. w i l l s e t , p ro p erly , ,have ,.trie,,.";''' . ,',diSridy^ritage o f g iv in g t o o .h ig h a -tem perSW -e f o r p r b p e r v s e t t i r i g j . 1_, ^I :w it lr trie r e s u lt ' t h a t th e. f r e e z in g method l i e s up trie f orm;work>f or 'a •’ V ^ ''co n sid era b le t im e , t h i s o b j e c t io n i s . s l i g h t in co m p a riso n .w ith t h e .• ■/ Ipfv. ^ d yaritriges-O fv g ettin g -the-.-concrete'‘. p la ced d u rin g th e s e v e r e w i n t e r y ^'(^,iShie.'-free.z'ing -m eth od .is .not.-em ployed'near-trie ,e n d ,o f th e coid ysp agori/.. • , when a lt e r n a t e s p e l l s o f c o ld and warm w eath er may be e x p e c te d ,a 'v . tVi . '. M .. ■ • ■; ‘ . - I • 1 " ,.- . i•. '.s .ii > 'V y 'jj,' . i v • ■ ' V l l l j V ; ' 1"1, i ’ ^ V J v ' ' v I - . * *' * \ f Uv,\ ' 1 ' 1 11 1 1 ‘1 nethod just- described-'Is- ript recommended by.-. trieVap:%#'', ' • v ' r ' -- ij v ’ t i » . ;I V V1 1- V - V' . - 1 -..i* i; : K 1 , - '■ • ;/ - ./ ’ . ,V, i,>‘ .> vs',1J rr-; f dr, -"genprai:' rise^ *i t . i s ir it e r e s t in g lt o : n o t e ,t h a t t h i s ty p e o f work: hash:---. V'9/. > and tihat iiie frdaen concrete eyident^ .-i- fe©ep.' ,'saibisf&ctdrily carried \ ' . h J ! 1 I ", •> 1 . - ' ! H 1, ■* , I ■ i I i ' ' ' . f 1' V * l- * , v- - - , 1V * s u f l e r e d n o -g r e a t i l l e f f e c t s 'Hewpverj--Iro aunzberg- s t r e s s e s - t h a t , i n ' , ." order- t o o b ta in - c o n c r e te o f -good ■s t r e n g t h , t h e s e p o in t s m ust be c o s p lie d w ith : I' ( I ) Gonerete-. m ust fr e e z e -b e fo r e , s e t t i n g begins^: ( 2 ) fr o z e n cori- ^ I " ' ''-Ii f '.I1 J ' 1 ,* n 1 , I i ' !j . . I • >,' F .I '> ,- I I -J I II . 1 1 ,'ll" • J, - ■' 'I crate- m ust-be ,p r o te c te d f r o m a l t e r n a t e ' f r e e z in g and- thaw ings - and (3 ) ' -V v card must be ta k en t o ' p ro v id e,,su b seq u en t -good cu rin g a f t e r fin a l'.th a w in g o '■",' S k e p tic is m o f t h e r e s u l t s o f Mr*. -Gunzberg i s ev id e n c ed in a d i s OUssionvOf th e s u b j e c t some ,y e a r s l a t e r k Mr0 R 0 B0 lo u n g o f th e ■'Hydro-?, ' - , 1: • ■ E l e c t r i c Power .Commission, O n tario $ fo r o n t o d s t a t e s ; ■ i t ( t h e p r e v io u s a r t i c l e ) i s v e r y in tr ig u in g -a n d I have made , s e v e r a l attem pts- t o ob tain - lik e v - r e s u lt s i n th e la b o r a to r y b u t have . -- Ia ile d o - I- h a v e 'n e v e r been a b le t o f r e e z e c o n c r e te i d a way th a t " d id riot g e t m t e r n a l s e g r e g a tio n o f t h e 'm ixing w ater i n t o i c e c r y s ­ t a l s =. As lo n g a s th a t- c o n d itio n .e x is t s ^ I -do n o t s e e ^how we can .' -e x p e c t t o have con crete' a s d u rab le a s - i t would o th e r w is e have b een , u n le ss- something- i s done t o r e c o n s o lid a t e trie c o n c r e te and e lim in a te ■ p o r e s ',le f t by t h e s e i c e C r y s ta la 0. ’.fu rth er ,,, i n our t e s t s we have n ev er been a b le t o g e t a n y th in g l i k e 95 p er c e n t Of trie - o r ig in a l S tren gth : ou t. o f a t e s t 'c y lin d e r t h a t w as f i r s t q u ick f r o z e n ,,t h e n thawed. ■o u t and ,cured norm ally*^ V f l r f T - 1I v . . ; n i ’- ' v. 'l i' :,.iii-i|-.fl.iii.- ..... . . n j|-iT,-.T.ITn , FT-V tj I' I . , ^ - j r . - w n y Htnn-HJI1 - y . r ;i ;. i] Tr r. .- ^ f- ~ t i - " ' - ' - ' - t -’-1---■■r/'-’ " - r - T T - r i r n i r - f - - - - i ^ ' i - - r i n n - ; - T r - . w ' T . i r - t y ' - p l — Ir.- ' ' ' &&/$<> Gunzbergj, "Frozen C oncrete Used' in R u ssia n B u ild in g s ," E n g in eer in g ,'H e w s GViI '(K ugust 6 , 1 9 3 1 ), 2 0 ? . , ■ ’ B 0-'Young, "19h2 A1G l Oonyerition Quiz, .'Sessiori,,"1-American ,Con­ c r e t e I n s t i t u t e J o u r n a l, XlV (Noven&er 19h 2) $i 127-129» "-ILl-'' Uei' Toung does: jitit mteialiibd1 ttio eb n d itlo a s' W d er .whichvM s ,v1\ :,,v: . /i . t e s t s , were con d u cted . I t i s d i f f i c u l t t o c o r r e la t e h i s r e s u l t s r a th -f'-1- „ 1'"- '-1' 11 \ ' i , i , -, ' / / ' others,*' , N e v e r th e le ss^ he i s v e r y "em phatic # s t a t i n g t h a t he has . n ever v/ i’", ' >. : been a b le t o .get a h ig h 'p e r c e n ta g e o f o r i g i n a l s tr e n g th from f r o z e n eon'iV-v., C rete i n . any^o f h i s t e s t s * H is c o n c lu s io n s a r e somewhat borne o u t by .'=,-' '' v ' ‘ * i ' I " rf .V ' ' ... ‘ ..'/'.'/Ir/ '-',Vi ' t e s t s con d u cted a t t h e S in n c s o ta Highway, Departm ent * T h eir r e s u l t s 'show. t h a t f r e e z in g c o n c r e t e .im m ed iately a fter),C a ,'S t# g . i s th e w o r s t c o n d itio n ', "I ‘ ■/ -1 m ight ,pcCur* S p eciiien s s a h je c te d t o f r e e z in g f o r s ix t e e n hdurs '" T '\ , .'.''I" ' ^ .' " . ' ' ' ' '-'V.''' ' ' im m ed iately a f t e r c a s t in g and t h e r e a f t e r cu red a t TO0 iP* under b u r la p . ■ v ■ ' • ' ' ; e x h ib it e d a s t r e n g t h o f o n ly 69 p e r c e n t , o f th e u n frozen sam ples j w h ile . V S1 ' ' • ' '. ' ' ■if t h e s to r a g e tem perature was n a in fa in e d a t IiO0 p , , th e specim ens ex~ h ib it e d o n ly 3 1 p e r c e n t Cf, th e u n frozen sam ples * '■However5. th e y d id f i n d t h a t c o n c r e te is, n o t g r e a t l y harmed by f r o s t a f t e r 2k t o '7 2' hours, cu rin g 1 , ‘ • * • 1 ' - i f su b se q u e n tly g iv e n good c u r in g * , and t h a t two weeks f r e e z in g h as1 l i t t l e i f an y more e f f e c t th an s ix t e e n hours f r e e z in g e x c e p t t h a t c o n c r e te g a in s l i t t l e S tr e n g th w h ile fro ze n * ^ ': f u r t h e r -e x p erim en ta l r e s u l t s r e p o r te d by H* H* S c o f ie ld ' may be summarized, "as 'fo llo w s # 1 f ( I ) C oncrete f r o z e n im m ed iately a f t e r p la c in g a t t a i n s o n th e '' ' a v era g e o f about j?0 p e r c e n t o f th e s tr e n g th o f th e norm al u n fro zen c o n C rete a t th e same age* , - - -' . %*' H* H itq h e id e r 5 '.'S ig n if ic a h t ,T e s ts .'o f F r o s t Zction^^ on^GmC r e ts 5 " "E n g in e e r in g Mewsj , C l !(December* 192$)* $82,*. ■ • ' : "i' ?*' - 12- . , • (2 ) ‘Jhere. i s some indication that dry concretes su ffer le s s In jw y V -',, V ■ than wet 'concretesj, especially;' a t early stages «.■1 ' • ’ ' ' " ■ '.1 S ! ' 1 ' ■ I I , ,1 ■ ' ' ’ ' . , . I " ‘ ' , . (I l) '_;fh^re''is s e # in d ic a t io h t h a t o ld e r oonoretd s; W r e -l e s s ,pirg* " portionate I q ss of Strength ,due to immediate, .freezing than, those':!tested • ■a t e a r lie r , periods. , \' :y, .. •, , . . - - . ' -. . (h) ,There i s l i t t l e difference between, a, ridh mix and a. lean mix i n t h e ir r e s i s t a n c e t o im m ediate fr e e z in g ,. L. ' “v “ »‘ vM■j * 5 l', ; 1 - *. ' I , t• ' f ^ I 1‘ ‘ ' (S) W e , r e s u i t s .s e e m t o in d ic a t e t h a t dry c o n c r e te s (2 m . , slump) ‘ ‘‘ t ' t . ^ I ' ’* ' .» i " *‘ , , • , ' i I;. , - ' •, ■- . 1■1 ■■ ,'i' 1. ■:......... , . ' \ ■ ■■■ may ,be fr o z e n s o l i d ,w ithout p r a c t i c a l in j u r y i f cured f o r 2h t o W hours ' 1 1 1 i n room**diy c o n d itio n s, b e fo r e f r e e z i n g «,7 , , -y- ■ I ■S<>, He S c o f i e l d ' s .c o n c lu s io n s summarize,..very n i c e l y , th e . o p in io n s ■ . ■ ■ ■ ' , - , ■ , .of m ost a u t h o r it ie s ^ a s a m a jo r ity a g r e e t h a t f r e e z in g ca n n o t .occur w ith ­ o u t in ju r y ' t o f r e s h l y poured O qncretei ' ■ ■ Howeyer» th e m in o r ity sta u n ch ly •' ■ con ten d s th a t , no harm. I s done by f r e e z in g provided, th e ,c o n c r e te ■i s .f r o z e n b e fo r e a c t u a l s e t t i n g b e g in s < E» A» - Hagy su p p o r ts iU M* -Gunsberg i n t h i s / .r e p o r t! , • . ■ • ;I n t h e y e a r 1930* i n t h s c o n s tr u c tio n o f a h o t e l in C in cin n a ti* . we .had a c o n d itio n o f -about th r e e w eeks o f CloSe t o z e r o weather.^ and we poured f o o t in g s o f th r e e t o f i v e y a r d s . • We d id n o t make any a ttem p t w hatever t o p r o t e c t t h e 1c o n c r e te ^ we, j u s t poured i t and " le t ... i t freeze*', and a f t e r th r e e Weqks i t thawed' o u t an d , t h e . co n cre te seemed j u s t a s p l a s t i c a s when'we poured ■i t . , Then w e .commenced t o tak e, c a r e o f i t > a f t e r i t thawed o n c e . We' had made c y lin d e r s a,t th e ' tim e' i t w as.p ou red and p r o te c te d them a l l * We .made c y lin d e r s front% . JHd S c o f i e l d 5 "Hot/ F r e e z in g and-Thawing A f f e c t Concrete*" C o n crete, XLV ( J u l y , .1937)* 12-13« ' , . / / t h i s fro zen , c o n c r e te a f t e r i t became , p l a s t i c a n d , cu red them , and , . . a f t e r , a s i x months p eriod ^ ,there"w as n e t over a f i v e p e r c e n t d if ~ ■ , ’ ,f^ r e n c e ,'ih:'ihe. tip33^ress#e-\str$hgth''a#:.the^tw d ccnc^etesj,: ' - . ‘X b t i i d y e t h a t nd 'damage w as cauedd- by th e con crete' f y e e t in g /ih '.- :' , _ ■■ ' th e 'p la s t ic “s t a t e ^ X : ' ■,■ . ; , -: A nother -experience:,-was c i t e d by Ha-.0»,W a tts, o f a concrete:-',exdbv-^ "■" on t h e - ground, f r o z e n a f t e r i t was f r e s h l y p o u red ;a t a tem p eratu re o f "1 eig h t-.a b o v e zerot... A fte r . I b y e a r s of. u se * th e C oncrete was. i n good' -, ■ . ' „ t r .- V y y , co n d itio n ,,? ' t ''', .. '' •'1 .'f ; ''V . The d i f f i c u l t y , i n ;in t e r p r e t in g t h e s e . r e s u l t s i s co m p lica ted b y •. th e .la c k o f ,knowledge o f / t h e e x t e n t o f t h e f r e e z in g damage t o th e .con­ c r e t e 0 I t i s : p o s s i b l e t h a t , t h e ■c o n c r e te i n th e f i e l d . s t r u c t u r e s d l s * .1 ' - ’ 1 ' • ■ 1 5 A - ‘ ‘ c u s se d had been damaged* b u t t h a t - i t r e t a in e d s u f f i c ie n t , str e n g th , t o •). ; ’ ' ' .re^ S ^ i; dpnq?9Let@3^' 6a t i s f a e 1l©rgF»i;. ■. ’ / ', ' ' - - . , " .; • ^ . • '. , ' I ' ' ’■ “ . V. v - 1 - The " c o n d itio n s . f a v o r in g , s e v e r e f r o s t damage a r e , Concrete., o f „h ig h p o r o s it y .and lo w str e n g th * t h e p r e se n c e o f w a te r .w ith in Or-In;. c o n ta c t w it h t h e c o n cre te* .and c o o l in g .t o a tem perature s e v e r a l ;d e g r e e s b elow th e f r e e z in g p o in t o v e r an -a p p recia b ly lo n g p erio d * T h u s.a c o n c r e te c o u ld c o n c e iv a b ly :be d e sig n e d w hich w ould r e s i s t f r e e z in g t o th e e x te n t ‘ t ' ’ , 1 1 - ' ' ■ t h a t . l t would remain- s e r v ic e a b le ., w h ile o th e r d e s ig n s would f a i l a f t e r exp osu re t o f r e e z in g o , • -■ ...A . Hagy» ”19U2 ACl Convention, Quiz S e s s io n „ "American Con­ c r e t e I n s t i t u t e J o u rn a l* XlV (November 191*2) •> ( 1 2 7 - 1 2 9 ■ ■■ • ' • ?Bo Co W a tts5:'V-l91t2 AC! C onvention Quiz -S essib n j UAmerican Con­ c r e t e I n s t i t u t e Jou rn al* H ? (November 1 9 1 2 ) 5 127- 1 2 9 ., ' ' •' f ■ io ;A® Eo C O llih S 5 H b estru ctio n o f C oncrete by F rO st55! American 1 C oncrete I n s t i t u t e J o u m a l5. XTI: (June. 1 9 1 5 ) 5 726-727» ‘ , ■ ( " C oncrete Mikey : ' •MiOEATOBt EQUIPMENT: ' '' ' "■ ' ............... ... . 1' " Mte&rig b t' t h e cojabrete' was ic e o r a p lis ie c l thryugh 'the u se d f 'a ia ip r k t d iy ’ c u b ic 1I e e t vC k p a c itto' -T hfm T xer i t e r im anufaeW ek by S e a t s fl Roebuck' and Gbnpany0 ' I t i s powered b y a Dunlap 1 /3 h op .0 s p l i t p h ase motor operat ir ig 'a t 1739 repein= ' 2g r.p.m . " , 'Z Specim eh MolCs The drum o f th e’ m ixer r o t a t e s a t ’' ' '' ' ' ’ ( MClds''f d r thie'.S 'i n i b y 12 i h e.. eO m p lessIb h ''specimens-were, o f - c a s t ' ' ‘ ir d ti w ith a rem ovable - m achined' b ase p l a t e » S t e e l beam m olds s 6 in® by 6 in® by 36 I n efl w ere m o d ifie d t o p r o tid e two molds f o r 6 lu „ c u b e se A ll, m olds w ere o i l e d b e fo r e u s e 0 C w ih gR b om '' - I The m o ist c lo s 'e t has' t h e o v e r a l l d im en sion s b f 1l 8 : f t 0 Iohg by ■ .. ; ' Ji. ( _ , , ' _ t, ; ^ " ' 9 f t c h ig h b y 5 f t o ’w ide= ,A ll w a lls ’ a r e e i t h e r 'c o n c r e t e o r c o n c r e te ' ’ , 1 . j ' j? ' 1 , i I . • I • * i ' b l o c k "th rou gh out o A 'Wooden door was u t i l i s e d a lth o u g h th e i n s i d e sur­ f a c e was c o m p le te ly en ca sed i n a s h e e t m eta l I i h e r 0 The s h e e t m etal; ■ l i n e r was- g iv e n one 'boat Of an o i l s e a l e r and two eOats' o f.'w a terp ro o f ■ v a rn ish o ' The m o is t f IO det m a in ta in ed 109 p e r c e n t h u m idity; through th e ' u s e o f th r e e 'A i n 0, f o g h o z a le g mounted a t t h e c e i lih g o C it y ta p w ater was u sed a lm o st e x c l u s i v e l y t o su p p ly the, -fog n o z z le s a t a room tempera­ tu r e o f 7 0 ° R 0 - E ci was' u s u a lly m aintained' w ith o u t th e a d d itio n , o f h o t w a ter o ReweVerfl d u rin g ex tre m e ly c o ld w eather* tem pered w a ter was need­ ed t o m a in ta in th e r e q u ir e d temper aturbo A lthough som e' o f th e specim ens ' ' ' ' - 4#% . ' . ' ' w 6re s o p la c e d a s t o r e c e iv e th e d i r e c t sp ray from th e fo g a o a s le s y , th e • f l e w o f w a te r was p o t s u f f i c i e n t t o in j u r e th e .'specimens 6 , r r , .V1- .-'V :• The f r e e z i n g 'c a b in e t was ^m anufactured. I o c a llsr ■by t h e lnterm oun* ' ' - a-; . ■ . ■ t u i h 'J n d u str ies Oompai^r t o bur s p e c i f i c a t i o n s . i n s i d e .dim en sions , pf' t h e ., ; ' ' . ‘ ■'[{ • c a b in e t a r e 19 i n i deep b y 30 in .v w id e 60 i n h ig h . -A 6 Iei^erNof,'.v'-.. '' ''' ' . , ' .-Vi sp u n :.glass in s u la t io n was u sed On a l l s u r fa c e s and w as c o m p le te ly e n - . , ' , ,CasOd-Imi, s h e e t, m e ta l. A ra ck f o r h old in g, C oncrete sp ecim en s'w as made t o ; ■ p r o v id e fo u r sh elV es' a n d -th e f l o o r o f th e c a b in e t f o r s t o r a g e .,; Each o f - > . the', s h e lv e s c o n ta in s ,c o o lin g , c o i l s ^ t h e s e n o i l s p r o v id in g 1-th e c o o lin g C l v •' • the. e n t i r e ' c a b in e t *' ; V;, ■.1 ■ r> " ,• • y .......... *'. •* ■_ 1- Temperature-"in th e c h e s t was c o n t r o ll e d by a p r e s s u r e c o n t r o lle r ty p e mercury s w it c h . The com pressor u n it Was m anufactured bgr York and a 1 / 3 h .p , C entury C a p a cito r S in g le Phase- Motor a t 1 7 5 ° rop .m . was u sed ■■ for'-power.:- x StoragefT shk;-' v' . - - - '- ■ I ' w a ter s to r a g e ta n k 27 in .- by 75 -in , by- ? i n . w a s-p ro v id ed f o r , S u f f i c i e n t w ater a t room tem pera* tu r e (a p p ro x im a tely 7 0° Jp0') was k ep t i n t h e tank t o c o m p le t e ly • cover a l l ' sp ecim en s<; ' A ir D eterm in a to r - . , th e,' th aw in g Of th e f r o z e n specim ens.- i - - '- :--i . ! ;,- - The p e rce n ta g e o f a i r i n th e a ir * e n tr a in e d sp ecim en s .was d e t e r - , , - mined by Acme A ir H e l d D eterm inator,., D ir e c t io n s s u p p lie d b y .t h e maim* f A ctu rer w ere f o llo w e d i n th e o p e r a tio n o f t h e de term in a to r... - - , - I 6i- ' .'V. % ■' 1 ■ K - ; , " -MTERIAiS' . ‘i , *' > • . A ggregate^w as s'dbured from tw o Montana S ooreeoi l o c a l a g g reg a te . from .th e' p i t o f th e G a lla t in Sand, and GraVaL Qompany a t B elgradO i . Montana ' Yv,. , (doi^'-i-lettey 'G*)j 'aaad: aggregate from' t h e 'B tr1Oau o f Reclam ation p la n t ^ t'V ' ■, -I I ZrtUVv/,'. 1LA G ^oh/E arry/.B am 'i i^ e le n a iVMontaiia ‘(ood e. ■ I* 1,'V ; ■'V'/i l i f ^eoaraa aggregate^ from B o lg rM a -Was graded BA ' M > *M h u s^ ','-i - -,.'K '4 •V ■■ 1 ; , . aggregate, w as p r o d u c e d "fcgr C rushihgi whi,ch gave a sm all' percentage'' "■:'/ . ' o f f l a k y p a r t i c l e s 1and a r e la t iv e l y " la rg e; p e r c e n ta g e o f fin ed ® 1V ' ' ■•■.•<• ^h eM ggP egd te o b ta in e d -fr'dia- Ganybn'.ferry Dam' w a s' produced 'byV'' ' r iv e r /d r e d g in g 'a n d ' c o n se q u e n tly th e a g g r e g a te co n ta in ed w e l l .-Pbundddr p M t ie f e d V "The- a g g r e g a te r e c e iv e d # 0 W ell g ra d ed ’ i n th r e e g ra d ess !" 3 / M in® t o ; 3 /8 M e 3,;;-3/8; I n / W 13 A 1I n ^ and 3 /d M * t o I l / B SnVr ; E or m ech a n ica l g r a d a tio n O f-V g g reg a tes a s Usedi s e e T ab le I » / ’ ■ : ■■■ ■'T ^ p e-Il iCement' Was used, i n a l l ,mixes'^ ' 'Mo e p e c i f i d in fo rm a tio n i d a v a il a b l e on th e ch em ica l co m p o sitio n o f t h e Cementi b u t m ' sample: t e s t e d ' a t T ridents. M n ta n a y showed a l k a l i p r e s e n t in q u a n t it ie s g r e a te r th an p e r Cent® ' ' '■' P rO tex was Used a s a n ’ adm ixture in th e -airmen t r a in e d concrete;®: I t W a s added- at th e r a t e C f one -,ounce t o a s a c k 'o f cement'd A r , v ' ''-'.'V . -17' TABLE I SIEVE ANALYSIS B e lg r a d e A g g r e g a te Coarse A ggregate Sand S ie v e i If # 16 F lE T # ib o Pan R etain ed P ercen t Gum. P ercen t S ie v e R eta in ed P ercen t Cum. P ercen t R eta in ed R eta in ed R eta in ed Chrams Grams R eta in ed ISl1 2j l 651 2L2 " W 212$ 1 .8 7 .7 1 0 .9 2k .? LO.O 11. u 3 .5 1 0 0 .0 1 . 8* 9 .5 * " 2 0 . k* 8$ . l * 9 6 .3 * 1 0 0 .0 F.M. 2 .$ d 0 0 I" 111 "ITkfir 1/ 2" 1299 3/8" 2009 Ik o f2ld Pan *>36 0 0 2 .2 2 5 .8 3 9 .9 2 ? .9 k .2 1 0 0 .0 0* 0 2 . 2* 2 8 .0 6 7 .9 * 9 5 .8 * loo.O F.M. 6 .6 6 Canyon F e r r y A g g r e g a te Coarse A ggregate Sand S ie v e Z # # # ft ti 16 30 Pan * R etained P ercen t Cum. P ercen t R eta in ed P ercen t Cum. P ercen t S ie v e R eta in ed Grams R eta in ed R eta in ed R eta in ed Grams 30 31U 29k 338 117U 290 108 1 .2 1 2 .3 1 1 .5 1 3 .3 4 6 .1 1 1 .4 2548 1 0 0 .0 4.2 1 . 2* 13.5* I" 2 5 . 0* 3/4" 1/2" 38.3* 84.4* 95.8* 1O0.O F.M. 2.58 IT B r #4 Pan 490 1532 1282 1078 674 920 32 8 .2 2 5 .5 2 1 .3 OoOb 1 0 0 .0 8 . 2* 3 3 .7 55 .0 * 18.0 ?3.0 1 1 .2 1 5 .3 8 4 .2 * "TT" These v a lu e s were used in computing th e f in e n e s s modulus 99.5* loo.o F.M . 7.4 7 HtOOBDBRE, , Mixing;and Casting ‘,'iyj.'mjidittg and c a s t in g was perform ed i n accordan ce w it h AVSgSMU. ■''= .'' ' . L \ W ' '.' " , - ' ' D e s ig n a tio n G 1 9 2 -4 9 w it h th e f o llo w in g ex ce p tio n s? r "' (I) '' '' ' .'4' Ho a ttem p t was made t o com pensate f o r m ortar r e t a in e d in th e la b o r a to r y m ixer o ' However fl a s much r e t a in e d m ortar a s p o s s i b l e was - ' ' , scrap ed tgr hand in t o th e rem ainder o f the- t e s t mixo . ' ' ' >■ ■ ( 2 ) Specim ens f o r f r e e z in g and th aw in g t e s t s w ere e a s t i n ; 6 i n . y, by 6 i n . by 6 i n . c u b e s. T hese t e s t sp ecim en s were form ed by p la c in g : '■ the' • c o n c r e te i n th e m olds i n o n ly two la y e r s o f a p p ro x im a tely equalvolum e> and .rodding ea ch la y e r 25 t i m e s . ' \ - (3 ) A th r e e m inute m ixing tim e was u sed f o r p la in c o n c r e t e , w h ile a ir -e n t r a in e d c o n c r e te was mixed f i v e m in u te s. 'I n - 1 ■ each b a tc h , th r e e 6 i n . by 12 i n . com pression C y lin d e r s and tw o b ind' cu b es’ w ere e a s t . One com pression c y lin d e r was t e s t e d a t 7 days and two w ere t e s t e d a t 28 d a y s . The two 6 i n . cubes w ere c a s t t o u se i n ' f r e e z in g and thaw ing t e s t s . ■ - Throughput th e t e s t , th e m ix r a t i o was k ep t a s n e a r ly co n sta n t as p o s s ib le . Th# m ix r a t i o was l e f t a t I ; 2 § r 3 b y w e ig h t , P r o te x b ein g added a t th e r a t e o f ap p ro x im a tely One ounce t o a sa ck o f cem ent in th e a ir - e n t r a in e d c o n c r e t e . per sa ck . The w a ter ,.cem ent r a t i o was h e ld a t 6§ g a llo n s Ho a llo w a n c e was made f o r w a ter a b so r p tio n b y a g g r e g a te , - s in c e th e m i n o b j e c t iv e o f th e s e t e s t s was n o t t o c o r r e la t e th e w ater-cem en t r a t i o t o th e e f f e c t o f low t e m p e r a tu r e s .. The w ater^cem ent r a t i o was sim p ly h e ld a s c o n s ta n t 6 s p o s s ib le , so, t h a t th e s t o r a g e .tem p eratu res would' be the', o n ly v a r ia b le i n th e t e s t s . I n i t i a l F r e e z e r .P r o c e d u r e , ■.................................... , ;* ’ ■ f 1 ■ Jr ' /" - 1 ■ =' f Z 1' 11 ■ 1I1 ' r 1 ' ' ", ‘ 1 ' I ", •v."ii !'KvVvkV^Iia twb; 0 .$»*• cu b es ,frbmi ea b h 'batch ,were,’ plabed' # . t h e ' f r e e s # • , ■ - . - . . . . - . ' •c h e s t im m e d ia te ly , a f t e r ca stin g , and m ain tain ed , a t , a c o n s ta n t ,,temperature. '' L ^ 1fold,.6 .p eriod ,-o f Zk h o u rs. , ; .' T hese c o n s ta n t tem p eratu res - t o w h ich .ea ch s e t ' o f ,'two cu b es w ere ,s u b j e c t e d ranged from h$ ..to ■$ d eg ree s F° b y ab ou t 8 . / , . '. . ............... , d e g r e e s Fe i n t e r v a l s „, A f t e r . t h i s p e r io d , o f , 2k h o u rss th e ,specimens: Wbre' ' ■■ 1'. ' .’r emoved,from. t h e .f r e e z e r ' and aH ow ed to . s e t f o r . 2h h ou rs,..in,,the 'labora*'''''' t o i y b e fo r e s t r ip p in g . , A f t e r s t r ip p in g , t h e specim ens..w ere .placed ' in' . th e . m o ist c l o s e t t o cu re u n t i l a t o t a l , age 'of 28 days was a t t a in e d » . Quring ................ ...' . ' ’ . . . . . , . The com pression sp ecim en s were, s t r ip p e d .a t . an a g e o f one day and ■ : p la c e d i i i . th e ; m o ist, c l o s e t U n t il a t o t a l a g e o f 7 , days and 28 d ays was ; , i ’ • 'V ’ a t t a in e d » ,The cu ring, o f th e s i x in c h cu b es h a s.b een m entioned p r e v io u s-. • , • 1Iyoi ' 1 ' ' , .. , . , . . 1 Ii ■ , : ■T e s t in g ; ; # ,,Compression, ,Specimens " T e stin g , o f com p ression sp ecim en s,w a s perform ed i n accordan ce w ith A*S4«M9 S ta n d a rd s, ia lo P l a s t e r o f p a r t s was u sed a s a cap p in g m ater- , A c tu a l t e s t i n g w as.perform ed i n a:Baldw in-Southw ark Tate. Emery, U n ivers a l.,T e s t in g M achine o f SOQl5OQiQ pound c a p a c ity . • in g u sed .w as 1000 pounds p er square in c h p e r m in u te. The r a t e of. I o a d - ! ■ ' ' - 20- • F r e e z in g -arid Thamzig 'C y c le s . ’. - /T " ^ 'V; ‘ jV* iflie'.vgi^c in c h -ctib es w ere:rem oved-Jfcoia, th e •m eisii c l o s e t a t a t o t a l." '. • ' ' ' ' , They w ere p la c e d in a warmJ; d ry room, f o r Zh hours ' ■ " , .. ' ' ' a f t ^ f s h iO h 'th ey w ere w eigh ed t o th e n earest,;.IO- grams.' A f t e r 1w eighing^ ' '• ■: ■ ‘ %;.I'th l^ .'^ s r e .v iti^ r se d in-'d w a ter hath..fpr^ i,2%. hoursv.- iA ft e r ,this■!period'.'-of' \ • ', age.:;;Q£:'28' dayso . ■' tim e thc^r,w e r e ■moved i n t o th e fr e e z e r , c h e s t a t 5 t o 10 d e g r e e s Fy' f o r 2h;:hohrso. T h e r e a fte r n one c y c le c o n s is t e d o f Z k hours i n th e water-',hath ,: ■v1I ' . ; . , ' . ; ■ 1V-'. V-,:;.; .. i' ,and,.2%' h o u r.s,in th e ,fr e e z e r =., A t th e end o f ev ery f i v e c y c l e s , th e s p e c , ’■ 'v'1{ i i e n s were a llo w e d t o a i r dry f o r 2t ,h o u r s and were rew eig h ed a f t e r , . '‘ - ' -'- * \ w hich t h e f r e e z in g and thaw ing c y c l e s w ere, r e su m e d ,, The tim e-tem per-: ■ , ' ' ' ' , ; ]1 •' ; , V| a tu r e -,curve s .£ o r th e f r e e z in g and thaw ing O yoies a r e shown in F ig u re I V -. T hese c a r v e s w ere o b ta in ed by th e u se o f an ir o n - c o n s t a n t^ i therm ocouple c a s t i n th e c e n te r o f , a t e s t s i x in c h c u b e , -2 1 80 ^ / S p e c im e n T ea p era tu re A ir T em perature Tim e-H ours -Water Tem perature Specim en Tem perature F ig u r e I 0 F r e e z in g cu rv e (u p p e r ) and th aw in g cu rve (Io w e r ) f o r s i x in c h cu b es u n d erg o in g f r e e z i n g and th aw ing c y c l e s 0 -2 2 4 MJX DAm ’'-v i * ! - i 1: - * .- ■ ■ I A t ■t h i s tim e an e x p la n a tio n o f t h e code l e t t e r s i s n eed ed . .................................... , . , , f i r s t . . l e t t e r o f th e cod e d e n o te s t h e mix. d e s ig n . T he. • S in c e t h e m ix was h e ld ' c o n s ta n t th rou gh ou t th e t e a t , t h i s number i s t h e same f o r a i l sp ecim en s. V i ‘ ! ,1 ‘ . ' ' ' •( " 7',.. ' «* ■. 1 -I . ; » ‘ The secon d l e t t e r d e n o te s th e so u rce o f th e a g g reg a te (G f o r B elg ra d e, arid.F . f o r CianyOn F e r r y ) . The t h ir d l e t t e r d e n o te s th e b a tc h number. ■ - The l e t t e r llXirt i s u sed -whenever an a ir - e n t r a in in g a g en t i s u s e d . . T hus, %f b r exam p le, th e code 1G5X shows number Ohe- m ix , B elg ra d e a g g reg a te* ' b a tch number f i f e , and t h a t P r o te x was u s e d , . , , As m entioned p r e v io u s ly * one 7 -d ay and two 2 8 -d a y com pression specim ens were c a s t . R e s u lt s o f th e s e t e s t s a r e g iv e n i n T ab le J J . . Gonplete information on mixes i s summarised in ,Tables I I I and . 1?« Mo change in proportions of m aterials was.made in the mixes when,an air-entraining agent was added, iV w as deemed advisable to' keep th e same :watdr-cem ent r a t i o t o b e t t e r e v a lu a te Ahe e f f e c t , o f the' >, ■ ' • ! 'i ■ .”" : ■ , >l'’ a ir - e n t r a in in g a g e n t . However $ th e q u a n t i t ie s were in c r e a s e d o n eq u a rter t o p r o v id e s u f f i c i e n t c o n c r e te s o th e p erce n ta g e o f a i r m ight b e d eterm ined i d th e a i r d e te r m in a to r . c i’ ' ■ '' -'.,'As seen , - I, ' ■- : i n th e ta b u la te d v a lu e s i n T a b le s^I I I and I F ) some.’,wide". ■■ ,, . . ■■; , ... i ■ ■ differences in slump were encountered fo r mixes th&t were' supposedly . Cf th e same d e s ig n . F or example* mixes'1G2X and IShX had slum ps o f I 3 /k in,„ while mix iG3X had a slump o f 5 1 /k in . , Mot exact ,explanation of; th is i s available* but the differences in, Amount of surface moisture V Vv- ’X -2 3 TABLti I I CQIlflitiSSIVti STRtiWiTHS Water-Cement R a tio B elgrad e No A ir-E n train m en t 7-Day Average 28 V v K JL O S tr e n g th Day S tren g th p si p si fay W eight B elgrad e A ir-E n tra in ed A verage ZO /-D ay Code S tren g th Day S tren g th p si p si IG l 1625 2880 108x 1247 1978 102 1660 2843 1G9X 1254 1958 103 1943 3149 IGlX 1840 3054 IGlt 1604 2618 1G2X 1804 2984 ig 5 1664 2980 1G3X 1777 2975 106 2118 3152 ig 4 x 2094 3115 107 2100 3125 A v er. 1669 2677 A ver. 1816 2964 Water-Cement R a tio 0 .5 7 7 by W eight Canyon Ferrj r A ir-E n tra in ed Cany Qn F erry No A ir-E n train m en t 7-Day A verage 28 A verage 2d 7-Day U vQ O Code S tr e n g th Day S tren g th S tren g th Day S tren g th p si p si p si p si IF l 2478 3840 IFlX 2169 3483 IF2 2376 3691 1F2X 2077 3029 1F3 1872 3288 1F3X 1767 3165 if 4 2259 3423 1F4X 2078 3211 1F5 2085 3280 IF SX 1989 2854 A ver. 2214 3504 A ver. 2016 3148 TABLE I I I BELGRADE AGGREGATE M X DATA Code Coarse A ggregate Sand Cement lb s . lb s . Ib a . Water-CflSient R a tio 0 .5 7 7 b Y W eight Temperature Water P ro te x P er cen t A ir C oncrete Mix CO. lb s . 0 F. Slump In . I n itia l F r e ezer Temperature ® F. LGl 60 50 20 1 1 .5 5 — —— 7ii 3 /2 27 1G2 60 50 20 1 1 .5 5 — — 72 2 IA 23 1G3 60 50 20 1 1 .5 5 — — 72 I 36 lfiii 60 50 20 n .5 5 — — 70 3 12 IfiS 60 50 20 1 1 .5 5 — — 62 2 1 /li 1 9 .5 106 60 50 20 1 1 .5 5 — — 65 2 3 /ii iil 2fi7 60 50 20 n .5 5 — — 67 2 U5 IfiQx 7S 6 2 .5 25 l i i .i i 10 10 71 6 U5 Ifi9X 75 6 2 .5 25 lii.ii 10 10 70 6 3 9 .5 IGlX 75 6 2 .5 25 lii.ii 5 ii.3 72 ii 1 /2 32 IfiZX 75 6 2 .5 25 lii.ii 5 h .9 72 I 3 /ii 25 IfiSX 75 6 2 .5 25 lii.ii 5 ii.2 72 5 VU 16 IfiiiX 75 6 2 .5 25 lii.ii 5 5 .2 72 I 3 /ii 7 TABLE IV CANTON FERfiI AGGREGATE MIX DATA Water-Cement R a tio 0 .5 7 7 by W eight 3 /1 6 - 3 /h 3/8-3/U 3/U-l 1/2 Sand Cement Water lbs. Temp. P ercen t C oncrete P ro tex Mix Slump A ir CO. in . 0 F I n itia l F re ezer Temp. 6 F. lbs. lbs. lbs. lbs. lbs. IF l 30 30 — 50 20 1 1 .5 5 — — 71 I 3/U 3F2 30 30 — 50 20 1 1 .5 5 — — 6U I IU 1F3 10 20 30 50 20 1 1 .5 5 — — 70 3 1/U 21 IFU 10 20 30 50 20 1 1 .5 5 — — 65 U 1 /2 U3 3F5 10 20 30 50 20 1 1 .5 5 — — 68 3 3/U 32 IFlX 3 7 .5 3 7 .5 — 6 2 .5 25 1U.U 5 3 .8 68 U 1F2X 37.5 3 7 .5 — 6 2 .5 25 lU.U 5 U.2 6U 3 3/U IU 1F3X 1 2 .5 25 3 7 .5 6 2 .5 25 lU.U 5 3 .1 70 5 1 /2 21 IFl4X 1 2 .5 25 3 7 .5 6 2 .5 25 1U.U 5 3 .2 65 6 U3 1F5X 1 2 .5 25 3 7 .5 6 2 .5 25 1U.U 5 3.U 68 8 1/2 32 5 5 S z- A ggregate Code on th e a g g r e g a te could a cco u n t f o r t h e difference in Slunrp0 T h is p o s s ­ i b i l i t y i s m ade p la u s ib le by th e f a c t t h a t th e a g g r e g a te s a s u sed were f i e l d ru n 3 and th e s u r fa c e m o istu re c o n te n t co u ld be e x p e c te d t o vary from one m ix t o another=, ' ' .I t w i l l a l s o b e n o te d t h a t 10 c c 0 o f P ro te x was u sed in m ixes ' , ' ■!■■■. ' , : : 108x and 10 % w h ile $ :,qe» o f P fo te x was u s e d in a l l su c c e e d in g a i r - , . <' ' ; i .wv.' '' ' ' __ ' '' '' ' ' " ' e n tr a in e d m ixes o’ !Phis change was (deemed) a d v is a b le i n o rd er t o reduce : th e ..p e r c e n ta g e o f e n tr a in e d a i r t o th e u s u a l w orking lim it s * , , O on crete tem p era tu res a t t h e tim e o f c a s tin g ; a l s o v a r ie d w ith in ' ■ s , •■ i . ,, , ■ ; ■ l i m i t s a s c o n t r o lle d by room tem p era tu re= However^ s in c e th e maximum '- : . , ' ■ '■ - ,' 4 J I i i '' I p o u fih g tem perature was 7U ;Po and t h e minimum was 6 2 ° i t was th o u g h t t h a t no s e r io u s e r r o r would b e ,in tr o d u c e d by f a i l i n g t o c o n t r o l p ou rin g tem p era tu res. ' ■' • ’ $he o r i g i n a l p la n f o r t h i s i n v e s t ig a t i o n m s t o u se the. a c c e le r ­ a te d fr e e z in g -a n d 'th a w in g t e s t s . t o d eterm in e t h e d u r a b ilit y o f con crete, h"':-. ' ' ; a s -'a ffected by a i r tem perature d u rin g j u s t th e Si*. h ou rs a f t e r c a s t in g », .< A 25. per; c e n t l o s s i n w e ig h t o f th e -specim en was t o have: b een consider-? ; Mvas f a ilu r e o ■ . I t was-assumed by the. author that the freezing would ' T : ' '- ' : ' .. '' - " ' . -have c o n s id e r a b ly more e f f e c t on th e d u r a b ilit y ' th a n i t / h a s , . . Howeverg ,' a t th e d a te o f i/r r itin g , no I p s s i n w eighty has, been reco rd ed on axij , sp e c ‘: ' ‘ ’ V‘im en0; : f o r ..th is reason^ .-the.' o r ig in a l,.p la n w as p a r t i a l l y d isca rd ed d ■?- ,1 ' v-' . The p la n t h a t was.1c a r r ie d o u t w h i l e embodying .some f a c t o r s t h a t were d is a g r e e a b le s was. t h e b e s t co m p ro m ise;th a t.co u ld be d e v is e d , ',E S s e n tla lly j, i t c o n s is te d , of. w ithdraw ing .one. o f th e, two cu b es o f each - hatch from the freezin g and' thawing Cycles a t an approximate age of J4. . t o 5 m onths. ' ■> One specim en m s th e n t e s t e d t o f a i l u r e i n com pression w h ile th e o th e r co n tin u ed in th e f r e e z in g and thawing c y c l e s . The l o s s i h d u r a b ili t y a s o f A ugust* 1951s i s th e n t o be d eterm ined b y th e l o s s i n s tr e n g th o f th e c o n c r e t e , ■f r e e z in g and thaw ing c y c le s w i l l be con­ t in u e d on th e rem aining sp ecim en s t o p r o v id e l o s s in w eig h t d a ta a t a la t e r d a te, ' ' , V- , T h is method i s u s e f u l i n p r o v id in g some d a ta , on t h e d e tr im e n ta l e f f e c t o f exp osu re t o le w tem p era tu res o f c o n c r e te i n th e p l a s t i c s t a t e , A lth ou gii i t rem oves th e p o s s i b i l i t y o f c h e c k in g •r e s u l t s a s o n ly one specimen i s tested in each manner * certain trends ar e recognizable, ■ ■ ! , He P r ic e 5 "Symposium on F r e e z in g and Thawing T e s t s o f , Con, c r e te " * 'A ,S.T .M , P ro c eed in g s 5 IV I {19b6} 1211).= •~28- ■ The sp ecim en s Tfvithdrami f o r com p ression t e s t s w ere capped and t e s t e d i n th e same manner a s th e 6 i n . by 12 i n . cy lin d ers® As i t has been fou n d t h a t 6 in ? cubes e x h ib it s t r e n g t h s ,18 p e r c e n t h ig h e r than 6 in® by 12 i n . C y lin d e r s 3^ com pression, s t r e n g t h s Were c e r r e d te d t o . a g ree w ith th e stan d ard t e s t c y lin d e r ? , The s tr e n g th s and m is c e lla n e o u s , in fo r m a tio n a re l i s t e d in T ab le V. , ,..The specim ens, f r o z e n w h ile s t i l l i n a .p l a s t i c s t a t e show u&% , m ista k a b le marks o f f r o s t c r y s t a l s form ed :d u rin g th e i n i t i a l s to r a g e ■ ■ ■ . p e r io d e . (S e e F ig u r e s 2 and 3 ) The ,e x t e r n a l f r o s t c r y s t a l ,p a tte r n s ’ ' ' ' o ccu r p red o m in a tely on th e upper h a l f o f th e sp ecim en , th e.am ou n t o f - -1 f r e e w a ter a v a ila b le on th e s u r fa c e s o f t h e c o n c r e te presum ably c o n t r o l."I ' , '• , , . ,; 1 V : ' ' l i n g ’ th e s i z e o f th e p attern s® Th® in t e r n a l; s t r u c t u r e o f th e specim ens have somewhat th e same appearance® F r o s t p a t t e r n s were n o te d on^aggre­ g a te exposed, d u rin g t h e com pression, t e s t s a s w e l l a s on th e cement m ortar i n c o n t a c t w ith th e a g g reg a te ? I t is , n o ted th a t; f r o s t p a tte r n s a r e s l i g h t l y more predom inant i n th e m ix es w ith th e h ig h e s t slumps? , . F r e e z e r tem p era tu res t h a t w ere o n ly a fe w d e g r e e s b elow 3 2 ° F® a ls o seemed t o fa v o r la r g e c r y s t a l growth more th a n t h e lo w er tem p era tu res« ' , . • 1*3................ ' .................. I , ............. ...... 1..... ^ ^ ... - H a rriso n -F =. Qonnerman3 " E ffe c t o f , S iz e and Shape' o f T e st Spec­ imen on Qbmpression .S tre n g th o f G oricrete3" ’ P u b lic Workss Z.VJI (January 1926) 9 31? ,- ' .T ' \ “ ' ' 29 - ‘ TABLE V COMPRESSIVE STRENGTHS OF SIX INCH CUBES Code Age When T ested F r e e z in g and Thawing C y c le s When T ested mo. IG l 1G2 1G3 IOii 105 106 107 108x 1G9X IGlX 1G2X 1G3X IGiiX IF l IF 2 1F3 IFii 1F5 IFlX 1F2X 1F3X IFiiX 1F 5X 5 5 5 5 5 5 5 5 5 5 5 5 5 ii U ii ii ii ii ii ii ii ii 50 50 50 50 50 50 50 50 50 50 50 50 50 IiO UO IiO iiO IiO iiO iiO iiO IiO IiO O r ig in a l Weight W eight When T e ste d kg kg p si p si 8 .3 5 8 .2 9 8 .5 8 8 .3 1 8 .3 5 8.1i3 8 .3 8 7 .8 5 7 .7 6 8 .2 k 8.iiO 8 . Ik 8 .3 8 8 .5 9 8 .5 8 8 .5 9 8 .7 9 8 .5 7 8 .3 8 8 .2 6 S.iiii 8 .5 7 8.iiO S.iiii 8 .ii3 8 .7 1 8 .k 6 8 .ii6 S.iiii S.iiO 7 .8 8 7 .8 0 8 .2 9 8 .5 0 8 .2 3 ii050 iillO 3390 3600 U020 ii900 5130 3520 3k60 2920 31k5 2990 2930 3510 35UO 3750 5020 2360 35kO 3kOO 3620 iiSlO 2700 3li30 3ii80 2870 3050 3U00 U150 k3iiO 2980 2930 2ii70 2670 2530 2ii80 2970 3000 3180 ii260 2000 3000 2880 3070 U080 2290 8.51 8 .6 9 8 .5 9 8. 72 8 .8 6 8 .6 1 8 . Ul 8 .3 7 8 .5 7 8 .6 5 8.U 5 Com pressive S tren g th Com pressive S tren g th A d ju sted to 6 x 12 q y ls . -3 0 - F ig u r e 2 . E x te r n a l f r o s t c r y s t a l p a tte r n on s i x in c h cube s u b je c te d t o f r e e z in g tem perature w h ile s t i l l p l a s t i c . -3 1 - "32— • BtfERHlEBTION. OF RESULTS As a' consequence o f th e method Of t e s t f i n a l l y adopted* th e r e s u l t s cannot tie in t e r p r e t e d 1t o p r e d ic t e x a c t l y th e a c t io n o f f r e e z in g on f r e s h con crete= However* a s p r e v io u s ly m entioned*1'c e r ta in tren d s are' reddily d is c e r n ib le t b p r o v id e some knowledge o f fh e e f f e c t o f th e fr e e z in g = r ,F ig u res ks ;5s 6* and 7 show th e r e s u l t s o f th e com pression t e s t s o f th e cubes ( s e e T a b le V) i n g r a p h ic a l form p l o t t i n g a d ju sted , com p ressive s tr e n g th i n pounds p er square in c h a t $ months f o r B elgrade a g g r e g a te sp ecim en s and 'k months f o r Canyon F e r r y a g g r e g a te specim ens a s o r d in a te and i n i t i a l f r e e z e r tem p eratu re i n d e g r e e s F a h r e n h e it as' a b s c is s a » ' ' ' A ls o p lo t t e d ,o n f i g u r e s t th rou gh 7 i s th e e x p e c te d s tr e n g th o f t h e c o n c r e te a t a g e s o f $ months and k months ( f o r B elg ra d e a g g r e g a te sp ecim en s# and Ganyon:Ferzy a g g r e g a te specim ens*, r e s p e c t iv e ly = ) These v a lu e s correspon d t o th e s tr e n g th s o f c o n c r e te cured n o rm a lly f o r th e s e p e r io d s o f time= t h e s e . ages= B o1specim ens w ere C a st f o r com pression t e s t i n g a t However* an in t e r p o la t io n o f th e r e s u lt s * o f th e R eport o f th e D ir e c to r o f R esea rch o f t h e P=G=A= 1928 s u g g e s t s .v a lu e s o f 156 p er c e n t o f 28 day s tr e n g th f o r 5 month specim ens* and 1U8 p e r ,cen t fo r k month specimens'*.;^. The v a lu e s p lo t t e d on; th e cu rves a r e computed from t h e s e p e r c e n ta g e s a n d .th e a v era g e 28 day s tr e n g th o f s i x ‘in= by tw elv e in= c y lin d e r s = , , ............................. ........ . ......................................................................... ........................... . 13 , lit= Q=. W ithey and JameS A ston* J o h n so n 's M a te r ia ls o f Con­ s t r u c t io n * ( 8 t h Od=I New Xorks John W iley and Sons* 19^6)* H^ti-ROO= . -33- •H M Q. S month axpiected s tr e n g t h I U630 Ps i 5 S M -P LI UJ 0) W §• O O 3000 - 0) -P W d -a TJ To 0 p s i 2000 I n i t i a l F r e e z e r T em perature - D eg. F F ig u r e 2 . C om pression r e s u l t s on t e s t cu b es u s in g B e lg r a d e a g g r e g a te w ith no a i r - e n t r a i n i n g a g e n t ad u ed . -H K i ct i -C 5 month e x p o r te d s t r e n g t h I^lBO p s i S g a> -5 CO W <D O i P S •ri TJ C •* # 2000 I n i t i a l F r e e z e r Tem perature - D eg. F F ig u r e 3» C om pression r e s u l t s on t e s t c u b e s u s in g B e lg r a d e a g g r e g a te w ith an a i r - e n t r a i n i n g a g e n t ad ded. A d ju ste d C om pressive S tr e n g th - p s i o r e n g tn k m oith - $190 p | i - — -- To 0 p s i A d ju ste d C om p ressive S tr e n g th - p s i £ I n i t i a l F r e e z e r T em perature - D eg. F ure k . C om pression r e s u l t s on t e s t cu b es u s in g Canyon F e r r y a g g r e g a te w ith no a i r - e n t r a i n i n g a g e n t ad ded. tr e n g th U mopth - I167 O pjsi To Q p s i I n i t i a l F r e e z e r Tem perature - D eg. F F ig u r e $ . C om pression r e s u l t s on t e s t c u b e s u s in g Canyon F e r r y a g g r e g a te ■ w it h an a i r - e n t r a i n i n g a g e n t ad d ed . From t h e s e C urvesjl i t i s se e n t h a t th e com p ressive s t r e n g t h o f th e 6 i n o cubes i s sm a lle r in a l l c a s e s th a n t h a t o f n o rm a lly cured c o n c r e te w it h v a lu e s o f 5 t o 50 p er c e n t l e s s . The n e x t problem t h a t a r i s e s i s how much o f th e d e tr im e n ta l e f f e c t can b e a t t r ib u t e d t o t h e i n i t i a l s to r a g e tem p era tu re, and how much t o th e su b seq u en t f r e e z in g and th aw in g c y c l e s 0 The problem i s by no means a sim p le one a s many f a c t o r s can in f lu e n c e th e r e s u l t . i t can be a tta c h e d i n t h i s m anner. However, I t i s g e n e r a lly a g reed b y m ost au­ t h o r i t i e s t h a t c o n c r e te poured a t 5 0 ° F„ or h ig h er s u f f e r s n o i l l e f f e c t ' due t o tem perature p r o v id in g i t i s g iv e n su b seq u en t good c u r in g . The h i g h e s t ^ i n i t i a l s t o r a g e tem perature g iv e n c o n c r e te sp ecim en s i n t h i s stu d y was i*5° F= S in c e t h i s ii.5° F . tem p eratu re i s n o t f a r d i f f e r e n t from t h e s u g g e ste d 5 0 ° Fe minimum, i t Can p rob ab ly be s a f e l y ,assumed t h a t any c o n c r e te g iv e n an i n i t i a l s to r a g e o f 2k hours a t ^,,Vand' su b se q u e n tly g iv e n 27 days, o f m o is t c u r in g a t 70° F 9 w i l l n o t be a f f e c t ­ ed by th e i n i t i a l s to r a g e tem p era tu re? T h is assum ption i s fu r th e r str e n g th e n e d by th e f a c t t h a t th e f r e s h l y poured c o n c r e te h a s a tempera­ tu r e o f a p p ro x im a tely 7 9 ° F 9 and a c o n s id e r a b le p e r io d o f tim e la p s e s b e fo r e t h e c o n c r e te r e a c h e s 1*5° F , , J f t h i s assum ption h o ld s t r u e , i t f o llo w s t h a t th e d e tr im e n ta l e f f e c t o f th e com pleted f r e e z in g and thaw ing c y c le s o n ly on th e s p e c i­ men s to r e d a t h5° F , Can be approxim ated b y -measuring th e d if f e r e n c e i n s tr e n g th s o f th e 6 i n , cube com pression specim en i n i t i a l l y s to r e d a t k$° Fe, and t h e s t r e n g t h o f n o rm a lly Cured c o n c r e te o f th e Same S g e 9 The p r o p o r tio n o f t h e d e tr im e n ta l e f f e c t t o b e a t t r ib u t e d t o - t h e i n i t i a l , s to r a g e .tem perature'.and t o . t h e su bseq u en t freezin g 'a n d " tW tv in g ' p y c le s i s . -somewhat more C om plicated f o r t h e specim ens s u b je c te d t o frees-#in g i tem p eratu res w h ile' s t i l l p la s tic = - . f o r t h i s p u rp o se # ' s i x 6 i n , cubes ' ' I ’ • r ' . , ‘ ■" t ’ i " w ere c a s t and p la c e d i n tiie f r e e z e r a t W* F= im m ed iately a f t e r c a s t in g f o r a p e r io d o f 2k hours= Thqy were su b se q u e n tly g iv e n 7 d a y s o f cu rin g in ' th e m o ist c l o s e t and th e n t e s t e d td f a i l u r e i n co m p ressio n =■ The sp ec? !mens w ere made from ’ B elg ra d e a g g r e g a te w ith o u t a ir -e n tr a in m e n t u sin g t h e same p r o p o r tio n s a s i n o th e r mixes= Fr1Om t h e s e s tr e n g th s end th e S tr e n g th s o f norm ally. Chred c o n c r e te g t h e l o s s i n s t r e n g t h due t o th e i n i t i a l s to r a g e teKp'erature’' can b e determ ined= The a v e r a g e 7 day co m p ressiv e s t r e n g t h o f the" s i x 6 in=' cubes i n i t i a l l y , s u b je c te d t o 8 ° Fi= was l 6 l 5 p si= The s tr e n g th c o r r e c te d t o norm al 6 in= by 12 in= c y lin d e r s i s 1370 p si= A g a in / r e f e r r in g t o a p r e v io u s report^^^ a ;? day specim en has. a s tr e n g th o f $9 p e r 'c e n t o f a 28 day s p e c im e n / w h ile a f iv e ' month specim en e x h ib it s a s t r e n g t h o f 1^6 p e r c e n t o f a 28 day, specim en= T h e r e f o r e / p r o j e c t in g th e 7 day s tr e n g th to a comparable fiv e 'm o n th 'S tr e n g th ,■t h e 6 in= cu b es would show a S tr e n g th o f 3620 p s i a t f i v e months = By p l o t t i n g t h i s v a lu e on. F ig u r e 2 and co n n ectin g i t t o th e p o in t o f no l o s s i n s tr e n g th due t o i n i t i a l S to ra g e tem p eratu re ( s p e c i­ men a t k$° F =) s t h e p r o p o r tio n o f th e d e tr im e n ta l e f f e c t t o be a t t r ib u t e d t o th e i n i t i a l s to r a g e tem p eratu re and th e su b seq u en t f r e e z in g and thaw­ in g c yKrc -l e s can b-e. / , y determ ined r;;-T f o r ea ch i n i t i a l sV'tol'' "dnr r a g e tem p''"Tera tu re, r , ti..iL " J 1F " v i; ' -r \ '' 'V l r - T -J r rm .-, "i/i,. ^ I b id = ' ' • ' , *“ -■Tffy-- t - v r “ -3 7 l^ hus5.-the o r d in a te above: t h is , l i n e and below th e, e x p e c te d S-- ,■ m onth.s tr e n g t h .r e p r e s e n ts t h e 'l o s s i n s t r e n g t h due t o t h e i n i t i a l storage'^ w h ile t h e o r d in a te b elo w t h i s l i n e and above, t h e , p lo t t e d v a lu e s rep re~ , ; SehtS- th e l o s s in s t r e n g t h ,d u e 'to th e 30 fr e e z in g , and thaw ing <^rcleso T h ese v a lu e s a r e a l l on th e b a s is o f S m o n th ? to ta l a g e . sp ecim en s '' B y - com putation from t h e a b o v e, t h e f r o z e n sample's w ould e x h ib it Z1 ap p roxim ately 79 p e r \c e n t o f th e; str e n g th , o f n o rm a lly cu red ; c o n c r e te o f ■ t h e 'Same age*. . , ,■■ ■ . - ■■ •,,, ' -The' p r o p o r tio n o f th e d e tr im e n ta l e f f e c t t o be a t t r ib u t e d t o th e i n i t i a l . s to r a g e temperature o f 8° F<> f o r t h e specim ens ■made w ith B elgrad e \ a g g r e g a te w ith a ir -^ it r a in m e n t j and Oanyon F e r r y a g g r e g a te w ith , and -with­ o u t a ir -e n tr a in m e n t w i l l b e . tak en a s the. sa m e,a s above= W h ile ,,th is 79 per c e n t v a lu e w i l l n o doubt b e approxim ate f o r th ese, sp e c im e n s, i t sh o u ld b e s u f f i c i e n t l y c l o s e t o e n a b le s a t is f a c t o r y c o n c lu s io n s t o be. drawn=, T h e r e fo r e , F ig u r e s ,3, Us and,3 are com pleted u s in g t h i s p e r c e n t­ a g e V a lu e0i . ... . , T t i s i n t e r e s t i n g t o note from Figures 2. through 5. t h a t , in ; e v e r y c a s e , sp ecim en s ex p o sed t o an i n i t i a l , ,sto ra g e tem perature o f about 3 2 ° F ° e x h ib it e d lo w er s t r e n g t h s th a n th ose: exposed, t o any. o th e r tem perature= N • l h i l e an e x a c t e x p la n a tio n i s n o t read ily a v a i l a b l e , several ,co n d itio n s e x is t t h a t c o u ld ca u se th e extreme- r e d u c tio n a t - th is, .tem perature=,, The fo rm a tio n o f i c e , c r y s t a l s on. th e i n t e r i o r s u r f a c e s o f th e aggregate, and t h e m ortar i n c o n ta c t w ith th e. a g g reg a te, c o u ld m a t e r ia lly red u ce th e bond betw een th e m ortar and t h e ,a g g r e g a t e , e n d # i n ,so d o in g , f h e s tr e n g th WQuld be .reduced* W h ile , t h is - a p p l i e s ?t©s a l l -specim ens - s u b je c te d t o . .• f r e e z in g tem peratureSg the. c o n d itio n s ,o f tenperature., c lo s e .,t o . 3 2 ° Pe V . , .fa v o r s th e ,growth o f ■l a r g e ■c r y s t a l s and ,w ould.A ggravate, th e, .red u ctio n s , in . b o n d ., A [Second .e x p la n a tio n ,could be t h a t - s h e e t i n g , sp ecim en s to. , , tem p eratu res c f o s e .f o =3 2 ° F® .would ^a llo w t h e ,con crete t o g a in i t s i n i t i a l s e t b e f o r e i t , w a s f u l l y fr o z e n .. T h is a cc o r d in g t o A®, .'41co n d itio n - t h a t s e r io u s ly ,r e d u c e s.,th e s t r e n g t h , , 15lG unaberg5 Sp0 C itb 5 p , 207= - G u n sb erg ^ 5 i s , . i ■,l \ / c o m u s io M s ...... ' ■' « S e v e r a l c o n c lu s io n s o m tie ' d r a w from ' th e .'fo reg o in g r e s u l t s »; iHan tie- tiwtiiartatid, a s " f e l l o w s - * '• ' . (! * ' ( I ) P i f i y 'f r e e z in g and' tihavrajig c y c l e s 1red u ce t h e ''com preasive stirengtihs j 'to 28 p er c e n t o f ' th e strength.' 'of ■norm al u n fro zen O eticrete0 ■ " ( 2 ) In g e n e r a l^ th e fr e e z in g , and thaw ing c y c le s .c a u s e d approx* 1 . I i ; , ■ - ■ !\ i I Im a tely th e .same n e t l o s s i n s tr e n g th ' r e g a r d le s s ' ©f t h e ' i n i t i a l s to r a g e ' temperattire t o which' the sp ecim en s w ere ,, , S U tijected 0 ' ■ '- ‘ ' ( 3 ) A f t e r t h e f r e e z in g and thaw ing c y c l e s w ere d isc o n tin u e d # th e sp ecim en s s u b je c te d t o i n i t i a l s to r a g e tem p era tu res o f a p p ro x im a tely 5 ° Fo i1 e x h ib it e d s t r e n g t h s o f 75 p o r c e n t o f th e •s tr e n g th s o f th e specim ens e x ­ p o sed t o A5° Fb i n i t i a l s to r a g e '^ ’ ( 4 ) S u b je c tin g th e sp ecim en s t o tin i n i t i a l s to r a g e tem perature , ' ' . . i ; o f a p p ro x im a tely 3 2 ° F= i s t h e w o rst c o n d it io n t h a t can o c c u r 0 From t h e above c o n c lu s io n s # i t can be seen t h a t c o n c r e te p la c e d i n th e f i e l d a t a i r tem p eratu res som ew hat'below 3 2 ° Fo can tie ex p ected t o a t t a i n a t l e a s t 70 p er c e n t Of th e str e n g th ' o f n orm ally cured conpreteo The c o n c r e te s o exp osed can tie ex p ecte d t o r e s i s t f r o s t a c t io n q u ite w e l l a s f i f t y c y c l e s o f th e a c c e le r a t e d f r e e z in g and' thawing t e s t s ' corresp on d s r o u g h ly t o : te n y e a r s o f s e r v ic e i n th e f i e l d f ■ S in c e e x a c t information i s n o t a v a i l a b l e s'‘c o n c r e t e :placem ent : ■sh o u ld tie suspended when "the a ir tem p eratu re approxim ates 3 2 i io u s damage may tie-- done t o t h e f r e s h c o n c r e te »■ F o1 a s s e r ■ • •\ ■ .The above c p n e lu s io n s can be c o r r e la t e d w ith th e p r e v io u s work o u t lin e d i n t h e e a r ly p a r t o f t h i s t h e s is * i f th e v a r y in g c o n d itio n s , under w hich th e 'p r e v io u s work was com pleted i s k ep t in m ind. Inasmuch, a s a s iz e a b l e f a c t o r o f s a f e t y i s in v o lv e d i n th e, d e s ig n o f a c o n cre te s tr u c tu r e * i t i d p o s s i b l e t h a t th e c o n c r e te could, s u f f e r a 21 per, c e n t lo s s , i n s tr e n g t h and s t i l l r e t a i n a h ig h enough u ltim a te s t r e s s t o rem ain c o m p le te ly W ith in th e s a f e w orking r a n g e . T h is co u ld b e th e s i t u a t io n w ith ithe r e p o r t s made by A , BU Guntberg and ,Ho Go W atts c i t e d p r e v io u s Iyo The e x p e r ie n c e c i t e d by Eo A= Hagy i s a s l i g h t l y d i f f e r e n t cond­ i t i o n * s in c e he o b v io u s ly d is tu r b e d th e p l a s t i c c o n c r e te an making ,new te s t, c y lin d e r s , Ho Ho S c o f i e l d r e p o r te d t h a t c o n c r e te f r o z e n im m ed iately a f t e r c a s t in g a t t a i n s on t h e a v era g e o f ab o u t f>0 p er c e n t o f th e s tr e n g th o f th e norm al u n fro zen c o n c r e te a t th e same age:,; The v a lu e o f ^O'p er­ c e n t l o s s i n s tr e n g th corresponds, t o th e maximum v a lu e o f 21 p er c e n t l o s s fou n d i n t h i s s tu d y . However* a 29 p e r c e n t d iv e r g e n c e i s p o s s ib le depending on th e r e l a t i v e s e v e r e n e s s o f th e t e s t s 0 ' I , A more a c c u r a te and com p lete c o r r e la t io n o f r e s u l t s m ight be drawn i f d e t a il e d d e s c r ip t io n s o f each t e s t were, .a v a ila b le 0 S in c e none a r e a v a ila b le * an approxim ate c o r r e la tio n * su ch as, t h e one above* i s a l l t h a t can be drawn,o "r-ijlj!*. SUGGESTIONS FOR,FtETHER.STUBY The au th or w ould l i k e , t o ta k e t h is , o p p o rtu n ity t o s u g g e s t p o s s J I b le o th e r p h a s e s ,o f stu d y ,in th e same T ie ld 0 . ■ ■ , The p e c u lia r a c t io n ,o f concrete when exp osed t o tem p eratu res o f approximately 3 2 ° Fo ,in d i c a t e s f u r t h e r s t u d y . i s ,needed t o p r e d ic t the. ■, c o n c r e te s tr e n g th and d u r a b ilit y exposed t o tem p eratu res in t h is , rangev . , A s t u d y ,o f th e a c t io n , of. c o n c r e te exp osed t o c o ld tem p eratu res . ‘ 1 i I 1 ' I - !■ I, I V , ' 1 , . ’ ’ a f t e r t h e c o n c r e te h a d .a t t a in e d i t s , i n i t i a l o r f i n a l s e t w ould be valu­ able i n com p letin g d ata, p u t fo r t h , by t h is , stu d y and th e, above m entioned Snggestpd Study0. , t APjRSIEJiX A C o n sid e r a tio n s In v o lv e d i n t h e Making o f F r e e z in g ,. and Thawing T e s t s on C oncrete The numerous a lt e r n a t io n s ©f f r e e z in g and thaw ing (O ften 2$ t o W -• y . . . . ' . p er annum) i n th e c lim a te o f th e tem perate zo n es cau se d e t e r io r a t io n in a l l p orou s ro ck and masonry s t r u c t u r e s 0 C oncrete i s p a r t i c u l a r l y su scep ­ t i b l e t o t h e w ea th erin g in f lu e n c e s o f n a tu re when su b je c te d t o sev ere e x , • ■ posure® ■ . The a c c e le r a t e d f r e e z in g and thaw ing t e s t grew b u t o f th e d e s ir e t o know th e r e l a t i v e d u r a b ilit y o f concrete® I n t h i s t e s t , t h e o b j e c t iv e h as been t o s e c u r e ^ i n a r e l a t i v e l y s h o r t le n g t h o f t im e , an in d e x o f th e le n g th o f s e r v ic e w hich may be e x p e c te d when s u b je c te d t o a g iv e n ty p e o f exposure® Of t h e a c c e le r a t e d t e s t s th u s f a r t r i e d , th e f r e e z in g and thaw­ in g t e s t , w hich ap p roach es c o n d itio n s i n n a tu r e , has been t h e m ost s a t i s * factory® S in c e t h e v a lu e o f th e in d e x o f d u r a b ilit y determ ined from th e d a ta from a. fr e e s in g -a n d -th a w in g t e s t i s dependent upon th e c o r r e la t io n . / w h id i e x i s t s betw een t h a t in d e x and th e a c t io n o f n a tu r e , t h e t e s t sh o u ld b e s o d e v is e d t h a t i t w i l l correspon d i n i t s a c t io n t o t h a t o f nature® ^ The o n ly im p ortan t d iv e r g e n c e sh o u ld be t h a t th e t e s t s e t s up a more r a p id r a t e o f d is in t e g r a t i o n i n t e s t sp ecim en s w ith o u t m o d ify in g th e pro­ c e s s o f d is in t e g r a t i o n accom p lish ed much more s lo w ly by nature® I t seems ap p aren t from s t u d ie s made t h a t th e d e t e r io r a t in g i n f l u ­ en ce o f f r e e z in g and thaw ing i s in t im a t e ly r e la t e d to* ( I ) t h e perme­ a b i l i t y o f th e c o n c r e te 5 ( 2 ) th e d eg ree t o w hich th e c o n c r e te i s s a tu r a te d w ith f r e e z a b le w a ter j and ( 3 ) th e amount Of' f r e e z a b le w a ter i n th e e o n - ere tep I n tu r n 5 th e s e f a c t o r s w i l l b e m a t e r ia lly in flu e n c e d by th e w a te r - Cempnt r a tio , of. ,th e . p a s t e , t h e , c h a r a c te r e f .th e a g g r e g a te s th e c o n s is te n c y Cf th e c o n c r e te , th e c u rin g c o n d it io n s , and th e p ro p o rtio n o f e n tra in ed a i r i n the' s e t 'cen crete* ' » T e s t d a ta in d ic a t e s t h a t th e r a t e o f d is in t e g r a t io n o f c o n cre te in c r e a s e s w ith th e r a t e t h a t th e tem p eratu re f a l l s d u rin g fr e e z in g = S in c e t h e f a l l o f atm osp h eric tem p eratu re i n th e v i c i n i t y o f 3 2 ° F= r a r e ly ex­ ce e d 3 9 F= p e r hour* i t d o es n o t appear d e s ir a b le t o lo w er th e tem perature a t to o f a s t a ra te= .U n til more d e te r m in a tiv e d a ta a re o b ta in ed * a l i m i t Of 1 0 ° F.» p e r hour i s su ggested = The th r e e ty p e s o f f r e e z in g and thaw ing t e s t s commonly u sed are: 1= - F r e e z in g immersed i n w a ter and thaw ing submerged in water= 2 o F r e e z in g p a r t ly immersed i n w a ter and thaw ing p a r t ly or w h o lly immersed i n water= 3= F r e e z in g in a i r a f t e r s a t u r a t in g i n w a ter and thaw ing su b- merged’ in water= I n .e a c h o f t h e s e t y p e s o f t e s t th e r e have b een a g r e a t many v a r i f th e tem p era tu re,O f t h e 1 specim en when p la c e d i n th e f r e e z e r ,, th e ■ a b le Sg r a t e o f f r e e z i n g , t h e minimum tem perature a t t a in e d , th e tem perature o f th e w a ter u sed i n th aw in g,, a n d ■t h e 'r a t e o f thawing= h ow ever, th e procedure o f ty p e 3 gave t h e m ost u n iform in d ic a t io n , o f q u a lit y o f t h e co n cretes. 16 : ■' ’ ■ 1■ - te s te d = . ---------- ~ B — ---------v V 1:....T " M= 0= W ithey, "C o n sid e r a tio n s I n v o lv e d in th e f a k in g o f F reez= in g -a n d -lh a w in g T e s t s on Concrete=** A=S=TsM= Proceedings;, JtLfI (1 9 it6 ), 1198-1207= ’ ‘ ' ' '' • - gpetiiroens' W w e d i d w a ter and f r o s e a in w ater e r e a f f e c t e d much "- m ere by. f r e e z in g a l t e r n a t i o n s »■ The d if f e r e n c e i s ‘thought' t o l i e 'i n t h e f a c t t h a t im m ersion f o r c e s more w a ter i n t o th e sp ecim en s becau se' o f th e ‘s l i g h t h y d r o s ta t ic head" t o w h ich t h e y a r e su b jected ,, ' V a rio u s schem es f o r r a t in g t h e e f f e c t Of f r e e z in g and thawing" have b een employed^ in c lu d in g v i s u a l in s p e c t io n s ■change' i n co m p ressiv e Strength* d e c r e a se i n modulus Of e l a s t i c i t y a s d eterm in ed 'by s t a t i c lo a d in g * change i n modulus Of e l M s t io it y b y t h e SOhic method* l o s s i n w e ig h t* 1and; change i n I e n g th 0 -: " . . ^ ' ‘ ’ ' ' 1 \ I ^ B a ile y Tremper*' "Symposuim o n ,F reeain glan d lT h aw iag T e s ts o f co n crete" * 'AoSoTftMo.' feoC eed in gs.y XLVI (191*6)* 1227-1229<, ( APEBaDK B' i Mechanism o f D is in te g r a tio n : A s :commonly u n d ersto o d and h e r e u sed 3 f r o s t :a c t io n i s t h e break­ down, ©f th e . s t r u c t u r e o f c o n c r e te Caused by! a lt e r n a t e f r e e z i n g , arid thaw in go She p r e se n c e o f m o istu re i n t h e pore's o f t h e C oncrete i s n e c e s s a r y f o r f r o s t a c t io n t o .o c c u r and t h e m oistu re,m ay e n te r e i t h e r by c a p illa r y a c t io n o r p r e ssu r e ,, „ The .d e te r io r a t io n u s u a lly m a n if e s t s ' i t s e l f , by s c a lin g and r a v e llin g , b u t i t may o ccu r w ith o u t d o in g ,e it h e r o '■ 1 * :I h e n c o n c r e te sp ecim en s a re f r o s e n and,.thawed (=,»«». »)» two. d is-6* t i n e t ty p e s o f d is in t e g r a t i o n have b een observed? ( I ) The specim ens ■ may show l i t t l e change i n w e ig h t and appearance b u t la r g e l o s s e s i n S tr e n g th and r e s i l i e n c e 3 o r ( 2) th e y may show p r o g r e s s iv e l o s s 'by crum bling and s p a l l i n g b u t r e l a t i v e l y l i t t l e , l o s s i n s tr e n g th , And, r e s i l i e n c e o f th e rem ain in g m a te r ia l = T hese are extrem es= Specimens f a i l i n g i n n e it h e r c a te g o r y w i l l show crum bling and l o s s o f str e n g th and r e s i l i e n c e o f th e rem ainin g, m a t e r ia l. 10 : , A lte r n a t e f r e e z in g And thaw ing o f c o n c r e te i s a c o n tr ib u to r y r a t h e r th a n a fundamental ca u se f o r i t s d e t e r io r a t io n c The f a c t t h a t th e tem p eratu re Of c o n c r e te d ro p s.b elo w 3 2 ° Po. h a s no S ig n if ic a n c e in i t s e l f g f o r d ry c o n c r e te may be f r o z e n and" thawed r e p e a t e d ly w ith n e g l i g i b l e damage» There must be w a ter in th e p o r e s b e fo r e harm can r e s u l t from f r e e z in g and i t must b e p r e s e n t in such an amount t h a t when i t in c r e a s e s in , volume a s i t changes S t a t e 5 t h e i c e formed w i l l more than f i l l t h e p o r e s c o n ta in in g i t 5 and s o vri.il d e v e lo p d is r u p , t i r e fo r c e s ■, ; , .. T h is much o f th e f r o s t a c t io n ,on c o n c r e te i s g e n e r a lly a cce p te d by. a l i o : Dowever5 th e problem .of. t h e e x a c t a c t io n o f , th e f r e e z in g w a ter w i t h # th e co n crete, i s s t i l l s u b j e c t t o , some ,c o n tr o v e r s y 0 . Two d if f e r e n t v ie w s o f th e problem w i l l b e ,p r e s e n te d here= A ,,R,...C o llin s, rep o rts? , ' ^ T = G=" PowerSy "A EorKing H y p o th e sis f o r P u r fh e r i S tu d ie s AC F r o s t R e s is ta n c e , o f C o n c r e te ,” .Am erican ConorOte .I n s t it u t e J o u rn a ls .XLI' (Feb». ’ i ?k $ } s 250-251. ' -l^Ro B o Young," " F r o st1R e s is t a n t C on cretes” Am erican C oncrete I n s t i t u t e J o u r n a l, ,XXKPI ( A p r il 1 9 h p ), h77°°h90o.. . From, t h e e v id e n c e a v a il a b l e . i t a p p e a r s , t h a t f r o s t damage., in ccO-* ,, cre te, and .o th er .porous m a te r ia ls , i s . due t o the. s e g r e g a tio n , o f i c e i n t o .la y e r s y r a t h e r , th an .:to th e, sim ple, ex p a n sio n o f .th e fro a en . m t e r . i n th e p o r e s 0 The mechanism: i s , in . f a c t s . .s im ila r t o th a t , o ccu rrin g iIn .,s o i l s , d u rin g f r o s t ..h e a v in g «,2P . % .O o llin s b ased .h is. c o n c lu s io n s , on an a p p lic a t io n o f T ab errS- th eo ry t o th e f r o s t r e s is t a n c e o f c o n c r e te 0 O o l lin s 8 e x p la n a tio n i s a s f o llo w s : C o o lin g begins, a t t h e exp osed s u r fa c e and ex ten d s s lo w ly inwards 0 When'any la y e r b elow t h e s u r fa c e r e a c h e s a s u f f i c i e n t l y low. tem pera.t o r e 3 t h e w a ter i n t h e l a r g e s t p o r e s b e g in s t o f r e e z e and th e l a t e n t , h e a t g iv e n up by i t te n d s t o m a in ta in c o n s ta n t tem perature a t th e p o in t p f i c e fo r m a tio n 0 The i c e . c r y s t a l s s o formed a r e i n c o n ta c t w ith u n fro zen w a ter i n t h e surroundingj> s m a lle r p o r e s g and# b y draw­ in g w a ter from, them# t h e c r y s t a l s eo n tih u e t o grow= , , , The f o r c e e x e r te d by i c e w i l l b e p erp en d icu lar' t o t h e c o ld su r­ f a c e ! npd i f t h e c o n c r e te i s Of lo w .str e n g th # a p la n e o f w eakness p a r a l l e l t o t h e c o ld s u r fa c e w i l l ten d t o form a t t h e l e v e l a t which , th e i c e i s form in g 0 _ , The w a ter drawn i n b y th e grow ing c r y s t a l s o f i c e w i l l , come f i r s t from th e l a r g e s t u n fro zen 'p o resa As t h e s e become em ptied# th e su p p ly ■w i l l be. r e s t r i c t e d and th e r a t e o f g ro w th -o f th e i c e w i l l , be checked^ The e v o lu t io n o f l a t e n t h e a t w i l l n o t th e n be; s u f f i c i e n t t o m ain tain th e tem p eratu re c o n s ta n t a t th e p o in t o f .ice**form ation and th e temper­ a tu r e w i l l b e g in t o f a l l once moreo As th e r e i s th en l i t t l e o r no w a ter i n th e l a r g e s t pores: in th e c o n c r e te im m ed ia tely b elo w th e f i r s t ic e , layer#., f r e e z in g w i l l n ot. . b e g in a g a in u n t i l e i t h e r th e tem p eratu re has dropped s u f f i c i e n t l y t o f r e e z e t h e p o r e s t h a t do c o n ta in w ater o r a l e v e l i s rea ch ed where th e la r g e r p o r e s a re n o t a f f e c t e d by t h e i c e form ing, ab ove them . The r e s u l t o f t h i s p r o c e s s i s t h a t c o n c r e te w i l l c o n ta in a., s e r i e s o f p la n e s o f w eakness p a r a l l e l t o t h e s u r fa c e o f cooling,o' During th e su b seq u en t c y c l e s o f f r e e z in g th e i c e w i l l ,a g a i n te n d t o form a t th e game l e v e l s As b efo re# b eca u se th e p o r e s th e r e have b een d iste n d e d by th e p r e v io u s ic e # ,a n d t h e f r e e z in g p o i n t ,o f t h e . w a ter i n them w i l l be h ig h e r th a n i n th e surrounding c o n c r e te 0 1 . ' • > ; - .V ^ ‘ ■- The damage t o t h e c o n c r e te i s c o n s id e r e d .to be c a u s e d ,n o t so much b y t h e a c t u a l in c r e a s e i n , volume o f t h e w a ter In "the p o r e s on f r e e z in g , '' ' '. . . . . ' H , '1 : ' ...... " ''' ' J ' ' ' y ' , I.';.’ I N " u - r r ' ' M , ■■ I- - . Ao Rq, G o l lin s # “D e s tr u c tio n o f G bncrete by F r o s t# ” American C oncrete ,I n s t it u t e J o u r n a l^ XLI (dune 191*1?)# 726-72%. ■ <7a s b y th e -grovrbh o f th e c r y s t a l s a fte r w a r d s and th e con seq u en t se g r e ­ g a tio n and c o n c e n tr a tio n ' o f i c e in t o ' th e l a y e r s . ' ' ' ■. , '' One b a s ic d isa g reem en t ap p ears in' th e d is c u s s io n o f t h e aforemen­ t io n e d h y p o th e sis* , 1, * • * ; . 1 E x p erim en ta l d a ta by M attim ore p u b lish e d i n th e P ro «' , , I . , I I • i i i j I • ‘ « i « 1 , I -> •> - i * - « 1 , e e e d in g s d f th e Highway R esea rch Boards 1936s shows t h a t in la b o r a to r y t e s t s th e low er th e r a t e o f f r e e z in g t h e s m a lle r th e d e s t r u c t iv e e f f e c t , ' whereas' th e O o llir is h y p o th e s is r e q u ir e d t h e 'o p p o s it e r e s u l t * 22 ■■■ ■ - Iri o ffe r in g - some o b j e c t io n s t o t h e Q o llin s h y p o th e sis^ Powers h as advanced h i s own th e o r y f o r t h e a c t io n o f f r e e a ia g w a ter in ' co n crete* e s s e n c e , h i s e x p la n a tio n o f th e a c t io n i s g iv e n a s f o llo w s ? in C onsider a ; s u r fa c e o f a specim en t h a t h a s been Sn c o n ta c t w ith w a ter f o r some tim e 'p r io r t o th e b e g in n in g o f th e f r e e z in g c y c l e * The w a ter c o n te n t o f th e ■ c o n c r e te n e a r t h e s u r fa c e i s p rob ab ly a t o r n ea r t o t a l 1s a t u r a t io n , and i s h ig h er* though perhaps o n ly s l i g h t l y * th an th e a v erage w a ter co n ten t o f t h e specimen*^; I f 1th e c o n c r e te i s th e n ex p o sed t o a' tem p eratu re ‘low er -•th an 3 2 ° F » 5 t h i s sh o u ld b e t h e seq u en ce o f e v e n ts * F i r s t s t h e w ater on ■' th e 'su rfa ce f r e e z e s , th u s s e a lin g t h e s u r fa c e o f th e c o n c r e t e | seco n d , th e w a t e r 'in th e c a p il la r y sp a c e s o f t h e c o n c r e te n e a r e s t th e s u r fa c e w i l l .f r e e z e 1and a s th e change i n s t a t e t a k e s p la c e * th e s t i l l u n fro zen w ater in th e. s a tu r a te d r e g io n w i l l b e d is p la c e d tow ards th e l e s s s a tu r a te d in t e r i o r . I f t h e vw a te r w ere f r e e t o move w ith o u t r e s i s t a n c e , n © 'h yd rau lic p r e s s u r e w a tev er would d evelop * However, s in c e th e w a ter i s r e q u ir e d t o "'Vi'1":-""T"' ? i' _ P ow ers, o p . c i t * , p» 2 6 6 . ' -O , move' th r o u g h ,a f I n e ^ te x tu r e d 5 porou s su b sta n ee5. t h e f o r c e c a u s in g 't h e ' ' movement m i l ,g iv e r i s e t o a Oorresponding f r i c t i o n a l r e s i s t a n c e ’ and grad-^ ' 1 ‘ "i e n t s o f h y d r a u lic p r e ssu r e w i l l be present during, th e movement o f "the , _ . w a te r accord in g, t o th e la w s o f h y d r a u lic flow* I f t h i s r e a c tio n - a g a in s t ■ t h e f o r c e ’d is p la c in g , th e w a ter i s s u f f i c i e n t l y h igh * th en i t can be r e ­ garded a s b e in g ca p a b le o f damaging th e specimen, ■ . On r e p e a te d f r e e z in g , and. thawing* .th e ■sa tu r a te d - r e g io n n ea r th e. s u r fa c e sh o u ld in c r e a s e in th ic k n e s s .a c c o r d in g , t o th e amount o f w ater ab sorb ed by t h e s p e c i m e n As th e th ic k n e s s o f t h i s r e g io n in c r e a s e s * th e 'r e s is t a n c e t o >,d isp la cem e n t -of' water o u t o f t h a t 1r e g io n tow ards - th e r e g io n o f low er water c o n te n t w i l l 1--increase-*- and when th e s a tu r a te d - r e g io n -be'cOmeb s u f f i c i e n t l y t h i c k the h y d r a u lic p r e s s u r e w i l l become -g rea ter th a n t h e s tr e n g th o f . th e -m a teria l and ca u se d is in t e g r a t io n - or s p a l l i n g 0, - ■ ,• Powers g iv e s a method f o r e s t im a t in g th e p o s s ib le h y d r a u lic d i s ­ r u p tiv e fo rce* , b u t i t w i l l n o t b e d is c u s s e d h ere 6 ', However* he s t a t e s th a t" th e h y d r a u lic p r e ssu r e w i l l 'depend on t h e p e r m e a b ility o f th e m ater­ i a l th rou gh w hich w a ter m ust f lo w t o e sc a p e from th e s a tu r a te d reg io n * '' V , and th e r a t e o f I r e e z in g 023 , ■I t m ust be s t r e s s e d t h a t n e it h e r o f th e above m entioned hypothe­ s i s a r e g e n e r a lly a c c e p te d . M eith er h a s i t been meant t o i n f e r ’th a t th e s e a r e th e o n ly h y p o th e s is on th e a c t io n o f f r e a s in g w ater in c o n c r e te » -Howeyer5 th e s e t w o . sam ples sh ou ld se r v e t o g iv e, -th e r e a d e r some knowledge o f th e th eo rie s,, in v o lv e d and th e problem s en co u n tered . 23 z b id . 2 2 1 - 2 # . ’ LITERATURE GlTBD A S) CONSULTED B atciieM eP 9, W= Ho '1928 EnglneerAhg■ » Bateman9 John Ho , 195U M a ter ia Ie o f C o ttstrn etio n a Pitm an P u b lish in g C orp oration # T oron tb i .■ B aner9 Edward Ao New-Iorko 1949 P la in ,C oncretb 9 M cGraw-Hill Book Company, 'Zndo9 ■-r C o l l i n s 9 A# :Ro 1945 American C oncrete I n s t i t u t e J o u r n a lo Gonnerffibh9 H a rriso n Fo G hhsberg9- A i Mo 1931 Hagy9. E». a :» .. 1942 Pow ers,; Tc Co P r i c e , We Ho 1926 . P u b lic Works,. ' . E n g in eer in g Hews0 Am erican C oncrete I n s t i t u t e J o u rn a l. 1945 1946 American, C on crete I n s t i t u t e J o u r n a ls A.. 8 . 1 . M. P r o c e e d in g so SCOfi b i d , He Ho 1937 Tremper9 B a ile y 1946 ■A»SoToM.. P r o c e e d in g s* , ' ' ' Watts,-, Ho1. Go C o n crete. ' 1942 1 t American C oncrete M s t i t u t e J o u rn a l. W ith ey9 Mo O= and A sto n 9 James 1946 J o h n so n 's M a te r ia ls o f C o n strn ctio n 9 : John W il^ r 'and S on s9 New I p r k . ' ■ W ith er, ’I . Oft 1946 AoB.,TJL P r o c e e d in g s. Io n n g 9 Ho Be 1940 American C oncrete I n s t i t u t e J o u rn a l. Ib n h g 9 Be Bi, 1942 American Concrete I n s t it u t e Journal. 103328 IiAJly MONTANA STATE UNIVERSITY LIBRARIES Iiiiiiiiiiaiiiiiiii 3 I 7 6 2 100 5 5 9 8 3 author S v e n so n . daW Y lQ lfflJ L 1MSj ae of s NAME ;flL I I P~tf, /T A : ocT at be*» L ____ L .,: iV ^ 'H 5 7 S c o p . Z. ? ' U C T JV 103328 y U . 8 .A .